CN207318397U - High pressure hydrogen pipeline shock wave and electrostatic coupling measuring system - Google Patents

High pressure hydrogen pipeline shock wave and electrostatic coupling measuring system Download PDF

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Publication number
CN207318397U
CN207318397U CN201721043232.0U CN201721043232U CN207318397U CN 207318397 U CN207318397 U CN 207318397U CN 201721043232 U CN201721043232 U CN 201721043232U CN 207318397 U CN207318397 U CN 207318397U
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electrostatic
release
pipe
shock wave
array
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潘旭海
汪志雷
闫伟阳
蒋益明
华敏
蒋军成
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Zhenjiang Ruihua Safety Technology Co ltd
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Nanjing Tech University
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Abstract

The utility model discloses high pressure hydrogen pipeline shock wave and electrostatic coupling measuring system, including hydrogen-storing device, nitrogen purging device, release device, electrostatic induction device, array of pressure sensors, photosensor arrays, electrostatic sensor array, signal pickup assembly and computer, hydrogen-storing device and nitrogen purging device are connected by the front end of admission line and surge tank respectively, the end of surge tank is equipped with emptying device and release device, the array of pressure sensors and photosensor arrays of the electrostatic sensor array being connected with electrostatic detection platform and signal pickup assembly connection are respectively equipped with release pipeline, electrostatic detection platform and it is connected with signal pickup assembly with computer, filming apparatus carries out high speed infrared shooting.The beneficial effects of the utility model are:The coupling effect under two kinds of factor varying levels can be studied at the same time in set of device;Experimental result is accurate, improves conventional efficient, and observation process is more complete.

Description

High pressure hydrogen pipeline shock wave and electrostatic coupling measuring system
Technical field
The utility model is related to the mechanism technical field of measurement and test of hydrogen self-ignition, more particularly to high pressure hydrogen pipeline shock wave with it is quiet It is electrically coupled measuring system.
Background technology
As clean energy resource, its use scope constantly expands hydrogen, but since hydrogen explosion limit section itself is wide, it is minimum Ignition energy is low, therefore once leakage out of control easily causes fire explosion.Different from other fuel gas, high pressure hydrogen leakage Easily spontaneous combustion afterwards, the mechanism for leaking spontaneous combustion for high pressure hydrogen at present are limited primarily to inverse joule thomson effect, electrostatic igniting reason By, ignition theory and other ignition theories are spread, wherein diffusion ignition theory research is the most extensive, it is big with Chinese science technology Learn and substantial amounts of experimental study has been carried out to diffusion ignition theory for the domestic and international scientific research institution of correlation of representative, analyze different shock waves Diffusion ignition theory meets situation under intensity and different release environment, it was demonstrated that the feasibility of diffusion ignition theory.With U.S. mulberry Also there are electrostatic ignition mechanism in Di Ya National Laboratories substantial amounts of experiment and theoretical research for the related scientific research mechanism of representative, to hydrogen Electro-static Driven Comb process is studied caused by different impurities in feed channel, and what related experiment also demonstrate that electrostatic ignition theory can Row.But in the experimental study of diffusion ignition theory and electrostatic ignition theory, all there are some, each single theory can not solve The experimental phenomena released, i.e., in the case where being unsatisfactory for the autoignition conditions of respective theoretical prediction, still there occurs spontaneous combustion for hydrogen.Passing through theory There may be the effect to intercouple between the different mechanism of analysis post analysis discovery, because shock wave, electrostatic, inverse Joule Thompson During the factor such as effect and instantaneous adiabatic compression is present in hydrogen gas leakage at the same time, wherein the effect against joule thomson effect It is present in any one hydrogen gas leakage diffusion process, but its temperature rising brought is not enough to trigger hydrogen self-ignition, wink When adiabatic compression also only occur that shock wave and electrostatic are the masters for causing hydrogen self-ignition in most cases in the case of small part Energy source is wanted, only shock wave or electrostatic one of which factor are studied in current research, still can completely does not disclose The mechanism of hydrogen self-ignition, it is therefore desirable to which a synthesis experiment platform, can couple the principal elements such as shock wave and electrostatic and carry out at the same time Research, so as to comprehensively observe the spontaneous combustion process of hydrogen in the case of total factor.But current all kinds of experimental provisions are only capable of realizing The test of single factors varying level, it is difficult to carry out the coupling experiment of a variety of mechanism.The utility model major function is permissible The shock wave and electrostatic produced during hydrogen gas leakage is measured at the same time, the coupling effect of shock wave and electrostatic can be observed, so that point The coupling mechanism and its influence factor of analysis research diffusion ignition theory and electrostatic ignition theory.
Utility model content
For above-mentioned problem, the utility model, which aims to provide one kind, can examine high pressure hydrogen to swash during releasing The experimental provision of ripple and electrostatic coupling action effect, can measure the effect effect of shock wave and electrostatic to hydrogen self-ignition process at the same time Fruit, realizes the quantitative analysis that result is influenced on multifactor varying level..
To achieve these goals, technical solution is as follows used by the utility model:
High pressure hydrogen pipeline shock wave and electrostatic coupling measuring system and method, including hydrogen-storing device, nitrogen purging device, release Put device, electrostatic induction device, array of pressure sensors, photosensor arrays, electrostatic sensor array, signal pickup assembly And computer, the hydrogen-storing device and the nitrogen purging device pass through the front end of its corresponding admission line and surge tank respectively Connecting, air intake valve is respectively equipped with the air inlet pipe, the end of the surge tank is equipped with emptying device and the release device, The electrostatic sensor array being connected with electrostatic detection platform and the signal acquisition are respectively equipped with the release device The array of pressure sensors and photosensor arrays of device connection, the end of the release device is lured equipped with the electrostatic Lead device and filming apparatus, the filming apparatus, the signal pickup assembly and the electrostatic monitoring platform with the calculating Machine connects.
Further improve, the release device include trapezoid platform release device, pipe main body, upstream release device and under Release device is swum, the pipe main body includes upstream release pipe, downstream release pipe and the nozzle set gradually, the upstream release Pipe end discharges pipe with the downstream by the upstream release device and is connected, and the downstream release pipe end passes through the downstream Release device is connected with the nozzle, is equipped with the trapezoid platform release device in the upstream release pipe successively and positioned at its end The release switch at end.
Further improve, the release switch is rupture disk clamper or pneumatic ball valve.
Further improve, No. 1 electrostatic that the electrostatic sensor array includes setting gradually along the pipe main body senses Device, No. 2 electrostatic transducers, No. 3 electrostatic transducers and No. 4 sensors, No. 1 sensor is located in the pipe main body and position In the end of the upstream release device, No. 2 electrostatic transducers and No. 3 electrostatic transducers are respectively positioned on the pipeline master In vivo and the both ends of the downstream release device are respectively provided at, the nozzle end is equipped with No. 4 electrostatic transducers.
Further improve, the photosensor arrays include 3 photoelectric sensings being sequentially arranged on pipe main body outer wall Device, the array of pressure sensors include be sequentially arranged at it is on the pipe main body outer wall and respectively with 3 photoelectric sensors pair The humidity sensor answered, temperature sensor and pressure sensor, are equipped with threeway conduit, the humidity sensor below the surge tank Device, the temperature sensor, the pressure sensor and 3 photoelectric sensors pass through conducting wire and signal pickup assembly respectively And threeway conduit connection.
Further improve, the electrostatic induction device includes static board, electrostatic probe, dielectric holder and supporting rod, electrostatic Plate is located at the electrostatic sensor array end, and the static board is connected by the dielectric holder and the supporting rod below Connect, the end of the static board is equipped with the electrostatic probe, the electrostatic probe ground connection.
Using above-mentioned measuring system, it surveys the shock wave and electrostatic coupling action effect that are produced during hydrogen leak The step of amount is:
1) according to test purpose, upstream measured particulate matter is added in release device or downstream release device;
2)After completing particulate matter addition, each device is connected into test system, then the system assembled is carried out airtight Property test, confirm air-tightness it is good;
3)Air in nitrogen purging device discharge surge tank is opened, hydrogen-storing device is then turned on and high pressure is injected into surge tank Hydrogen, starts release switch, hydrogen drives particulate matter to be rushed along pipe main body through electrostatic sensor array after reaching specified pressure Hit electrostatic induction device and produce spark discharge, electrostatic sensor array and array of pressure sensors by the data monitored difference Computer is reached by electrostatic detection platform and signal pickup assembly, the pipe outward ignition situation that filming apparatus will be observed that reaches meter Calculation machine;
4)Stop supply hydrogen, open nitrogen purging device and extinguish jet flame, and cool down the measuring system.
The beneficial effects of the utility model are:1. the shock wave and the electrostatic coupling experiment that establish high pressure hydrogen pipeline first are flat Platform, can be measured at the same time in once testing shock wave during high pressure hydrogen is released produce, the product of transmittance process and electrostatic Tired, release process, it is not necessary to change device or repeatedly measure, fundamentally ensure that the accuracy of experiment, improve reality Test efficiency;2. pass through electrostatic sensor array, the outer electrostatic transducer of pipe, the knot for inducing electrostatic electrification device and grounded probe in pipe Close, particulate matter can be understood in the process with generation, accumulation and the release of electrostatic in gas flow with complete display, Discharge energy when earlier device is only capable of the exterior static release of measurement pipeline is compared, observation process is more complete;
3. by different type release switch and discharging pressure, the shock wave of varying strength can be produced;Pass through different Grain thing point of addition and additive amount, can produce the electrostatic of varying strength.And then changed by studying two kinds of the quantitative of factor The generation frequency of hydrogen self-ignition in journey, can analyze influence degree of the different factors to hydrogen self-ignition, and then can be by right Than the coupling effect of two kinds of factors of analysis of experimental results of single factors.
Brief description of the drawings
Fig. 1 is the utility model structure diagram.
Fig. 2 is trapezoid platform release device structure diagram.
Fig. 3 is nozzle section structure diagram.
Wherein:1- hydrogen-storing devices, 11- admission lines, 12- air intake valves, 2- nitrogen purging devices, 3- release devices, 31- Trapezoid platform release device, 311- particulate matters, 32- pipe main bodies, 321- upstreams release pipe, 322- downstreams release pipe, 323- sprays Mouth, 33- upstreams release device, 34- downstreams release device, 35- release switches, 351- rupture disks, 4- electrostatic induction devices, 41- Static board, 42- electrostatic probes, 43- dielectric holders, 44- supporting rods, 5- array of pressure sensors, 51- humidity sensors, 52- temperature Spend sensor, 53- pressure sensors, 6- electrostatic sensor arrays, 61-1 electrostatic transducers, 62-2 electrostatic transducers, 63- No. 3 electrostatic transducers, 64-4 sensors, 7- signal pickup assemblies, 8- surge tanks, 81- threeway conduits, 82- photoelectric sensors Array, 9- emptying devices, 10- filming apparatus, 101- high-speed cameras, 102- infrared photography devices.
Embodiment
In order to make those of ordinary skill in the art be better understood on the technical solution of the utility model, with reference to attached Figure and embodiment are further described the technical solution of the utility model.
High pressure hydrogen pipeline shock wave shown in 1 and electrostatic coupling measuring system referring to the drawings, including hydrogen-storing device 1, nitrogen Blow device 2, release device 3, electrostatic induction device 4, array of pressure sensors 5, electrostatic sensor array 6, signal acquisition dress Put 7, photosensor arrays 82, electrostatic detection platform, filming apparatus 10 and computer, the hydrogen-storing device 1 and the nitrogen Blow device 2 is connected to the front end of surge tank 8 by its corresponding admission line 11 respectively, and the air inlet pipe 11 is equipped with control The air intake valve 12 that air inlet pipe is turned on and off, the end of the surge tank 8 are equipped with emptying device 9 and the release device 3, institute Stating release device 3 includes trapezoid platform release device 31, pipe main body 32, upstream release device 33 and downstream release device 34, The pipe main body 32 includes upstream release pipe 321, downstream release pipe 322 and the nozzle 323 set gradually, the upstream release The end of pipe 321 discharges pipe 322 with the downstream by the upstream release device 33 and is connected, the downstream release pipe 322 End is connected by the downstream release device 34 with the nozzle 323, and the spray nozzle front end opening is big, its diameter AB is 0.15m, its distal opening is small, and diameter CD is 0.032m, for controlling jet-impingement form;In upstream release pipe 321 according to It is secondary to be equipped with the trapezoid platform release device 31 and the release switch 35 positioned at its end.
The nitrogen purging device is business nitrogen cylinder, and storage pressure 12.5MPa, the hydrogen-storing device is hydrogen steel Bottle, the admission line and surge tank form by 304 stainless steels, its maximum working pressure (MWP) is 14MPa, length in hydrogen container 0.25m, tank interior diameter 0.12m, the admission line length being connected with hydrogen gas cylinder are 1.5m, internal diameter 0.15m, admission line and tank Body wall thickness is 0.015m, and blow-down pipe is by ball valve opened manually and closing, the gases at high pressure when bleeder breaks down It can be discharged into by blow-down pipe in external environment;The release switch is rupture disk clamper or pneumatic ball valve, in research difference Operating mode when, different release switches is docked in downstream respectively;The length of release pipeline can be 0.36m or 1.2m or 3.05m, upstream Release device and downstream release device are respectively the connecting pipe of threeway shape, its length is 0.04m, internal diameter 0.015m, Its T-shaped projection can be as the place to place of addition particulate matter, while release device also serves as the one of connection upstream and downstream pipeline A fixing device, when studying different operating modes, places particulate matter 311 in upstream release device or downstream release device.
The photosensor arrays 82 include 3 photoelectric sensors being sequentially arranged on pipe main body outer wall, the pressure Force sensor array 5 includes the humidity being sequentially arranged on 32 outer wall of pipe main body corresponding with 3 photoelectric sensors respectively and passes Sensor 51, temperature sensor 52 and pressure sensor 53, the lower section of the surge tank 8 are equipped with the threeway conduit 81 communicated therewith, The humidity sensor 51, the temperature sensor 52, the both ends point of the pressure sensor 53 and 3 photoelectric sensors It is not connected by conducting wire with signal pickup assembly 7 and threeway conduit 10, to record the state change of gas in pipe constantly.
The electrostatic sensor array 6 includes cricoid No. 1 electrostatic transducer set gradually along the pipe main body 32 61st, 62, No. 3 electrostatic transducers 63 of No. 2 electrostatic transducers and No. 4 sensors 64, are installed at the 0.01m of upstream release device downstream There is No. 1 electrostatic transducer 61,62 He of No. 2 electrostatic transducers is respectively equipped with the both ends of the downstream release device 34 No. 3 electrostatic transducers 63, are equipped with insulation figure layer on the 1-3 electrostatic transducers, it is embedded on the inside of pipe main body In wall, the smooth straight of release inner-walls of duct ensure that;The ring of a diameter of 0.4m is equipped with the 323 downstream 0.5m of nozzle No. 4 electrostatic transducers 64 of shape, 1 to No. 4 electrostatic transducer are connected with the electrostatic detection platform.
The electrostatic induction device 4 includes static board 41, electrostatic probe 42, dielectric holder 43 and supporting rod 44, in distance Static board 41 is placed at the 1.5m of nozzle downstream, the static board 41 is diameter 0.25m, the rounded tinned copper plate of thickness 0.01m, its It is connected by the dielectric holder 43 with the supporting rod 44 below, the downstream 0.005m cloth at rounded tinned copper plate center The electrostatic probe 42 is equipped with, the electrostatic probe 42 is grounded, and the electrostatic probe is due to detecting tin plating copper coin by containing miscellaneous The electrostatic electricity produced during the airflow scouring of matter, and then calculate the energy discharged during spark discharge.
The filming apparatus 10 is being set at nozzle 10cm, and the filming apparatus 10 includes 101 He of high-speed camera Infrared photography device 102, with detection pipe outward ignition situation and analysis ignition location.
The filming apparatus, the signal pickup assembly and the electrostatic monitoring platform are connected with the computer, this Electrostatic monitoring platform model can be ETS-624 electrostatic monitoring platforms in utility model.
The method measured using above-mentioned high pressure hydrogen pipeline shock wave and electrostatic coupling measuring system, its step are:
1) above-mentioned each device is placed on horizontal experimental bench, destatics all devices outside apparatus for deivation and be both needed to electrostatic and connect Ground, according to test purpose, upstream adds measured particulate matter in release device or downstream release device;
2)Pipeline all departments are connected firmly, air tightness test then is carried out to the system assembled, suds can be used Each coupling part is smeared, with the air-tightness of check device, confirms that air-tightness is good;
For possible metal particulate in simulation Hydrogen Line, addible material has iron oxide, ferrous oxide, oxidation Asia Lead, silica, the particulate matter quality scope of all kinds of materials is 0.1-5g, 30 μm of particle diameter D90 <.Needing to measure release switch When producing the influence of process to electrostatic, particulate matter can be added in the trapezoid platform of release switch upstream;Studying different releases Under mode, during the influence of the length of pipe main body and shock strength electric stress, the upstream of pipeline can be discharged in downstream, approached Particle is added in upstream release device at release switch;In research lip jet and the generation feelings of electrostatic in air mixed process During condition, particulate matter can be added in the release device of downstream.
3)After particulate matter addition is completed, open in nitrogen purging device discharge surge tank after air, closing nitrogen purging Device valve, is then turned on hydrogen-storing device and high pressure hydrogen is injected into surge tank, treats that hydrogen will in pressure gauge display buffer tank When reaching specified pressure, hydrogen flowing quantity is reduced;High pressure hydrogen discharges in downstream forms shock wave and with high pressure hydrogen in pipeline Quick flowing;Hydrogen drives particulate matter to produce electrical fire along pipe main body through electrostatic sensor array impact electrostatic induction device Flower electric discharge, the data monitored are passed through electrostatic detection platform and signal by electrostatic sensor array and array of pressure sensors respectively Harvester reaches computer, and the pipe outward ignition situation that filming apparatus will be observed that reaches computer;
4)Hydrogen gas cylinder valve can be closed after lighting a fire, stops supply hydrogen, opens nitrogen purging device, extinguish Jet bubble reactor, reduces unit temp, prepares next round experiment.
When release switch is starts ball valve, surge tank, which reaches specified pressure, can stop injecting hydrogen;In release switch For rupture disk when, need to constantly inject hydrogen until rupture disk reaches specified pressure and ruptures, the unlatching of band pneumatic ball valve or explosion After piece rupture, high pressure hydrogen jet stream just quickly exports downstream flow to pipe main body from surge tank, is flowing through placement particulate matter Upstream release device or downstream release device when, can by the particulate matter placed in device roll up suction high-speed flow in, along pipe Advance and be finally together discharged into air-flow by nozzle in external environment condition in road;High-speed flow by nozzle rectification passes through external No. 4 Annular electrostatic sensors, the static board of direct impact induced electrostatic electrification(I.e. tin plating copper dish), static board occur impact Electricity, due to having insulated therefore have accumulated a large amount of electrostatic, when accumulation of static electricity to a certain extent when can be with the ground connection electrostatic probe on right side Sufficiently large potential difference is formed so as to which spark discharge occur, is grounded at this time around electrostatic probe by the mixing of hydrogen and air Fuel gas surrounds, and the energy of spark discharge release will light ambient gas, and the energy of electric spark release can be examined by electrostatic Survey platform record.
The intensity and spread speed of shock wave can be detected by array of pressure sensors in the process, if occurring in pipe Spontaneous combustion can also detect the superpressure pressure wave that detonation produces by pressure sensor, while photoelectric sensor can be to be in detection pipe The no position that igniting and igniting occurs and occurs;Electrostatic sensor array can detect in pipeline metal particulate at different cross section It is powered so that analyze electrostatic accumulation and release process;It is mingled with metallic particles in air-flow and is discharged into outside by nozzle Behind space, effect and the electrostatic spark of air-flow and electrostatic induction metal dish can be observed by high-speed camera and infrared imaging The process of discharge igniting.
The advantages of basic principle, main feature and the utility model of the utility model has been shown and described above.One's own profession The technical staff of industry is it should be appreciated that the present utility model is not limited to the above embodiments, described in above embodiments and description Simply illustrate the utility model principle, on the premise of not departing from the spirit and scope of the utility model, the utility model is also Various changes and modifications are had, these various changes and improvements fall within the scope of the claimed invention.The utility model Claimed scope is defined by the appending claims and its equivalent thereof.

Claims (6)

1. high pressure hydrogen pipeline shock wave and electrostatic coupling measuring system, it is characterised in that including hydrogen-storing device, nitrogen purging dress Put, release device, electrostatic induction device, array of pressure sensors, photosensor arrays, electrostatic sensor array, signal are adopted Acquisition means and computer, the hydrogen-storing device and the nitrogen purging device pass through its corresponding admission line and surge tank respectively Front end connection, be respectively equipped with air intake valve in the air inlet pipe, the end of the surge tank is equipped with emptying device and described releases Device is put, the electrostatic sensor array being connected with electrostatic detection platform and the letter are respectively equipped with the release device The array of pressure sensors and photosensor arrays of number harvester connection, the end of the release device are equipped with described Electrostatic induction device and filming apparatus, the filming apparatus, the signal pickup assembly and the electrostatic monitoring platform are and institute State computer connection.
2. high pressure hydrogen pipeline shock wave according to claim 1 and electrostatic coupling measuring system, it is characterised in that described to release Putting device includes trapezoid platform release device, pipe main body, upstream release device and downstream release device, the pipe main body bag Upstream release pipe, downstream release pipe and the nozzle set gradually is included, the upstream release pipe end is discharged by the upstream to be filled To put and be connected with downstream release pipe, the downstream release pipe end is connected by the downstream release device with the nozzle, The trapezoid platform release device and the release switch positioned at its end are equipped with successively in the upstream release pipe.
3. high pressure hydrogen pipeline shock wave according to claim 2 and electrostatic coupling measuring system, it is characterised in that described to release It is rupture disk or pneumatic ball valve to decontrol pass.
4. high pressure hydrogen pipeline shock wave according to claim 3 and electrostatic coupling measuring system, it is characterised in that described quiet Electric transducer array includes No. 1 electrostatic transducer, No. 2 electrostatic transducers, No. 3 electrostatic biographies set gradually along the pipe main body Sensor and No. 4 electrostatic transducers, No. 1 electrostatic transducer are located in the pipe main body and are located at the upstream release device End, No. 2 electrostatic transducers and No. 3 electrostatic transducers are respectively positioned in the pipe main body and are respectively provided at described The both ends of downstream release device, the nozzle end are equipped with No. 4 electrostatic transducers.
5. high pressure hydrogen pipeline shock wave according to claim 2 and electrostatic coupling measuring system, it is characterised in that the light Electric transducer array includes 3 photoelectric sensors being sequentially arranged on pipe main body outer wall, and the array of pressure sensors includes It is sequentially arranged on the pipe main body outer wall and humidity sensor corresponding with 3 photoelectric sensors, temperature sensor respectively And pressure sensor, the surge tank lower section are equipped with threeway conduit, the humidity sensor, the temperature sensor, the pressure Force snesor and 3 photoelectric sensors are connected by conducting wire with signal pickup assembly and threeway conduit respectively.
6. according to claim 1-5 any one of them high pressure hydrogen pipeline shock wave and electrostatic coupling measuring system, its feature exists In the electrostatic induction device includes static board, electrostatic probe, dielectric holder and supporting rod, and static board is located at the electrostatic and passes Sensor array ends, the static board are connected by the dielectric holder with the supporting rod below, the static board End is equipped with the electrostatic probe, the electrostatic probe ground connection.
CN201721043232.0U 2017-08-21 2017-08-21 High pressure hydrogen pipeline shock wave and electrostatic coupling measuring system Active CN207318397U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107490598A (en) * 2017-08-21 2017-12-19 南京工业大学 High pressure hydrogen pipeline shock wave and electrostatic coupling measuring system and method
CN114910600A (en) * 2021-02-08 2022-08-16 中国石油化工股份有限公司 Combustion behavior visualization test device and method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107490598A (en) * 2017-08-21 2017-12-19 南京工业大学 High pressure hydrogen pipeline shock wave and electrostatic coupling measuring system and method
CN114910600A (en) * 2021-02-08 2022-08-16 中国石油化工股份有限公司 Combustion behavior visualization test device and method

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Effective date of registration: 20210705

Address after: Room 205, new material industrial park, 180 Jingang Avenue, Zhenjiang New District, Jiangsu Province, 212001

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