CN207468698U - A kind of exclusion device of electrolytic manganese dioxide - Google Patents
A kind of exclusion device of electrolytic manganese dioxide Download PDFInfo
- Publication number
- CN207468698U CN207468698U CN201721268240.5U CN201721268240U CN207468698U CN 207468698 U CN207468698 U CN 207468698U CN 201721268240 U CN201721268240 U CN 201721268240U CN 207468698 U CN207468698 U CN 207468698U
- Authority
- CN
- China
- Prior art keywords
- container
- inner shaft
- manganese dioxide
- shaft
- outer shaft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 230000007717 exclusion Effects 0.000 title claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 17
- 239000000706 filtrate Substances 0.000 claims abstract description 12
- 238000001914 filtration Methods 0.000 claims abstract description 11
- 229940099596 manganese sulfate Drugs 0.000 claims abstract description 7
- 235000007079 manganese sulphate Nutrition 0.000 claims abstract description 7
- 239000011702 manganese sulphate Substances 0.000 claims abstract description 7
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims abstract description 7
- 230000002093 peripheral effect Effects 0.000 claims abstract description 4
- 238000000746 purification Methods 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 238000001556 precipitation Methods 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 230000000717 retained effect Effects 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 15
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 13
- 239000011572 manganese Substances 0.000 description 12
- 229910052748 manganese Inorganic materials 0.000 description 11
- 239000012535 impurity Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 235000006748 manganese carbonate Nutrition 0.000 description 2
- 239000011656 manganese carbonate Substances 0.000 description 2
- 229940093474 manganese carbonate Drugs 0.000 description 2
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 2
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 2
- GSFSVEDCYBDIGW-UHFFFAOYSA-N 2-(1,3-benzothiazol-2-yl)-6-chlorophenol Chemical compound OC1=C(Cl)C=CC=C1C1=NC2=CC=CC=C2S1 GSFSVEDCYBDIGW-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- CJDPJFRMHVXWPT-UHFFFAOYSA-N barium sulfide Chemical compound [S-2].[Ba+2] CJDPJFRMHVXWPT-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
The utility model is related to a kind of exclusion devices of electrolytic manganese dioxide, container including holding manganese sulfate solution, rotatable hollow inner shaft is installed across its bottom in the container, the interior outer shaft sleeve is equipped with the outer shaft being located in container that can be rotated with it, outer shaft peripheral wall is provided with the stirring rod of solution that can be in stirring container, it can make one section exposing of the inner shaft close to container bottom by being lifted up outer shaft, solution in container is filtered by one section of inner shaft of the exposing, filtrate after filtering flows into the clarifier-tank being arranged on the downside of the container, the inner shaft top is provided with the funnel connected with inner shaft inner cavity, the cleaner reacted with filtrate can be conveyed into the clarifier-tank from the funnel through inner shaft inner cavity.The utility model is filtered solution using the inside and outside axis that stirring rod is driven to rotate, and reaction generation precipitation in container is made to be retained in container, stirring, filtering is achieved that without other ancillary equipments, substantially increases production efficiency.
Description
Technical field
The utility model is related to a kind of exclusion devices of electrolytic manganese dioxide.
Background technology
Mainly include manganese oxide ore and manganese carbonate ore with industrial application value in natural manganese ore, according to the taste of manganese ore
With the difference of impurity content, two kinds of processes of general use internal and international at present carry out deep processing processing to it：When pair
In objectionable impurities（Such as phosphorus, sulphur）Low high-grade ore can be directly using pyrometallurgical smelting process production Mn series alloy product or as battery
Manganese powder；Second is that for most of manganese carbonate and partial oxidation manganese ore, the general serial salt using hydrometallurgical technology production manganese
Product.However, with the exploitation year by year to manganese resource, GOOD TASTE, low impurity ANOMALY IN FINE QUALITY MANGANESE DEPOSITS increasingly depleted, therefore, for
The research and development and utilization for the complicated manganese ore that manganese content is low, impurity content is high, which become, improves domestic manganese ore deep processing enterprise in the world
The key of the market competitiveness also largely determines that can manganese ore processing industry sustainable development.Electricity is prepared existing
During solving manganese dioxide, impurity and purification need to be carried out to intermediate the product sulfur acid manganese solution, and current manganese sulfate electrolyte
Clarification time is long, influences production efficiency.
Utility model content
For above-mentioned technical problem, the utility model provides a kind of removal of impurities for the electrolytic manganese dioxide for improving production efficiency
Device.
Technical solution is used by the utility model solves above-mentioned technical problem：A kind of removal of impurities dress of electrolytic manganese dioxide
It puts, the container including holding manganese sulfate solution is equipped with rotatable hollow inner shaft, the inner shaft in the container across its bottom
Outer to be arranged with the outer shaft being located in container that rotated with it, outer shaft peripheral wall is provided with the stirring of solution that can be in stirring container
Stick, can make that solution of the inner shaft in one section of container bottom exposing, container passes through the exposing by being lifted up outer shaft one
Section inner shaft is filtered, and the filtrate after filtering flows into the clarifier-tank being arranged on the downside of the container, and the inner shaft top is provided with
The funnel connected with inner shaft inner cavity can convey the removal of impurities reacted with filtrate from the funnel through inner shaft inner cavity into the clarifier-tank
Agent.
Preferably, offer opening connect with its inner cavity in the one section of inner shaft exposed, be open on covered with strainer, by
Filtrate after the strainer filtering flows into the clarifier-tank from inner cavity,
Preferably, the inside and outside axis is connected by flat key.
Preferably, the inner shaft is fixed with the flat key close to container bottom end, the outer shaft inner wall is from its bottom end end
It is extended with keyway upwardly, the flat key can be embedded in keyway.
Preferably, the outer shaft top is provided with carrying handle.
Preferably, the stirring slurry rotated with the inner shaft is equipped in the clarifier-tank.
Preferably, the clarifier-tank bottom is provided with the seal cover board of flexible connection, filter plate is provided on cover board.
As can be known from the above technical solutions, the utility model carried out solution using the inside and outside axis that stirring rod is driven to rotate
Filter makes reaction generation precipitation in container be retained in container, is achieved that stirring, filtering without other ancillary equipments, significantly
Improve production efficiency.
Description of the drawings
Fig. 1 is the structure diagram of the preferred embodiment of the utility model.
Specific embodiment
The utility model is discussed in detail with reference to Fig. 1, this utility model illustrative examples and illustrate to use
To explain the utility model, but be not intended to limit the scope of the present invention.
A kind of exclusion device of electrolytic manganese dioxide, the container 1 including holding manganese sulfate solution pass through it in the container
Bottom is equipped with rotatable hollow inner shaft 2, which is equipped with the outer shaft 3 being located in container that can be rotated with it, outer shaft
Peripheral wall is provided with the stirring rod 4 of solution that can be in stirring container, can make inner shaft close to container bottom by being lifted up outer shaft
One section is exposed, and the solution in container is filtered by one section of inner shaft of the exposing, and the filtrate inflow after filtering is arranged on described
Clarifier-tank 91 on the downside of container, the inner shaft top is provided with the funnel 93 connected with inner shaft inner cavity, from the funnel through in inner shaft
Chamber can convey the cleaner reacted with filtrate, cleaner such as Sodium Dimethyldithiocarbamate etc. into the clarifier-tank, so as to make filtrate beautiful with good fortune
Sodium reaction generation precipitation, removes impurity, realizes purification.Stirring and filtering are not only realized by inside and outside shaft simultaneously as a result,
Its is simple in structure, efficient；And can continuously realize that two level cleans, substantially increase clean-up effect.
Specifically, the opening 5 connected with its inner cavity is offered in one section of inner shaft of exposing, covered with strainer 6 in opening,
It is flowed out by the filtrate after the strainer filtering from inner cavity.The agitated reaction generation such as manganese sulfate leachate and barium sulphide is miscellaneous in container
Matter precipitates, and solution can enter inner shaft inner cavity by strainer, and precipitation is then retained in container, realizes the purpose of purification.
In implementation process, the inside and outside axis is connected by flat key 7, and outer shaft rotates simultaneously in realization；Specifically described
Inner shaft is fixed with the flat key close to container bottom end, and the outer shaft inner wall has upwardly extended keyway 8, and institute from its bottom end end face
It states outer shaft top and is provided with carrying handle 9.When mounted, it holds handle to be inserted in the outer shaft along internal axle axial, makes flat key embedding
Enter in keyway；After the completion of stirring, to hold handle and be lifted up outer shaft so that flat key is detached from keyway, while exposes opening, so as to
Realize filtering.Precipitation blocks strainer in order to prevent, in filter process, can rotate inner shaft, make precipitation inside using centrifugal force
It is thrown away on the outside of axis, precipitation is avoided to be gathered near strainer.
The stirring slurry 92 rotated with the inner shaft is equipped in implementation process, in the clarifier-tank, it is right in purification process
Mixed solution is stirred.The clarifier-tank bottom is provided with the seal cover board 94 of flexible connection, and filter plate 95 is provided on cover board；
After the completion of the solution reaction in clarifier-tank, seal cover board can be opened, solution is made to be filtered off through filter plates and is precipitated, realizes secondary mistake
It filters out miscellaneous.From the above it can be seen that the utility model can continuously remove the manganese sulfate solution in electrolysis dioxy manganese metal preparation process
Miscellaneous purification can not only improve production efficiency, but also easy to operate simple, at low cost.
The above embodiment is only for illustration of the utility model, and is not the limitation to the utility model, related skill
The those of ordinary skill in art field, can be with various changes can be made in the case where not departing from the spirit and scope of the utility model
And modification, therefore all equivalent technical solutions should also belong to the scope of the utility model.
Claims (7)
1. a kind of exclusion device of electrolytic manganese dioxide, the container including holding manganese sulfate solution, it is characterised in that：In the container
Interior to be equipped with rotatable hollow inner shaft across its bottom, interior outer shaft sleeve is equipped with the outer shaft being located in container that can be rotated with it,
Outer shaft peripheral wall is provided with the stirring rod of solution that can be in stirring container, can make inner shaft close to container bottom by being lifted up outer shaft
One section of exposing, the solution in container is filtered by one section of inner shaft of the exposing, and the filtrate after filtering flows into and is arranged on institute
The clarifier-tank on the downside of container is stated, the inner shaft top is provided with the funnel connected with inner shaft inner cavity, from the funnel through inner shaft inner cavity
The cleaner reacted with filtrate can be conveyed into the clarifier-tank.
2. the exclusion device of electrolytic manganese dioxide according to claim 1, it is characterised in that：It is opened up in the one section of inner shaft exposed
There is an opening connected with its inner cavity, opening is upper covered with strainer, by the filtrate after the strainer filtering from the inner cavity inflow purification
Pond.
3. the exclusion device of electrolytic manganese dioxide according to claim 1, it is characterised in that：The inside and outside axis passes through flat key
Connection.
4. the exclusion device of electrolytic manganese dioxide according to claim 3, it is characterised in that：The inner shaft is close to container bottom end
Place is fixed with the flat key, and outer shaft inner wall has upwardly extended keyway from its bottom end end face, and the flat key can be embedded in keyway.
5. the exclusion device of electrolytic manganese dioxide according to claim 4, it is characterised in that：The outer shaft top, which is provided with, to be carried
Knob handle.
6. the exclusion device of electrolytic manganese dioxide according to claim 1, it is characterised in that：In the clarifier-tank be equipped with
The stirring slurry of the inner shaft rotation.
7. the exclusion device of electrolytic manganese dioxide according to claim 1, it is characterised in that：The clarifier-tank bottom is provided with
The seal cover board of flexible connection is provided with filter plate on cover board.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201721268240.5U CN207468698U (en) | 2017-09-30 | 2017-09-30 | A kind of exclusion device of electrolytic manganese dioxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201721268240.5U CN207468698U (en) | 2017-09-30 | 2017-09-30 | A kind of exclusion device of electrolytic manganese dioxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN207468698U true CN207468698U (en) | 2018-06-08 |
Family
ID=62267395
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201721268240.5U Active CN207468698U (en) | 2017-09-30 | 2017-09-30 | A kind of exclusion device of electrolytic manganese dioxide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN207468698U (en) |
-
2017
- 2017-09-30 CN CN201721268240.5U patent/CN207468698U/en active Active
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240428 Address after: 425200 No. 26, Gongye Avenue, Shuangpai County industrial concentration area, Yongzhou City, Hunan Province Patentee after: Yongzhou Haoli New Material Technology Co.,Ltd. Country or region after: China Address before: 545000 No.4, Chuyang Road, Liuzhou City, Guangxi Zhuang Autonomous Region (Liudong New Area) Patentee before: LIUZHOU KAITONG NEW MATERIAL TECHNOLOGY Co.,Ltd. Country or region before: China |
|
| TR01 | Transfer of patent right |