CN2076099U - Sewage treatment apparatus by electrochemical method - Google Patents

Sewage treatment apparatus by electrochemical method Download PDF

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Publication number
CN2076099U
CN2076099U CN 90202351 CN90202351U CN2076099U CN 2076099 U CN2076099 U CN 2076099U CN 90202351 CN90202351 CN 90202351 CN 90202351 U CN90202351 U CN 90202351U CN 2076099 U CN2076099 U CN 2076099U
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CN
China
Prior art keywords
electrooxidation
pipe
electrode plate
electrocoagulation
water inlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN 90202351
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Chinese (zh)
Inventor
刘又新
孙耀庭
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Planning And Design Institute Of Aeronautical Industry Ministry Of Aeronautics And Astronautics
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Planning And Design Institute Of Aeronautical Industry Ministry Of Aeronautics And Astronautics
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Application filed by Planning And Design Institute Of Aeronautical Industry Ministry Of Aeronautics And Astronautics filed Critical Planning And Design Institute Of Aeronautical Industry Ministry Of Aeronautics And Astronautics
Priority to CN 90202351 priority Critical patent/CN2076099U/en
Publication of CN2076099U publication Critical patent/CN2076099U/en
Expired - Lifetime legal-status Critical Current

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Abstract

The utility model relates to a sewage treatment apparatus by electrochemical method, composed of an electrooxidation part and an electrocoagulation part. In the electrooxidation part, the electric current density of bipolar electrodes which are composed of insoluble mesh-shaped polar plates and chargeable particles can reach 10-20 A/dm +[2]. In the electrocoagulation part, iron and aluminium are used as soluble electrodes which can generate coagulant, such as ferric hydroxide and aluminum hydroxide for next processing. The utility model can achieve the purpose of purifying the wastewater which is produced by printing and electroplating with high efficiency and energy saving process. No medicament need to be added, so a medicament casting system is saved, and the salt content of the water can not be increased. The utility model is favorable for recycling water.

Description

Sewage treatment apparatus by electrochemical method
The utility model relates to the device that a kind of electrochemical process that is specially adapted to processing waste water containing chrome and dyeing waste water is disposed of sewage.
Existing electrochemical process mainly is with electrolytic process processing waste water containing chrome and dyeing waste water device, is to adopt electrolysis to add dispensing and the electrocoagulation treatment and purification sewage that forms, does not carry out electrooxidation before electrolysis treatment.
At home, have and before electrolysis, add iron trichloride as electrolytic coagulant, and to the electrolysis water outlet with lime deionized and decoloured (CN85106939A), this method needs to increase administration system and the overhead charges except dispensing, its pole plate all adopts the solubility battery lead plate, and the butted line battery lead plate also must equally regularly replace with intermediate electrode plate.
The device (CN86203520U) that replaces low-voltage dc power supply electrolysis treatment dyeing and printing sewage with the high-voltage pulse electrolysis is arranged, and its pole plate all adopts the solubility battery lead plate, and the butted line battery lead plate also must equally regularly replace with intermediate electrode plate.
Adopted monopolar cell (CN85109756A) in the U.S., every pole plate all needs wiring, more tired fiber crops when changing pole plate.
Adopted bipolar cell in Japan, the parts of this equipment are many, structure, processed complex (CN86107225A).
Above prior art is not all carried out the electrooxidation stage and is directly carried out electrolysis treatment sewage.
The purpose of this utility model is to provide a kind of electrochemical process device of disposing of sewage, and is made up of electrooxidation and electrocoagulation two portions.Sewage carries out electrocoagulation again through electrooxidation earlier.
In the electrooxidation part, by the bipolar electrode of the many electrifiable granulometric composition between insoluble netted pole plate and pole plate, current density reaches 10~20 amperes/decimeter 2, direct decomposing harmful substances destroys the molecular bonding structure of dirt in the sewage, reaches the purpose of purifying waste water, and has improved processing efficiency, has saved electric energy.The rear portion of this device is to be link electrode with insoluble mesh electrode, is one or more groups electrode plate groups of target with solubility electrode (its electrode materials can select for use iron or aluminium or iron to add aluminium), and current density is 0.4~0.5 ampere/decimeter 2, because iron and aluminum ion that anode dissolution produces generate extremely strong coagulating agent, can not add other chemical agent and can carry out coagulation sewage, reach the purpose of purifying waste water through equipment for separating liquid from solid again,, also can not increase the saltiness that purifies back water owing to do not add other chemical agent.
Below in conjunction with accompanying drawing the utility model is further described.
Accompanying drawing is a schematic perspective view of the present utility model.
The feature of electrooxidation part is by water inlet manifold (1), water inlet control valve door (2), diffuser tube (3), ring flange (4), insoluble mesh electrode plate (5), terminal stud (6), ring flange (7), bolt (8), plexi-glass tubular (9), electrifiable granular filler (10), reducing pipe (11), manifold trunk (12) is formed.Water inlet manifold (1) welds with the lower end of diffuser tube (8) or is bonding, and diffuser tube (3) forms with plastic plate Volume weldering, is down taper, and the upper end has ring flange (4) to be connected with bolt with the ring flange of plexi-glass tubular (9) lower end.It is a plurality of that two ends have the plexi-glass tubular (9) of ring flange, all connects with bolt.Electrifiable granular filler (10) is housed in each section plexi-glass tubular.Reducing pipe (11) is positive taper, forms with plastic plate Volume weldering, and the lower end has ring flange (7) to be connected with bolt with plexi-glass tubular ring flange topmost.Be equipped with the insoluble mesh electrode plate of seal washer and garden shape (5) between every group of ring flange.The upper end of reducing pipe (11) and manifold trunk (12) welding or bonding.The positive and negative supply lead of insoluble mesh electrode plate and transmission line joins.After sewage enters this device, by just (+), negative (-) electrode are connected direct supply, sewage will carry out oxidation under the effect of positive and negative electrode, built-in granular filler, be subjected to drainage flow from bottom to top and be suspended state, each particle all is subjected to the electrode effect and forms the electrified body with positive and negative electrode, under big density galvanic action, battery lead plate and particle all carry out electrooxidation to sewage, thereby have improved the oxidation efficiency to sewage.
Electrocoagulation partly comprises water inlet pipe (21), the cell body of Chang Kaiing (20) above, intermediate electrode plate (22), wiring mesh electrode plate (27), (28), catchment tray (23), total rising pipe (24), compressed air inlet pipe (25), scum pipe (26) is formed.The water inlet pipe (21) of electrocoagulation part is connected with the manifold trunk (12) of electrooxidation part, and water inlet pipe (21) is connected with the preceding bottom of cell body (20).The rectangular parallelepiped that opens wide above cell body (20) is, be equipped with in the groove be parallel to each other and with groove bottom and long trough wall surface vertical rectangular metal (iron or aluminium) plate (being intermediate electrode plate (22)) and the insoluble rectangle mesh electrode of wiring plate (negative plate (27) wherein simultaneously, positive plate (28)), position relation between intermediate electrode plate and the link electrode plate is that polylith intermediate electrode plate (22) is housed between link electrode plate (27) or (28).The positive-negative power line can directly be welded in the upper end of link electrode plate, and also available terminal stud links to each other.With the relative water side of cell body (20) feed-water end, be provided with catchment tray (23), current enter total rising pipe (24) by catchment tray (23).Be provided with scum pipe (26) with the eliminating sediment in cell body (20) bottom, and the bottom is furnished with the porous compressed air pipe in cell body, to reach with the uniform purpose of pneumatic blending.
Electrooxidation part and electrocoagulation part can be contained on the same chassis, constitute a cover sewage disposal device, also can not establish the chassis as shown in the figure.After sewage enters this part, effect through bipolar electrode plate (one or more groups), make sewage further be subjected to oxidation, anode (iron or aluminium) is dissolved in the water simultaneously, form metal (iron or aluminium) ion, generate good coagulating agent, do the solid-liquid separation processing Zong can enter next step through catchment tray, rising pipe, thereby sewage is purified with sewage.Solid-liquid separation can be with the also available sedimentation and filtration of air-float filtration.In the electrocoagulation device, be provided with the pressurized air stirring pipe, can regularly stir, keep the activation of electrode cleaning, improve purification efficiency, the bottom is provided with scum pipe, but routine cleaning purifies this device.
In the electrooxidation part, adopted insoluble netted pole plate and granuloplastic bipolar electrode, made the current density of passing through reach 10~20 amperes/decimeter 2Thereby, improve oxidation efficiency.

Claims (5)

1, a kind of electrochemistry waste disposal plant of partly forming by electrocoagulation part and electrooxidation, it is characterized in that by water inlet pipe (21), cell body (20), intermediate electrode plate (22), wiring mesh electrode plate (27), (28), catchment tray (23), total rising pipe (24), compressed air inlet pipe (25), before the electrocoagulation part that scum pipe (26) is formed, connect one by water inlet manifold (1), water inlet control valve door (2), diffuser tube (3), ring flange (4), insoluble mesh electrode plate (5), terminal stud (6), ring flange (7), bolt (8), plexi-glass tubular (9), electrifiable granular filler (10), reducing pipe (11), the electrooxidation part that manifold trunk (12) is formed.
2, waste disposal plant according to claim 1 is characterized in that the electrooxidation part by water inlet manifold, the water inlet control valve door, diffuser tube, ring flange, insoluble mesh electrode plate, terminal stud, ring flange, bolt, plexi-glass tubular, reducing pipe, collection pipe is formed, and adopts electrifiable granular filler between pole plate, after the granular filler energising, current density is at 10~20 amperes/decimeter 2
3, waste disposal plant according to claim 1 is characterized in that electrocoagulation link electrode plate partly, adopts welding process to be connected with transmission line, also can be connected with transmission line by terminal stud.
4, waste disposal plant according to claim 2 is characterized in that electrooxidation plexi-glass tubular (9) partly, can adopt plastics tubing or Glass Steel Tube.
5, waste disposal plant according to claim 3 is characterized in that the electrocoagulation part, the cell body of Chang Kaiing (20) above, and can select hard polyvinyl chloride plate or glass epoxy or steel lining plastic plate for use is material.
CN 90202351 1990-03-09 1990-03-09 Sewage treatment apparatus by electrochemical method Expired - Lifetime CN2076099U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 90202351 CN2076099U (en) 1990-03-09 1990-03-09 Sewage treatment apparatus by electrochemical method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 90202351 CN2076099U (en) 1990-03-09 1990-03-09 Sewage treatment apparatus by electrochemical method

Publications (1)

Publication Number Publication Date
CN2076099U true CN2076099U (en) 1991-05-01

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Application Number Title Priority Date Filing Date
CN 90202351 Expired - Lifetime CN2076099U (en) 1990-03-09 1990-03-09 Sewage treatment apparatus by electrochemical method

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CN (1) CN2076099U (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101367571B (en) * 2007-08-17 2011-01-19 财团法人工业技术研究院 Electric coagulation reactor and process for treating waste water
CN102153220A (en) * 2011-02-21 2011-08-17 中国科学院生态环境研究中心 Method for treating and recycling polishing waste water of plated part in electroplating industry
CN102531242A (en) * 2012-02-16 2012-07-04 江苏科润环境工程有限公司 Electric flocculating method for treating sewage
CN102616897A (en) * 2012-03-23 2012-08-01 嘉兴锦浩环保科技有限公司 Electric flocculation device
CN102642897A (en) * 2012-05-09 2012-08-22 中国水电顾问集团中南勘测设计研究院 Electrochemical treatment equipment for treating heavy metal wastewater
CN101980967B (en) * 2007-05-31 2012-09-05 恩雅爱尔兰有限公司 An electrocoagulation cell
WO2012136064A1 (en) * 2011-04-08 2012-10-11 General Electric Company Method for purifying aqueous stream, system and process for oil recovery and process for recycling polymer flood
CN102730804A (en) * 2011-04-08 2012-10-17 通用电气公司 A method for purifying water
CN102781846A (en) * 2009-06-29 2012-11-14 普罗特高公司 Apparatus and method for electrochemical treatment of wastewater
CN104071932A (en) * 2014-07-21 2014-10-01 湖南大学 Treating method and electric flocculation device for Cu-EDTA complex wastewater
CN105229202A (en) * 2013-05-13 2016-01-06 霍加纳斯股份有限公司 Negative electrode, electrochemical cell and uses thereof
CN106006848A (en) * 2016-06-06 2016-10-12 河北工业大学 Treatment method for waste sapphire crystal polishing liquid
CN109553165A (en) * 2017-09-27 2019-04-02 李硕仁 The wastewater treatment equipment of high pressure gas can be passed through
CN109910132A (en) * 2019-03-08 2019-06-21 南京工程学院 The bubble and hole of FRP reinforced concrete improve device and its application method

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101980967B (en) * 2007-05-31 2012-09-05 恩雅爱尔兰有限公司 An electrocoagulation cell
CN101367571B (en) * 2007-08-17 2011-01-19 财团法人工业技术研究院 Electric coagulation reactor and process for treating waste water
CN102781846B (en) * 2009-06-29 2015-04-08 普罗特高公司 Apparatus and method for electrochemical treatment of wastewater
CN102781846A (en) * 2009-06-29 2012-11-14 普罗特高公司 Apparatus and method for electrochemical treatment of wastewater
CN102153220A (en) * 2011-02-21 2011-08-17 中国科学院生态环境研究中心 Method for treating and recycling polishing waste water of plated part in electroplating industry
WO2012136064A1 (en) * 2011-04-08 2012-10-11 General Electric Company Method for purifying aqueous stream, system and process for oil recovery and process for recycling polymer flood
CN102730804A (en) * 2011-04-08 2012-10-17 通用电气公司 A method for purifying water
CN102531242A (en) * 2012-02-16 2012-07-04 江苏科润环境工程有限公司 Electric flocculating method for treating sewage
CN102616897A (en) * 2012-03-23 2012-08-01 嘉兴锦浩环保科技有限公司 Electric flocculation device
CN102616897B (en) * 2012-03-23 2013-10-30 嘉兴锦浩环保科技有限公司 Electric flocculation device
CN102642897A (en) * 2012-05-09 2012-08-22 中国水电顾问集团中南勘测设计研究院 Electrochemical treatment equipment for treating heavy metal wastewater
AU2014267490B2 (en) * 2013-05-13 2018-10-18 Hoganas Ab (Publ) Cathode, electrochemical cell and its use
CN105229202A (en) * 2013-05-13 2016-01-06 霍加纳斯股份有限公司 Negative electrode, electrochemical cell and uses thereof
CN105229202B (en) * 2013-05-13 2019-03-15 霍加纳斯股份有限公司 Cathode, electrochemical cell and application thereof
US10676378B2 (en) 2013-05-13 2020-06-09 Höganäs Ab (Publ) Cathode, electrochemical cell and its use
CN104071932B (en) * 2014-07-21 2016-04-27 湖南大学 A kind for the treatment of process of Cu-EDTA complexing waste water and electric flocculation plant
CN104071932A (en) * 2014-07-21 2014-10-01 湖南大学 Treating method and electric flocculation device for Cu-EDTA complex wastewater
CN106006848A (en) * 2016-06-06 2016-10-12 河北工业大学 Treatment method for waste sapphire crystal polishing liquid
CN106006848B (en) * 2016-06-06 2019-04-12 河北工业大学 The processing method of sapphire crystal polishing waste liquid
CN109553165A (en) * 2017-09-27 2019-04-02 李硕仁 The wastewater treatment equipment of high pressure gas can be passed through
CN109910132A (en) * 2019-03-08 2019-06-21 南京工程学院 The bubble and hole of FRP reinforced concrete improve device and its application method

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