CN207169393U - A kind of Biohazard Waste based on fuse salt is burned, pyrolysis exhaust gas purification system - Google Patents

A kind of Biohazard Waste based on fuse salt is burned, pyrolysis exhaust gas purification system Download PDF

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Publication number
CN207169393U
CN207169393U CN201720399313.8U CN201720399313U CN207169393U CN 207169393 U CN207169393 U CN 207169393U CN 201720399313 U CN201720399313 U CN 201720399313U CN 207169393 U CN207169393 U CN 207169393U
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China
Prior art keywords
biohazard waste
tail gas
dehydrater
molten salt
utility
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CN201720399313.8U
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Chinese (zh)
Inventor
冯宜鹏
李勇峰
苏建修
付成果
郭昊
马孝琴
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Henan Institute of Science and Technology
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Henan Institute of Science and Technology
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Abstract

It the utility model is related to a kind of Biohazard Waste based on fuse salt to burn, be pyrolyzed exhaust gas purification system, it includes flue gas quenching tower, sack cleaner, the first dehydrater, molten salt reaction device, spray column, the second dehydrater and the air-introduced machine being sequentially connected with by pipeline.Pipeline between flue gas quenching tower and sack cleaner is provided with to add the feeding screw of activated carbon.The utility model can improve the clean-up effect that Biohazard Waste is burned, is pyrolyzed tail gas, simplify purification process.When chlorine-containing waste in Biohazard Waste(Plastic containing chlorine, rubber etc.)With nitrogenous discarded object(Diseased organ, nitrogenous medicine etc.)When content is higher, clean-up effect of the present utility model becomes apparent, and not only more can thoroughly remove chloride, the nitrogen-containing pollutant of tail gas middle and high concentration, reduce environmental pollution, moreover it is possible to realize the simultaneous removing of the two, simplify tail gas clean-up technique.

Description

A kind of Biohazard Waste based on fuse salt is burned, pyrolysis exhaust gas purification system
Technical field
The utility model belongs to burning, pyrolysis tail gas clean-up technical field, and in particular to a kind of medical treatment based on fuse salt Castoff burning, the cleaning system and method for being pyrolyzed tail gas.
Background technology
Biohazard Waste has caused by referring to medical and health organization in medical prevention, health care and other correlated activations The waste of directly or indirectly infectious, toxicity and other harmfulness.Because its harmfulness is larger, international regulations must carry out nothing Evilization processing.Wherein, existing most popular technology is burning, pyrolysis processing, but containing substantial amounts of in Biohazard Waste Chlorinated organics(PVC plastic, rubber, leather etc.)And itrogenous organic substance(Human body or animal deformed limb, nitrogenous discarded medicine etc.) Cause to contain cl contaminant containing higher concentration in the tail gas of its output(HCl)And nitrogen-containing pollutant(HCN、NOx), it is therefore necessary to Harmless treatment is carried out to tail gas.
At present, it is semidry method to remove the conventional method of HCl, HCN, and removes NOx and then use selective catalytic reduction more (SCR methods), aerogenesis pollutant could be purified in two steps by generally requiring, and process is complex.In addition, semidry method is acid dirty When dye thing concentration is higher, treatment effect is general, and Biohazard Waste is burned, acid contaminant very high concentrations in pyrolysis aerogenesis, is caused Make semidry method general to its tail gas acid gas removal effect.
Utility model content
The utility model aims to overcome that prior art defect, there is provided a kind of Biohazard Waste based on fuse salt is burnt Burn, the cleaning system and method for pyrolysis tail gas, its can with simultaneous removing chloride, nitrogen-containing pollutant, and removal efficiency is higher.
To achieve the above object, the utility model adopts the following technical scheme that:
A kind of Biohazard Waste based on fuse salt is burned, pyrolysis exhaust gas purification system, and it includes sequentially connecting by pipeline Flue gas quenching tower, sack cleaner, the first dehydrater, molten salt reaction device, spray column, the second dehydrater and the air-introduced machine connect.
It is further preferred that it is provided with pipeline between flue gas quenching tower and sack cleaner to add activated carbon Feeding screw.
Specifically, the quantity of the molten salt reaction device is two, two molten salt reaction devices are connected in parallel, and one with one It is standby.Both only connect one, when fuse salt reaches saturation in a reactor, switch to another reactor, while will reach Fuse salt to saturation is discharged, add in the reactor after emptying fuse salt and being heated to melt it is standby.
Specifically, above-mentioned cleaning system also includes the first shunt valve and the second shunt valve;The both ends of first shunt valve It is connected in parallel with sack cleaner(According to the pressure difference at both ends safety valve can be controlled to be opened and closed), one end of second shunt valve with Pipeline connection between molten salt reaction device and spray column, the pipeline connection between the other end and the second dehydrater and air-introduced machine (According to the pressure difference at both ends safety valve can be controlled to be opened and closed).
Biohazard Waste burning, the method for being pyrolyzed tail gas clean-up are carried out using said system, is specially:To molten salt reaction Added in device and fuse salt and be heated to molten condition, Biohazard Waste is burned, be pyrolyzed tail gas introducing flue gas quenching tower and cold But to less than 200 DEG C, tail gas after cooling after sack cleaner removes large-size particles thing, the first dehydrater removes moisture, React removing pollutant into molten salt reaction device, removes the tail gas after pollutant and is sequentially removed water through spray column and second Discharged after device.
Fuse salt refers to the alkali metal bases of molten state under high temperature, the mixture of salt, employed in the utility model Melting salt component be by potassium, sodium, lithium alkaloid compound and its esters compound group into mixture.The fuse salt specifically may be used Think NaOH+Na2CO3、KOH+K2CO3、NaOH+K2CO3、KOH+Na2CO3Or LiOH+Li2CO3, wherein, potassium, sodium, the bases of lithium Weight percentage of the compound in fuse salt is not less than 40%.
Fuse salt in the utility model burns to Biohazard Waste, pyrolysis tail gas middle and high concentration it is chloride, containing polluted by nitrogen Thing can be removed thoroughly, and the main chemical reactions occurred in molten salt reaction device are as follows:
Note:1)M represents K, Na, Li alkali metal in formula;2)Reaction equation(3)Only alkaloid compound is in high-temperature molten-state Lower progress(With NOx this reaction does not occur for the alkaloid compound of solvent state).
Compared to the prior art, advantage of the present utility model is:The utility model can improve Biohazard Waste burn, The clean-up effect of tail gas is pyrolyzed, simplifies purification process.When chlorine-containing waste in Biohazard Waste(Plastic containing chlorine, rubber etc.)With containing Nitrogen discarded object(Diseased organ, nitrogenous medicine etc.)When content is higher, clean-up effect of the present utility model becomes apparent, not only can be compared with Thoroughly to remove chloride, the nitrogen-containing pollutant of tail gas middle and high concentration, reduce environmental pollution, moreover it is possible to realize that the synchronization of the two takes off Remove, simplify tail gas clean-up technique.
Brief description of the drawings
Fig. 1 is the structure that exhaust gas purification system was burned, was pyrolyzed in the Biohazard Waste described in the utility model based on fuse salt Schematic diagram.
Embodiment
The technical solution of the utility model is further discussed in detail with reference to embodiments, but it is of the present utility model Protection domain is not limited thereto.
Embodiment 1
As shown in fig. 1, a kind of Biohazard Waste based on fuse salt burns, is pyrolyzed exhaust gas purification system, and it includes logical Cross the flue gas quenching tower 1, sack cleaner 3, the first dehydrater 5, molten salt reaction device, spray column 11, that pipeline is sequentially connected with Two dehydraters 12 and Roots's air-introduced machine 13.It is provided with pipeline between flue gas quenching tower 1 and sack cleaner 3 to add work The feeding screw 2 of property charcoal.
The quantity of the molten salt reaction device is two, is the first molten salt reaction device 7 and the second molten salt reaction respectively Device 9, two molten salt reaction devices are connected in parallel, the using and the reserved.First molten salt reaction device 7 and the institute of the second molten salt reaction device 9 Pipeline on be respectively equipped with the first valve 6 and the second valve 8, to control gas path on-off.Above-mentioned cleaning system also includes the One shunt valve 4 and the second shunt valve 10;The both ends of first shunt valve 4 are connected in parallel with sack cleaner 3(Can be according to both ends Pressure difference control the safety valve to be opened and closed), between one end of second shunt valve 10 and molten salt reaction device and spray column 11 Pipeline connects, the pipeline connection between the other end and the second dehydrater 12 and Roots's air-introduced machine 13(Can according to the pressure difference at both ends come Control safety valve opening and closing).Shower is installed, for absorbing the alkali particle carried in gas in spray column.
Biohazard Waste burning, the method for being pyrolyzed tail gas clean-up are carried out using said system, it is into molten salt reaction device Add fuse salt(NaOH+Na2CO3, contents of the NaOH in fuse salt is 60wt%)And molten condition is heated to, by medical waste Thing burns, pyrolysis tail gas introduces flue gas quenching tower and is cooled to less than 200 DEG C, and the tail gas after cooling removes through sack cleaner After large-size particles thing, the first dehydrater remove moisture, react removing pollutant into molten salt reaction device, and removing is dirty Tail gas after dye thing is sequentially discharged after spray column and the second dehydrater.Detailed process is as follows:Tail gas is from medical castoff burning Stove, pyrolysis oven discharge, its temperature is about 300 ~ 600 DEG C.In order to reduce the generation of bioxin, tail gas initially enters flue gas quenching tower 1, less than 200 DEG C are rapidly cooled to, cooling water used is industrial water.Tail gas after cooling and the work from feeding screw 2 Property charcoal mixing, the wherein less particulate matter of particle diameter is adsorbed in activated carbon, after sack cleaner 3 is entered, the big grain in tail gas Footpath particulate matter and activated carbon are removed.After the water removal of the first dehydrater 5, tail gas enters the first molten salt reaction device 7, tail gas In chloride, nitrogen-containing pollutant and fuse salt react generation villaumite, nitrate etc., if at the same time containing CO in tail gas, Then CO and molten salt reaction generation H2, thus while pollutant is removed, tail gas is had certain value.When When one molten salt reaction device 7 reaches saturation, switching gas circuit uses the second standby molten salt reaction device 9(First molten salt reaction Saturation fuse salt in device 7 empties, add new salt, bases melted as fuse salt and being heated to it is standby).It is anti-from fuse salt The gas for answering device to export enters spray column 11, salt, the bases particle carried in gas is removed using industrial Water spray, then be passed through Discharged after the water removal of second dehydrater 12.
Experiment effect is verified:Using the remarkable box Muffle furnace of QSXL-1230 types atmosphere protection, 800 DEG C are warming up to, will be certain Biohazard Waste after amount crushes is put into stove, and being passed through air makes its sustained combustion, the gas after burning is passed directly into is The flue gas quenching tower 1 of system, HCl, NOx, HCN concentration after purification in gas are continued to monitor in the top of the system, end.As a result Display:HCl concentration reaches as high as about 6100ppm in non-purified preceding gas, and NOx is up to about 2450ppm, and HCN is up to about 950ppm, and HCl, NOx, HCN are not detected in gas after purifying(The detection lowest limit is 0.1ppm).The result shows this reality There is significant removal effect for high concentration HCl, NOx, HCN in Biohazard Waste combustion tail gas with novel system.
In summary:Tthe utility model system can effectively improve the purification efficiency that Biohazard Waste is burned, is pyrolyzed tail gas, Simplify purification process technique:When tail gas is chloride, nitrogenous pollution concentration is higher, advantage becomes apparent, and only need to change and add in time Fuse salt can is added to meet the pollutant removing of higher concentration, supreme limit value.Tthe utility model system also by the dechlorination of tail gas, Denitration is integrated in same step and completed, and technological process is simpler.In addition, causticizing process can be used after molten salt reaction saturation(Papermaking The bases reclaiming technique that industry is widely used)Regeneration, regenerates bases by carbonate therein, makes fuse salt again It can recycle.
Above-described embodiment be to explanation of the present utility model, be not to restriction of the present utility model, it is any new to this practicality Scheme after type simple transformation belongs to the scope of protection of the utility model.

Claims (3)

1. a kind of Biohazard Waste based on fuse salt is burned, pyrolysis exhaust gas purification system, it is characterised in that including passing through pipeline The flue gas quenching tower that is sequentially connected with, sack cleaner, the first dehydrater, molten salt reaction device, spray column, the second dehydrater and draw Blower fan;
Pipeline between flue gas quenching tower and sack cleaner is provided with to add the feeding screw of activated carbon.
2. the Biohazard Waste based on fuse salt burns, is pyrolyzed exhaust gas purification system as claimed in claim 1, it is characterised in that The quantity of the molten salt reaction device is two, and two molten salt reaction devices are connected in parallel, the using and the reserved.
3. the Biohazard Waste based on fuse salt burns, is pyrolyzed exhaust gas purification system as claimed in claim 2, it is characterised in that Also include the first shunt valve and the second shunt valve;The both ends of first shunt valve are connected in parallel with sack cleaner, and described Pipeline connection between one end of two shunt valves and molten salt reaction device and spray column, the other end and the second dehydrater and air-introduced machine Between pipeline connection.
CN201720399313.8U 2017-04-17 2017-04-17 A kind of Biohazard Waste based on fuse salt is burned, pyrolysis exhaust gas purification system Expired - Fee Related CN207169393U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106955575A (en) * 2017-04-17 2017-07-18 河南科技学院 A kind of Biohazard Waste based on fuse salt burns, is pyrolyzed exhaust gas purification system and method
CN108654291A (en) * 2018-07-20 2018-10-16 株洲中车南方环保科技有限公司 Small-sized living garbage incinerator flue gas preprocess method and preprocessor
CN109331557A (en) * 2018-11-22 2019-02-15 合肥中亚环保科技有限公司 A kind of cement kiln bypass flue gas purifying method
CN112128766A (en) * 2020-09-22 2020-12-25 王玲 Waste plastic pyrolysis incineration disposal line and waste plastic pyrolysis incineration disposal method
CN114251661A (en) * 2021-11-30 2022-03-29 上海工程技术大学 Low-nitrogen combustion circulating fluidized bed system for treating kitchen garbage and application thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106955575A (en) * 2017-04-17 2017-07-18 河南科技学院 A kind of Biohazard Waste based on fuse salt burns, is pyrolyzed exhaust gas purification system and method
CN108654291A (en) * 2018-07-20 2018-10-16 株洲中车南方环保科技有限公司 Small-sized living garbage incinerator flue gas preprocess method and preprocessor
CN109331557A (en) * 2018-11-22 2019-02-15 合肥中亚环保科技有限公司 A kind of cement kiln bypass flue gas purifying method
CN112128766A (en) * 2020-09-22 2020-12-25 王玲 Waste plastic pyrolysis incineration disposal line and waste plastic pyrolysis incineration disposal method
CN114251661A (en) * 2021-11-30 2022-03-29 上海工程技术大学 Low-nitrogen combustion circulating fluidized bed system for treating kitchen garbage and application thereof
CN114251661B (en) * 2021-11-30 2023-05-30 上海工程技术大学 Low-nitrogen combustion circulating fluidized bed system for treating kitchen waste and application thereof

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Granted publication date: 20180403