CN207764116U - Multi-parameter water quality detector - Google Patents

Multi-parameter water quality detector Download PDF

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Publication number
CN207764116U
CN207764116U CN201721574530.2U CN201721574530U CN207764116U CN 207764116 U CN207764116 U CN 207764116U CN 201721574530 U CN201721574530 U CN 201721574530U CN 207764116 U CN207764116 U CN 207764116U
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China
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port
valve
magnetic valve
solenoid valve
way magnetic
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CN201721574530.2U
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Chinese (zh)
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荣明军
王石亮
苏立新
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Jiangsu Blue Creative Intelligent Polytron Technologies Inc
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Jiangsu Blue Creative Intelligent Polytron Technologies Inc
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Abstract

The utility model discloses a kind of multi-parameter water quality detector.The multi-parameter water quality detector includes:Peristaltic pump;Multiple digestion instruments;Multiple first electromagnetic switch valves corresponding with the multiple digestion instrument and multiple second electromagnetic switch valves respectively;First three-way magnetic valve, the second three-way magnetic valve and third three-way magnetic valve;Multiple first communicating pipes;First various way solenoid valve, the second various way solenoid valve and third various way solenoid valve;Quantitative endless tube;Second communicating pipe;Photoelectric sensor;Third connecting pipe;4th connection;5th communicating pipe;Programmable controller is electrical connected with the first three-way magnetic valve, the second three-way magnetic valve, third three-way magnetic valve, peristaltic pump, the first various way solenoid valve, the second various way solenoid valve, third various way solenoid valve, photoelectric sensor, digestion instrument, the first electromagnetic switch valve and the second electromagnetic switch valve.In this way, the multi-parameter water quality detector in the utility model uses multiple digestion instruments, what can be synchronized is detected the multiple parameters to water sample.

Description

Multi-parameter water quality detector
【Technical field】
The utility model is related to field of water quality detection, more particularly to multi-parameter water quality detector.
【Background technology】
For water quality detection it is generally necessary to detect many kinds of parameters, as in water COD, BOD, ammonia nitrogen, total phosphorus, total nitrogen, temperature, The general characteristics parameter such as pH value, conductivity, dissolved oxygen and turbidity.It refers to one that COD, which defines COD (COD or CODcr), Under conditions of determining strictly, the reducing substances in water consume oxygen under the action of the strong oxidizer added outside when by oxygenolysis The quantity of agent indicates that COD reflects the degree polluted by reducing substances in water with the mg/L of oxygen.BOD (Biochemical Oxygen Demand's writes a Chinese character in simplified form):Biochemical oxygen demand (BOD) or bod (COD on the five) indicate The comprehensive instruction of one of the aerobic pollutions matter content such as Organic substance in water.Illustrate biochemical action of the Organic substance in water due to microorganism Oxygenolysis is carried out, the total quantity of consumed oxygen in water when being allowed to inorganization or aerifying.Ammonia nitrogen refers in water with free Nitrogen existing for ammonia (NH3) and ammonium ion (NH4+) form.The nitrogen content of animality organic matter is generally compared with vegetalitas organic matter It is high.It is being measured after orthophosphates as a result, phosphorous with every liter of water sample that total phosphorus is that the phosphorus of various forms is transformed by water sample after resolution Milligram number metering.PH value indicates the numerical value of aqueous solution acidity or degree of alkalinity.Conductivity is tensor, in water quality detection, be with The ability of the solution conduction electric current of digital representation.The partial pressure of oxygen, the temperature of water have close in the content and air of oxygen in water Cut relationship, oxygen in water number be an index for weighing water body self-purification ability.Turbidity refer in water suspended matter to light Through when the obstruction degree that is occurred.
The detection of the parameters such as COD, BOD, ammonia nitrogen, total phosphorus, total nitrogen can be detected by spectrophotometer, object Matter molecule under different conditions, absorbs or situations such as the wavelength of emission spectrum, intensity, polarization state and the structure of the substance is special Sign has intrinsic relationship.The molecular structure of different material is different, corresponds to different Absorption and emission spectras;Same substance It is different in the same absorption intensity for absorbing peak position when concentration difference.Therefore, by a certain substance in detection water to specific wavelength The degree of absorption of light, you can determine the concentration of the substance in water.
In the prior art, it needs, by carrying out pre-treatment after corresponding reagent is added dropwise, to need at this time accurate in water quality detection Quantitative metering water quality sample and reagent, so as to obtain more accurate testing result.In addition, a kind of current water quality Detector can only detect a kind of characteristic parameter of water sample, in this way in order to detect multiple characteristic parameters of water quality, need with more water Quality detection instrument.
【Utility model content】
One of the purpose of this utility model is to provide a kind of multi-parameter water quality detector, can be to multiple ginsengs of water sample Number is detected, and integrated level is high.
Purpose according to the present utility model, the utility model provide a kind of multi-parameter water quality detector comprising:It wriggles Pump;Multiple digestion instruments;Multiple first electromagnetic switch valves corresponding with the multiple digestion instrument and multiple second electromagnetism respectively Switch valve, wherein one end of the first electromagnetic switch valve is connected to the upper port of corresponding digestion instrument, the second electromagnetic switch valve One end is connected to the lower port of corresponding digestion instrument, and when not being triggered driving, the first electromagnetic switch valve and the second electromagnetism are opened It closes valve to be closed, when being triggered driving, the first electromagnetic switch valve and the second electromagnetic switch valve are closed;First three-way magnetic valve, Two three-way magnetic valves and third three-way magnetic valve, each three-way magnetic valve include public port, normally closed port and normally opened port, Be not triggered driving when, the normally closed port is closed, the normally opened port open, and the public port connects with the normally opened port Logical, when being triggered driving, the normally closed port open, the normally opened port is closed, the public port and the normal-closed end Mouth connection;Multiple first communicating pipes;First various way solenoid valve, the second various way solenoid valve and third various way solenoid valve are each mostly logical Solenoid valve includes a public port and multiple seperated ports, can be controlled by public port and the multiple seperated end The seperated port of a connection in mouthful, the first various way solenoid valve includes the seperated port of resolution, air fission port and multiple appearances Device fission port, wherein the container fission port of the first various way solenoid valve passes through corresponding first communicating pipe and corresponding appearance respectively Fluid connection in device;Quantitative endless tube, first end are connected to the public port of the first various way solenoid valve, second end and second The normally closed port of three-way magnetic valve is connected to;Second communicating pipe, first end are connected to the public port of the second three-way magnetic valve, Second end is connected to the public port of the first three-way magnetic valve, and the part of the second communicating pipe is placed in the peristaltic pump and by institute State peristaltic pump driving;Photoelectric sensor, the second communicating pipe being placed between the peristaltic pump and the second three-way magnetic valve On;Third connecting pipe, first end are connected to the normally closed port of the first three-way magnetic valve, second end and the second various way solenoid valve Public port is connected to, and the seperated port of the second various way solenoid valve is connected with the other end of corresponding first electromagnetic switch valve respectively; 4th communicating pipe, first end port connection seperated with the resolution of the first various way solenoid valve, second end and third threeway electromagnetism The normally closed port of valve is connected;5th communicating pipe, first end are connected to the normally opened port of third three-way magnetic valve, second end with The public port of third various way solenoid valve is connected to, the seperated port of third various way solenoid valve respectively with corresponding second electromagnetic switch The other end of valve is connected;Programmable controller, with the first three-way magnetic valve, the second three-way magnetic valve, third three-way magnetic valve, Peristaltic pump, the first various way solenoid valve, the second various way solenoid valve, third various way solenoid valve, photoelectric sensor, digestion instrument, first Electromagnetic switch valve and the second electromagnetic switch valve are electrical connected.
Compared with prior art, the multi-parameter water quality detector in the utility model uses multiple digestion instruments, can be with Synchronous is detected the multiple parameters to water sample.
【Description of the drawings】
It will be better understood in conjunction with refer to the attached drawing and next detailed description, the utility model, wherein same attached drawing The corresponding same structure member of label, wherein:
Fig. 1 is the structural schematic diagram of the quantitative measuring device in the first embodiment of the utility model;
Fig. 2 is the structural schematic diagram of the water quality testing meter in the second embodiment of the utility model;
Fig. 3 is the flow chart of the application method of the water quality testing meter in the second embodiment of the utility model;
Fig. 4 is the structural schematic diagram of the water quality testing meter in the 3rd embodiment of the utility model;
Fig. 5 is the structure diagram of the check system of the water quality testing meter in the fourth embodiment of the utility model;
Fig. 6 is the flow chart of the method for calibration of the water quality testing meter in the fourth embodiment of the utility model.
【Specific implementation mode】
To keep the above objects, features, and advantages of the utility model more obvious and easy to understand, below in conjunction with the accompanying drawings and have Body embodiment is described in further detail the utility model.
Quantitative measuring device
In the first embodiment, the utility model provides a kind of quantitative measuring device of water quality testing meter.As shown in Figure 1 , for the structural schematic diagram of the quantitative measuring device 100 in the first embodiment of the utility model.
The quantitative measuring device 100 includes peristaltic pump P1, the first three-way magnetic valve V1, multiple first communicating pipes L1, the Two three-way magnetic valve V2, various way solenoid valve D1, quantitative endless tube LC, the second communicating pipe L2, photoelectric sensor G1 and PLC technology Device.
The peristaltic pump P1 can be along first direction (such as counterclockwise) rotation, also can be along opposite with first direction the Two directions (such as clockwise) rotation.Each three-way magnetic valve includes public port COM, normally closed port NC and normally opened port NO. When three-way magnetic valve V1 and V2 are not triggered driving, the normally closed port NC is closed, and the normally opened port NO is opened, the public affairs Port COM is connected to the normally opened port NC altogether.When three-way magnetic valve V1 and V2 are triggered driving, the normally closed port NC It opens, the normally opened port NO is closed, and the public port COM is connected to the normally closed port NC.
The various way solenoid valve D1 includes a public port C and multiple seperated ports (1,2,3 ..., 9, A), energy It is enough controlled public port is connected to one in the multiple seperated port (1,2,3 ..., 9, A), the seperated end Mouth includes resolution fission port A and multiple containers fission port (2,3 ..., 9), wherein container fission port 2,3 ..., 9 pass through corresponding first communicating pipe L1 and the fluid connection in corresponding container respectively.In Fig. 1, illustrate come it is much a Container, including one container of standard specimen, two container of standard specimen, three container of standard specimen, actual water sample container, performance water sample container, dilution hold Device, reagent A container, reagent B containers, their ports seperated with container 2,3 ... respectively, 9 connections.
The first end of the quantitative endless tube LC is connected to the public port C of various way solenoid valve D1, second end and the two or three The normally closed port NC of three-way electromagnetic valve V2 is connected to.The length of the quantitative endless tube is predetermined length value, such as 400mm, 250mm, by It is definite value in length, the cross-sectional area of quantitative endless tube LC internal channels is known definite value again, therefore the capacity of quantitative endless tube LC is just It is known predetermined volumes.
The first end of second communicating pipe L2 is connected to the public port of the second three-way magnetic valve V2, second end and the one or three The public port COM connections of three-way electromagnetic valve V1, the part of the second communicating pipe L2 is placed in the peristaltic pump P1 and by described compacted Dynamic pump P1 drivings.Photoelectric sensor G1 is placed on the second communicating pipe between the peristaltic pump P1 and the second three-way magnetic valve V2 On L2.Programmable controller and the second three-way magnetic valve V2, the first three-way magnetic valve V1, peristaltic pump P1, photoelectric sensor G1 electricity Property be connected.
The quantitative extraction for the liquid in target container that the quantitative measuring device 100 can be selected arbitrarily and fixed Measure sample introduction.
When carrying out quantitative extraction, the programmable controller control the various way solenoid valve D1 public port and one Container fission port (2,3 ..., 9) is connected to, and the liquid in the container fission port (2,3 ..., 9) and target container passes through the A connecting pipe L1 connections, can select a target container (such as actual water sample container) in this way, and triggering driving the two or three is powered Magnet valve V2 drives the peristaltic pump P1 to be rotated in a first direction, with the rotation of the peristaltic pump P1, port seperated with the container Liquid in the target container (such as actual water sample container) being connected is driven by the public of the various way solenoid valve D1 Port C enters the quantitative endless tube LC, has in the second communicating pipe L2 that the photoelectric sensor G1 detects corresponding position Feedback signal is provided when liquid to the programmable controller.The programmable controller is receiving the photoelectric sensor G1's The peristaltic pump P1 is controlled after feedback signal be rotated further by the predetermined time (such as 3s, 4s etc.) stop afterwards.Stop in the peristaltic pump P1 After only, the programmable controller no longer triggers the second three-way magnetic valve V2 of driving, then controls the peristaltic pump P1 along with the The opposite second direction rotation in one direction, passes through the normally open end of the second three-way magnetic valve V2 by the liquid in the second communicating pipe L2 Mouth NC discharges, the liquid quantified in endless tube LC described at this time is exactly to be carried from selected target container (such as actual water sample container) The liquid for the predetermined volumes got.In a specific embodiment, if necessary to the actual water sample in extraction actual water sample container When, it is necessary to the ports 5 seperated with a container public port C for controlling the various way solenoid valve D1 are connected to.
When carrying out quantitative sample injection after quantitative extraction, the programmable controller controls the public affairs of the various way solenoid valve D1 Port C port A connections seperated with resolution altogether, the second three-way magnetic valve V2 of triggering driving, the first three-way magnetic valve V1, then control The peristaltic pump P1 is rotated in a second direction, and the liquid in the quantitative endless tube LC is delivered in digestion instrument.
The quantitative endless tube LC designs of the sampling of quantitative measuring device 100 of the utility model, use two three-way magnetic valve V1 And V2 can be by the first triple valve V1 discharges when sampling extra, metering is accurate.In addition, 100 structure of quantitative measuring device Simply, few using device, it is simple to operate.
The container fission port 4 for depicting various way solenoid valve D1 is only exemplary in Fig. 1, Fig. 2 and Fig. 4 by first Communicating pipe L1 is connected in the container of standard specimen three, in fact, each container fission port of various way solenoid valve D1 all passes through correspondence First communicating pipe and the fluid connection in corresponding container.
Improved water quality testing meter
In a second embodiment, the utility model provides a kind of improved water quality testing meter.As shown in Figure 2, for this The structural schematic diagram of water quality testing meter 200 in the second embodiment of utility model.
The water quality testing meter 200 includes:Peristaltic pump P1, digestion instrument 210, the first three-way magnetic valve V1, the second threeway Solenoid valve V2, third three-way magnetic valve V3, multiple first communicating pipes L1, various way solenoid valve D1, quantitative endless tube LC, the second communicating pipe L2, photoelectric sensor G1, the first electromagnetic switch valve H1, the second electromagnetic switch valve H2, third connecting pipe L3, the 4th communicating pipe L4, 5th communicating pipe L5 and programmable controller.
When each three-way magnetic valve V1, V2 and V3 are not triggered driving, the normally closed port NC is closed, described normally opened Port NO is opened, and the public port COM is connected to the normally opened port NC.It is triggered drive in three-way magnetic valve V1, V2 and V3 When dynamic, the normally closed port NC is opened, and the normally opened port NO is closed, and the public port COM connects with the normally closed port NC It is logical.
The various way solenoid valve D1 includes a public port C and multiple seperated ports (1,2,3 ..., 9, A), energy It is enough controlled public port is connected to one in the multiple seperated port (1,2,3 ..., 9, A).The fission end Mouthful include resolution fission port A, air fission port 1 and multiple containers fission port (2,3 ..., 9), wherein the container divides Body end mouth 2,3 ..., 9 pass through corresponding first communicating pipe L1 and the fluid connection in corresponding container respectively.
The quantitative endless tube LC, various way solenoid valve D1, the second communicating pipe L2, peristaltic pump, the first three-way magnetic valve in Fig. 2 V1, the second three-way magnetic valve V2 mutual connected relation in Fig. 1 they connected relation it is consistent, just repeat no more here .
The first end of third connecting pipe L3 is connected to the normally closed port of the first three-way magnetic valve V1, second end and the first electromagnetism One end of switch valve H1 is connected to, and the other end of the first electromagnetic switch valve H1 is connected to the upper port of digestion instrument 210.4th connects The port C connections seperated with the resolution of various way solenoid valve D1 of the first end of siphunculus L4, second end is with third three-way magnetic valve V3's Normally closed port is connected.The first end of 5th communicating pipe L5 is connected to the normally opened port of third three-way magnetic valve V3, second end with One end of second electromagnetic switch valve H2 is connected to, and the other end of the second electromagnetic switch valve H2 is connected to the lower port of digestion instrument 210.
First electromagnetic switch valve H1 and the second electromagnetic switch valve H2 is the normally closed electromagnetic switch valve of high temperature, can withstand and disappear The heating of device 210 is solved, high temperature resistance is strong, and the service life that can improve the water quality testing meter in this way is long.It is opened in electromagnetism Close valve H1 and H2 be triggered driving when, electromagnetic switch valve H1 and H2 conducting is not triggered driving in electromagnetic switch valve H1 and H2 When, electromagnetic switch valve H1 and H2 are closed.Programmable controller and the first three-way magnetic valve V1, the second three-way magnetic valve V2, third Three-way magnetic valve V3, various way solenoid valve D1, peristaltic pump P1, photoelectric sensor G1, digestion instrument 210, the first electromagnetic switch valve H1 It is electrical connected with the second electromagnetic switch valve H2.
The water quality testing meter 200 can be used in the quantitative extraction of the liquid in arbitrarily selected target container and quantify Sample introduction can be also used for the drain for digestion instrument 210.
When carrying out quantitative extraction, the programmable controller controls the public port C and one of the various way solenoid valve D1 A container fission port (2,3 ..., 9) is connected to, which passes through first with the liquid in selected target container Communicating pipe L1 is connected to, and triggering the second three-way magnetic valve V2 of driving drives the peristaltic pump P1 to be rotated in a first direction, with described The rotation of peristaltic pump P1, liquid in the target container that port seperated with the container is connected is driven to pass through described be powered more The public port C of magnet valve D1 enters the quantitative endless tube LC, and the second of corresponding position is detected in the photoelectric sensor G1 Feedback signal is provided when having liquid in communicating pipe L2 to the programmable controller, the programmable controller is receiving the light It controls after the peristaltic pump P1 is rotated further by the predetermined time and stops after the feedback signal of electric transducer.After peristaltic pump stopping, The programmable controller P1 no longer triggers the second three-way magnetic valve V2 of driving, then controls the edges peristaltic pump P1 and first party It is rotated to opposite second direction, the liquid in the second communicating pipe L2 is arranged by the normally opened port of the second three-way magnetic valve V2 Go out, the liquid in the quantitative endless tube LC described at this time is exactly the liquid for the predetermined volumes extracted from selected target container.
When carrying out quantitative sample injection after quantitative extraction, the programmable controller controls the public affairs of the various way solenoid valve D1 Port C port A connections seperated with resolution altogether, the second three-way magnetic valve V2 of triggering driving, the first three-way magnetic valve V1, third threeway Solenoid valve V3, triggering driving the first electromagnetic switch valve H1 and the second electromagnetic switch valve H2, then controls the peristaltic pump P1 along the Two directions rotate, by the liquid in the quantitative endless tube LC by clearing up fission port A, third three-way magnetic valve V3, the second electricity Magnetic switch valve V2 is delivered in digestion instrument 210.
When carrying out drain, the programmable controller controls the public port C and air point of the various way solenoid valve D1 Body end mouth 1 is connected to, the second three-way magnetic valve V2 of triggering driving, the first three-way magnetic valve V1, triggering the first electromagnetic switch valve of driving H1 and the second electromagnetic switch valve H2, then controls the peristaltic pump P1 and is rotated in a first direction, and air is passed through air fission end Mouth 1, quantitative endless tube LC, the second three-way magnetic valve V2, the first three-way magnetic valve V1, the first electromagnetic switch valve H1 are conveyed into resolution dress In setting 210, the liquid in digestion instrument 210 is arranged by the normally opened port of the second electromagnetic switch valve H2, third three-way magnetic valve V3 Go out.
In a preferred embodiment, the water quality testing meter 200 further includes having the 4th three-way magnetic valve V4, and the four or three The public port of three-way electromagnetic valve V4 is connected to the normally opened port of third three-way magnetic valve V3, the row carried out from digestion instrument 210 Liquid includes removal waste fluid and row's dilution, the normally open end that the control based on the programmable controller passes through the 4th three-way magnetic valve V4 Mouth and normally closed port difference removal waste fluid and row's dilution.As shown in Figure 2, the normally opened port of the 4th three-way magnetic valve V4 is for arranging Go out waste liquid, for cleaning solution to be discharged, the total displacement of such waste liquid can reduce very much, more environmentally friendly for normally closed port.
In one embodiment, the water quality testing meter 200 can also quantitatively carry mixed liquor in digestion instrument 210 It takes and quantitative sample injection, in this embodiment, the length of the 4th communicating pipe L4 is consistent with the quantitative length of endless tube LC, i.e., the 4th connection The capacity of pipe L4 and the capacity of quantitative endless tube LC are consistent.Mixed liquor carries out quantitative extraction and determines in digestion instrument 210 Before measuring sample introduction, more parts of liquid of 211 quantitative sample injection of digestion tube described in warp-wise, for example may include 1 part of actual water sample and 8 parts Dilution later can carry out mixed liquor in digestion instrument 210 quantitative extraction and quantitative sample injection.
Next following operation is executed successively:
The promotion of mixed liquor in digestion instrument 210:The programmable controller controls the public of the various way solenoid valve D1 Port C port A connections seperated with resolution, the first three-way magnetic valve V1 of triggering driving, the second three-way magnetic valve V2, the three or three are powered Magnet valve V3, triggering driving the first electromagnetic switch valve H1 and the second electromagnetic switch valve H2, drives the peristaltic pump P1 along first direction Rotation, with the rotation of the peristaltic pump P1, mixed liquor in digestion instrument 210 it is driven by H2, V3, D1, into institute Quantitative endless tube LC is stated, is provided when having liquid in the second communicating pipe L2 that the photoelectric sensor G1 detects corresponding position Feedback signal gives the programmable controller, the programmable controller to be controlled after the feedback signal for receiving the photoelectric sensor It makes after the peristaltic pump P1 is rotated further by the predetermined time and stops.
The discharge of mixed liquor in quantitative endless tube LC:The programmable controller controls the public of the various way solenoid valve D1 The ports 1 seperated with air port C are connected to, and triggering the second three-way magnetic valve V2 of driving drives the peristaltic pump P1 along first direction Rotation, with the rotation of the peristaltic pump P1, the mixed liquor in quantitative endless tube LC and the second communicating pipe L2 is powered by the one or three The normally opened port of magnet valve V1 is discharged.
The discharge of residual mixed liquor in digestion instrument 210:The programmable controller controls the various way solenoid valve D1's The ports 1 seperated with air public port C are connected to, and triggering driving three-way magnetic valve V2, V1, electromagnetic switch valve H1, H2 drive institute It states peristaltic pump P1 to be rotated in a first direction, with the rotation of the peristaltic pump P1, residual mixed liquor passes through in digestion instrument 210 The normally opened port of three three-way magnetic valve V3 is discharged.At this point, there is the mixed liquor of predetermined volumes in only the 4th communicating pipe L4.
The quantitative sample injection of mixed liquor:The programmable controller controls the public port C of the various way solenoid valve D1 and disappears Fission port A connections are solved, triggering driving three-way magnetic valve V2, V1, V3, electromagnetic switch valve H1, H2 drive the edges the peristaltic pump P1 Second direction rotates, and with the rotation of the peristaltic pump P1, the mixed liquor of the predetermined volumes in the 4th communicating pipe L4 is transported to In the digestion instrument 210.
It thereby realizes and quantitative extraction and quantitative sample injection is carried out to mixed liquor in digestion instrument 210.In one application, It can be diluted to obtain 9 portions of mixed liquors using 8 parts of dilutions pair, 1 part of actual water sample, can then extract 1 portion of mixed liquor, it will Remaining 8 portions of mixed liquors discharge, wherein 1 part here refers to the predetermined volumes for quantifying endless tube LC.
The digestion instrument 210 includes digestion tube 211, heating unit 212, temperature sensor (not shown), colorimetric unit 213 and heat-sink unit (not shown), the upper port of the upper port of the digestion tube 211 as the digestion instrument 210 is described to disappear Solve lower port of the lower port of pipe 211 as the digestion instrument 210.The heating unit 212 is arranged in the digestion tube 211 lower periphery, for being heated to the digestion tube.The temperature sensor is for incuding in the digestion tube 211 Liquid temperature.The heat-sink unit is used to carry out cooling to the digestion tube.The colorimetric unit 213 includes hair Light source and light receiving unit are penetrated, light receiving unit reception obtains photosignal through the light of the liquid to be measured in digestion tube, And sending photosignal to programmable controller, programmable controller obtains the pre- of liquid to be measured based on the photosignal Determine the measured value of characteristic parameter.
The water quality testing meter 200 further includes having communication interface (not shown), the programmable controller to obtain detection The measured value of predetermined characteristic parameter of liquid to be measured server is uploaded to by communication interface.The communication interface can be Wireless communication interface, such as wifi, bluetooth, mobile communication interface (interface of 3G, 4G mobile communication network) etc. can also be Wire communication interface.The water quality testing meter 200 can detect the features such as COD, BOD, ammonia nitrogen, total phosphorus, the total nitrogen of actual water sample Parameter.
Water quality testing meter 200 in the utility model is designed using annular water channel, using quantitative endless tube, in quantitative sampling essence Degree is high, and metering is accurate, easy to operate.
The application method of water quality testing meter
The application method of water quality testing meter 200 is described below.As shown in Figure 3, it illustrates the second of the utility model The flow chart of the application method 300 of water quality testing meter 200 in embodiment.The application method 300 includes the following steps.
Step 310, quantitative extraction and the quantitative sample injection for carrying out actual water sample to be detected successively, with elder generation from actual water sample container The water sample of middle extraction predetermined volumes enters quantitative endless tube, and the water sample of the predetermined volumes in quantitative endless tube is then delivered to digestion tube In 211.
Specifically, the public port D1 of various way solenoid valve D1 is connected to by the programmable controller with container fission port 5, Wherein container fission port 5 is connected to actual water sample container.The programmable controller triggering driving V1, drives the peristaltic pump P1 It is rotated in a first direction.The programmable controller controls the peristaltic pump after the feedback signal for receiving the photoelectric sensor P1 stops after being rotated further by the predetermined time, and after peristaltic pump stopping, the programmable controller P1 no longer triggers driving second Three-way magnetic valve V2 then controlled the peristaltic pump P1 and is rotated along the second direction opposite with first direction, by the second communicating pipe Liquid in L2 is discharged by the normally opened port of the second three-way magnetic valve V2, the liquid in the quantitative endless tube LC described at this time be exactly from The actual water sample for the predetermined volumes extracted in actual water sample container.
Next, the programmable controller controls the public port C port As seperated with resolution of the various way solenoid valve D1 Connection, triggering driving V1, V2, V3, H1 and H2 then control P1 and are rotated in a second direction, by the reality in the quantitative endless tube LC Border water sample is delivered to digestion tube 211 by clearing up seperated port A, V3, V2.
It, can the repeated quantitative extraction for executing actual water sample to be detected and quantitative if necessary to more parts of actual water samples Sample introduction.
Step 320, quantitative extraction and the quantitative sample injection for carrying out reagent successively, predetermined volumes are extracted with elder generation from reagent container Reagent enter quantitative endless tube LC, then the reagent of the predetermined volumes in quantitative endless tube LC is delivered in digestion tube 211.
Specifically, the quantitative extraction with actual water sample and the substantially same mode of quantitative sample injection may be used, carry out successively The sole difference of the quantitative extraction of reagent and quantitative sample injection, the two is:When carrying out the quantitative extraction of reagent, more energization magnetic On the seperated port of the public port C of valve D1 is communicated to the reagent of reagent A or B containers is connected to container 8 or 9.In fig. 2, It shows 2 reagent containers, in other embodiments, can also there was only 1 reagent container, can also be 3 or more examinations Agent container, this depends on concrete application.
Step 330, the heating devices heat of digestion instrument is to predetermined first temperature and predetermined hold-time, to disappear Solution.
In one application, it is heated between 150-200 degree, and continues 10-40 minutes.
Step 340, it radiates to the digestion tube 211 to be cooled to predetermined second temperature, for example is cooled to 50-100 Degree.
Step 350, transmitting light source emits light, light-receiving through the liquid in the digestion tube to the light receiving unit Unit reception obtains photosignal through the light of the liquid in digestion tube, and sends photosignal to programmable controller, Programmable controller obtains the measured value of the predetermined characteristic parameter of actual water sample to be measured to be measured based on the photosignal.
Step 360, the actual measurement of the predetermined characteristic parameter for the actual water sample to be measured that the programmable controller obtains detection Value is uploaded to server by communication interface.
Depending on realizing that demand, the application method 300 are quantitatively extracted with before quantitative sample injection in progress actual water sample, can also Cleaning to the digestion tube 210.
The cleaning to the digestion tube 210 includes:
Removal waste fluid is carried out to the liquid in digestion tube 210;
Be diluted non-quantitation extraction and the non-quantitation sample introduction of liquid successively, extracted from diluent container with elder generation dilution into Enter quantitative endless tube LC and the second communicating pipe L2, then the dilution in quantitative endless tube LC and the second communicating pipe L2 is delivered to and is disappeared It solves in pipe 210;
Liquid in digestion tube 211 is carried out to clear washing lotion.
Non-quantitation extracts:Control the public port port seperated with a selected container of the various way solenoid valve D1 Connection, triggering driving V1, drives P1 to be rotated in a first direction, the programmable controller is receiving the photoelectric sensor G1's It controls after the peristaltic pump P1 is rotated further by the predetermined time and stops after feedback signal, be just extracted the target liq of non-quantitation at this time. When carrying out non-quantitation sample introduction after non-quantitation extraction, the programmable controller controls the public port of the various way solenoid valve Port connection seperated with resolution, triggering driving V1, V2, V3, H1 and H2 conducting, then controls the peristaltic pump P1 in a second direction Liquid in quantitative the endless tube LC and the second communicating pipe L2 is delivered in digestion instrument by rotation.
By replacing different reagent, the water quality testing meter 200 can detect COD, BOD of actual water sample, ammonia nitrogen, The different characteristic parameter such as total phosphorus, total nitrogen.
Multi-parameter water quality detector
In the third embodiment, the utility model provides a kind of multi-parameter water quality detector.As shown in Figure 4, for this The structural schematic diagram of multi-parameter water quality detector 400 in the 3rd embodiment of utility model.
Multi-parameter water quality detector 400 in Fig. 4 is whole similar in structure with the water quality testing meter 200 in Fig. 2, different Place is:Multi-parameter water quality detector 400 in Fig. 4 includes multiple digestion instrument 210a, 210b, 210c, multiple first electricity Magnetic switch valve H1, multiple second electromagnetic switch valve H2, the second various way solenoid valve D2, third various way solenoid valve D3.In this embodiment In, various way solenoid valve D1 is referred to as the first various way solenoid valve.The water quality in multi-parameter water quality detector 400 and Fig. 2 in Fig. 4 The identical part in structure and principle of detector 200, is just not repeated here, please refers to above.
One end of first electromagnetic switch valve H1 is connected to the upper port of corresponding digestion instrument, the second electromagnetic switch valve H2's One end is connected to the lower port of corresponding digestion instrument.The first end of third connecting pipe L3 is normally closed with the first three-way magnetic valve V1's Port is connected to, and second end is connected to the public port of the second various way solenoid valve D2, the seperated port point of the second various way solenoid valve D2 It is not connected with the other end of corresponding first electromagnetic switch valve H1.The first end of 5th communicating pipe L5 and third three-way magnetic valve The normally opened port of V3 is connected to, and second end is connected to the public port of third various way solenoid valve D3, third various way solenoid valve D3's Seperated port is connected with the other end of corresponding second electromagnetic switch valve H2 respectively.Programmable controller also with energization magnetic more than second Valve D2, third various way solenoid valve D3 are electrical connected.
Due to being needed from multiple resolutions with multiple digestion instruments when carrying out quantitative sample injection, removal waste fluid, clearing washing lotion One is selected in device and is used as target digestion instrument, can be operated accordingly later.If it is desired to selected digestion instrument 210a, then the public port for just controlling second, third various way solenoid valve D2 and D3 seperated end corresponding with digestion instrument 210a Mouth connection, while triggering the corresponding first electromagnetic switch valve H1 and the second electromagnetic switch valve H2 of driving digestion instrument 210a.
It is also similar in the application method and the application method of water quality testing meter 200 of multi-parameter water quality detector 400, difference Be in:
Need to select one from multiple digestion instruments in advance as target digestion instrument;
It can be carried out for another target digestion instrument to be checked when a target digestion instrument is cleared up and cooled down Survey quantitative extraction and the quantitative sample injection of water sample or reagent;
It can be disposably directed to quantitative extraction and quantitative sample injection that different digestion instruments carries out water sample to be detected successively, it Property is directed to quantitative extraction and quantitative sample injection that different digestion instruments carries out reagent successively again afterwards.
The check system and method for water quality testing meter
In the fourth embodiment, the utility model provides a kind of check system 500 of water quality testing meter.As shown in Figure 5, It is the structural schematic diagram of the check system 500 of the water quality testing meter in the fourth embodiment of the utility model.The verification system System 500 includes:Management server 560 and water quality testing meter 520.The water quality testing meter 520 can be water quality as shown in Figure 2 Detector can also be multi-parameter water quality detector as shown in Figure 4, can also be other water quality testing meters.
Water quality testing meter 520 can be communicated with the management server 560 by network 504, and interior includes standard Water sample container 522 and actual water sample container 524, wherein standard water sample is accommodated in the standard water sample container 522, the standard The standard value of the predetermined characteristic parameter of water sample is known and is stored in management server 560, the actual water sample container It is accommodated in 524 and needs to be surveyed actual water sample, the water quality testing meter 520 regularly detects the actual water sample in actual water sample container The measured value of predetermined characteristic parameter, and the measured value of the predetermined characteristic parameter for the actual water sample that detection obtains is uploaded to management clothes Business device 560.
Water quality testing meter 520 can also be in examination criteria water sample container 522 standard water sample predetermined characteristic parameter value, And the measured value for the predetermined characteristic parameter that detection obtains standard water sample is uploaded to management server 560, the management server Whether the measured value of the 560 predetermined characteristic parameters based on standard water sample and the difference of standard value verify the water quality testing meter 520 It goes wrong.Specifically, be more than predetermined ratio in the measured value of the predetermined characteristic parameter of standard water sample and the deviation of standard value, than Such as positive and negative 10%, then illustrate water quality testing meter normal operation, otherwise, then it is assumed that water quality testing meter operation goes wrong, and can arrange Related personnel carries out inspection calibration.In addition to the management server 560, who and is unaware of the predetermined characteristic parameter of standard water sample Standard value.
In a preferred embodiment, (such as time random) of the management server 560 periodically or non-periodically Checking command, after the checking command for receiving the management server 560, the water quality detection are sent to water quality testing meter 520 The value of the predetermined characteristic parameter of standard water sample in 520 ability examination criteria water sample container of instrument, and detection is obtained into standard water sample The measured value of predetermined characteristic parameter is uploaded to management server 560.In this way, when the water quality testing meter 520 and being unaware of needs Standard water sample in standard water sample container is detected, 560 time of the management server it is random to water quality testing meter 520 send checking commands, i.e., the time that the water quality testing meter 520 is detected the standard water sample in standard water sample container Point is random, rather than fixed, improves the confidence level of 520 detection data of the water quality testing meter in this way.
The standard water sample container in the water quality testing meter is replaced every predetermined period, for example one month replaces once, keeps away The standard water sample exempted from standard water sample container caused by overlong time is rotten.In addition, pre- in different standard water sample containers 522 The standard value for determining characteristic parameter is different.
In the fourth embodiment, the utility model provides the method for calibration 600 of also a kind of water quality testing meter.As shown in Figure 6 , for the flow chart of the method for calibration 600 of the water quality testing meter in the fourth embodiment of the utility model.The verification side Method 600 includes the following steps.
Step 610, the water quality testing meter 520 regularly detects the predetermined characteristic of the actual water sample in actual water sample container The measured value of parameter, and the measured value of the predetermined characteristic parameter for the actual water sample that detection obtains is uploaded to management server 560;
Step 620, the predetermined characteristic ginseng for the standard water sample that the water quality detection 520 can also be in examination criteria water sample container Several values, and the measured value for the predetermined characteristic parameter that detection obtains standard water sample is uploaded to management server;
Step 630, the measured value of predetermined characteristic parameter of the management server 560 based on standard water sample and standard value Difference verifies whether the water quality testing meter 520 goes wrong.Here go wrong refer to water quality testing meter 520 testing number According to not being inconsistent standardization, this may be due to caused by water quality testing meter 520 failure of itself, it is also possible to since water quality is examined Caused by the detection parameters of survey instrument 520 are changed, it is also possible to caused by other problems.
Preferably, (time is random) of the management server 560 periodically or non-periodically is sent to water quality testing meter 520 Checking command, after the checking command for receiving the management server 560,520 ability examination criteria water sample of the water quality testing meter The value of the predetermined characteristic parameter of standard water sample in container, and the measured value that the predetermined characteristic parameter for obtaining standard water sample will be detected It is uploaded to management server 520.
In this way, the check system based on the water quality testing meter in the utility model and method, realization water quality that can be long-range The verification of detector 520, it is not necessary to scene, can be carried out whenever and wherever possible, promote the work effect of Site Detection Environment Monitoring Unit Rate saves significantly on manpower.Meanwhile can accomplish that random repeatedly verification, long-term monitoring are spot-check at any time, improve detection data Confidence level;The standard value of the predetermined characteristic parameter of standard water sample is secrecy, different, Nobody Knows its it is specific be worth, this into One step improves the confidence level of detection data.
Above description fully discloses specific embodiment of the present utility model.It should be pointed out that being familiar with the neck Right of any change that the technical staff in domain does specific embodiment of the present utility model all without departing from the utility model The range of claim.Correspondingly, the scope of the claims of the utility model is also not limited only to the specific embodiment party Formula.

Claims (8)

1. a kind of multi-parameter water quality detector, which is characterized in that it includes:
Peristaltic pump;
Multiple digestion instruments;
Multiple first electromagnetic switch valves corresponding with the multiple digestion instrument and multiple second electromagnetic switch valves respectively, wherein the One end of one electromagnetic switch valve is connected to the upper port of corresponding digestion instrument, and one end of the second electromagnetic switch valve disappears with corresponding The lower port connection for solving device, when not being triggered driving, the first electromagnetic switch valve and the second electromagnetic switch valve are closed, and are being touched When hair driving, the first electromagnetic switch valve and the second electromagnetic switch valve are closed;
First three-way magnetic valve, the second three-way magnetic valve and third three-way magnetic valve, each three-way magnetic valve include public port, Normally closed port and normally opened port, when not being triggered driving, the normally closed port is closed, the normally opened port open, the public affairs Port is connected to the normally opened port altogether, and when being triggered driving, the normally closed port open, the normally opened port is closed, institute Public port is stated to be connected to the normally closed port;
Multiple first communicating pipes;
First various way solenoid valve, the second various way solenoid valve and third various way solenoid valve, each various way solenoid valve include one public Port and multiple seperated ports, what can be controlled is connected to public port with one in the multiple seperated port, the The seperated port of one various way solenoid valve includes the seperated port of resolution, air fission port and multiple containers fission port, wherein the The container fission port of one various way solenoid valve passes through corresponding first communicating pipe and the fluid connection in corresponding container respectively;
Quantitative endless tube, first end are connected to the public port of the first various way solenoid valve, second end and the second three-way magnetic valve Normally closed port connection;
Second communicating pipe, first end are connected to the public port of the second three-way magnetic valve, second end and the first threeway electromagnetism The public port of valve is connected to, and the part of the second communicating pipe is placed in the peristaltic pump and is driven by the peristaltic pump;
Photoelectric sensor was placed on the second communicating pipe between the peristaltic pump and the second three-way magnetic valve;
Third connecting pipe, first end are connected to the normally closed port of the first three-way magnetic valve, second end and the second various way solenoid valve Public port connection, the seperated port of the second various way solenoid valve respectively with the other end phase of corresponding first electromagnetic switch valve Even;
4th communicating pipe, first end port connection seperated with the resolution of the first various way solenoid valve, second end and third threeway The normally closed port of solenoid valve is connected;
5th communicating pipe, first end are connected to the normally opened port of third three-way magnetic valve, and be powered magnetic more second end and third The public port of valve is connected to, the seperated port of third various way solenoid valve respectively with the other end phase of corresponding second electromagnetic switch valve Even;
Programmable controller, with the first three-way magnetic valve, the second three-way magnetic valve, third three-way magnetic valve, peristaltic pump, first Various way solenoid valve, the second various way solenoid valve, third various way solenoid valve, photoelectric sensor, digestion instrument, the first electromagnetic switch valve and Second electromagnetic switch valve is electrical connected.
2. multi-parameter water quality detector according to claim 1, which is characterized in that when carrying out quantitative extraction, it is described can Programmable controller controls public port seperated with the container port connection of the first various way solenoid valve, the container fission port and Liquid in target container is connected to by the first communicating pipe, and triggering the second three-way magnetic valve of driving drives the peristaltic pump along the One direction rotates, and with the rotation of the peristaltic pump, the liquid in the target container that port seperated with the container is connected is driven The dynamic public port by the first various way solenoid valve enters the quantitative endless tube, and corresponding positions are detected in the photoelectric sensor Feedback signal is provided when having liquid in second communicating pipe at the place of setting to the programmable controller, the programmable controller is being received It controls after the peristaltic pump is rotated further by the predetermined time and stops after to the feedback signal of the photoelectric sensor, stop in the peristaltic pump After only, the programmable controller no longer triggers the second three-way magnetic valve of driving, then controls the peristaltic pump edge and first party It is rotated to opposite second direction, the liquid in the second communicating pipe is discharged by the normally opened port of the second three-way magnetic valve, this Shi Suoshu quantifies the liquid that the liquid in endless tube is exactly the predetermined volumes extracted from target container.
3. multi-parameter water quality detector according to claim 2, which is characterized in that quantified after quantitative extraction into When sample, the programmable controller controls the public port port connection seperated with resolution of the first various way solenoid valve, triggering driving First three-way magnetic valve, the second three-way magnetic valve, third three-way magnetic valve control the second various way solenoid valve and third and are powered magnetic more The public port of valve is connected to the seperated port corresponding to target digestion instrument, and triggering drives the target digestion instrument corresponding First electromagnetic switch valve and the second electromagnetic switch valve then control the peristaltic pump and are rotated in a second direction, by the quantitative loop Liquid in pipe is delivered to target resolution by the seperated port of resolution, third three-way magnetic valve, corresponding second electromagnetic switch valve In device.
4. multi-parameter water quality detector according to claim 1, which is characterized in that described programmable when carrying out drain The public port port seperated with air that controller controls the first various way solenoid valve is connected to, the first three-way magnetic valve of triggering driving, Second three-way magnetic valve, corresponding first electromagnetic switch valve of triggering driving target digestion instrument and the second electromagnetic switch valve, second The public port of various way solenoid valve and third various way solenoid valve is connected to the seperated port corresponding to target digestion instrument, is then controlled It makes the peristaltic pump to be rotated in a first direction, air is passed through into air fission port, quantitative loop, the first three-way magnetic valve, second Three-way magnetic valve, the first electromagnetic switch valve are conveyed into target digestion instrument, and the liquid in target digestion instrument passes through corresponding The normally opened port discharge of second electromagnetic switch valve, third three-way magnetic valve.
5. multi-parameter water quality detector according to claim 4, which is characterized in that it further includes having the 4th threeway electromagnetism Valve, the public port of the 4th three-way magnetic valve are connected to the normally opened port of third three-way magnetic valve, and the drain includes removal waste fluid With clear washing lotion, the control based on the programmable controller passes through the normally opened port of the 4th three-way magnetic valve and normally closed port point Other removal waste fluid and clear washing lotion.
6. multi-parameter water quality detector according to claim 1, which is characterized in that the length and quantitative loop of the 4th communicating pipe The length of pipe is consistent,
The promotion of mixed liquor in target digestion instrument:The programmable controller control the public port of the various way solenoid valve with The seperated port connection of resolution, the first three-way magnetic valve of triggering driving, the second three-way magnetic valve, third three-way magnetic valve, triggering are driven Corresponding first electromagnetic switch valve of moving-target digestion instrument and the second electromagnetic switch valve, control the second various way solenoid valve and third is more The public port of three-way electromagnetic valve is connected to the seperated port corresponding to target digestion instrument, drives the peristaltic pump along first direction Rotation, with the rotation of the peristaltic pump, mixed liquor in digestion instrument is driven to pass through the second electromagnetic switch valve, the three or three Three-way electromagnetic valve, various way solenoid valve quantify endless tube into described, and detect corresponding position in the photoelectric sensor second connects Feedback signal is provided when having liquid in siphunculus to the programmable controller, the programmable controller is receiving the photoelectric transfer It controls after the peristaltic pump is rotated further by the predetermined time and stops after the feedback signal of sensor,
The discharge of mixed liquor in quantitative endless tube:The programmable controller controls the public port and air of the various way solenoid valve Seperated port connection, triggering the second three-way magnetic valve of driving, drives the peristaltic pump to be rotated in a first direction, with the wriggling The rotation of pump, the mixed liquor quantified in endless tube and the second communicating pipe are discharged by the normally opened port of the first three-way magnetic valve,
The discharge of residual mixed liquor in target digestion instrument:The programmable controller controls the common end of the various way solenoid valve Mouth port connection seperated with air, the first three-way magnetic valve of triggering driving, the second three-way magnetic valve, triggering drive target resolution dress Corresponding first electromagnetic switch valve and the second electromagnetic switch valve are set, the public affairs of the second various way solenoid valve and third various way solenoid valve are controlled Port is connected to the seperated port corresponding to target digestion instrument altogether, drives the peristaltic pump to be rotated in a first direction, with institute The rotation of peristaltic pump is stated, residual mixed liquor is discharged by the normally opened port of third three-way magnetic valve in digestion instrument,
The quantitative sample injection of mixed liquor:The programmable controller controls the public port end seperated with resolution of the various way solenoid valve Mouth connection, triggering the first, second, third three-way magnetic valve of driving, triggering drive corresponding first electromagnetism of target digestion instrument to open Valve and the second electromagnetic switch valve are closed, the public port of the second various way solenoid valve and third various way solenoid valve is controlled and corresponds to target The seperated port of digestion instrument is connected to, and the peristaltic pump is driven to be rotated in a second direction, with the rotation of the peristaltic pump, the 4th The mixed liquor of predetermined volumes in communicating pipe is transported in the digestion instrument, and the target digestion instrument fills for multiple resolutions One in setting.
7. multi-parameter water quality detector according to claim 1, which is characterized in that each digestion instrument include digestion tube, Heating unit, temperature sensor, colorimetric unit and heat-sink unit, the upper port of the digestion tube is as the upper of the digestion instrument Port, the lower port of the lower port of the digestion tube as the digestion instrument, the heating unit are arranged in the digestion tube Lower periphery, for being heated to the digestion tube, the temperature sensor is used to incude liquid in the digestion tube Temperature, the heat-sink unit is for radiating to the digestion tube;The colorimetric unit includes transmitting light source and light-receiving Unit, light receiving unit receive the light through the liquid to be measured in digestion tube and obtain spectrum electric signal, and by spectrum telecommunications Number send programmable controller to, programmable controller obtains to be measured in target digestion instrument based on the spectrum electric signal The predefined parameter value of liquid.
8. multi-parameter water quality detector according to claim 7, which is characterized in that the multi-parameter water quality detector also wraps Communication interface is included, the programmable controller passes through the predefined parameter value for the liquid to be measured that detection obtains on communication interface Reach server.
CN201721574530.2U 2017-11-22 2017-11-22 Multi-parameter water quality detector Active CN207764116U (en)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Address after: 214000 floor 1-5, building 8, 2018 Lihu Avenue, Wuxi City, Jiangsu Province

Patentee after: JIANGSU LANCHUANG INTELLIGENT TECHNOLOGY Co.,Ltd.

Address before: 214000 9th floor, building A1, No.999, gaolang East Road, Binhu District, Wuxi City, Jiangsu Province

Patentee before: JIANGSU LANCHUANG INTELLIGENT TECHNOLOGY Co.,Ltd.