CN207877919U - Sodium carbonate removal device in a kind of alkaline zinc plating liquid - Google Patents

Sodium carbonate removal device in a kind of alkaline zinc plating liquid Download PDF

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Publication number
CN207877919U
CN207877919U CN201820048877.1U CN201820048877U CN207877919U CN 207877919 U CN207877919 U CN 207877919U CN 201820048877 U CN201820048877 U CN 201820048877U CN 207877919 U CN207877919 U CN 207877919U
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sodium carbonate
crystallization tank
zinc plating
cooling
alkaline zinc
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CN201820048877.1U
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Chinese (zh)
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曾小勇
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Taicang Su Xin Machinery Equipment Co Ltd
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Taicang Su Xin Machinery Equipment Co Ltd
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Abstract

The utility model proposes sodium carbonate removal devices in a kind of alkaline zinc plating liquid, including pallet, the pallet is equipped with crystallization tank, cooling-water machine, and the cooling-water machine is connected to the crystallization tank, the crystallization tank lower part is communicated with dewaterer, and the dewaterer lower part is communicated with holding tank;Rabbling mechanism and heat exchange pipe dish are equipped in the crystallization tank, the heat exchange pipe dish is connected to the cooling-water machine, the present apparatus is reasonable for structure, sodium carbonate in alkaline zinc plating liquid is become into Sorbet shape crystalline solid by crystallisation by cooling, then crystalline solid and liquid medicine itself are detached by centrifugal dehydrator, liquid medicine is flowed back by accumulator tank in electroplating bath, form an On The Cycle Working Process, ensure the quality of liquid medicine in electroplating bath, simultaneously, the present apparatus reduces relevant operating personnel, to reduce human cost input, equipment is simple, it is easy to operate, treatment effeciency is high, effect is good, and, the synchronization job of production and liquid medicine processing can be achieved, substantially increase treatment effeciency, improve economic benefit.

Description

Sodium carbonate removal device in a kind of alkaline zinc plating liquid
Technical field
The utility model is related to sodium carbonate removal devices in field of chemical equipment more particularly to alkaline zinc plating liquid.
Background technology
Contain caustic soda (being generated in electroplating process) inside electroplate liquid, generation oxidation is contacted instead with air on electroplate liquid surface Sodium carbonate should be will produce.With the lasting progress of plating, the carbonate content inside electroplating liquid medicine can be continuously improved, and work as sodium carbonate Concentration be more than admissible range, electroplating velocity can be caused slack-off, influence electroplating effect.
Alkaline zinc plating liquid will produce the accumulation of sodium carbonate after producing and using 1 year, general to require to be no more than 60g/L, when containing Electroplating liquid medicine internal resistance increases when amount is more than 80g/L, temperature rises quickening, plating upper density limit reduces, and the electric conductivity of electroplate liquid is deteriorated.Work Skill requires current density range to be actually only raised to 1.3A/dm2 or so for 1~4A/dm2, when current density is slightly higher, just has Corner is burnt while electroplating liquid medicine heating is too fast, and dispersibility and covering power are deteriorated, and electroplating liquid medicine is pale brown without limpid, coating The phenomenon that brittleness becomes larger.Electroplating efficiency reduces, electroplating time increases, and waste of resource increases cost.
Traditional processing includes following several method:
1) winter nights freeze method of cleaning:Bath solution is extracted into storage outdoors slot, carries out one night of naturally frozen by winter Evening, the next morning cleaning storage trench bottom sodium carbonate.The method needs continuous freezing at least 3 times, but cannot fully erased carbon Sour sodium.Disadvantage:It is cooled down using environment temperature, season limitation is big, and southern temperature height is not met by requirement, needs to prepare one Electroplate liquid is pumped through with trough big as plating sump volume and is transferred back again to handle, volume accounts for greatly hall space, processing speed Slowly, it and needs to stop production, low production efficiency, utilization rate of equipment and installations declines, and the production cost increases.
2) artificial ice cube freezes method of cleaning:Suitable stainless steel metal bucket is taken, ice cube is filled, is put into solution, static one section Time, solution can crystallize precipitation on ice bucket outer wall afterwards to the cold, and such continuous processing is multiple, you can carbonate content is reduced, It but cannot fully erased sodium carbonate.Disadvantage:Using the indirect cooling electroplate liquid in ice cube part, heat exchange efficiency is low, complicated for operation, processing Speed is very slow.The method is also required to stop production, low production efficiency, and utilization rate of equipment and installations declines, and the production cost increases.
3) white lime or quick lime method of cleaning.Disadvantage:The filter plant for needing to invest a set of large size, to the operation water of worker It is flat to require height, there is the risk for scrapping whole slot electroplate liquid, also needs to taking electroplate liquid into the carbonic acid for clearing up trench bottom again away after having handled Calcium, quantities are huge.Equipment also needs to stop production, and cost increases.
4) solution cleaning part depreciation-retirement method:When cleaning and maintenance, a part of bottom solution is scrapped, a part of new soln weight is added New slot allocation.Disadvantage:Electroplate liquid, equipment, which need to be scrapped, need to stop production processing, and cost is very high.
Utility model content
In order to solve the above technical problems, the utility model proposes sodium carbonate removal device in a kind of alkaline zinc plating liquid, packet Pallet is included, the pallet is equipped with crystallization tank, cooling-water machine, and the cooling-water machine is connected to the crystallization tank, the crystallization tank lower part It is communicated with dewaterer, the dewaterer lower part is communicated with holding tank;Rabbling mechanism and heat exchange pipe dish, institute are equipped in the crystallization tank Heat exchange pipe dish is stated to be connected to the cooling-water machine.
Preferably, it is connected to by motor-driven valve between the crystallization tank and the dewaterer.
Preferably, the heat exchanger tube disc-annular shape is set to the crystallization tank inner wall.
Preferably, the rabbling mechanism includes stirring motor, and the stirring motor output end is connected with paddle.
Preferably, the crystallization tank outer wall is equipped with insulating layer.
The utility model proposes alkaline zinc plating liquid in sodium carbonate removal device have following advantageous effect:Present apparatus structure is closed Reason, becomes Sorbet shape crystalline solid by crystallisation by cooling by sodium carbonate in alkaline zinc plating liquid, then will be crystallized by centrifugal dehydrator Body and liquid medicine itself detach, and liquid medicine is flowed back by accumulator tank in electroplating bath, form an On The Cycle Working Process, ensure electroplating bath The quality of interior liquid medicine, meanwhile, the present apparatus reduces relevant operating personnel, and to reduce human cost input, equipment is simple, Easy to operate, treatment effeciency is high, and effect is good, and, it can be achieved that the synchronization job that production and liquid medicine are handled, substantially increases processing Efficiency improves economic benefit.
Description of the drawings
It is required in being described below to embodiment in order to illustrate more clearly of the technical scheme in the embodiment of the utility model Attached drawing to be used is briefly described.
Fig. 1 is the positive structure schematic of the utility model;
Fig. 2 is the side structure schematic diagram of the utility model;
Wherein, 1, pallet;2, crystallization tank;3, cooling-water machine;4, dewaterer;5, holding tank;6, motor-driven valve;7, exchange heat pipe dish; 8, stirring motor;9, paddle;10, insulating layer.
Specific implementation mode
The following will be combined with the drawings in the embodiments of the present invention, carries out the technical scheme in the embodiment of the utility model Clearly and completely describe.
As shown in Figure 1 and Figure 2, the utility model proposes sodium carbonate removal devices in a kind of alkaline zinc plating liquid, including pallet 1, the pallet 1 is equipped with crystallization tank 2, cooling-water machine 3, and the cooling-water machine 3 is connected to the crystallization tank 2,2 lower part of the crystallization tank It is communicated with dewaterer 4,4 lower part of the dewaterer is communicated with holding tank 5;Rabbling mechanism and heat exchanger tube are equipped in the crystallization tank 2 Disk 7, the heat exchange pipe dish 7 are connected to the cooling-water machine 3.
When the utility model is used, crystallization tank 2 is connected by catheter with electroplating bath, the meeting after plating in electroplating bath It generates the largely mixed solution containing sodium carbonate, holding tank 5 by liquid back pipe to be connected with electroplating bath, be located in electroplating bath Alkaline zinc plating liquid enters crystallization tank 2 by catheter, and crystallization tank 2 passes through the mutual cooperation between frozen water machine and the wheel of paddle 9, ice Ice water in water dispenser enters in heat exchange pipe dish 7, reduces the temperature in crystallization tank 2, the sodium carbonate in alkaline zinc plating liquid is made to become ice Sand-like crystalline solid, mixture of ice and water are entered to by motor-driven valve 6 in the dewaterer 4 of lower part, and dewaterer 4 is by crystalline solid and liquid medicine sheet Status is from liquid medicine enters accumulator tank, and the liquid medicine in accumulator tank is reflowable in electroplating bath, and this completes a processing to follow Ring, after the completion, the alkaline zinc plating liquid in electroplating bath enter back into crystallization tank 2, handle back and forth, by the alkaline zinc plating in electroplating bath Concentration of sodium carbonate control ensures the quality of product processing within 60g/L in liquid.
The present apparatus is reasonable for structure, sodium carbonate in alkaline zinc plating liquid is become Sorbet shape crystalline solid by crystallisation by cooling, then Crystalline solid and liquid medicine itself are detached by centrifugal dehydrator 4, liquid medicine is flowed back by accumulator tank in electroplating bath, is formed one and is followed The ring course of work ensures the quality of liquid medicine in electroplating bath, meanwhile, the present apparatus reduces relevant operating personnel, to reduce Human cost is put into, and equipment is simple, easy to operate, and treatment effeciency is high, and effect is good, and, it can be achieved that production and liquid medicine were handled Synchronization job substantially increases treatment effeciency, improves economic benefit.
The present apparatus is applicable not only to the removal of sodium carbonate in the carbonate liquid in alkaline zinc plating liquid, is also suitable zinc-nickel alloy liquid Etc. the removal of sodium carbonate in other electroplate liquids.
In use, in order to ensure that the stability of crystallization tank 2, and lowering temperature uniform, 7 annular of heat exchange pipe dish are set to institute 2 inner wall of crystallization tank is stated, the rabbling mechanism includes stirring motor 8, and 8 output end of the stirring motor is connected with paddle 9, passes through Paddle 9 stirs, and it is uniform to ensure that fluid temperature declines, ensures that crystallization effect is good, and is equipped with heat preservation in 2 outer wall of the crystallization tank Layer 10, prevents 2 temperature rise of crystallization tank.
A variety of modifications of embodiment will be apparent to those skilled in the art, determine herein The General Principle of justice can be realized in other embodiments without departing from the spirit or scope of the present utility model.Cause This, the utility model is not intended to be limited to the embodiments shown herein, and is to fit to and principles disclosed herein The widest range consistent with features of novelty.

Claims (5)

1. sodium carbonate removal device in a kind of alkaline zinc plating liquid, which is characterized in that including pallet, the pallet is equipped with crystallization Slot, cooling-water machine, the cooling-water machine are connected to the crystallization tank, and the crystallization tank lower part is communicated with dewaterer, under the dewaterer Portion is communicated with holding tank;Rabbling mechanism and heat exchange pipe dish are equipped in the crystallization tank, the heat exchange pipe dish connects with the cooling-water machine It is logical.
2. sodium carbonate removal device in alkaline zinc plating liquid according to claim 1, which is characterized in that the crystallization tank and institute It states and is connected to by motor-driven valve between dewaterer.
3. sodium carbonate removal device in alkaline zinc plating liquid according to claim 1, which is characterized in that the heat exchanger tube disk ring Shape is set to the crystallization tank inner wall.
4. sodium carbonate removal device in alkaline zinc plating liquid according to claim 1, which is characterized in that the rabbling mechanism packet Stirring motor is included, the stirring motor output end is connected with paddle.
5. sodium carbonate removal device in alkaline zinc plating liquid according to claim 1, which is characterized in that the crystallization tank outer wall Equipped with insulating layer.
CN201820048877.1U 2018-01-12 2018-01-12 Sodium carbonate removal device in a kind of alkaline zinc plating liquid Active CN207877919U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201820048877.1U CN207877919U (en) 2018-01-12 2018-01-12 Sodium carbonate removal device in a kind of alkaline zinc plating liquid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201820048877.1U CN207877919U (en) 2018-01-12 2018-01-12 Sodium carbonate removal device in a kind of alkaline zinc plating liquid

Publications (1)

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CN207877919U true CN207877919U (en) 2018-09-18

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109537036A (en) * 2019-01-05 2019-03-29 上海裕继金属制品有限公司 A kind of auxiliary system of electroplating technology

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109537036A (en) * 2019-01-05 2019-03-29 上海裕继金属制品有限公司 A kind of auxiliary system of electroplating technology
CN109537036B (en) * 2019-01-05 2020-10-20 上海裕继金属制品有限公司 Auxiliary system of electroplating process

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