CN206901934U - It is a kind of to induce crystallisation to handle industrial water system - Google Patents
It is a kind of to induce crystallisation to handle industrial water system Download PDFInfo
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- CN206901934U CN206901934U CN201720233183.0U CN201720233183U CN206901934U CN 206901934 U CN206901934 U CN 206901934U CN 201720233183 U CN201720233183 U CN 201720233183U CN 206901934 U CN206901934 U CN 206901934U
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Abstract
The utility model provides one kind to induce crystallisation to handle industrial water system, including electro-chemical water processor, regulating reservoir, crystallizer I, crystallizer II, inclined tube or inclined-plate clarifying basin, ultrasonic wave dispersing device, crystal seed separator.Mainly by improving the pH value of raw water, make the CaCO in water3、MgCO3In saturation state, the CaCO of saturation state3、MgCO3With being mixed in seeded crystallization device, crystal seed is that iron powder or aluminum oxide, magnesia, dolomite, calcium carbonate etc. can cause CaCO for particulate and other dirts3、MgCO3The material of crystallization, CaCO3、MgCO3Will be in seed crystals with other dirts, and gradually grow up, adsorb CaCO3、MgCO3The crystal seed of other dirts precipitates in inclined tube or inclined-plate clarifying basin, the CaCO of the crystal seed carrying of inclined tube or inclined-plate clarifying basin bottom precipitation3、MgCO3By crystal seed separator sub-argument go out crystal seed with other dirts and return again to crystallizer to be continuing with.
Description
Technical field
Treatment of Industrial Water technical field is the utility model is related to, it is especially a kind of to induce crystallisation to handle industrial water system.
Background technology
Chemical industry, petroleum industry, power industry, metallurgical industry, the industry such as air-conditioning system of building need industrial cycle
Water is cooled down working media, and nature does not have pure water, natural water in the cyclic process of the Nature always with
The external world contacts, thus the impurity containing heterogeneity and varying number in water, the Ca in water2+、Mg2+Deng in metal ion and water
CO3 2-、HCO3 -、SO4 2-、Cl-And NO3 -Deng anion binding together, during water is heated, due to being concentrated by evaporation,
Easily form CaCO3、MgCO3、CaSO4、MgSO4Deng incrustation scale, at the same the inevitable face of recirculating cooling water system fall into dust or
Other raw material dust of person, have little time precipitation and be just returned in recirculated water, these dirts adhere in heat exchanger heat transfer inside pipe wall, shape
The incrustation scale more hard into quality;On the other hand, recirculated cooling water water temperature and pH value are suitable for the breeding life of most of microbe
It is long, and with the continuous circulating and evaporating of recirculated cooling water, the nutrient source in water is consequently increased, and more promotes microorganism largely numerous
Grow.Microorganism is blended together with sludge, forms biological clay, and ultimately form biofouling.These dirts are attached to heat-transfer area
On, cause that the thermal efficiency is low, heat exchanger blocks, have a strong impact on the normal operation of equipment, while with energy consumption increase, maintenance
Increase, disposal of pollutants increase.
Add medical method in conventional recirculated water, although can antiscale and sterilization algae removal to a certain extent, addition
Medicament be also pollutant in itself, cause secondary environmental pollution.
Utility model content
The utility model provides one kind to induce crystallisation processing industrial water system and method.Cardinal principle is to pass through raising
The pH value of raw water, make the CaCO in water3、MgCO3In saturation state, the CaCO of saturation state3、MgCO3Particulate and other dirts
Mixed with seeded crystallization device, crystal seed is that iron powder or aluminum oxide, magnesia, dolomite, calcium carbonate etc. can cause CaCO3、
MgCO3The material of crystallization, CaCO3、MgCO3Will be in seed crystals with other dirts, and gradually grow up, adsorb CaCO3、
MgCO3The crystal seed of other dirts precipitates in inclined tube or inclined-plate clarifying basin, and the crystal seed of inclined tube or inclined-plate clarifying basin bottom precipitation is taken
The CaCO of band3、MgCO3By crystal seed separator sub-argument go out crystal seed with other dirts and return again to crystallizer to be continuing with.After processing
Water hardness clearance more than 90%, basicity are (with CaCO3Meter) clearance more than 90%, delivery turbidity≤10mg/L;Clear
Dirty CaCO3Content is high, can make CaCO3Product or as cement raw material.
The utility model includes electro-chemical water processor, regulating reservoir, crystallizer I, crystallizer II, inclined tube or sloping plate deposition
Pond, ultrasonic wave dispersing device, crystal seed separator, it is characterised in that:Raw water water inlet is connected with regulating reservoir, outlet of regulating reservoir and knot
Brilliant device I, crystallizer II, inclined tube or inclined-plate clarifying basin, crystal seed separator are sequentially connected and connect;Electro-chemical water processor and regulating reservoir
Between be provided with alkali lye membrane pump and pipeline;Acid solution membrane pump and pipeline are provided between electro-chemical water processor and water outlet;Crystal seed point
Include ultrasonic wave dispersing device, crystal seed separator, crystal seed storage tank, crystal seed seperator from device device;Crystal seed storage tank connects with crystallizer I
Connect.
Further, electro-chemical water processor produces acid, alkaline water, and analysis is crystallized with the incrustation ion in crystal seed inducible alkaline water
Go out.
Further, electro-chemical water processor is a kind of including casing, hermatic door, minus plate, positive plate, barrier film, downside
Water inlet, upside delivery port etc. form;Ion barrier film is inserted between positive plate, minus plate, cathode-anode plate is passed through certain electric current
After the direct current of density, acid water formation acid solution room is produced between positive plate and barrier film, is produced between minus plate and ionic membrane
Raw alkali lye forms alkali lye room;Housing is rectangle or circle, and housing is welded as a minus plate part, steel plate;Sealing
Door is connected using hinge or sliding rail with casing, is sealed between hermatic door and casing using sealing joint strip, and hermatic door is fixed
Plate;Manual or automatic snaking;Anode is that have ruthenium iridium coating rectangle, annular, the titanium plate or titanium net of angle arc.Water inlet
Mouthful, delivery port use porous water distribution form, uniform fluid flow between pole plate.Described barrier film is not limited to Bipolar Membrane, ceramic membrane, the moon
Ionic membrane, cationic membrane etc. can be used in isolating the film that cathode-anode plate produces acid & alkali liquid.
Further, regulating reservoir, crystallizer I, crystallizer II, inclined tube or inclined-plate clarifying basin are a kind of one or combination of monomers
Structure, can be that armored concrete is constructed, can also be that fiberglass, steel plate, stiffness plastic plate are made, regulating reservoir, knot
Brilliant device I, crystallizer II are provided with electric mixer;Inclined tube or swash plate group are provided with inclined tube or inclined-plate clarifying basin, strengthens absurd creature precipitation.
Another system form of the present utility model is:Including electro-chemical water processor, crystallizer I, crystallizer II, inclined tube
Or inclined-plate clarifying basin, ultrasonic wave dispersing device, crystal seed separator, it is characterised in that:Raw water is intake and electro-chemical water processor
Connection, the outlet of electro-chemical water processor and crystallizer I, crystallizer II, inclined tube or inclined-plate clarifying basin, crystal seed separator successively phase
Connection;Alkali lye membrane pump and pipeline are provided between electro-chemical water processor and water outlet;Crystal seed separator is beaten including ultrasonic wave
Dissipate device, crystal seed separator, crystal seed storage tank, crystal seed seperator;Crystal seed storage tank is connected with crystallizer I.
Further, electro-chemical water processor produces acid, alkaline water, and analysis is crystallized with the incrustation ion in crystal seed inducible alkaline water
Go out.
Further, electro-chemical water processor is a kind of including casing, hermatic door, minus plate, positive plate, barrier film, downside
Water inlet, upside delivery port etc. form;Ion barrier film is inserted between positive plate, minus plate, cathode-anode plate is passed through certain electric current
After the direct current of density, acid water formation acid solution room is produced between positive plate and barrier film, is produced between minus plate and ionic membrane
Raw alkali lye forms alkali lye room;Housing is rectangle or circle, and housing is welded as a minus plate part, steel plate;Sealing
Door is connected using hinge or sliding rail with casing, is sealed between hermatic door and casing using sealing joint strip, and hermatic door is fixed
Plate;Manual or automatic snaking;Anode is that have ruthenium iridium coating rectangle, annular, the titanium plate or titanium net of angle arc.Water inlet
Mouthful, delivery port use porous water distribution form, uniform fluid flow between pole plate.Described barrier film be not limited to Bipolar Membrane, ceramic membrane,
Anionic membrane, cationic membrane etc. can be used in isolating the film that cathode-anode plate produces acid & alkali liquid.
Further, regulating reservoir, crystallizer I, crystallizer II, inclined tube or inclined-plate clarifying basin are a kind of one or combination of monomers
Structure, can be that armored concrete is constructed, can also be that fiberglass, steel plate, stiffness plastic plate are made, regulating reservoir, knot
Brilliant device I, crystallizer II are provided with electric mixer;Inclined tube or swash plate group are provided with inclined tube or inclined-plate clarifying basin, strengthens absurd creature precipitation.
Brief description of the drawings
Fig. 1:The system schematic of the utility model one;
Fig. 2:Another embodiment system schematic of the utility model;
In figure:1st, raw water is intake, 2, raw water to crystallizer II intake, 3, regulating reservoir, 4, crystallizer I, 5, crystallizer II, 6,
Inclined tube or inclined-plate clarifying basin, 7, ultrasonic wave dispersing device, 8, crystal seed separator, 9, crystal seed storage tank, 10, crystal seed seperator, 11, sludge
Pump, 12, alkali lye membrane pump, 13, acid solution membrane pump, 14, electro-chemical water processor, 15, the sour side water inlet pipe of electro-chemical water processing,
16th, electro-chemical water processing alkali side water inlet pipe, 17, electro-chemical water processing alkali side water inlet pipe (coming from sedimentation basin water outlet), 18, water outlet.
Embodiment
The utility model specific implementation is provided below in conjunction with the accompanying drawings.
As shown in Figure 1:
The higher raw water 1 of hardness, basicity enters regulating reservoir 3, with electrochemical treater 14 caused by alkali lye mix, adjusting
Following react occurs in pond 3:
HCO3 -+OH-→H2O+CO3 2-
Ca2++CO3 2-→CaCO3↓
Mg2++CO3 2-→MgCO3↓
CaCO after reaction in regulating reservoir 33、MgCO3Exist in saturation state, pH value is increased to more than 9.5;CaCO3With
MgCO3Crystallize for nucleus with the crystal seed in crystallizer I 4, and gradually grow up, pH value is basically unchanged.
Crystal seed, CaCO3And MgCO3Crystal and incomplete reaction alkali lye enter crystallizer II 5, the HCO in raw water3 -、Ca2 +、Mg2+The following reaction of supervention life is relayed in crystallizer II 5:
HCO3 -+OH-→H2O+CO3 2-
Ca2++CO3 2-→CaCO3↓
Mg2++CO3 2-→MgCO3↓
CaCO caused by the reaction of crystallizer II 53、MgCO3Continuation is combined with crystal seed, and crystal is grown up, OH-Content reduces, pH value
Gradually reduce.
The CaCO that crystal seed combines3、MgCO3Other dirt particles that crystal, raw water carry are from the bottom of inclined tube (plate) settling tank 6
Sewage draining exit excludes;The water outlet of sedimentation basin 6 is neutralized to suitable pH value with acid solution caused by electro-chemical water processor 14, for industrial production
Recycle.The crystal seed and soil mixture of inclined tube or the blowdown of inclined-plate clarifying basin 6 discharge are broken up through dispersing device 7, crystal seed, CaCO3
And MgCO3Other dirt particles in crystal and raw water depart from, and the crystal seed gone out through the sub-argument of seperator 10 is delivered to through sludge pump 11
Crystallizer I 4 recycles.
Above-described electro-chemical water processor 14 be it is a kind of include casing, hermatic door, case inner cathode plate, positive plate, point
Sub- film, downside water inlet, upside delivery port etc. form;Barrier film is inserted between positive plate, minus plate, in low voltage electric field direct current
In the presence of, water power is from caused H+And OH-, the positive and negative ion between cathode-anode plate in the aqueous solution moves to opposite polarity pole plate
Move, react as shown in formula:
H2O+4e-→2H2↑+4OH-(cathodic region reaction)
2H2O→O2↑+4H++4e-(anode region reaction)
Between anode and cathode under the isolation of molecular film, negative electrode OH-'s increases, and forms basic region;Anode H+Increasing
It is more, form acidic region.Housing is rectangle or circle, and housing is welded as a minus plate part, steel plate;Sealing
Door is connected using hinge or sliding rail with casing, is sealed between hermatic door and casing using sealing joint strip, and hermatic door is fixed
Positive plate;Negative electrode uses plug-in type activity minus plate, is easy to manually take out snaking;Anode be have ruthenium iridium coating rectangle, annular,
The titanium plate or titanium net of angle arc.Water inlet, delivery port use porous water distribution form, uniform fluid flow between pole plate.This example electrochemistry
Processor, which is intake, uses the water after processing, Ca in water2+、Mg2+Most of to have removed, content is relatively low, cloudy in running
Pole plate incrustation amount is seldom, can be removed by artificial scraping plate of automatic device periodically or in processor.
The utility model crystal seed use magnetic, iron powder or aluminum oxide, magnesia, dolomite, calcium carbonate etc. any for
Crystal seed.This example uses crystal seed as magnetic.
Above-mentioned ultrasonic wave dispersing device 7, including shell, transducer, ultrasonic transformer, power-supply controller of electric, transducer cooling device,
Charging aperture, discharging opening etc. form, and using ultrasonic wave in physical characteristics such as water transmission cavitation effect, shearing effects, make strong sound field
Treatment fluid, allow in fluid and wrap up the CaCO of magnetic3And MgCO3Particle under ultrasonic field action, be allowed to disperse, crush, loosely,
Release and realize magnetic and CaCO3And MgCO3Separation.
Above-mentioned crystal seed seperator 10 uses magnetic seperator, including water inlet, delivery port, rotation steel cylinder, reductor, permanent magnetism
Body, scraper plate etc. form, and isolate the magnetic in dirt.
Above-mentioned crystal seed separator 8 uses fixed permanent magnet mode, and realization is further separated out what is contained in sedimentation basin water outlet
A small amount of magnetic.
As shown in Figure 2:
Electro-chemical water processor 3 is in the presence of low voltage electric field direct current, and water power is from caused H+And OH-, between cathode-anode plate
Positive and negative ion in the aqueous solution migrates to opposite polarity pole plate, reacts as shown in formula:
H2O+4e-→2H2↑+4OH-(cathodic region reaction)
2H2O→O2↑+4H++4e-(anode region reaction)
Between anode and cathode under the isolation of molecular film, negative electrode OH-'s increases, and forms basic region, anode H+Increase,
Form acidic region.The higher raw water 1 of hardness, basicity enters the basic region of electro-chemical water processor 3, after electrochemical treatments
PH is increased to more than 9.5, CaCO in water3、MgCO3Exist in saturation state;The CaCO of saturation3And MgCO3With in crystallizer I 4
Crystal seed is crystallized for nucleus, and pH value is basically unchanged.
Crystal seed, crystal CaCO3And MgCO3Do not participate in reaction alkali lye-enter crystallizer II 5 completely, the HCO in raw water3 -、
Ca2+、Mg2+Continue that following react occurs:
HCO3 -+OH-→H2O+CO3 2-
Ca2++CO3 2-→CaCO3↓
Mg2++CO3 2-→MgCO3↓
CaCO after reaction in crystallizer II 53、MgCO3Crystallized with crystal seed for nucleus, OH in water-Content reduce, pH value by
Gradually reduce.
Crystal seed, CaCO3And MgCO3Other dirt particles that crystal, raw water carry enter inclined tube (plate) settling tank 6 together,
Inclined tube (plate) bottom blow-down mouth excludes;Primary water after processing produces in the top water outlet of sedimentation basin 6 with electro-chemical water processor 14
Acid solution neutralize after for production system recycle.Inclined tube or the crystal seed and soil mixture warp of the blowdown of inclined-plate clarifying basin 6 discharge
Ultrasonic wave dispersing device 7 is broken up, and delivering to crystallizer I 4 through sludge pump 11 through the crystal seed that crystal seed seperator 10 is isolated recycles.
Above-described electro-chemical water processor 3 is a kind of including casing, hermatic door, case inner cathode plate, positive plate, molecule
Film, downside water inlet, upside delivery port etc. form;Ionic membrane is inserted between positive plate, minus plate, cathode-anode plate is passed through certain electricity
After the direct current of current density, acid water formation acid solution room is produced between positive plate and barrier film, between minus plate and ionic membrane
Produce alkali lye and form alkali lye room;Housing is rectangle or circle, and housing is welded as a minus plate part, steel plate;It is close
Closure door is connected using hinge or sliding rail with casing, is sealed between hermatic door and casing using sealing joint strip, and hermatic door is solid
Determine plate;Negative electrode uses plug-in type activity minus plate, is easy to manually take out snaking;Anode be have ruthenium iridium coating rectangle,
Annular, the titanium plate or titanium net of angle arc.Water inlet, delivery port use porous water distribution form, uniform fluid flow between pole plate.This example is adopted
Ca in raw water water is pre-processed with electrochemical treater2+、Mg2+Higher, minus plate has a certain amount of incrustation in running, can
To be removed by artificial scraping plate of automatic device periodically or in processor.
The utility model crystal seed uses iron powder or aluminum oxide, magnesia, dolomite, calcium carbonate etc. any for crystal seed.
This example uses magnetic as crystal seed.
Above-mentioned ultrasonic wave dispersing device 7 include shell, transducer, ultrasonic transformer, power-supply controller of electric, transducer cooling device,
Charging aperture, discharging opening etc. form, and using ultrasonic wave in physical characteristics such as water transmission cavitation effect, shearing effects, make strong sound field
Treatment fluid, allow in fluid and wrap up the CaCO of magnetic3And MgCO3Particle under ultrasonic field action, be allowed to disperse, crush, loosely,
Release and realize magnetic and CaCO3And MgCO3Separation.
Above-mentioned crystal seed seperator 10 uses magnetic seperator, including water inlet, delivery port, rotation steel cylinder, reductor, permanent magnetism
Body, scraper plate etc. form, and realize the magnetic isolated in dirt.
Above-mentioned crystal seed separator 8 uses fixed permanent magnet mode, and realization is further separated out what is contained in sedimentation basin water outlet
A small amount of magnetic.
Claims (6)
- It is 1. a kind of to induce crystallisation to handle industrial water system, including electro-chemical water processor, regulating reservoir, crystallizer I, crystallizer IIth, inclined tube or inclined-plate clarifying basin, ultrasonic wave dispersing device, crystal seed separator, it is characterised in that:Raw water is intake to be connected with regulating reservoir Connect, outlet of regulating reservoir is sequentially connected and connect with crystallizer I, crystallizer II, inclined tube or inclined-plate clarifying basin, crystal seed separator;Electrification Learn and be provided with alkali lye membrane pump and pipeline between hydrotreater and regulating reservoir;Between electro-chemical water processor and water outlet be provided with acid solution every Membrane pump and pipeline;Crystal seed separator includes ultrasonic wave dispersing device, crystal seed separator, crystal seed storage tank, crystal seed seperator;Crystal seed Storage tank is connected with crystallizer I.
- It is 2. according to claim 1 a kind of to induce crystallisation to handle industrial water system, it is characterised in that at electro-chemical water Reason device is that a kind of casing, hermatic door, minus plate, positive plate, barrier film, downside water inlet, upside delivery port etc. of including forms;Sun Between pole plate, minus plate insert ion barrier film, after cathode-anode plate is passed through the direct current of certain current density, positive plate with every Acid solution room is formed from acid water is produced between film, alkali lye is produced between minus plate and ionic membrane and forms alkali lye room;Housing is rectangular Shape or circle, housing are welded as a minus plate part, steel plate;Hermatic door uses hinge or sliding rail and casing Connection, sealed between hermatic door and casing using sealing joint strip, hermatic door fixed anode pole plate;Manual or automatic snaking;Anode It is to have ruthenium iridium coating rectangle, annular, the titanium plate or titanium net of angle arc;Water inlet, delivery port use porous water distribution form, pole plate Between uniform fluid flow;Described barrier film is not limited to Bipolar Membrane, ceramic membrane, anionic membrane, cationic membrane etc. and can be used in isolating Cathode-anode plate produces the film of acid & alkali liquid.
- It is 3. according to claim 1 a kind of to induce crystallisation to handle industrial water system, it is characterised in that regulating reservoir, crystallization Device I, crystallizer II, inclined tube or inclined-plate clarifying basin are a kind of one or combination of monomers structures, can be armored concrete construct, Can also be that fiberglass, steel plate, stiffness plastic plate are made, regulating reservoir, crystallizer I, crystallizer II are provided with electric stirring Device;Inclined tube or swash plate group are provided with inclined tube or inclined-plate clarifying basin, strengthens absurd creature precipitation.
- It is 4. a kind of to induce crystallisation to handle industrial water system, including electro-chemical water processor, crystallizer I, crystallizer II, inclined tube Or inclined-plate clarifying basin, ultrasonic wave dispersing device, crystal seed separator, it is characterised in that:Raw water is intake and electro-chemical water processor Connection, the outlet of electro-chemical water processor and crystallizer I, crystallizer II, inclined tube or inclined-plate clarifying basin, crystal seed separator successively phase Connection;Alkali lye membrane pump and pipeline are provided between electro-chemical water processor and water outlet;Crystal seed separator is beaten including ultrasonic wave Dissipate device, crystal seed separator, crystal seed storage tank, crystal seed seperator;Crystal seed storage tank is connected with crystallizer I.
- It is 5. according to claim 4 a kind of to induce crystallisation to handle industrial water system, it is characterised in that at electro-chemical water Reason device is that a kind of casing, hermatic door, minus plate, positive plate, barrier film, downside water inlet, upside delivery port etc. of including forms;Sun Between pole plate, minus plate insert ion barrier film, after cathode-anode plate is passed through the direct current of certain current density, positive plate with every Acid solution room is formed from acid water is produced between film, alkali lye is produced between minus plate and ionic membrane and forms alkali lye room;Housing is rectangular Shape or circle, housing are welded as a minus plate part, steel plate;Hermatic door uses hinge or sliding rail and casing Connection, sealed between hermatic door and casing using sealing joint strip, hermatic door fixed anode pole plate;Manual or automatic snaking;Anode It is to have ruthenium iridium coating rectangle, annular, the titanium plate or titanium net of angle arc;Water inlet, delivery port use porous water distribution form, pole plate Between uniform fluid flow;Described barrier film is not limited to Bipolar Membrane, ceramic membrane, anionic membrane, cationic membrane etc. and can be used in isolating Cathode-anode plate produces the film of acid & alkali liquid.
- It is 6. according to claim 4 a kind of to induce crystallisation to handle industrial water system, it is characterised in that regulating reservoir, crystallization Device I, crystallizer II, inclined tube or inclined-plate clarifying basin are a kind of one or combination of monomers structures, can be armored concrete construct, Can also be that fiberglass, steel plate, stiffness plastic plate are made, regulating reservoir, crystallizer I, crystallizer II are provided with electric stirring Device;Inclined tube or swash plate group are provided with inclined tube or inclined-plate clarifying basin, strengthens absurd creature precipitation.
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CN106746061A (en) * | 2017-03-10 | 2017-05-31 | 山东深信节能环保科技有限公司 | One kind processes industrial water system and method to induce crystallisation |
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