CN207313499U - A kind of device using biomass material rapid polymerization humic acid - Google Patents

Abstract

The utility model discloses a kind of device using biomass material rapid polymerization humic acid, including：Reactor, reaction fluid circulation, heating system, liquid add system, reception device and waste gas afterheat recovery unit, the liquid is added system and is connected with the reactor, the reaction fluid circulation is connected with the reactor, the heating system respectively, after the reaction solution in the reactor is pumped to the heating system, the reactor is re-fed into, forms circulating-heating circuit；The discharge port of the reactor is connected with the feed inlet of the reception device, and the exhaust outlet of the reception device is connected with the waste gas afterheat recovery unit.The utility model can overcome the defect that the problem of being difficult to maintain reaction constant temperature and pressure in existing equipment, realize rapid polymerization humic acid and environmental protection and energy saving.

Description

A kind of device using biomass material rapid polymerization humic acid

Technical field

The technical field of rapid polymerization humic acid is the utility model is related to, it is more particularly to a kind of quick using biomass material It polymerize the device of humic acid.

Background technology

Humic acid is natural macromolecular organic polymer, contains various active group --- carboxyl, phenolic hydroxyl group, alcoholic extract hydroxyl group, Quinonyl, carbonyl etc., have the physics such as network (chela) conjunction, absorption, infiltration, bonding, exchange, dilution, sustained release, stabilization, surface-active, change Characteristic and bioactivity are learned, has become the green power material of national economy sustainable development.According to production humic acid material Difference, humic acid is divided into humatite source humic acid and non-mineral source biomass humic acid.Humatite source humic acid with Weathered coal, peat, lignite are raw material, and extracted, processing obtains.Non-mineral source biomass humic acid is with the non-ore deposit of industrial and agricultural production Material resource biomass by-products are raw material, process to obtain using biotechnology or chemical technology.

Humatite source humic acid derives from non-renewable coal resources, and production capacity and price are seriously restricted.Biology Matter humic acid derives from reproducible biomass resource, and such as stalk, forestry waste, animal waste, stock number are rich Richness, therefore the important directions that biomass humic acid will develop as Humic Acid Industry.But the starting of biomass humic acid is than later, 《Humic acid》Periodical the 1st phase in 2013 " humic acid fertilizer is classified (exposure draft) " just formally extracts the general of biomass humic acid Read.Limited by production technology and corollary equipment, the development of biomass Humic Acid Industry is slower.

Biomass humic acid currently on the market is to pass through biology with molasses, agricultural byproducts processing leftover bits and pieces etc. for raw material The method of fermentation prepares what production obtained, and fulvic acid, and product chemistry are only contained in the biomass humic acid that this method obtains Phenyl ring is seldom inside the skeleton of component, and the production cycle length of humic acid, according to the difference of raw material and zymotechnique, the production cycle can Differed at several thoughtful 2 years, and since the temperature in reaction process is difficult to control, cause to react insufficient, reaction rate is slow.

In recent years, occur different equipment to the production efficiency of humic acid and extraction to improve, such as Chinese Shen Please number be：201310548129.1 patent of invention《The technique and special purpose device of humic acid are extracted from rubbish sepage》Disclose It is a kind of that humic acid in rubbish sepage can be extracted to technique and the special purpose device that left outside agricultural fertilizer uses, and in China Application No.：201410487433.4 patent of invention《Domestic sludge extracts the device and method of humic acid》Disclose a kind of energy Can from domestic sludge high efficiency extraction humic acid and the simple equipment of operating method；For another example Chinese Application No.： 201610963621.9 patent of invention《The device and method of humic acid is extracted from weathered coal》Disclose including：Flour mill, Separator, alkali reaction container, sour reaction container, circulating pump, filter, drying machine；And by using the mode of filter fast filtering, Washing process is taken and is greatly shortened, can the interior completion when 2 is small, clarification washing facility largely reduces, while can be by humic acid Liquid is highly concentrated, reduces coming into operation for humic acid drying equipment, and significantly reduce the consumption of dry steam.But existing disclosed It is mainly used for the middle extraction humic acid from garbage disposal, domestic sludge, weathered coal in the equipment of humic acid polymerization/extraction, not There is the device using biomass as raw material rapid polymerization humic acid to disclose.

Utility model content

The purpose of this utility model is to provide a kind of device using biomass material rapid polymerization humic acid, Neng Gouke The problem of being difficult to maintain reaction constant temperature and pressure in existing equipment has been taken, has realized rapid polymerization humic acid and environmental protection and energy saving.

To achieve the above object, the utility model provides a kind of dress using biomass material rapid polymerization humic acid Put, including：Reactor, reaction fluid circulation, heating system, liquid add system, reception device and waste gas residual heat recycling dress Put；

The liquid is added system and is connected with the reactor；

The reaction fluid circulation is connected with the reactor, the heating system respectively, for by the reactor In reaction solution pump to the heating system after, be re-fed into the reactor, form circulating-heating circuit；

The discharge port of the reactor is connected with the feed inlet of the reception device, the exhaust outlet of the reception device and institute State waste gas afterheat recovery unit connection.

Preferably, in above-mentioned technical proposal, the reactor, including：Reactor tank body, reactor feed valve, reaction Device outlet valve, reactor air intake, reactor exhaust outlet, reaction solution circulate into and reaction solution loop exit, liquid add mouth with And discharge pipe；

The reactor tank body is made of the cylindrical tube at middle part, upper cone and lower cone three parts；Wherein, on described Cone is provided with the first reaction solution circulation import, reactor exhaust outlet and liquid and adds mouth；Set in the middle part of the cylindrical tube There is the second reaction solution loop exit；The lower cone is provided with reaction solution circulation import, reactor air intake and discharge pipe；

The liquid, which adds mouth and adds system with liquid, to be connected；It is the reaction solution loop exit of the reactor, described anti- Answer liquid circulation import to be connected with the reaction fluid circulation, the outlet valve of the reactor through the discharge pipe with it is described Reception device is connected.

Preferably, in above-mentioned technical proposal, the reaction fluid circulation, including circulating pump and circulation line, it is described Circulating pump be centrifugal pump, the circulation line includes input duct and outlet pipe；

The heating system, including：Heater, steam inlet and steam (vapor) outlet；

The steam inlet is arranged on the top of the heater, and the steam (vapor) outlet is arranged on the heater Lower part, the input duct of the recycle system of reaction are connected with the bottom of the heater, the recycle system of reaction it is described The inlet of outlet pipe is connected with the heater middle and upper part, and the outlet pipe is bifurcated and connected with the heater.

Preferably, in above-mentioned technical proposal, the reception device by receiving tank feed inlet, gas-liquid separator, receive tank body, Receiving tank lower cone and delivery pump composition；

One end of the receiving tank feed inlet is connected through discharge pipe with the reactor, its other end and the gas-liquid point Connected from device, the discharge port of the gas-liquid separator is connected with the reception tank body, and the bottom for receiving tank body connects with described Closed cans lower cone connects, and the receiving tank lower cone is connected through pipeline with the feed inlet of the delivery pump.

Preferably, in above-mentioned technical proposal, the waste gas afterheat recovery unit includes retracting device air intake and described time Ejector condenser, sump and the condenser of receiving apparatus air intake connection, the liquid outlet of the ejector condenser Connected with the top of the sump, the condenser is connected with the top of the sump.

Compared with prior art, the utility model has the advantages that：

1st, the reactor in a kind of biomass rapid polymerization humic acid equipment of the utility model, volume is big, floor space Small, production capacity is big, is advantageously implemented the scale conversion of biomass.

2nd, the reaction fluid circulation in a kind of biomass rapid polymerization humic acid equipment of the utility model, passes through heating Device is to reaction mass indirectly heat, rather than is constantly passed through steam heating, causes reaction system to contain so that steam water will not be brought into The problem of high problem of water, the energy consumption of increase subsequent evaporation concentration, occurs, this advantageously reduces the water content of reaction solution, improves liquid The concentration of solid content in body.

3rd, in a kind of biomass rapid polymerization humic acid equipment of the utility model, except being passed through steam heating to reactor Outside, fluid circulation also is reacted by designing, reaction solution circulation being heated by heater repeatedly is conducive to keep The uniformity of the heating-up temperature of reaction solution and the constant temperature for maintaining reaction solution, overcome and are difficult to maintain reaction permanent in existing equipment The problem of warm constant pressure, thus be conducive to biomass uniformly, be rapidly and thoroughly converted into humic acid, improve reaction efficiency.

4th, the reception device in a kind of biomass rapid polymerization humic acid equipment of the utility model, vapour liquid separator 33 go out Mouth is tubaeform, steam is expanded evaporation when discharging, so that vapor-liquid separation effect is good, and after reaction, reaction solution is band Pressure is put, i.e., from high pressure to normal pressure, reacting liquid temperature is at 180 DEG C or so, and entering atmospheric pressure environment will flash naturally, and loudspeaker Mouth, the design of taper make the steam after flash distillation send rapidly, are conducive to the progress of flash distillation, vapor-liquid separation effect is good, is conducive to drop The water content of low reaction liquid, further increases the concentration of solid content in liquid, and is conducive to the drying of subsequent product, reduces Energy consumption for drying.

5th, the waste gas afterheat recovery unit in a kind of biomass rapid polymerization humic acid equipment of the utility model, recycling effect Rate is up to 80%, and hot sewage returns to configuration liquid, avoids the discharge of exhaust gas and waste water, is conducive to environmental protection.

Brief description of the drawings

Fig. 1 is the structure diagram of the device according to the present utility model using biomass material rapid polymerization humic acid；

Fig. 2 is the reactor of the utility model and the structure diagram of liquid replenishment system；

Fig. 3 is the reaction fluid circulation of the utility model and the structure diagram of heating system；

Fig. 4 is the structure diagram of the reception device of the utility model；

Fig. 5 is the structure diagram of the waste gas afterheat recovery unit of the utility model.

Main Reference Numerals explanation：

101- reactors, 102- liquids add system, 103- reaction fluid circulations, 104- heating systems, 105- receptions Device, 106- waste gas afterheat recovery units；

1- cylindrical tubes, 2- upper cones, 3- lower cones, 4- reactor feed valves, 5- reactor outlet valves, 6- reactors Air intake, 7- reactor exhaust outlets, 8- reaction solution loop exits, the first reaction solutions of 91- circulation import, the second reaction solutions of 92- follow Ring import, 10- liquids add mouth, 11- constant pressure and flow metering pumps, and 12- liquids add pipeline, 13- diaphragm valves, 14- support ears, 15- support columns, 16- discharge pipes；

21- input ducts, 22- outlet pipes, 23- centrifugal pumps, 24- heaters, 25- steam inlets, 26- steam (vapor) outlets；

31- receives tank body, 32- receiving tank feed inlets, 33- gas-liquid separators, 34- receiving tank lower cones, 35- delivery pumps；

41- retracting device air intakes, 42- ejector condensers, 43- sumps, 44- condensers, 45- cold water inlets, 46- Hot outlet of sewer, 47- cooling water inlets, 48- cooling water outlets.

Embodiment

Below in conjunction with the accompanying drawings, specific embodiment of the present utility model is described in detail, it is to be understood that this practicality New protection domain and from the limitation of embodiment.

Explicitly indicated that unless otherwise other, otherwise in entire disclosure and claims, term " comprising " or its change Change such as "comprising" or " including " etc. and will be understood to comprise stated element or part, and do not exclude other members Part or other parts.

Fig. 1 shows the dress using biomass material rapid polymerization humic acid according to the utility model preferred embodiment The structure diagram put, a kind of device using biomass material rapid polymerization humic acid as shown in Figure 1, including：Reactor 101st, react fluid circulation 103, heating system 104, liquid and add system 102, reception device 105 and waste gas residual heat recycling dress Put 106；Its herb liquid is added system 102 and is connected with reactor 101, reaction fluid circulation 103 respectively with reactor 101, plus Hot systems 104 connect, and after the reaction solution in reactor 101 is pumped to heating system 104, are re-fed into reactor, are formed Circulating-heating circuit；The discharge port of reactor 101 is connected with the feed inlet of reception device 105, to cause material conveying conveniently to exist The discharge outlet of reactor 101 installs pumping machine to pump material, the exhaust outlet and waste gas afterheat recovery unit of reception device 106 106 connections.Vertical type is in for convenience of reactor 101 in the present embodiment, reactor 101 is provided with support column 15 in bottom, excellent Choosing sets 3 foot formula support columns and is fixedly connected by support ear 14 with reactor tank body.

Referring to Fig. 2, preferable reactor 101 in the present embodiment, including：It is reactor tank body, reactor feed valve 4, anti- Answer device outlet valve 5, reactor air intake 6, reactor exhaust outlet 7, reaction solution circulation import and reaction solution loop exit 8, liquid Add mouth 10 and discharge pipe 16；More particularly turning in detail to Fig. 1 and Fig. 2, reactor tank body is by upper cone 2, the circle at middle part Column-shaped barrel 1 and 3 three parts of lower cone composition；In the present embodiment, the ratio of the height of reactor tank body and diameter for 2~ 5, ratio preferably 3；Material is facilitated to enter from reactor tank body top or discharged easy to exhaust gas from reactor tank body to be more preferable, on Cone 2 is preferably 90 ° of upper cones, while upper cone 2 is provided with the first reaction solution circulation import 91,7 and of reactor exhaust outlet Liquid adds mouth 10, and medicine company is added and reactor feed valve 4 is provided with mouth 10, and reactor feed valve 4 is from compression type pneumatic operated valve Door, a diameter of 500~800mm；And lower cone 3 is preferably 60 ° of lower cones, while lower cone 3 is provided with the second reaction solution and follows Ring import 92, reactor air intake 6 and discharge pipe 16, reactor outlet valve 5, reactor discharging are provided with discharge pipe 16 Valve 5 is pneumatic ball valve, a diameter of 100~400mm；On the one hand 60 ° of lower cones are conducive to material and flow into discharge pipe 16 naturally, separately On the one hand lower cone 3 is provided with reactor air intake 6, is passed through hot gas from the bottom of reactor 101 so that hot gas is on nature Absorption heat is come into full contact with the reaction solution (material) in reactor 101 may advantageously facilitate and accelerate reaction during rising.This Outside, the first reaction solution circulation import 91 that the circulation import 92 of the second reaction solution and the upper cone 2 that lower cone 3 is provided with are provided with is same When from reactor 101 following be sent into reaction solution, the reaction solution to feeding is broken up in the middle part of reactor tank body and is come, formed pair The stirring action of reaction solution so that reaction solution contact is more abundant, and reaction evenly, and is provided with the middle part of cylindrical tube 1 Reaction solution loop exit 8, from upper and lower centrum counter current flow enter reactor tank body reaction solution mixing after again reacted liquid loop exit Flow out after 8 mixing, further homogenize reaction solution, this is compared in the existing equipment using mechanical agitation form, energy consumption It is relatively low, and it is too big to solve the problems, such as that reaction unit cannot design.

Referring again to 1 and Fig. 3, the liquid of reactor 101, which adds mouth 10 and adds system 102 with liquid, to be connected；Reactor 101 Reaction solution loop exit 8, reaction solution circulation import with reaction fluid circulation 103 connect, the reactor of reactor 101 goes out Material valve 5 is connected through discharge pipe 16 with reception device 105.As shown in figure 3, reaction fluid circulation 103, including circulating pump and The circulating pump of circulation line is centrifugal pump 23, and circulation line includes input duct 21 and outlet pipe 22；And heating system 104, Including：Heater 24, steam inlet 25 and steam (vapor) outlet 26；Understand that steam inlet 25 is arranged on heater turning in detail to Fig. 3 24 top, steam (vapor) outlet 26 are arranged on the lower part of heater 24, input duct 21 and the heater 24 of recycle system of reaction 103 Bottom connection, the reaction solution loop exit 8 being more particularly provided with the middle part of cylindrical tube 1 of reactor 101 connects, And 22 inlet of outlet pipe of recycle system of reaction 103 is connected with 24 middle and upper part of heater, another port, that is, liquid outlet is divided into The the first reaction solution circulation import 91 and second reaction solution circulation import with the upper and lower centrum of reactor 101 respectively of two branches 92 connections, so as to form the circuit of a circulation, this circulation loop will under the interaction of centrifugal pump 23 and circulation line Reaction solution iterative cycles in reactor 101.Since existing equipment is mostly passed through using from top or bottom or waist single-point Steam heats, and the temperature, pressure in such mode of heating reactor are difficult to remain constant, and the utility model and in except setting Put steam inlet 25 to be passed through outside steam heating to reactor, also react fluid circulation by designing, reaction solution is circulated anti- Multiple is heated by heater, due to be reaction solution be directly over heater carry out steady temperature heating, after heating Reaction solution is divided to two branches to return in reactor, the constant temperature of reaction solution, and the thermal perturbation coefficient to reactor 101 reduces , so as on the one hand be conducive to keep the uniformity of the heating-up temperature of reaction solution and maintain the constant temperature of reaction solution, the opposing party Face overcomes since constant temperature is so as to be conducive to keep the pressure in reactor 101 constant and is difficult to remain anti-in existing equipment The problem of answering constant temperature and pressure, (reaction solution in the present embodiment is biomass and its to the reaction solution that may advantageously facilitate into reactor His liquid) uniformly, be thoroughly converted into humic acid, so as to quickly polymerize humic acid；Simultaneous reactions liquid is reacting Under the action of the circulatory system 103, the mass transfer of the material material of reaction, enhanced biological matter raw material and reaction liquid is disturbed by circulating Heat transfer, makes reaction more uniform and complete.Empirical tests, using the device experiment of the utility model, by setting recycle system of reaction The volume of 103 reactors can accomplish 300 cubes of sizes, and existing simple reaction kettle is only capable of accomplishing 5 cubes of sizes, compares The device of the utility model gets up greatly to meet the demand of industrialized production.In addition, in the present embodiment heater 24 kind Class includes but not limited to round trip sheath tube heater, tube still heater, shell-and-plate heater, and the preferred shell and tube of the present embodiment adds Hot device, carries out indirectly heat to the liquid circulated in reactor 101 by tube still heater, is conducive to react fluid circulation 103 pairs of 101 herb liquid indirectly heats of reactor, rather than heated by steam, if according to traditional reactor, mode of heating is Indirectly heat directly heats, and indirectly heat reaction is uneven, and reaction time is grown；Directly heat however it is open close enter steam to protect Steady temperature and pressure are held, can constantly there is condensed water generation, causes reaction system water content high, the energy of increase subsequent evaporation concentration Consumption.And it is to send reaction solution to heater heating under the action of fluid circulation 103 is reacted directly add using the present apparatus Heat, heating process cross the addition of no moisture, this advantageously reduces the water content of reaction solution, improve the concentration of solid content in liquid.

In biomass and the reaction process of medicine, for that can add and supplement in time medicine, and added there is provided liquid and be System 102, liquid, which adds system 102, as depicted in figs. 1 and 2 includes medicine liquid tank and constant pressure and flow metering pump 11, and medicine liquid tank goes out liquid Mouth is connected through diaphragm valve 13 with the inlet of constant pressure and flow metering pump 11, and the liquid outlet of constant pressure and flow metering pump 11 is added through liquid Pipeline 12 is added mouth 10 with the liquid of reactor 101 and is connected.

Further, the reception device 105 in the present embodiment is as shown in Figure 4 by receiving tank feed inlet 32, gas-liquid separator 33rd, tank body 31, receiving tank lower cone 34 and delivery pump 35 is received to form；One end of receiving tank feed inlet 32 is through discharge pipe 16 Connected with the hypocentrum 3 of reactor 101, its other end is connected with gas-liquid separator 33；The discharge port of gas-liquid separator 33 is with connecing Closed cans body 31 connects, and the bottom for receiving tank body 31 is connected with receiving tank lower cone 34, and receiving tank lower cone 34 is through pipeline and conveying The feed inlet connection of pump 35.Gas-liquid separator 33 is arranged on the surface for receiving tank body 31, in the liquid outlet of gas-liquid separator 33 The center of the liquid outlet of the heart and receiving tank lower cone 34 is on same vertical line, so that gas-liquid separator 33 is by after gas-liquid separation Smoothly from liquid outlet submitting under the pumping of delivery pump 35 of receiving tank lower cone 34, vapour liquid separator 33 is exported to be tubaeform, Expansion evaporation when discharging steam, so that vapor-liquid separation effect is good, and after reaction, reaction solution is discharge with pressure, i.e., from High pressure is to normal pressure, and reacting liquid temperature is at 180 DEG C or so, and entering atmospheric pressure environment will flash naturally, and horn mouth, the design of taper The steam after flash distillation is sent rapidly, be conducive to flash distillation progress, through experiment using the present apparatus carry out verification experimental verification when, it can be achieved that The flash distillation of 15% moisture in reaction solution, reduces the water content of reaction solution, further increases the concentration of solid content in liquid, have Beneficial to the drying of subsequent product, energy consumption for drying is reduced.

As another utility model of the present embodiment, filled as shown in figure 5, waste gas afterheat recovery unit 106 includes recycling Put air intake 41, the ejector condenser 42 connected with retracting device air intake 41, sump 43 and condenser 44.With reference to figure 1 and Fig. 5 is referring to retracting device air intake 41 is connected with the gas outlet of gas-liquid separator 33, and the top of ejector condenser 42 is set Cold water inlet 45 is equipped with, its bottom is provided with liquid outlet.The liquid outlet of ejector condenser 42 is connected with the top of sump 43, Condenser 44 is connected with the top of sump 43；Ejector condenser 42 first further carries out gas-liquid separation to the hot vapour of entrance, The steam isolated in the liquid inflow sump 43 isolated ascends into condenser 44 and carries out condensation separation again, to subtract The discharge of few exhaust gas, so as to fulfill the recycling to hot sewage；Condensation of the condenser 44 to waste vapour is mainly by condenser 44 Lower part and top cooling water inlet 47 and cooling water outlet 48 are set respectively, cold water is flowed into from condenser from cooling water inlet 47 48 adverse current of cooling water outlet on 44 tops flows out the cooling reached to waste vapour.The bottom of sump 43 is provided with hot sewage to go out Mouthfuls 46, organic efficiency is up to more than 80%, and hot sewage, which returns 102 liquids, to be added system 102 and re-used, avoid exhaust gas and The discharge of waste water, is conducive to environmental protection.

In conclusion the course of work of the utility model is during use：Biomass material from reactor feed mouth entrance after, Inlet valve is closed, reactor inlet valve is opened, is passed through steam, while opens reactor air bleeding valve, temperature of reactor reaches 105 DEG C Reactor air bleeding valve is closed afterwards.Heater inlet valve, is passed through steam.The pipeline valve on reaction fluid circulation is opened, Open the circulation pump at the same time, circulating pump flow through heater quilt from reaction solution loop exit extraction liquid in the middle part of reactor, reaction solution Import is circulated by reaction solution after heating and enters reactor from reactor bottom and top respectively.Mended in reaction process by liquid Adding system supplements the loss of liquid.After the completion of reaction, the outlet valve of reactor bottom is opened, reaction solution is from reception device feed inlet Tangentially enter, the separation of gas and liquid is realized in gas-liquid separator, liquid material is fallen into reception device, from connecing The bottom of receiving apparatus is transported to lower waste gas afterheat recovery unit by delivery pump；Gas enters waste gas afterheat recovery unit, passes through Exhaust gas and waste heat are converted into hot sewage by ejector condenser recycling, and hot sewage is directly used in configuration liquid, are recycled.

Reactor in a kind of biomass rapid polymerization humic acid equipment of the utility model, volume is big, and floor space is small, Production capacity is big, is advantageously implemented the scale conversion of biomass.The utility model heats it except being passed through steam to reactor Outside, fluid circulation also is reacted by designing, reaction solution circulation being heated by heater repeatedly is conducive to keep anti- Answer the uniformity of the heating-up temperature of liquid and maintain the constant temperature of reaction solution, overcome and be difficult to maintain reaction constant in existing equipment The problem of temperature, thus be conducive to biomass uniformly, be rapidly and thoroughly converted into humic acid, improve reaction efficiency.And receive Device, vapor-liquid separation effect it is good, it can be achieved that in reaction solution moisture flash distillation, reduce the water content of reaction solution, further improve The concentration of solid content in liquid, is conducive to the drying of subsequent product, reduces energy consumption for drying.In addition, waste gas afterheat recovery unit, Organic efficiency is up to 80%, and hot sewage returns to configuration liquid, avoids the discharge of exhaust gas and waste water, is conducive to environmental protection.

The description of the foregoing specific exemplary embodiment to the utility model be in order to illustrate and illustration purpose.These Description is not wishing to for the utility model to be defined to disclosed precise forms, and it will be apparent that according to the above instruction, can carry out Many change and variations.The purpose of selecting and describing the exemplary embodiment is that explain the certain principles of the utility model And its practical application, so that those skilled in the art can realize and utilize a variety of examples of the utility model Property embodiment and various chooses and changes.The scope of the utility model is intended to by claims and its waits similar shape Formula is limited.

Claims (5)

1. a kind of device using biomass material rapid polymerization humic acid, including：Reactor (101), reaction fluid circulation (103), heating system (104), liquid add system (102), reception device (105) and waste gas afterheat recovery unit (106), its It is characterized in that：

The liquid is added system (102) and is connected with the reactor (101)；

The reaction fluid circulation (103) connects with the reactor (101), the heating system (104) respectively, and formation follows Ring heating circuit；

The discharge port of the reactor (101) is connected with the feed inlet of the reception device (105), the reception device (105) Exhaust outlet connected with the waste gas afterheat recovery unit (106).

2. the device according to claim 1 using biomass material rapid polymerization humic acid, it is characterised in that described Reactor (101), including：Reactor tank body, reactor feed valve (4), reactor outlet valve (5), reactor air intake (6), Reactor exhaust outlet (7), reaction solution circulation import, reaction solution loop exit (8), liquid add mouth (10) and discharge pipe (16), wherein reaction solution circulation import includes the first reaction solution circulation import (91) and the second reaction solution circulation import (92)；

The reactor tank body is made of the cylindrical tube (1) at middle part, upper cone (2) and lower cone (3) three parts；Wherein, The upper cone (2) is provided with the first reaction solution circulation import (91), reactor exhaust outlet (7) and liquid and adds mouth (10)；Institute State and be provided with reaction solution loop exit (8) in the middle part of cylindrical tube (1)；The lower cone (3) is provided with the circulation of the second reaction solution Import (92), reactor air intake (6) and discharge pipe (16)；

The liquid, which adds mouth (10) and adds system (102) with liquid, to be connected；The reaction solution of the reactor (101) recycles Mouth (8), reaction solution circulation import are connected with the reaction fluid circulation (103), the discharging of the reactor (101) Valve (5) is connected through the discharge pipe (16) with the reception device (105).

3. the device according to claim 1 using biomass material rapid polymerization humic acid, it is characterised in that described React fluid circulation (103), including circulating pump and circulation line, the circulating pump is centrifugal pump (23), the circulation pipe Road includes input duct (21) and outlet pipe (22)；

The heating system (104), including：Heater (24), steam inlet (25) and steam (vapor) outlet (26)；

The steam inlet (25) is arranged on the top of the heater (24), and the steam (vapor) outlet (26) is arranged on the heating The lower part of device (24), the input duct (21) of the recycle system of reaction (103) are connected with the bottom of the heater (24), institute The inlet for stating the outlet pipe (22) of recycle system of reaction (103) is connected with the heater (24) middle and upper part, described Outlet pipe (22) is bifurcated and connected with the heater (24).

4. the device according to claim 1 using biomass material rapid polymerization humic acid, it is characterised in that described to connect Receiving apparatus (105) by receiving tank feed inlet (32), gas-liquid separator (33), receive tank body (31), receiving tank lower cone (34) with And delivery pump (35) composition；

One end of the receiving tank feed inlet (32) is connected through discharge pipe (16) with the reactor (101), its other end with Gas-liquid separator (33) connection, the discharge port of the gas-liquid separator (33) is connected with the reception tank body (31), described Receive tank body (31) bottom connected with the receiving tank lower cone (34), the receiving tank lower cone (34) through pipeline with it is described The feed inlet connection of delivery pump (35).

5. the device according to claim 1 using biomass material rapid polymerization humic acid, it is characterised in that described useless The injection that gas waste-heat recovery device (106) includes retracting device air intake (41), connected with the retracting device air intake (41) Formula condenser (42), sump (43) and condenser (44), liquid outlet and the sewage of the ejector condenser (42) The top connection of groove (43), the condenser (44) connect with the top of the sump (43).