Utility model content
Based on this, it is necessary to have the transparent conducting film optical effect for the function that prevents adhesion is poor to ask for existing
A kind of topic, there is provided transparent conducting film and touch screen that can improve optical effect.
A kind of transparent conducting film, including:
Base material, including the first surface and second surface being oppositely arranged;
It is sequentially formed in the first hard conating, the first transparency conducting layer and the first metal layer of the first surface;
It is sequentially formed in the second hard conating, the second transparency conducting layer and second metal layer of the second surface;
First hard conating and/or second hard conating are embedded with multiple particles backwards to the surface of the base material, with
Multiple projections are formed on the surface of the first metal layer and/or the second metal layer;
Wherein, the particle diameter of the particle is the flat site thickness of first hard conating or second hard conating
5% to 25%, the flat site is the region that first hard conating or second hard conating are not provided with the particle.
Existing with the conducting film for preventing adhesion function, the thickness that the particle diameter of particle must be more than hard conating could be in metal
The surface of layer forms projection.Therefore, the particle size of particle is limited to the thickness of hard conating, can not further reduce.However,
Grain particle diameter is bigger, then the haze value increase of conductive film, light transmission rate reduce, and then influence the optical effect of conductive film.
And in the present embodiment, because particle is embedded at the surface of the first hard conating and/or the second hard conating, and particle
Particle diameter is the 5% to 25% of the flat site thickness of the first hard conating or the second hard conating, much smaller than the thickness of hard conating.Cause
This, the particle diameter of particle is not limited by hard coat layer thickness, the particle diameter of particle relative to particle in existing resist blocking and that conducting film grain
Footpath can further reduce, and so as to reduce haze value, lifting light transmission rate, finally improve optical effect.
In one of the embodiments, the material phase of the particle and first hard conating and second hard conating
Together.
That is, particle and the optical parametric of the first hard conating and the second hard conating (being collectively referred to as hard conating below) also phase
Together.Therefore, in particle and the linkage interface of hard conating, light propagation institute is impacted smaller, and it is one that particle is closer with hard conating
Individual entirety.During when light through the hard conating containing particle, distortion caused by its round is smaller.Therefore, transparent conductivity
Film reach resist blocking and that, purpose that resistance to compression connects simultaneously, moreover it is possible to further avoid its optical property from being adversely affected.
In one of the embodiments, the material of the particle is silica, organosilicon polymer, acrylic
Thing or styrene polymer.
Above material has the advantage that translucency is good, is easily obtained, can be on the premise of performance requirement is met for particle
Reduce cost.
In one of the embodiments, along perpendicular to the first metal layer and/or the second metal layer surface
On direction, the multiple raised height is 0.1~0.5 μm.
In one of the embodiments, the thickness of the flat site is 0.5~2 μm.
Raised height is higher, then resist blocking and that effect is better.But as the rise of height, the size of particle accordingly need
Increase, so as to cause the haze value of transparent conducting film also to increase therewith, and will serious shadow after reaching to a certain degree
Ring the optical effect of transparent conducting film.And in above-mentioned thickness and altitude range, transparent conducting film can be preferably simultaneous
Care for resist blocking and that and optical effect.
In one of the embodiments, the particle is spherical in shape.Particle surface spherical in shape is smoother, can effectively prevent pair
Transparency conducting layer and metal level cause to damage.
In one of the embodiments, the base material is polycyclic alkene or makrolon or polyethylene terephthalate
Film.
The two kinds of film can meet the requirement to the birefringence and its deviation of base material, and be easy to obtain.Cause
This, can advantageously reduce the cost of transparent conducting film.
In one of the embodiments, the raised distribution density is 100~3000/mm2。
It when raised distribution density is excessive, can cause that the haze value of transparent conducting film is excessive, light transmission rate reduces, enter
And have a strong impact on the outward appearance and optical effect of transparent conducting film.And if raised distribution density is too small, then resist blocking and that
Effect is limited.In above-mentioned roughness and density range, transparent conducting film can preferably take into account resist blocking and that and optical effect.
A kind of touch screen, the touch screen are made as the transparent conducting film any one of above preferred embodiment
Into the touch screen includes Touch Zone and lead district, and the first metal layer and the second metal layer are located at the lead district;
The Touch Zone include by first transparency conducting layer first electrode that forms of etching and by the etching of the second transparency conducting layer and
Into second electrode;The lead district is included by the first metal layer and the first transparency conducting layer quilt positioned at the lead district
The first lead formed is etched, and shape is etched by the second metal layer and positioned at the second transparency conducting layer of the lead district
Into the second lead.
In above-mentioned touch screen, by the first metal layer, second metal layer, the first transparency conducting layer and the second transparency conducting layer
Directly etching obtains the first lead and the second lead.It is therefore not necessary to formed and first electrode and the second electricity by silk-screen mode again
The lead of pole electrical connection.Compared with traditional touch screen, due to without silk-screen, the contact conductor directly formed by gold-tinted processing procedure
Width can further reduce, therefore touch screen has narrow frame.
Embodiment
For the ease of understanding the utility model, the utility model is more fully retouched below with reference to relevant drawings
State.Preferred embodiment of the present utility model is given in accompanying drawing.But the utility model can come in many different forms
Realize, however it is not limited to embodiment described herein.On the contrary, the purpose for providing these embodiments is made to of the present utility model
The understanding of disclosure more thorough and comprehensive.
It should be noted that when element is referred to as " being fixed on " another element, it can be directly on another element
Or there may also be element placed in the middle.When an element is considered as " connection " another element, it can be directly connected to
To another element or it may be simultaneously present centering elements.Term as used herein " vertical ", " horizontal ", " left side ",
" right side " and similar statement are for illustrative purposes only.
Unless otherwise defined, all of technologies and scientific terms used here by the article is led with belonging to technology of the present utility model
The implication that the technical staff in domain is generally understood that is identical.It is simply in term used in the description of the present utility model herein
The purpose of description specific embodiment, it is not intended that in limitation the utility model.Term as used herein " and/or " include
The arbitrary and all combination of one or more related Listed Items.
Fig. 1 and Fig. 2 is referred to, the transparent conducting film 10 in the utility model preferred embodiment includes base material 11, the
One hard conating 12, the first transparency conducting layer 13, the first metal layer 14, the second hard conating 22, the second transparency conducting layer 23 and second
Metal level 24.
Base material 11 includes the first surface (upper surface shown in Fig. 1) and second surface (lower surface shown in Fig. 1) being oppositely arranged.
Base material 11 is formed by amorphism thin polymer film.Because amorphism thin polymer film is smaller simultaneously than crystalline polymer film birefringence
And uniformly, the irregular colour that can be eliminated in transparent conducting film 10 of the present utility model is even.For amorphous of the present utility model
Birefringence in the face of property thin polymer film is preferably 0~0.001, and more preferably 0~0.0005.It is new for this practicality
The deviation of birefringence in the face of the amorphism thin polymer film of type is preferably less than 0.0005, and more preferably 0.0003
Below.
Foregoing birefringence and its deviation can be reached by selecting the amorphism thin polymer film of suitable species.Specifically
In the present embodiment, base material 11 is polycyclic alkene or makrolon or pet film.The two types
Film can meet the requirement of birefringence and its deviation.The thickness of the base material 11 formed by amorphism thin polymer film is 20 μm
~200 μm.
First hard conating 12, the first transparency conducting layer 13 and the first metal layer 14 are sequentially formed in the first table of base material 11
Face.Second hard conating 22, the second transparency conducting layer 23 and second metal layer 24 are sequentially formed in the second surface of base material 11.Its
In:
First hard conating 12 plays a protective role to the first surface of base material 11.First hard conating 12 includes binding agent tree
Fat.The resin glue includes the hardening resin composition for example based on ultraviolet, electron ray.Hardening resin composition
Preferably comprise polymer obtained from glycidyl acrylate based polymer carries out addition reaction with acrylic acid.Or solidification
Property resin combination preferably comprises polyfunctional acrylic ester polymer (pentaerythrite, dipentaerythritol etc.).Curable resin group
Compound also includes polymerization initiator.
First transparency conducting layer 13 is formed at the surface of the first hard conating 12.First transparency conducting layer 13 is by visible region
Sheet resistance value (the unit of transmissivity height (more than 80%) and per unit area in domain (380nm~780nm):Ω/m2) be
500Ω/m2Following layer is formed.Preferred 15nm~the 100nm of thickness of first transparency conducting layer 13, more preferably 15nm~
50nm.First transparency conducting layer 13 is for example by indium tin oxide (ITO), indium tin oxide or indium oxide-zinc oxide composites
Any formation.
The first metal layer 14 is formed on the surface of the first transparency conducting layer 13.The first metal layer 14 is of the present utility model
When transparent conducting film is used for such as touch panel, connected up for being formed in the outside of touch input area.On forming the
The material of one metal level 15, representational is copper, silver, it is possible to use the arbitrary metal of excellent electric conductivity in addition.
The thickness of the first metal layer 14 is preferably 50nm~500nm, more preferably 100nm~300nm.
Further, the second hard conating 22, the second transparency conducting layer 23 and second metal layer 24 respectively with the first hard conating
12nd, the film layer structure of the first transparency conducting layer 13 and the first metal layer 14, function and material composition are identical, therefore no longer superfluous herein
State.
In addition, the first hard conating 12 and/or the second hard conating 22 are embedded with multiple particles 15 backwards to the surface of base material 11, with
Multiple raised 16 are formed on the surface of the first metal layer 14 and/or second metal layer 24.The particle diameter of particle 15 is the first hard conating
12 or second hard conating 22 the thickness of flat site 17 5% to 25%.Wherein, flat site 17 is the first hard conating 12 or the
Two hard conatings 22 are not provided with the region of particle 15.
Specifically, particle 15 can irregularly, can also preset rules (as equably) be distributed in the first hard conating 12
And/or second in hard conating 22.Particle 15 can be spheric granules, or unsetting particle.For spheric granules when, particle 15
Particle diameter be its diameter;During without amorphous particles, the particle diameter of particle 15 is equal to the arithmetic mean of instantaneous value of the size in its all directions.
Particle 15 is embedded at the surface of the first hard conating 12 and/or the second hard conating 22, is not contacted directly with base material 11.
Therefore, still can be in the first metal layer 14 and/or second metal layer 24 when the particle diameter of particle 15 is less than the thickness of flat site 17
Surface formed projection 16.Specifically in embodiment, particle 15 is spherical in shape.The surface of particle 15 spherical in shape is smoother, can be effective
Prevent that transparency conducting layer and metal level are caused to damage.
Particle 15 can only be embedded at the surface in the first hard conating 12 or the second hard conating 22, so as to obtain one side formed with
The transparent conducting film 10 of projection 16;Particle 15 also can be embedded at the surface of the first hard conating 12, and it is hard to be also embedded at second
The surface of coating 22, so as to obtain the two-sided transparent conducting film 10 formed with projection 16.
Illustrated by taking the first hard conating 12 as an example:
Particle 15 protrudes from the surface of the first hard conating 12, so that the surface of the first hard conating 12 forms the area of evagination
Domain, and the region that the first hard conating 12 is not provided with particle 15 then forms flat site 17.Due to the first transparency conducting layer 13 and
One metal level 14 is cascading the surface with the first hard conating 12, therefore both surface configurations and the table of the first hard conating 12
Face shape is identical.Therefore, in the first metal layer 14 and 14 corresponding region of particle, multiple raised 16 can be formed.
Similarly, when containing particle 15 in the second hard conating 22, the surface of second metal layer 24 can also form multiple raised 16.
When using volume to volume technique (roll to roll process) to manufacture the transparent conductive film 10 of strip, by
The surface of the first metal layer 14 and/or second metal layer 24 is set to form multiple raised 16 in particle 15.Therefore, transparent lead is being crimped
During electric thin film 10, multiple raised 16 can make to form point contact between two neighboring metal level, so as to prevent its inter-adhesive, pressure
Connect.
Existing with the conducting film for preventing adhesion function, the thickness that the particle diameter of particle must be more than hard conating could be in metal
The surface of layer forms projection.Therefore, the particle size of particle is limited to the thickness of hard conating, can not further reduce.However,
Grain particle diameter is bigger, then the haze value increase of conductive film, light transmission rate reduce, and then influence the optical effect of conductive film.
And in transparent conductive film 10, because particle 15 is embedded at the first hard conating 12 and/or the second hard conating 22
Surface, and the particle diameter of particle 15 is the thickness of flat site 17 of the first hard conating 12 or the second hard conating 22 (being collectively referred to as hard conating below)
The 5% to 25% of degree, much smaller than the thickness of hard conating.Therefore, the particle diameter of particle 15 is not limited by hard coat layer thickness, particle 15
Particle diameter can further be reduced relative to the particle diameter of particle in existing resist blocking and that conducting film, so as to reduce haze value, lifting light it is saturating
Rate is crossed, finally improves optical effect.
In the present embodiment, the surface of the first hard conating 12 and the second hard conating 22 is embedded with particle 15, so that first
The surface of metal level 14 and second metal layer 24 is each formed with multiple raised 16.
That is, the two-sided of resulting transparent conducting film 10 is each formed with multiple raised 16.Therefore, crimping
During transparent conducting film 10, the point position that contact is put between adjacent two metal levels is increased, therefore the effect that its resist blocking and that, resistance to compression connect
Fruit is more preferable.
Referring to Fig. 3, in another embodiment, the surface of any of the first hard conating 12 and second hard conating 22 is embedding
Provided with particle 15, so that the surface of the first metal layer 14 or second metal layer 24 is formed with multiple raised 16.
That is, the resulting only one side of transparent conducting film 10 has projection 16.Resist blocking and that, resistance to compression can played
While connecing effect, moreover it is possible to avoid the shade of two layers of particle 15 from being overlapped mutually, further to mitigate mist degree, so as to lift transparent lead
The optical effect of electric thin film 10.
In the present embodiment, particle 15 is identical with the material of the first hard conating 12 and the second hard conating 22.
Because particle 15 is identical with the material of the first hard conating 12 and the second hard conating 22 (being collectively referred to as hard conating below), therefore its
Optical parametric is also identical.Therefore, in the linkage interface of particle 15 and hard conating, it is impacted smaller that light propagates institute, particle 15 with
It is an entirety that hard conating is closer.During when light through the first hard conating 12 and the second hard conating 22 containing particle 15, its
Distortion is smaller caused by round.Therefore, transparent conducting film 10 reach resist blocking and that, purpose that resistance to compression connects simultaneously, also
It is avoided that its optical property is adversely affected.
Further, in the present embodiment, the material of particle 15 is silica, organosilicon polymer, acrylic polymer
Compound or styrene polymer.
Above material has the advantage that translucency is good, is easily obtained, and can meet the premise of performance requirement for particle 15
Decline low cost.Certainly, also other suitable materials can be selected according to the performance and cost needs of reality.
In order to realize, more preferably resist blocking and that, resistance to compression connect effect and optical effect, have for the dense degree of projection 16
It is corresponding to require.
In the present embodiment, the first metal layer 14 and/or the surface of second metal layer 24, the distribution density of projection 16 is 100
~3000/mm2。
When the distribution density of projection 16 is excessive, it can cause that the haze value of transparent conducting film 10 is excessive, light transmission rate drop
It is low, and then have a strong impact on the outward appearance and optical effect of transparent conducting film 10.And if the distribution density of projection 16 is too small, then
The effect of resist blocking and that is limited.In above-mentioned roughness and density range, transparent conducting film 10 can preferably take into account resist blocking and that
And optical effect.
In addition, more preferably resist blocking and that, resistance to compression connect effect and optical effect in order to realize, for the first hard conating 12 i.e. the
The thickness of two hard conatings 22 and the height of projection 16 have corresponding requirement.
In the present embodiment, it is multiple on edge on the direction on the first metal layer 14 and/or the surface of second metal layer 24
The height of projection 16 is 0.1~0.5 μm.Further, in the present embodiment, the thickness of flat site 17 is 0.5~2 μm.
The height of projection 16, refer to that projection 16 protrudes from the height on the first metal layer 14 and/or the surface of second metal layer 24
Degree.Because the size of particle 15 is smaller, therefore it is difficult to be accurately controlled each raised 16 height.Therefore, by projection 16
Highly control is in above-mentioned altitude range.It is pointed out that in actual production, due to being difficult to each particle 15
Accurately controlled, therefore the height for having the projection 16 that few partial particulate 15 is formed being difficult to avoid that is located above range
Outside.But influenceed caused by part projection 16 negligible.Moreover, above-mentioned height also may refer in preset range
The arithmetic mean of instantaneous value of interior a number of raised 16 height.
In general, the height of projection 16 is higher, then resist blocking and that effect is better.But with the rise of height,
The size of grain 15 so as to cause the haze value of transparent conducting film 10 also to increase therewith, and reaches one mutually in requisition for increase
Determine will to have a strong impact on after degree the optical effect of transparent conducting film 10.And in above-mentioned altitude range, transparent conductivity
Film 10 can preferably take into account resist blocking and that and optical effect.
Wherein, the height of projection 16 can be changed by adjusting the insert depth of the size of particle 15 and particle 15.
Above-mentioned transparent conducting film 10, particle 15 form the first metal layer 14 and/or the surface of second metal layer 24
Multiple raised 16, so as to play a part of preventing adhesion.It is additionally, since particle 15 and is embedded at the first hard conating 12 and/or second
The surface of hard conating 22, and the particle diameter of particle 15 is the thickness of flat site 17 of the first hard conating 12 or the second hard conating 22
5% to 25%, much smaller than the thickness of hard conating.Therefore, it is above-mentioned transparent compared with traditional conducting film with the function that prevents adhesion
The particle diameter of particle is substantially reduced in conductive membrane 10.The particle diameter of particle 15 is smaller, and the effect of blocking to light is weaker.Therefore, may be used
Haze value, the lifting light transmission rate of above-mentioned transparent conducting film 10 are reduced, so as to finally improve optical effect.
In addition, the utility model also provides a kind of touch screen.Also referring to Fig. 4, in the utility model preferred embodiment
Touch screen 200 as made by the transparent conducting film 10 in above-described embodiment.Wherein:
Touch screen 200 includes Touch Zone 210 and lead district 220.Specifically, Touch Zone 210 is located in touch screen 200
Portion, and lead district 220 is then around the circumferentially disposed of Touch Zone 210.The first metal layer 14 and second metal layer 24 are located at lead district
220。
Touch Zone 210 includes first electrode 211 and second electrode 212.Wherein, first electrode 211 is by the first electrically conducting transparent
The etching of layer 13 forms;Second electrode 212 is etched by the second transparency conducting layer 23 and formed.First electrode 211 and second electrode 212 are lost
It is carved into electrode pattern.Specifically, electrode pattern is general elongated and intersects vertically in latticed, relative first electrode 211
And second electrode 212 forms the two poles of the earth of capacitance structure.
Lead district 220 includes the first lead 221 and the second lead 222.First lead 221 is by the first metal layer 14 and is located at
First transparency conducting layer 13 of lead district 220 is etched to form;Second lead 222 is then by second metal layer 24 and positioned at lead district
220 the second transparency conducting layer 23 is etched to form.First lead 221 and the second lead 222 are double-decker, so as to realize with
First electrode 211 and second electrode 212 electrically connect.
It is transparent by the first metal layer 14, second metal layer 24, the first transparency conducting layer 13 and second in above-mentioned touch screen
The directly etching of conductive layer 23 obtains the first lead 221 and the second lead 222.Therefore, because without silk-screen, directly by gold-tinted processing procedure
The width of the contact conductor of formation can further reduce, therefore touch screen has narrow frame.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality
Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, the scope that this specification is recorded all is considered to be.
Embodiment described above only expresses several embodiments of the present utility model, and its description is more specific and detailed,
But therefore it can not be interpreted as the limitation to utility model patent scope.It should be pointed out that the common skill for this area
For art personnel, without departing from the concept of the premise utility, various modifications and improvements can be made, these are belonged to
The scope of protection of the utility model.Therefore, the protection domain of the utility model patent should be determined by the appended claims.