CN207330633U - A kind of utilization system of high-ammonia nitrogen low C OD waste water - Google Patents

A kind of utilization system of high-ammonia nitrogen low C OD waste water Download PDF

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Publication number
CN207330633U
CN207330633U CN201721013586.0U CN201721013586U CN207330633U CN 207330633 U CN207330633 U CN 207330633U CN 201721013586 U CN201721013586 U CN 201721013586U CN 207330633 U CN207330633 U CN 207330633U
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China
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pipeline
waste water
ammonia nitrogen
water
pipe
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CN201721013586.0U
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Chinese (zh)
Inventor
仲伟伟
李永波
马朝卫
徐东辉
李志勇
段小洛
聂鹏举
李伟华
朱光辉
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Yima Coal Industry Zongneng New Energy Co Ltd
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Yima Coal Industry Zongneng New Energy Co Ltd
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Abstract

The utility model discloses a kind of utilization system of high-ammonia nitrogen low C OD waste water, wherein, coal gasification apparatus process spent water carrys out water pipe connection oil partiting precipitation pool, oil partiting precipitation pool connects coagulation floatation, coagulation floatation connection comprehensive adjustment pond, comprehensive adjustment pond connects batch-type IMC bioreactors, batch-type IMC bioreactors connect flocculation sedimentation tank, flocculation sedimentation tank connects ozone contact and buffer pool, ozone contact and buffer pool connection BAF biological aerated filter, BAF biological aerated filter is connected back to sink, reuse sink connects more medium filter, more medium filter connects circulation.The utility model reduces sewage discharge, reaches industrial wastewater comprehensive utilization, drops low water usage cost, improves the purpose of industrial water efficiency.

Description

A kind of utilization system of high-ammonia nitrogen low C OD waste water
Technical field
Industrial wastewater multistep treatment utilization system is the utility model is related to, is specially a kind of high-ammonia nitrogen low C OD waste water Utilization system.
Background technology
China's gross amount of water resources enriches, but due to populous, year water only has 2710m3 per capita, about the world per capita The 1/4 of year water, per capita water resource deficiency.In national 600 Duo Ge organizational systems cities, there are nearly 400 urban water shortages, wherein more than 130 A serious water shortage.Along with water resource spatial and temporal distributions are uneven, the development of China's economy and society is seriously constrained.Water resource can Sustainable utilization, reasonable disposition water resource, improves water utilization rate, establishes a water-saving society, it appears particularly urgent and important.
The major reason for causing China's water resource deficiency is that water-use efficiency is low and quantity of wastewater effluent is big.China's industrial water Water withdrawal account for more than the 20% of national water withdrawal, national about 62,000,000,000 m3 of stain disease total emission volumn, wherein industrial wastewater accounts for 66%.Statistics shows that China's ten thousand yuan of value added water consumptions of industry are 5 ~ 10 times of developed country, and the recycling rate of waterused of water is 50%, and developed country, up to 85%, this also shows that China's water resource Land use systems are extensive, and water-use efficiency is low.
U-GAS coal gasification waste waters be using the high concentrated organic wastewater produced in U-GAS gasification technology coal course of gas, Water-quality constituents is complicated, and pollutant concentration is high.Coal dust, salinity and positive phosphorus, total phosphorus content are higher in waste water, and containing a small amount of oils, The poisonous and harmful substance such as cyanide and a large amount of ammonia nitrogens, its feature are high-ammonia nitrogen low C OD, belong to more intractable and recycle highly concentrated Spend organic industrial sewage.Processing and recycling to coal gasification waste water, merely by physics, physical chemistry, chemical method into Row processing, it is difficult to achieve the goal, generally require the processing system by being made of several method, can be only achieved recycling and require Degree.
Therefore a kind of simple in structure, efficient process, and the less U-GAS coal gasification waste waters processing system of environmental pollution are provided System, excavates the potentiality that Industrial Wastewater Treatment recycles, and improves industrial water efficiency, gives industrial wastewater as new water resource Exploitation, has been a urgent problem needed to be solved.
The content of the invention
In order to overcome above-mentioned deficiency of the prior art, the utility model provides one kind and is directed to U-GAS coal gasification courses The waste water of generation, high ammonia nitrogen, low COD coal gas wastes can be handled to meeting that national standard discharges, and reach and recycle bar The coal gasification waste water treatment and comprehensive utilization system of part.
What the purpose of this utility model was realized in:
A kind of utilization system of high-ammonia nitrogen low C OD waste water, including carry out water pipe 1 with coal gasification apparatus process spent water and connect The oil partiting precipitation pool 2 connect, oil partiting precipitation pool 2 connect coagulation floatation 3 by pipeline;Coagulation floatation 3 is connected by pipeline Comprehensive adjustment pond 6 is connect, comprehensive adjustment pond 6 connects batch-type IMC bioreactors 7, batch-type IMC biological respinses by pipeline Device 7 connects flocculation sedimentation tank 10 by pipeline, and flocculation sedimentation tank 10 connects ozone contact and buffer pool 13 by pipeline, smelly Oxygen contacts and buffer pool 13 connects BAF biological aerated filter 15 by pipeline, and BAF biological aerated filter 15 is connected by pipeline Take back and use sink 16, reuse sink 16 connects more medium filter 18 by pipeline, and more medium filter 18 is connected by pipeline Connect circulation 19;
It is provided with that aluminium polychloride adds pipe 4 and polyacrylamide adds pipe 5 on the coagulation floatation 3;
It is provided with that methanol adds pipe 8 and lye adds pipe 9 on the batch-type IMC bioreactors 7;
It is provided with that aluminium polychloride adds pipe 11 and polyacrylamide adds pipe 12 on the flocculation sedimentation tank 10;
The ozone contact and buffer pool 13 are connected with ozone generator 14 at the same time.
Be connected with sodium hypochlorite adds pipe 17 to the reuse sink 16 at the same time.
Positive beneficial effect:The utility model, can be by U-GAS coal gas chemical industry by various physicochemical treatment unit organic assemblings The high ammonia nitrogen of skill output, low COD wastewater treatments the heel row matter that discharges water reach GB8978-1996《Integrated wastewater discharge standard》In two classes The primary standard of pollutant, and comprehensively utilized, sewage discharge is reduced, drops low water usage cost, reduces water resource waste, is improved Industrial water efficiency, achievees the purpose that environmental protection, and society, environmental benefit are notable, and technology occupies domestic pharmaceutical industry industry advanced level.
Brief description of the drawings
Fig. 1 is the system block diagram of the utility model;
It is in figure:Coal gasification apparatus process spent water comes water pipe 1, oil partiting precipitation pool 2, coagulation floatation 3, polyaluminium Aluminium adds pipe 4, polyacrylamide adds pipe 5, comprehensive adjustment pond 6, batch-type IMC bioreactors 7, methanol add pipe 8, Lye add pipe 9, flocculation sedimentation tank 10, aluminium polychloride add pipe 11, polyacrylamide adds pipe 12, ozone contact and Buffer pool 13, ozone generator 14, BAF biological aerated filter 15, reuse sink 16, sodium hypochlorite add pipe 17, more Jie Mass filter 18, circulation 19.
Embodiment
As shown in Figure 1, a kind of utilization system of high-ammonia nitrogen low C OD waste water, including with coal gasification apparatus process spent water Carry out the oil partiting precipitation pool 2 of the connection of water pipe 1, oil partiting precipitation pool 2 connects coagulation floatation 3 by pipeline;Coagulation floatation 3 Comprehensive adjustment pond 6 is connected by pipeline, comprehensive adjustment pond 6 connects batch-type IMC bioreactors 7, batch-type by pipeline IMC bioreactors 7 connect flocculation sedimentation tank 10 by pipeline, and flocculation sedimentation tank 10 connects ozone contact by pipeline and delays Rush pond 13, ozone contact and buffer pool 13 and BAF biological aerated filter 15, BAF biological aerated filter 15 are connected by pipeline Connected back to by pipeline and more medium filter 18, more medium filter 18 are connected by pipeline with sink 16, reuse sink 16 Circulation 19 is connected by pipeline;
It is provided with that aluminium polychloride adds pipe 4 and polyacrylamide adds pipe 5 on the coagulation floatation 3;
It is provided with that methanol adds pipe 8 and lye adds pipe 9 on the batch-type IMC bioreactors 7;
It is provided with that aluminium polychloride adds pipe 11 and polyacrylamide adds pipe 12 on the flocculation sedimentation tank 10;
The ozone contact and buffer pool 13 are connected with ozone generator 14 at the same time.
Be connected with sodium hypochlorite adds pipe 17 to the reuse sink 16 at the same time.
Embodiment 1
A kind of utilization system of high-ammonia nitrogen low C OD waste water, including following process:Coal gas waste coagulation air-float process, IMC biochemical treatments process, ozone contact process, BAF aeration biochemical treatment process.
The coal gas waste coagulation air-float process is:Technique waste water from U-GAS gasification process is high ammonia nitrogen, low COD waste water, and contain a large amount of coal dusts and a small amount of oils, the sewage of cyanide, oil separator sedimentation basin is initially entered through primary deposition Afterwards, into coagulation air-float process.The main function of coagulation air-float is that polyacrylamide and polyaluminium are added in technique waste water Aluminium, makes coal dust in technique waste water and oily substance agglomerated together by the means such as stirring, being aerated, and acts on and carrying out through air supporting Remove, so that the operation of coal dust and oily substance to subsequent biochemical treatment process mitigated in waste water impacts.
The IMC biochemical treatment processes are:Technique waste water after coagulation air-float by regulating reservoir by technique waste water PH and Water temperature is adjusted to claimed range, and technique waste water enters main body treatment process --- batch-type sewage disposal IMC biochemical reactors. Sewage removes the pollutants such as organic matter in water removal, ammonia nitrogen, total phosphorus to greatest extent therebetween by aerobic, anoxic alternating action. This method concentrates the processes such as water inlet, aeration, stirring, precipitation, draining in one reaction pool, and periodically running is completed to Waste The pretreatment of water.
The ozone contact process is:Technique waste water enters after the processing of batch-type sewage disposal IMC biochemical reactors After flocculation sedimentation tank realizes separation of solid and liquid, water outlet enters ozone contact process.The main function of ozone contact utilizes ozone Macromolecular long-chain organic matter in technique waste water is decomposed into small molecule short chain organic matter by oxidation, and it is biochemical to improve technique waste water Property, and with ozone sterilization effect, remove waste water in bacterium and microorganism, with prevent caused bacterium in waste water recycling, Equipment corrosion, damage caused by microbial growth.Ozone contact process has organic matter in certain removal ability, but main work With being to improve the biodegradability of technique waste water and remove the bacterium and microorganism in technique waste water, improving follow-up BAF with this is aerated Biochemical treatment process treatment effect.
The BAF aeration biochemicals treatment process is:Technique waste water is promoted to BAF aeration and biologicals after ozone contact, by pump Filter tank.In BAF biological aerated filter, technique waste water is existed by repeating aeration operation in reactor using the biomembrane in pond During constantly being contacted with technique waste water, the organic matter in one side adsorption and oxidation sewage, on the other hand retains in sewage and hangs Float, completes the decomposition to Waste Organic substance in water and denitrogenation dephosphorizing process, realizes the final comprehensive utilization of technique waste water.
The utility model, can be by the high ammonia of U-GAS coal gasifying process outputs by various physicochemical treatment unit organic assemblings Nitrogen, low COD wastewater treatments the heel row matter that discharges water reach GB8978-1996《Integrated wastewater discharge standard》In two pollutants level-one Standard, and comprehensively utilized, sewage discharge is reduced, drops low water usage cost, reduces water resource waste, improves industrial water effect Rate, achievees the purpose that environmental protection, and society, environmental benefit are notable, and technology occupies domestic pharmaceutical industry industry advanced level.Pass through the system It can ensure the qualified discharge of U-GAS coal gasifying process sewage and offer good condition is further provided, it is related to following Several units:1st, IMC (sequencing batch activated sludge processing system), by repeating to be aerated in single reaction tank, stirring of stopping the supple of gas or steam, sinks Shallow lake and emissions operation, the process of decomposing organic matter (BOD) and ammonia nitrogen removal (NH3-N) is completed using aerobic and anaerobe, Have the characteristics that simple in structure, high treating effect, impact resistance, dephosphorization denitrification effect are good, be particularly suitable for handling trade effluent;2nd, dish Formula jet aerator, is suitable for intermittent aerating, and material corrosion resistance, wearability are preferable, and service life is long, aeration rate is high;3rd, use On the one hand larger molecular organics in waste water are carried out oxygenolysis using ozone, improve giving birth to for organic matter by ozone contact technique The property changed;On the other hand acted on using ozone sterilization, remove bacterium and microorganism in waste water, produced by preventing in waste water recycling Bacterium, equipment corrosion, damage caused by microbial growth;4th, using BAF aeration and biological treatment process, weight in reactor is passed through Multiple aeration operation, using biological oxidation and suspended matter retention two functions completion organic matter decomposes and the process of denitrogenation dephosphorizing, has Easy to operate, the advantages that effluent quality is high;5th, using more medium filter, the content of suspended matter is reduced.
Above example is merely to illustrate the excellent embodiment of selecting of the utility model, but the utility model be not limited to it is above-mentioned Embodiment, in the knowledge that the field those of ordinary skill possesses, within the spirit and principles of the utility model Any modification, equivalent substitute and improvement for being made etc., it should all cover in the claimed technical solution scope of the utility model Within.

Claims (6)

  1. A kind of 1. utilization system of high-ammonia nitrogen low C OD waste water, it is characterised in that:Including coming with coal gasification apparatus process spent water Water pipe(1)The oil partiting precipitation pool of connection(2), oil partiting precipitation pool(2)Coagulation floatation is connected by pipeline(3);Coagulation floatation (3)Comprehensive adjustment pond is connected by pipeline(6), comprehensive adjustment pond(6)Batch-type IMC bioreactors are connected by pipeline(7), Batch-type IMC bioreactors(7)Flocculation sedimentation tank is connected by pipeline(10), flocculation sedimentation tank(10)Connected by pipeline smelly Oxygen contacts and buffer pool(13), ozone contact and buffer pool(13)BAF biological aerated filter is connected by pipeline(15), BAF exposures Gas biofilter(15)Connected back to by pipeline and use sink(16), reuse sink(16)More medium filter is connected by pipeline (18), more medium filter(18)Circulation is connected by pipeline(19).
  2. A kind of 2. utilization system of high-ammonia nitrogen low C OD waste water according to claim 1, it is characterised in that:Described Coagulation floatation(3)On be provided with aluminium polychloride and add pipe(4)Pipe is added with polyacrylamide(5).
  3. A kind of 3. utilization system of high-ammonia nitrogen low C OD waste water according to claim 1, it is characterised in that:Described Batch-type IMC bioreactors(7)On be provided with methanol and add pipe(8)Pipe is added with lye(9).
  4. A kind of 4. utilization system of high-ammonia nitrogen low C OD waste water according to claim 1, it is characterised in that:Described Flocculation sedimentation tank(10)On be provided with aluminium polychloride and add pipe(11)Pipe is added with polyacrylamide(12).
  5. A kind of 5. utilization system of high-ammonia nitrogen low C OD waste water according to claim 1, it is characterised in that:Described Ozone contact and buffer pool(13)It is connected with ozone generator at the same time(14).
  6. A kind of 6. utilization system of high-ammonia nitrogen low C OD waste water according to claim 1, it is characterised in that:Described Reuse sink(16)Being connected with sodium hypochlorite adds pipe at the same time(17).
CN201721013586.0U 2017-08-14 2017-08-14 A kind of utilization system of high-ammonia nitrogen low C OD waste water Expired - Fee Related CN207330633U (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108751571A (en) * 2018-05-17 2018-11-06 山西华仕低碳技术研究院有限公司 One kind being used for coal chemical industry oil product synthetic wastewater processing unit
CN109502929A (en) * 2019-01-08 2019-03-22 辽宁中舟得水环保科技有限公司 A kind of processing method of coking of coal waste water
CN110143690A (en) * 2019-05-09 2019-08-20 知合环境(北京)有限责任公司 A kind of processing method of aquiculture waste water
CN112707379A (en) * 2020-12-30 2021-04-27 苏州清然环保科技有限公司 Method for treating high ammonia nitrogen wastewater and recovering ammonia and magnesium ammonium phosphate reactor suitable for method
CN113461278A (en) * 2021-08-17 2021-10-01 江苏索普化工股份有限公司 Biochemical method for efficiently treating total nitrogen in wastewater
CN114075010A (en) * 2020-08-10 2022-02-22 中国石油化工股份有限公司 Differentiation treatment process and system for production sewage series and salt-containing sewage series of coal-to-methanol process
CN114350412A (en) * 2021-12-10 2022-04-15 未名合一生物环保有限公司通道分公司 Household garbage pyrolysis gas carbonization treatment system and technology thereof
ES2977208A1 (en) * 2022-12-30 2024-08-20 Univ Valladolid WATER TREATMENT SYSTEM (Machine-translation by Google Translate, not legally binding)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108751571A (en) * 2018-05-17 2018-11-06 山西华仕低碳技术研究院有限公司 One kind being used for coal chemical industry oil product synthetic wastewater processing unit
CN109502929A (en) * 2019-01-08 2019-03-22 辽宁中舟得水环保科技有限公司 A kind of processing method of coking of coal waste water
CN109502929B (en) * 2019-01-08 2019-11-12 辽宁中舟得水环保科技有限公司 A kind of processing method of coking of coal waste water
CN110143690A (en) * 2019-05-09 2019-08-20 知合环境(北京)有限责任公司 A kind of processing method of aquiculture waste water
CN114075010A (en) * 2020-08-10 2022-02-22 中国石油化工股份有限公司 Differentiation treatment process and system for production sewage series and salt-containing sewage series of coal-to-methanol process
CN114075010B (en) * 2020-08-10 2023-05-30 中国石油化工股份有限公司 Differentiation treatment process and system for production sewage series and salt-containing sewage series of coal-to-methanol process
CN112707379A (en) * 2020-12-30 2021-04-27 苏州清然环保科技有限公司 Method for treating high ammonia nitrogen wastewater and recovering ammonia and magnesium ammonium phosphate reactor suitable for method
CN113461278A (en) * 2021-08-17 2021-10-01 江苏索普化工股份有限公司 Biochemical method for efficiently treating total nitrogen in wastewater
CN114350412A (en) * 2021-12-10 2022-04-15 未名合一生物环保有限公司通道分公司 Household garbage pyrolysis gas carbonization treatment system and technology thereof
ES2977208A1 (en) * 2022-12-30 2024-08-20 Univ Valladolid WATER TREATMENT SYSTEM (Machine-translation by Google Translate, not legally binding)

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