CN207619159U - A kind of condensate polishing treatment regenerative wastewater ammonia recovery system - Google Patents

A kind of condensate polishing treatment regenerative wastewater ammonia recovery system Download PDF

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Publication number
CN207619159U
CN207619159U CN201721606991.3U CN201721606991U CN207619159U CN 207619159 U CN207619159 U CN 207619159U CN 201721606991 U CN201721606991 U CN 201721606991U CN 207619159 U CN207619159 U CN 207619159U
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CN
China
Prior art keywords
regenerative wastewater
ammonia
degassing film
pump
film device
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Withdrawn - After Issue
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CN201721606991.3U
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Chinese (zh)
Inventor
沈万中
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Zhejiang Haiyan Power System Resources Environmental Technology Co Ltd
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Zhejiang Haiyan Power System Resources Environmental Technology Co Ltd
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Abstract

The utility model discloses a kind of condensate polishing treatment regenerative wastewater ammonia recovery systems, including regenerative wastewater collecting pit, regenerative wastewater delivery pump, regenerative wastewater collecting pit blender, filter backwash pump, quartz filter, accurate filter, heat exchanger, degassing film device, condensed water precision processing system neutralization pond, acid storage tank, sour metering pump, ammonia absorption cycle tank, ammonia absorbent recirculation pump, ammonolysis product recycling can, degassing film cleaning system and system pipeline valve.The pH value and temperature that the utility model passes through adjusting (raising) regenerative wastewater, the conjugate of ammonium ion and water in regenerative wastewater is set to be converted to the conjugate direction of ammonia and water, only allowed by degassing film gas by characteristic, reach the recycling of ammonia in waste water come cyclic absorption ammonia with acid in the other side of degassing film, effectively by the ammonia recycling in waste water, meanwhile reducing the discharge of ammonia nitrogen and processing cost in waste water.

Description

A kind of condensate polishing treatment regenerative wastewater ammonia recovery system
【Technical field】
The utility model is related to the technical field of Treatment of Industrial Water, more particularly to a kind of condensate polishing treatment regenerative wastewater ammonia The technical field of recovery system.
【Background technology】
In nuclear power conventional island condensed water precision processing system and thermoelectricity condensed water precision processing system, condensed water precision processing system Filtering and demineralization for removing the steam condensate after driving electrical power generators of doing work through steam turbine, mainly remove and use In the ammonia (ammonium ion) of the pH values of adjusting/raising water for preventing equipment pipe etc. from corroding and being added in systems, the ammonia of this part (ammonium ion) enters regenerative wastewater after regeneration.
Conventional is also currently used condensate polishing treatment regenerative wastewater processing method, and being will be at all condensate fine The waste water conjunction portion of reason regenerative system is discharged into neutralization pond, and being discharged into industrial wastewater after pH adjusts qualification is handled, on the one hand again Ammonia-nitrogen content in raw waste water is very high, and the difficulty of removal ammonia nitrogen is increased to subsequent industrial wastewater, on the other hand, due to needing Ammonia nitrogen is removed, therefore the operating cost of industrial wastewater can increase, be not used in energy-saving and emission-reduction, and treated that ammonia nitrogen can not It recycles.
【Utility model content】
The purpose of this utility model is exactly to solve the problems of the prior art, proposes a kind of condensate polishing treatment regenerative wastewater Ammonia (ammonium ion) in waste water can be recycled in condensate polishing treatment regenerative system and meet industrial production by ammonia recovery system The requirement of product (ammonium chloride or ammonium sulfate), largely reduces the discharge of condensed water precision processing system regenerative wastewater ammonia nitrogen.
To achieve the above object, the utility model proposes a kind of condensate polishing treatment regenerative wastewater ammonia recovery system, packets Include regenerative wastewater collecting pit, regenerative wastewater delivery pump, regenerative wastewater collecting pit blender, filter backwash pump, quartz sand filtration Device, accurate filter, heat exchanger, degassing film device, condensed water precision processing system neutralization pond, acid storage tank, sour metering pump, ammonia absorb Circulating tank, ammonia absorbent recirculation pump, ammonolysis product recycling can, degassing film cleaning system and system pipeline valve, the regenerative wastewater Collecting pit is equipped with the storage regeneration being connected with regenerative wastewater collecting pit and replaces the positive resin regenerating tank of the waste water generated and coagulates Precision processing alkali storage tank is born water, the regenerative wastewater collecting pit further includes the first pH for detecting pH value of waste water in regenerative wastewater collecting pit Detector, the regenerative wastewater collecting pit blender are arranged in regenerative wastewater collecting pit, the regenerative wastewater collecting pit with again Raw waste water delivery pump is connected, and the raw waste water delivery pump is connected with the quartz filter for preventing impurity from entering system, the stone Sand filter is connected with the accurate filter of protection degassing film equipment safety, the accurate filter and control regenerated water temperature The heat exchanger of degree is connected, and the heat exchanger is connected with degassing film device, and the degassing film device, which includes several, allows gas By without allow liquid by membrane separator, the degassing film device is additionally provided with acid adding pipe through the side of gas, described Degassing film device is connected with condensed water precision processing system neutralization pond, and it is solidifying that detection is equipped in the condensed water precision processing system neutralization pond Bear water the 2nd pH detectors of pH value of waste water in precision processing system neutralization pond, the condensed water precision processing system neutralization pond be used for The ammonolysis product recycling can for storing recovery product is connected, and the ammonolysis product recycling can is connected with ammonia absorption cycle tank, and the ammonia absorbs Circulating tank is connected with acid storage tank, and sour metering pump, the acid storage tank, acid metering are equipped between the ammonia absorption cycle tank and acid storage tank Pump, ammonia absorption cycle tank cooperate regulation and control ammonolysis product recycling can in recovery product concentration, the ammonolysis product recycling can also with Ammonia absorbent recirculation pump for exporting recovery product is connected.
Preferably, the heating agent of the heat exchanger is steam or hot water, the water outlet of the heat exchanger is equipped with temperature detection Inductor, the heat exchanger, which is equipped with alternative heat exchanger, makes the bypass of system normal operation.
Preferably, the degassing film device is connected with the degassing film cleaning system for cleaning degassing film device.
Preferably, be additionally provided in the condensed water precision processing system neutralization pond neutralization pond acid adding pipe, neutralization pond drainpipe, Neutralization pond adds alkali pipe and neutralization pond blender.
Preferably, it is described degassing film device quantity be one and more than one, be between each degassing film device The connection type that serial or parallel connection or connection in series-parallel combine, the quantity of the membrane separator be one and more than one.
Preferably, the regenerative wastewater delivery pump is equipped with the first delivery pipe of controllable switch, the regenerative wastewater Delivery pump is connected by the first delivery pipe with condensed water precision processing system neutralization pond, and the filter backwash pump is equipped with controllable The second delivery pipe of switch is made, the filter backwash pump is connected by the second delivery pipe with condensed water precision processing system neutralization pond It is logical.
Preferably, the quantity of the system pipeline valve is two and two or more.
Preferably, being hydrochloric acid or sulfuric acid in the acid storage tank.
The beneficial effects of the utility model:The utility model is made by the pH value and temperature of adjusting (raising) regenerative wastewater The conjugate of ammonium ion and water is converted to the conjugate direction of ammonia and water in regenerative wastewater, only allows gas logical by degassing film The characteristic crossed reaches the recycling of ammonia in waste water in the other side of degassing film with acid come cyclic absorption ammonia, effectively will be in waste water Ammonia recycling, meanwhile, reduce the discharge of ammonia nitrogen and processing cost in waste water.
The feature and advantage of the utility model will be described in detail by embodiment combination attached drawing.
【Description of the drawings】
Fig. 1 is a kind of condensate polishing treatment regenerative wastewater ammonia recovery system of the utility model.
In figure:1- regenerative wastewaters collecting pit, 2- regenerative wastewaters delivery pump, 3- regenerative wastewater collecting pits blender, 4- filterings Device backwashing pump, 5- quartz filters, 6- accurate filters, 7- heat exchangers, 8- degassings film device, 9- condensate polishing treatments system System neutralization pond, 10- acid storage tanks, 11- acid metering pump, 12- ammonia absorption cycles tank, 13- ammonia absorbent recirculation pump, the recycling of 14- ammonolysis products Tank, 15- degassing films cleaning system, 16- system pipelines valve, 1111- positive resins regenerating tank, the first pH detectors of 1112-, 1113- condensate polishing treatment alkali storage tank, the first delivery pipes of 21-, the second delivery pipes of 41-, 71- temperature detections inductor, by 72- Road, 81- membrane separators, 82- acid addings pipe, the 2nd pH detectors of 91-, 92- neutralization pond acid addings pipe, 93- neutralization ponds drainpipe, 94- Neutralization pond adds alkali pipe, 95- neutralization pond blenders.
【Specific implementation mode】
Refering to fig. 1, a kind of condensate polishing treatment regenerative wastewater ammonia recovery system of the utility model, including regenerative wastewater are collected Pond 1, regenerative wastewater delivery pump 2, regenerative wastewater collecting pit blender (can also be Hydraulic Circulation stirring) 3, filter backwash pump 4, quartz filter 5, accurate filter 6, heat exchanger 7, degassing film device 8, condensed water precision processing system neutralization pond 9, acid storage Tank (hydrochloric acid or sulfuric acid) 10, sour metering pump 11, ammonia absorption cycle tank 12, ammonia absorbent recirculation pump 13, ammonolysis product (ammonium chloride or sulfuric acid Ammonium) recycling can 14, degassing film cleaning system 15 and system pipeline valve 16, the regenerative wastewater collecting pit 1 be equipped with again The positive resin regenerating tank 1111 and condensate polishing treatment alkali for the waste water that the storage regeneration and displacement that raw wastewater collection pond 1 is connected generate Storage tank 1113, the regenerative wastewater collecting pit 1 further include the first pH detections for detecting waste water pH value in regenerative wastewater collecting pit 1 Device 1112, the regenerative wastewater collecting pit blender 3 are arranged in regenerative wastewater collecting pit 1, regenerative wastewater collecting pit blender 3 stir evenly the water in regenerative wastewater collecting pit 1, and regenerative wastewater collecting pit 1 can accommodate contains ammonia more than primary and primary Regenerative wastewater and the lye for adjusting (raising) pH of required addition.The regenerative wastewater collecting pit 1 is conveyed with regenerative wastewater Pump 2 is connected, and regenerative wastewater delivery pump 2 can be immersible pump or vertical self-sucking pump or horizontal self-sucking pump or long shaft submerged pump or vacuum Water leading cylinder adds centrifugal pump.The raw waste water delivery pump 2 is connected with the quartz filter 5 for preventing impurity from entering system, quartz sand Filter 5 can be vertical vessel water cap perforated plate construction or vertical vessel quartz sand graduation structure or horizontal filter structure, Can also be that other filter devices are used for the pretreatment of regenerative wastewater and meet the inflow requirement of follow-up degassing film device.It is described Quartz filter 5 is connected with the accurate filter 6 of the protection degassing safety of film device 8, accurate filter 6 can be vertical line around Filter cartridge construction or vertical jetting suede filter cartridge construction or vertical big flow filter cartridge construction or horizontal big flow filter cartridge construction, can also be it The accurate filter or cartridge filter of its form.7 phase of heat exchanger of the accurate filter 6 and control regenerative wastewater temperature Even, the heating agent of heat exchanger 7 can be steam or hot water, can also be the heating agent (thermal energy such as comprehensive utilization waste heat) of other properties, give up The outlet temperature of water can automatically adjust according to the heat exchanger wastewater outlet temperature of setting.The heat exchanger 7 is filled with degassing film Set 8 be connected, it is described degassing film device 8 include several permission gases by without allow liquid by membrane separator 81, The degassing film device 8 is additionally provided with acid adding pipe 82 through the side of gas, and hydrochloric acid or sulfuric acid is added by acid adding pipe 82 to absorb With recycling degassing film device 8 through the ammonia of gas side.The degassing film device 8 and 9 phase of condensed water precision processing system neutralization pond Even, the of pH value of waste water in detection condensed water precision processing system neutralization pond 9 is equipped in the condensed water precision processing system neutralization pond 9 Two pH detectors 91.The condensed water precision processing system neutralization pond 9 and 14 phase of ammonolysis product recycling can for storing recovery product Even, the ammonolysis product recycling can 14 is connected with ammonia absorption cycle tank 12, and the ammonia absorption cycle tank 12 is connected with acid storage tank 10, institute It states and is equipped with sour metering pump 11 between ammonia absorption cycle tank 12 and acid storage tank 10, the acid storage tank 10, sour metering pump 11, ammonia absorption follow Ring tank 12 cooperates, and ammonia absorption efficiency and recovery ammonia product are improved by repeatedly absorbing by way of acid cycle Concentration, the ammonolysis product recycling can 14 are also connected with the ammonia absorbent recirculation pump 13 for exporting recovery product.
The heating agent of the heat exchanger 7 is steam or hot water, and the water outlet of the heat exchanger 7 is equipped with temperature detection inductor 71, the heat exchanger 7, which is equipped with alternative heat exchanger 7, makes the bypass 72 of system normal operation, needs cleaning, inspection in heat exchanger 7 Repair, safeguard or condensate polishing treatment regenerative wastewater temperature meet set temperature require when directly can complete system by bypassing Operation.
The degassing film device 8 is connected with the degassing film cleaning system 15 for cleaning degassing film device 8, and deaerate Membrane cleaning Degassing film device 8 is cleaned when system 15 declines for 8 recovering effect of film device that deaerates.
Be additionally provided in the condensed water precision processing system neutralization pond 9 neutralization pond acid adding pipe 92, neutralization pond drainpipe 93, in With pond plus alkali pipe 94 and neutralization pond blender 95.
It is described degassing film device 8 quantity be one and more than one, between each degassing film device 8 for connect or simultaneously The connection type that connection or connection in series-parallel combine, to reach best recovering effect, the quantity of the membrane separator 81 is one and one More than a.
The regenerative wastewater delivery pump 2 is equipped with the first delivery pipe 21 of controllable switch, the regenerative wastewater delivery pump 2 It is connected with condensed water precision processing system neutralization pond 9 by the first delivery pipe 21, the filter backwash pump 4 is equipped with controllable Second delivery pipe 41 of switch, the filter backwash pump 4 pass through the second delivery pipe 41 and condensed water precision processing system neutralization pond 9 Be connected, when quartz filter 5 need backwash, accurate filter 6 need replacing filter element, degassing film device 8 need clearly When washing, system carries bypath system can be directly by the waste water in regenerative wastewater collecting pit 1 through regenerative wastewater delivery pump 2 or filtering Device backwashing pump 4 is sent to condensed water precision processing system neutralization pond 9.The quantity of the system pipeline valve 16 be two and two with On.
Utility model works process:
A kind of condensate polishing treatment regenerative wastewater ammonia recovery system of the utility model during the work time, absorbs in condensed water The positive resin of ammonium ion 1111 regenerated and replaced in positive resin regenerating tank, be drained into regenerative wastewater collecting pit 1 (the other drainings of positive resin regenerating tank 1111 are without ammonium ion so not entering the wastewater collection pond of this system, and be directly discharged into solidifying Bear water precision processing system neutralization pond 9 or partial drainage individually recycle), the volume of regenerative wastewater collecting pit 1 be large enough to hold it is primary or The water needed for positive resin is repeatedly regenerated and replaces, there are certain when accommodating primary recycling and replacing the water needed for positive resin Surplus.(raising) pH value, ammonium ion are adjusted by condensate polishing treatment alkali storage tank 1113 plus alkali in regenerative wastewater collecting pit 1 It is converted to the direction of ammonia and water under conditions of high ph-values with water and conjugate, meanwhile, the regeneration in regenerative wastewater collecting pit 1 Wastewater collection pond blender 3 stirs evenly pool inner water matter.
The regenerative wastewater stirred evenly passes through stone successively from regenerative wastewater collecting pit 1 after the boosting of regenerative wastewater delivery pump 2 Enter degassing film device 8 after sand filter 5, accurate filter 6, heat exchanger 7, the purpose of equipment quartz filter 5 is anti- Only impurity etc. enters subsequent system, meets the requirement of degassing film device 8;The purpose that accurate filter 6 is arranged is protection degassing The safety of film device 8 plays the function of 8 safety of protection degassing film device when the system of front works abnormal;Setting heat exchange The purpose of device 7 is to improve the temperature of regenerative wastewater, the characteristics of using ammonium hydroxide itself, convenient for generating more free ammonias, regeneration The temperature of waste water carries out automatically controlling, and prevents the excessively high damage for causing degassing film device 8 of temperature.
Deaerate film device 8 be equipped with only allow gas by without allow liquid by membrane separator 81, by degassing After film device 8, regenerative wastewater is discharged into condensed water precision processing system neutralization pond 9;Degassing film device 8 is additionally provided with through the side of gas Acid adding pipe 82, the ammonia that hydrochloric acid or sulfuric acid is added by acid adding pipe 82 to absorb and recycle degassing film device 8 through gas side, leads to Cross the cycle of acid solution (hydrochloric acid or sulfuric acid) becomes recycling product to reach the ammonia for quickly absorbing and being penetrated from degassing film device 8 (ammonium chloride or ammonium sulfate), the number of cycle is to cross on the basis of the concentration of product requirement.Meanwhile to ensure the abundant suction of ammonia It receives, degassing film device 8 can be produced to be arranged with serial or parallel connection or series-parallel mode, is repeatedly absorbed to reach good ammonia Gas recovering effect.The recycling product (ammonium chloride or ammonium sulfate) for reaching recycling concentration is then transported in ammonolysis product recycling can 14 Storage, while supplementing the absorption that acid solution (hydrochloric acid or sulfuric acid) continues ammonia in ammonia absorption cycle tank 12.It is stored in ammonolysis product Recycling product in recycling can 14, can be periodically by ammonia absorbent recirculation pump 13 discharge system to user or transport device.
Above-described embodiment is the explanation to the utility model, is not the restriction to the utility model, any new to this practicality Scheme after type simple transformation belongs to the scope of protection of the utility model.

Claims (8)

1. a kind of condensate polishing treatment regenerative wastewater ammonia recovery system, it is characterised in that:Including regenerative wastewater collecting pit (1), again Raw waste water delivery pump (2), regenerative wastewater collecting pit blender (3), filter backwash pump (4), quartz filter (5), precision Filter (6), heat exchanger (7), degassing film device (8), condensed water precision processing system neutralization pond (9), acid storage tank (10), acid metering Pump (11), ammonia absorption cycle tank (12), ammonia absorbent recirculation pump (13), ammonolysis product recycling can (14), degassing film cleaning system (15) And system pipeline valve (16), the regenerative wastewater collecting pit (1) are equipped with the storage being connected with regenerative wastewater collecting pit (1) The positive resin regenerating tank (1111) and condensate polishing treatment alkali storage tank (1113) for the waste water that regeneration and displacement generate, the regenerated Water collecting pit (1) further includes the first pH detectors (1112) for detecting pH value of waste water in regenerative wastewater collecting pit (1), the regeneration Wastewater collection pond blender (3) setting is in regenerative wastewater collecting pit (1), the regenerative wastewater collecting pit (1) and regenerative wastewater Delivery pump (2) is connected, and the regenerative wastewater delivery pump (2) is connected with the quartz filter (5) for preventing impurity from entering system, institute It states quartz filter (5) with the accurate filter (6) of protection degassing film device (8) safety to be connected, the accurate filter (6) It is connected with the heat exchanger (7) of control regenerative wastewater temperature, the heat exchanger (7) is connected with degassing film device (8), the degassing film Device (8) include several allow gases by without allow liquid by membrane separator (81), the degassing film device (8) side for penetrating gas is additionally provided with acid adding pipe (82), the degassing film device (8) and condensed water precision processing system neutralization pond (9) it is connected, is equipped in detection condensed water precision processing system neutralization pond (9) and gives up in the condensed water precision processing system neutralization pond (9) 2nd pH detectors (91) of water pH value, the condensed water precision processing system neutralization pond (9) and the ammonia for storing recovery product Product recycling tank (14) is connected, and the ammonolysis product recycling can (14) is connected with ammonia absorption cycle tank (12), the ammonia absorption cycle Tank (12) is connected with acid storage tank (10), and sour metering pump (11) is equipped between the ammonia absorption cycle tank (12) and acid storage tank (10), The acid storage tank (10), sour metering pump (11), ammonia absorption cycle tank (12) cooperates, and regulation and control ammonolysis product recycling can (14) is interior to return The concentration of product is received, the ammonolysis product recycling can (14) is also connected with the ammonia absorbent recirculation pump (13) for exporting recovery product.
2. a kind of condensate polishing treatment regenerative wastewater ammonia recovery system as described in claim 1, it is characterised in that:The heat exchange The heating agent of device (7) is steam or hot water, and the water outlet of the heat exchanger (7) is equipped with temperature detection inductor (71), the heat exchange Device (7), which is equipped with alternative heat exchanger (7), makes the bypass (72) of system normal operation.
3. a kind of condensate polishing treatment regenerative wastewater ammonia recovery system as described in claim 1, it is characterised in that:The degassing Film device (8) is connected with the degassing film cleaning system (15) for cleaning degassing film device (8).
4. a kind of condensate polishing treatment regenerative wastewater ammonia recovery system as described in claim 1, it is characterised in that:The condensation It is additionally provided with neutralization pond acid adding pipe (92), neutralization pond drainpipe (93), neutralization pond in crystal's processing system neutralization pond (9) and adds alkali pipe (94) and neutralization pond blender (95).
5. a kind of condensate polishing treatment regenerative wastewater ammonia recovery system as described in claim 1, it is characterised in that:The degassing The quantity of film device (8) be one and more than one, between each degassing film device (8) be serial or parallel connection or connection in series-parallel knot The connection type of conjunction, the quantity of the membrane separator (81) be one and more than one.
6. a kind of condensate polishing treatment regenerative wastewater ammonia recovery system as described in claim 1, it is characterised in that:The regeneration Waste water delivery pump (2) is equipped with the first delivery pipe (21) of controllable switch, and the regenerative wastewater delivery pump (2) is defeated by first Pipe (21) is sent to be connected with condensed water precision processing system neutralization pond (9), the filter backwash pump (4) is equipped with controllable switch The second delivery pipe (41), filter backwash pump (4) passes through the second delivery pipe (41) and neutralized with condensed water precision processing system Pond (9) is connected.
7. a kind of condensate polishing treatment regenerative wastewater ammonia recovery system as described in claim 1, it is characterised in that:The system The quantity of pipeline valve (16) is two and two or more.
8. a kind of condensate polishing treatment regenerative wastewater ammonia recovery system as described in claim 1, it is characterised in that:The acid storage It is hydrochloric acid or sulfuric acid in tank (10).
CN201721606991.3U 2017-11-27 2017-11-27 A kind of condensate polishing treatment regenerative wastewater ammonia recovery system Withdrawn - After Issue CN207619159U (en)

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Application Number Priority Date Filing Date Title
CN201721606991.3U CN207619159U (en) 2017-11-27 2017-11-27 A kind of condensate polishing treatment regenerative wastewater ammonia recovery system

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107857395A (en) * 2017-11-27 2018-03-30 浙江海盐力源环保科技股份有限公司 A kind of condensate polishing treatment regenerative wastewater ammonia recovery system
CN113880287A (en) * 2021-11-19 2022-01-04 西安热工研究院有限公司 Ammonia nitrogen recovery device and method for resin regeneration wastewater of power plant fine treatment system

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107857395A (en) * 2017-11-27 2018-03-30 浙江海盐力源环保科技股份有限公司 A kind of condensate polishing treatment regenerative wastewater ammonia recovery system
CN107857395B (en) * 2017-11-27 2024-01-09 浙江海盐力源环保科技股份有限公司 Condensate fine treatment regeneration wastewater ammonia recovery system
CN113880287A (en) * 2021-11-19 2022-01-04 西安热工研究院有限公司 Ammonia nitrogen recovery device and method for resin regeneration wastewater of power plant fine treatment system
CN113880287B (en) * 2021-11-19 2024-04-26 西安热工研究院有限公司 Ammonia nitrogen recovery device and method for resin regeneration wastewater of fine treatment system of power plant

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