CN207169393U - A kind of Biohazard Waste based on fuse salt is burned, pyrolysis exhaust gas purification system - Google Patents
A kind of Biohazard Waste based on fuse salt is burned, pyrolysis exhaust gas purification system Download PDFInfo
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- CN207169393U CN207169393U CN201720399313.8U CN201720399313U CN207169393U CN 207169393 U CN207169393 U CN 207169393U CN 201720399313 U CN201720399313 U CN 201720399313U CN 207169393 U CN207169393 U CN 207169393U
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- Prior art keywords
- biohazard waste
- tail gas
- dehydrater
- molten salt
- utility
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- 150000003839 salts Chemical class 0.000 title claims abstract description 59
- 239000002699 waste material Substances 0.000 title claims abstract description 27
- 238000000746 purification Methods 0.000 title claims abstract description 14
- 238000000197 pyrolysis Methods 0.000 title claims description 11
- 239000007789 gas Substances 0.000 claims abstract description 51
- 238000006243 chemical reaction Methods 0.000 claims abstract description 31
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003546 flue gas Substances 0.000 claims abstract description 12
- 238000010791 quenching Methods 0.000 claims abstract description 12
- 230000000171 quenching effect Effects 0.000 claims abstract description 12
- 239000007921 spray Substances 0.000 claims abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 abstract description 16
- 239000003344 environmental pollutant Substances 0.000 abstract description 11
- 231100000719 pollutant Toxicity 0.000 abstract description 11
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000460 chlorine Substances 0.000 abstract description 4
- 229910052801 chlorine Inorganic materials 0.000 abstract description 4
- 239000003814 drug Substances 0.000 abstract description 3
- 239000004033 plastic Substances 0.000 abstract description 3
- 239000005060 rubber Substances 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 210000000056 organ Anatomy 0.000 abstract description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 239000002585 base Substances 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- -1 lithium alkaloid compound Chemical group 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Chemical group 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229930013930 alkaloid Natural products 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000008235 industrial water Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000001994 activation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 238000009993 causticizing Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical group 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000006298 dechlorination reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000002458 infectious effect Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 239000002906 medical waste Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Treating Waste Gases (AREA)
Abstract
It the utility model is related to a kind of Biohazard Waste based on fuse salt to burn, be pyrolyzed exhaust gas purification system, it includes flue gas quenching tower, sack cleaner, the first dehydrater, molten salt reaction device, spray column, the second dehydrater and the air-introduced machine being sequentially connected with by pipeline.Pipeline between flue gas quenching tower and sack cleaner is provided with to add the feeding screw of activated carbon.The utility model can improve the clean-up effect that Biohazard Waste is burned, is pyrolyzed tail gas, simplify purification process.When chlorine-containing waste in Biohazard Waste(Plastic containing chlorine, rubber etc.)With nitrogenous discarded object(Diseased organ, nitrogenous medicine etc.)When content is higher, clean-up effect of the present utility model becomes apparent, and not only more can thoroughly remove chloride, the nitrogen-containing pollutant of tail gas middle and high concentration, reduce environmental pollution, moreover it is possible to realize the simultaneous removing of the two, simplify tail gas clean-up technique.
Description
Technical field
The utility model belongs to burning, pyrolysis tail gas clean-up technical field, and in particular to a kind of medical treatment based on fuse salt
Castoff burning, the cleaning system and method for being pyrolyzed tail gas.
Background technology
Biohazard Waste has caused by referring to medical and health organization in medical prevention, health care and other correlated activations
The waste of directly or indirectly infectious, toxicity and other harmfulness.Because its harmfulness is larger, international regulations must carry out nothing
Evilization processing.Wherein, existing most popular technology is burning, pyrolysis processing, but containing substantial amounts of in Biohazard Waste
Chlorinated organics(PVC plastic, rubber, leather etc.)And itrogenous organic substance(Human body or animal deformed limb, nitrogenous discarded medicine etc.)
Cause to contain cl contaminant containing higher concentration in the tail gas of its output(HCl)And nitrogen-containing pollutant(HCN、NOx), it is therefore necessary to
Harmless treatment is carried out to tail gas.
At present, it is semidry method to remove the conventional method of HCl, HCN, and removes NOx and then use selective catalytic reduction more
(SCR methods), aerogenesis pollutant could be purified in two steps by generally requiring, and process is complex.In addition, semidry method is acid dirty
When dye thing concentration is higher, treatment effect is general, and Biohazard Waste is burned, acid contaminant very high concentrations in pyrolysis aerogenesis, is caused
Make semidry method general to its tail gas acid gas removal effect.
Utility model content
The utility model aims to overcome that prior art defect, there is provided a kind of Biohazard Waste based on fuse salt is burnt
Burn, the cleaning system and method for pyrolysis tail gas, its can with simultaneous removing chloride, nitrogen-containing pollutant, and removal efficiency is higher.
To achieve the above object, the utility model adopts the following technical scheme that:
A kind of Biohazard Waste based on fuse salt is burned, pyrolysis exhaust gas purification system, and it includes sequentially connecting by pipeline
Flue gas quenching tower, sack cleaner, the first dehydrater, molten salt reaction device, spray column, the second dehydrater and the air-introduced machine connect.
It is further preferred that it is provided with pipeline between flue gas quenching tower and sack cleaner to add activated carbon
Feeding screw.
Specifically, the quantity of the molten salt reaction device is two, two molten salt reaction devices are connected in parallel, and one with one
It is standby.Both only connect one, when fuse salt reaches saturation in a reactor, switch to another reactor, while will reach
Fuse salt to saturation is discharged, add in the reactor after emptying fuse salt and being heated to melt it is standby.
Specifically, above-mentioned cleaning system also includes the first shunt valve and the second shunt valve;The both ends of first shunt valve
It is connected in parallel with sack cleaner(According to the pressure difference at both ends safety valve can be controlled to be opened and closed), one end of second shunt valve with
Pipeline connection between molten salt reaction device and spray column, the pipeline connection between the other end and the second dehydrater and air-introduced machine
(According to the pressure difference at both ends safety valve can be controlled to be opened and closed).
Biohazard Waste burning, the method for being pyrolyzed tail gas clean-up are carried out using said system, is specially:To molten salt reaction
Added in device and fuse salt and be heated to molten condition, Biohazard Waste is burned, be pyrolyzed tail gas introducing flue gas quenching tower and cold
But to less than 200 DEG C, tail gas after cooling after sack cleaner removes large-size particles thing, the first dehydrater removes moisture,
React removing pollutant into molten salt reaction device, removes the tail gas after pollutant and is sequentially removed water through spray column and second
Discharged after device.
Fuse salt refers to the alkali metal bases of molten state under high temperature, the mixture of salt, employed in the utility model
Melting salt component be by potassium, sodium, lithium alkaloid compound and its esters compound group into mixture.The fuse salt specifically may be used
Think NaOH+Na2CO3、KOH+K2CO3、NaOH+K2CO3、KOH+Na2CO3Or LiOH+Li2CO3, wherein, potassium, sodium, the bases of lithium
Weight percentage of the compound in fuse salt is not less than 40%.
Fuse salt in the utility model burns to Biohazard Waste, pyrolysis tail gas middle and high concentration it is chloride, containing polluted by nitrogen
Thing can be removed thoroughly, and the main chemical reactions occurred in molten salt reaction device are as follows:
Note:1)M represents K, Na, Li alkali metal in formula;2)Reaction equation(3)Only alkaloid compound is in high-temperature molten-state
Lower progress(With NOx this reaction does not occur for the alkaloid compound of solvent state).
Compared to the prior art, advantage of the present utility model is:The utility model can improve Biohazard Waste burn,
The clean-up effect of tail gas is pyrolyzed, simplifies purification process.When chlorine-containing waste in Biohazard Waste(Plastic containing chlorine, rubber etc.)With containing
Nitrogen discarded object(Diseased organ, nitrogenous medicine etc.)When content is higher, clean-up effect of the present utility model becomes apparent, not only can be compared with
Thoroughly to remove chloride, the nitrogen-containing pollutant of tail gas middle and high concentration, reduce environmental pollution, moreover it is possible to realize that the synchronization of the two takes off
Remove, simplify tail gas clean-up technique.
Brief description of the drawings
Fig. 1 is the structure that exhaust gas purification system was burned, was pyrolyzed in the Biohazard Waste described in the utility model based on fuse salt
Schematic diagram.
Embodiment
The technical solution of the utility model is further discussed in detail with reference to embodiments, but it is of the present utility model
Protection domain is not limited thereto.
Embodiment 1
As shown in fig. 1, a kind of Biohazard Waste based on fuse salt burns, is pyrolyzed exhaust gas purification system, and it includes logical
Cross the flue gas quenching tower 1, sack cleaner 3, the first dehydrater 5, molten salt reaction device, spray column 11, that pipeline is sequentially connected with
Two dehydraters 12 and Roots's air-introduced machine 13.It is provided with pipeline between flue gas quenching tower 1 and sack cleaner 3 to add work
The feeding screw 2 of property charcoal.
The quantity of the molten salt reaction device is two, is the first molten salt reaction device 7 and the second molten salt reaction respectively
Device 9, two molten salt reaction devices are connected in parallel, the using and the reserved.First molten salt reaction device 7 and the institute of the second molten salt reaction device 9
Pipeline on be respectively equipped with the first valve 6 and the second valve 8, to control gas path on-off.Above-mentioned cleaning system also includes the
One shunt valve 4 and the second shunt valve 10;The both ends of first shunt valve 4 are connected in parallel with sack cleaner 3(Can be according to both ends
Pressure difference control the safety valve to be opened and closed), between one end of second shunt valve 10 and molten salt reaction device and spray column 11
Pipeline connects, the pipeline connection between the other end and the second dehydrater 12 and Roots's air-introduced machine 13(Can according to the pressure difference at both ends come
Control safety valve opening and closing).Shower is installed, for absorbing the alkali particle carried in gas in spray column.
Biohazard Waste burning, the method for being pyrolyzed tail gas clean-up are carried out using said system, it is into molten salt reaction device
Add fuse salt(NaOH+Na2CO3, contents of the NaOH in fuse salt is 60wt%)And molten condition is heated to, by medical waste
Thing burns, pyrolysis tail gas introduces flue gas quenching tower and is cooled to less than 200 DEG C, and the tail gas after cooling removes through sack cleaner
After large-size particles thing, the first dehydrater remove moisture, react removing pollutant into molten salt reaction device, and removing is dirty
Tail gas after dye thing is sequentially discharged after spray column and the second dehydrater.Detailed process is as follows:Tail gas is from medical castoff burning
Stove, pyrolysis oven discharge, its temperature is about 300 ~ 600 DEG C.In order to reduce the generation of bioxin, tail gas initially enters flue gas quenching tower
1, less than 200 DEG C are rapidly cooled to, cooling water used is industrial water.Tail gas after cooling and the work from feeding screw 2
Property charcoal mixing, the wherein less particulate matter of particle diameter is adsorbed in activated carbon, after sack cleaner 3 is entered, the big grain in tail gas
Footpath particulate matter and activated carbon are removed.After the water removal of the first dehydrater 5, tail gas enters the first molten salt reaction device 7, tail gas
In chloride, nitrogen-containing pollutant and fuse salt react generation villaumite, nitrate etc., if at the same time containing CO in tail gas,
Then CO and molten salt reaction generation H2, thus while pollutant is removed, tail gas is had certain value.When
When one molten salt reaction device 7 reaches saturation, switching gas circuit uses the second standby molten salt reaction device 9(First molten salt reaction
Saturation fuse salt in device 7 empties, add new salt, bases melted as fuse salt and being heated to it is standby).It is anti-from fuse salt
The gas for answering device to export enters spray column 11, salt, the bases particle carried in gas is removed using industrial Water spray, then be passed through
Discharged after the water removal of second dehydrater 12.
Experiment effect is verified:Using the remarkable box Muffle furnace of QSXL-1230 types atmosphere protection, 800 DEG C are warming up to, will be certain
Biohazard Waste after amount crushes is put into stove, and being passed through air makes its sustained combustion, the gas after burning is passed directly into is
The flue gas quenching tower 1 of system, HCl, NOx, HCN concentration after purification in gas are continued to monitor in the top of the system, end.As a result
Display:HCl concentration reaches as high as about 6100ppm in non-purified preceding gas, and NOx is up to about 2450ppm, and HCN is up to about
950ppm, and HCl, NOx, HCN are not detected in gas after purifying(The detection lowest limit is 0.1ppm).The result shows this reality
There is significant removal effect for high concentration HCl, NOx, HCN in Biohazard Waste combustion tail gas with novel system.
In summary:Tthe utility model system can effectively improve the purification efficiency that Biohazard Waste is burned, is pyrolyzed tail gas,
Simplify purification process technique:When tail gas is chloride, nitrogenous pollution concentration is higher, advantage becomes apparent, and only need to change and add in time
Fuse salt can is added to meet the pollutant removing of higher concentration, supreme limit value.Tthe utility model system also by the dechlorination of tail gas,
Denitration is integrated in same step and completed, and technological process is simpler.In addition, causticizing process can be used after molten salt reaction saturation(Papermaking
The bases reclaiming technique that industry is widely used)Regeneration, regenerates bases by carbonate therein, makes fuse salt again
It can recycle.
Above-described embodiment be to explanation of the present utility model, be not to restriction of the present utility model, it is any new to this practicality
Scheme after type simple transformation belongs to the scope of protection of the utility model.
Claims (3)
1. a kind of Biohazard Waste based on fuse salt is burned, pyrolysis exhaust gas purification system, it is characterised in that including passing through pipeline
The flue gas quenching tower that is sequentially connected with, sack cleaner, the first dehydrater, molten salt reaction device, spray column, the second dehydrater and draw
Blower fan;
Pipeline between flue gas quenching tower and sack cleaner is provided with to add the feeding screw of activated carbon.
2. the Biohazard Waste based on fuse salt burns, is pyrolyzed exhaust gas purification system as claimed in claim 1, it is characterised in that
The quantity of the molten salt reaction device is two, and two molten salt reaction devices are connected in parallel, the using and the reserved.
3. the Biohazard Waste based on fuse salt burns, is pyrolyzed exhaust gas purification system as claimed in claim 2, it is characterised in that
Also include the first shunt valve and the second shunt valve;The both ends of first shunt valve are connected in parallel with sack cleaner, and described
Pipeline connection between one end of two shunt valves and molten salt reaction device and spray column, the other end and the second dehydrater and air-introduced machine
Between pipeline connection.
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CN201720399313.8U CN207169393U (en) | 2017-04-17 | 2017-04-17 | A kind of Biohazard Waste based on fuse salt is burned, pyrolysis exhaust gas purification system |
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Publication Number | Publication Date |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106955575A (en) * | 2017-04-17 | 2017-07-18 | 河南科技学院 | A kind of Biohazard Waste based on fuse salt burns, is pyrolyzed exhaust gas purification system and method |
CN108654291A (en) * | 2018-07-20 | 2018-10-16 | 株洲中车南方环保科技有限公司 | Small-sized living garbage incinerator flue gas preprocess method and preprocessor |
CN109331557A (en) * | 2018-11-22 | 2019-02-15 | 合肥中亚环保科技有限公司 | A kind of cement kiln bypass flue gas purifying method |
CN112128766A (en) * | 2020-09-22 | 2020-12-25 | 王玲 | Waste plastic pyrolysis incineration disposal line and waste plastic pyrolysis incineration disposal method |
CN114251661A (en) * | 2021-11-30 | 2022-03-29 | 上海工程技术大学 | Low-nitrogen combustion circulating fluidized bed system for treating kitchen garbage and application thereof |
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2017
- 2017-04-17 CN CN201720399313.8U patent/CN207169393U/en not_active Expired - Fee Related
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106955575A (en) * | 2017-04-17 | 2017-07-18 | 河南科技学院 | A kind of Biohazard Waste based on fuse salt burns, is pyrolyzed exhaust gas purification system and method |
CN108654291A (en) * | 2018-07-20 | 2018-10-16 | 株洲中车南方环保科技有限公司 | Small-sized living garbage incinerator flue gas preprocess method and preprocessor |
CN109331557A (en) * | 2018-11-22 | 2019-02-15 | 合肥中亚环保科技有限公司 | A kind of cement kiln bypass flue gas purifying method |
CN112128766A (en) * | 2020-09-22 | 2020-12-25 | 王玲 | Waste plastic pyrolysis incineration disposal line and waste plastic pyrolysis incineration disposal method |
CN114251661A (en) * | 2021-11-30 | 2022-03-29 | 上海工程技术大学 | Low-nitrogen combustion circulating fluidized bed system for treating kitchen garbage and application thereof |
CN114251661B (en) * | 2021-11-30 | 2023-05-30 | 上海工程技术大学 | Low-nitrogen combustion circulating fluidized bed system for treating kitchen waste and application thereof |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
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Granted publication date: 20180403 |