CN206886686U - A kind of calcium carbide furnace system of blowing oxygen and heat integration - Google Patents

A kind of calcium carbide furnace system of blowing oxygen and heat integration Download PDF

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Publication number
CN206886686U
CN206886686U CN201720608166.0U CN201720608166U CN206886686U CN 206886686 U CN206886686 U CN 206886686U CN 201720608166 U CN201720608166 U CN 201720608166U CN 206886686 U CN206886686 U CN 206886686U
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coal
oxygen
pyrolysis
stove
gas
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CN201720608166.0U
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孙宝林
陈水渺
马政峰
吴道洪
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Shenwu Technology Group Corp Co Ltd
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Shenwu Technology Group Corp Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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Abstract

The utility model belongs to coal chemical technology, more particularly to a kind of production technology on calcium carbide.The calcium carbide furnace system of blowing oxygen and heat integration provided by the utility model, including:Solid mixer, pulverized coal pyrolysis stove, cyclone dust collectors, oil gas condensation device, pyrolysis air purifying apparatus, gas mixer, oxygen coal mixed spray stove, oxygen valve group and breeze blowing tank.Thus, the calcium carbide furnace system carries out calcium carbide production using the mixed spray stove of oxygen coal, and the mixed spray stove of the oxygen coal makes carbon dust and pulverized limestone synthesize calcium carbide, solves the problems, such as that calcium carbide produces high power consumption using high temperature caused by oxygen coal injection and energy;It is heat-fed using caused pyrolysis coke in pulverized coal pyrolysis stove and lime stone into the mixed spray stove of oxygen coal as raw materials for production, improves heat utilization ratio;As coal pyrolysis thermal source after being mixed by the use of flue gas caused by the mixed spray stove of oxygen coal with the pyrogenic steam of pulverized coal pyrolysis stove, the waste heat for realizing flue gas and pyrogenic steam recycles, and the upgrading for solving the problems, such as low-order coal utilizes.

Description

A kind of calcium carbide furnace system of blowing oxygen and heat integration
Technical field
The utility model belongs to coal chemical technology, more particularly to a kind of production technology on calcium carbide.
Background technology
Calcium carbide is commonly called as calcium carbide, is reacted and is made by coke and calcium oxide, is that important coalification chemical product and basic chemical industry are former Material, mainly for the production of acetylene and ethynylation chemical product.The acetylene gas for producing to obtain can be used for preparing a variety of chemistry productions Product, including the series of products such as vinyl chloride serial, vinyl acetate series and acrylic.Therefore, calcium carbide is sent out Chinese national economy Exhibition is had a very important role, and calcium carbide yield is continuously increased nearly ten years.But current calcium carbide production technology is present The bigger technical problem of limitation.
Although the existing history for many years of development of calcium carbide industry, in the calcium carbide production technology of routine, use always The lime stone and carbon materials of block grain are chemically reacted, instead as raw materials for production under the hot conditions more than 2000 DEG C Calcium carbide should be generated;Wherein, must be used the main reason for high temperature in production process be used block stock specific surface area It is small so that the raw material needs that chemical reaction could be completed under conditions of higher temperature.Moreover, in traditional calcium carbide production technology In, be typically used as raw materials for production from quality block semi-coke and lime, cause powdery semi-coke and lime must not be without low price at Reason, therefore, adds the production cost of calcium carbide indirectly.Correlative study shows, in the technical process of production calcium carbide, passes through drop The granularity of low feed coal so that the smelting temperature of calcium carbide can be reduced to 1800 DEG C or so.Therefore, high cost utilizes low-order coal etc. The hot method production calcium carbide of low cost feedstock oxygen is the direction of calcium carbide industry research, and calcium carbide synthesis production cost can be greatly lowered. In the prior art, use the method for oxygen hot method production calcium carbide for:Block calcic raw material and carbon raw material are preheated in epimere shaft furnace Enter after to 800~1300 DEG C in hypomere electric arc furnaces, by oxygen and breeze blowing and the compound heat supply temperature of electrode in electric arc furnaces 1700~2200 DEG C are risen to, reaction generation high-grade calcium carbide, by gas turbine combustion after caused calcium carbide furnace gas removing dust purification Electrical power generators are driven, waste gas sensible heat is reclaimed by waste heat boiler.But the major defect of the hot method of oxygen is not solve in the prior art Certainly technical problem existing for block material reaction, because block stock specific surface area is small so that the hot method of the oxygen still needs higher Temperature conditionss under could complete reaction, thus, cause system production high energy consumption;Moreover, the production of the hot method of oxygen in the prior art Raw material remains as the higher block coke and lime stone of price, does not effectively reduce cost of material;The production system produces High-temperature flue gas go to preheat raw material and generating just with the high-temperature gas, do not utilize the property such as reproducibility of the high-temperature gas Matter, thus, the utilization ratio after high-temperature gas recovery need further to be improved.According to current research, oxygen heat is directly realized by Method low cost production calcium carbide technical difficulty is larger.In the prior art, in current calcium carbide production technology, also mainly added using electric arc The method of heat, for example, in the technique of the electric arc heated production calcium carbide of routine, mainly produced by using the electric energy of electric arc furnaces Calcium carbide, its specific production process are:Added mixture into by the entrance or pipeline of electric furnace upper end in electric furnace, open or close 2000 DEG C or so are heated in the electric furnace closed, the calcium carbide melted, using the calcium carbide of fusing after cooling down break process as into Product are packed;Wherein, CO gas is generated in course of reaction, the gas is then according to different types of furnace of calcium carbide with difference Mode discharge the furnace of calcium carbide.But the above-mentioned technology using electricity production of conventional electric arc heated method next life stone, which has following technology, asks Topic:The technique of electric arc heated production calcium carbide consumes a large amount of electric energy, can not directly utilize the heat energy of coal dust firing;Also, institute The reaction temperature needed is high, and energy expenditure is big, requires high to refractory material;Existing electric arc heated production calcium carbide technology can not utilize Powder, causes the waste of powder, causes the increase of production cost indirectly;Produced in existing electric arc heated production calcium carbide technology High-temperature flue gas, the heat that the high-temperature flue gas contains can not make full use of.Therefore, how designing one kind can utilize powdery former Expect as raw materials for production, make full use of the heat of product, reduce reaction temperature, the calcium carbide production technology of low cost, turn into current It is badly in need of the technical barrier solved.
Utility model content
For above-mentioned problem present in prior art, the utility model provides a kind of blowing oxygen and heat energy synthesis profit Calcium carbide furnace system, the calcium carbide furnace system carry out calcium carbide production using the mixed spray stove of oxygen coal, and the mixed spray stove of the oxygen coal is sprayed using oxygen coal High temperature and energy caused by blowing make carbon dust and pulverized limestone synthesize and be carried in calcium carbide, with traditional calcium carbide production technology all of electric energy The mode of heating of heating load is different, and heat caused by oxygen coal combustion can be made full use of to substitute part or all of electric energy, solved Calcium carbide produces the problem of high power consumption;By the use of in pulverized coal pyrolysis stove caused pyrolysis coke as production calcium carbide raw material, and by heat Solution coke is heat-fed with lime stone and is used as raw materials for production into the mixed spray stove of oxygen coal, improves heat utilization ratio, reduces production cost; Have that gas flow is big, temperature is high using flue gas caused by the mixed spray stove of oxygen coal(Flue gas exit temperature is up to 1500 DEG C -1700 DEG C), with And CO content in smoke it is high the characteristics of, using the flue gas with pulverized coal pyrolysis stove pyrolysis caused by pyrogenic steam mix after as fine coal Coal pyrolysis thermal source in pyrolysis oven, the part of waste heat for realizing flue gas and pyrogenic steam fully recycle, and solve low-order coal Upgrading utilize the problem of, reduce production cost;Through using pyrogenic steam caused by pyrolysis in pulverized coal pyrolysis stove and condensation, be net Change obtains oil, the gas product of high-quality, realizes waste recovery, produces new benefit, reduce cost indirectly.
In order to solve the above technical problems, the technical solution adopted in the utility model is:
The utility model provides a kind of calcium carbide furnace system of blowing oxygen and heat integration, it is characterised in that bag Include solid mixer, pulverized coal pyrolysis stove, cyclone dust collectors, oil gas condensation device, pyrolysis air purifying apparatus, gas mixer, oxygen Coal mixed spray stove, oxygen valve group and breeze blowing tank, wherein:The pulverized coal pyrolysis stove is connected with the solid mixer;The rotation The inlet end of wind deduster is connected with the pyrolysis gas outlet of the pulverized coal pyrolysis stove, the outlet side of the cyclone dust collectors with it is described Oil gas condensation device connects;The pyrolysis air purifying apparatus is connected with the oil gas condensation device;The gas mixer enters Offgas outlet of the mouth respectively with the pyrolysis air purifying apparatus and the mixed spray stove of the oxygen coal is connected, the outlet of the gas mixer It is connected with the pyrolysis gas entrance of the pulverized coal pyrolysis stove;The side wall of the mixed spray stove of the oxygen coal is provided with charging aperture and injection mouth, institute The coke export that charging aperture is stated with the pulverized coal pyrolysis stove is connected, it is described injection mouth respectively with the oxygen valve group and the coal dust Injection tank connects.
Inventor has found that the utility model provides a kind of calcium carbide furnace system of blowing oxygen and heat integration, should Calcium carbide furnace system carries out calcium carbide production using the mixed spray stove of oxygen coal, and the mixed spray stove of the oxygen coal utilizes high temperature and energy caused by oxygen coal injection Carbon dust and pulverized limestone is set to synthesize in calcium carbide, with traditional calcium carbide production technology and provide the mode of heating of heat not all of electric energy Together, heat caused by oxygen coal combustion can be made full use of to substitute part or all of electric energy, calcium carbide is solved and produce asking for high power consumption Topic;Caused pyrolysis coke is heat-fed as the raw material for producing calcium carbide, and by pyrolysis coke and lime stone by the use of in pulverized coal pyrolysis stove Into the mixed spray stove of oxygen coal as raw materials for production, heat utilization ratio is improved, reduces production cost;Produced using the mixed spray stove of oxygen coal Flue gas have that gas flow is big, temperature is high(Flue gas exit temperature is up to 1500 DEG C -1700 DEG C)And CO content in smoke is high Feature, as the coal pyrolysis in pulverized coal pyrolysis stove after the flue gas is mixed with pyrogenic steam caused by pyrolysis in pulverized coal pyrolysis stove Thermal source, the part of waste heat for realizing flue gas and pyrogenic steam fully recycle, and the upgrading for solving the problems, such as low-order coal utilizes, drop Low production cost;Using pyrogenic steam caused by pyrolysis in pulverized coal pyrolysis stove oil, the gas of high-quality are obtained by condensation, purification Product, waste recovery is realized, produce new benefit, reduce cost indirectly.
According to specific embodiment of the utility model, in addition to oxygen coal gun, including:Muzzle, oxygen intake and coal powder entrance, The muzzle is connected with the injection mouth of the mixed spray furnace sidewall of the oxygen coal, and the oxygen intake is connected with the oxygen valve group, described Coal powder entrance is connected with the outlet of the breeze blowing tank.
According to specific embodiment of the utility model, the lance head of the oxygen coal gun is the inclined hole knot that angle is assembled to center Structure.
According to specific embodiment of the utility model, the pulverized coal pyrolysis stove is that fluid bed or down-flow fluidized bed using ECT fast pyrogenation react Device;The pyrolysis air purifying apparatus includes desulfurization unit, deamination unit, de- benzene unit, de- naphthalene unit.
According to specific embodiment of the utility model, in addition to calcium carbide holding vessel, the discharging opening with the mixed spray stove of the oxygen coal Connection.
The beneficial effects of the utility model are as follows:
(1)The utility model provides a kind of calcium carbide furnace system of blowing oxygen and heat integration, the furnace of calcium carbide system System carries out calcium carbide production using the mixed spray stove of oxygen coal, the mixed spray stove of the oxygen coal using high temperature caused by oxygen coal injection and energy make carbon dust and Pulverized limestone synthesizes calcium carbide, different from the mode of heating for providing heat in traditional calcium carbide production technology all of electric energy, can Make full use of heat caused by oxygen coal combustion to substitute part or all of electric energy, solve the problems, such as that calcium carbide produces high power consumption.
(2)The utility model provides a kind of calcium carbide furnace system of blowing oxygen and heat integration, the furnace of calcium carbide system System using caused pyrolysis coke in pulverized coal pyrolysis stove as the raw material for producing calcium carbide, and by pyrolysis coke and lime stone be heat-fed to As raw materials for production in the mixed spray stove of oxygen coal, heat utilization ratio is improved, reduces production cost.
(3)The utility model provides a kind of calcium carbide furnace system of blowing oxygen and heat integration, the furnace of calcium carbide system System has that gas flow is big, temperature is high using flue gas caused by the mixed spray stove of oxygen coal(Flue gas exit temperature is up to 1500 DEG C -1700 DEG C)、 And CO content in smoke it is high the characteristics of, using the flue gas with pulverized coal pyrolysis stove pyrolysis caused by pyrogenic steam mix after as powder Coal pyrolysis thermal source in coal heat decomposition stove, the part of waste heat for realizing flue gas and pyrogenic steam fully recycle, and solve low order The problem of upgrading of coal utilizes, reduces production cost.
(4)The utility model provides a kind of calcium carbide furnace system of blowing oxygen and heat integration, the furnace of calcium carbide system System obtains oil, the gas product of high-quality using pyrogenic steam caused by pyrolysis in pulverized coal pyrolysis stove by condensation, purification, realizes Waste recovery, new benefit is produced, reduces cost indirectly.
(5)The utility model provides a kind of calcium carbide furnace system of blowing oxygen and heat integration, the furnace of calcium carbide system System can improve H2 contents in reaction furnace exhaust gas by pyrolysis, available for various industrial chemicals.
Brief description of the drawings
Fig. 1 is structural representation of the present utility model.
Wherein, 1, pulverized coal pyrolysis stove, 2, cyclone dust collectors, 3, oil gas condensation device, 4, pyrolysis gas cleaning system, 5, oxygen coal Mixed spray stove, 6, solid mixer, 7, breeze blowing tank, 8, oxygen valve group, 9, gas mixer.
Embodiment
Embodiment of the present utility model is described below in detail.The embodiments described below is exemplary, is only used for explaining The utility model, and it is not intended that to limitation of the present utility model.Unreceipted particular technique or condition in embodiment, according to Technology or condition described by document in the art are carried out according to product description.Agents useful for same or the unreceipted life of instrument Manufacturer person is produced, being can be by the conventional products of acquisition purchased in market.
In description of the present utility model, it is to be understood that term " first ", " second " are only used for describing purpose, and It is not intended that instruction or hint relative importance or the implicit quantity for indicating indicated technical characteristic.Thus, define One or more this feature can be expressed or be implicitly included to the feature of " first ", " second ".Of the present utility model In description, " multiple " are meant that two or more, unless otherwise specifically defined.
In the utility model, unless otherwise clearly defined and limited, term " installation ", " connected ", " connection ", " Gu It is fixed " etc. term should be interpreted broadly, for example, it may be fixedly connected or be detachably connected, or integrally;Can be Mechanically connect or electrically connect;Can be joined directly together, can also be indirectly connected by intermediary, can be two The connection of element internal or the interaction relationship of two elements.For the ordinary skill in the art, can basis Concrete condition understands concrete meaning of the above-mentioned term in the utility model.
According to one side of the present utility model, the utility model provides a kind of blowing oxygen and heat integration Calcium carbide furnace system, including solid mixer 6, pulverized coal pyrolysis stove 1, cyclone dust collectors 2, oil gas condensation device 3, pyrolysis gas purification dress 4, gas mixer 9, oxygen coal mixed spray stove 5, oxygen valve group 8 and breeze blowing tank 7 are put, wherein:The solid mixer, for inciting somebody to action Feed coal and lime stone are well mixed;The pulverized coal pyrolysis stove, is connected with the solid mixer, for the institute that will be well mixed State feed coal and the lime stone carries out pyrolysis processing;The pyrolysis of the inlet end of the cyclone dust collectors and the pulverized coal pyrolysis stove Gas outlet connection, outlet side is connected with the oil gas condensation device;The oil gas condensation device is connected with the cyclone dust collectors, For caused pyrolysis gas in the pulverized coal pyrolysis stove to be carried out into condensation process;The pyrolysis air purifying apparatus and the oil gas are cold Solidifying device connection, the gas for will be discharged in the oil gas condensation device carry out purified treatment;The gas mixer enters Offgas outlet of the mouth respectively with the pyrolysis air purifying apparatus and the mixed spray stove of the oxygen coal is connected, the outlet of the gas mixer It is connected with the pyrolysis gas entrance of the pulverized coal pyrolysis stove, for the gas for discharging the pyrolysis air purifying apparatus and the oxygen coal Flue gas caused by mixed spray stove is mixed, and the pyrolytic reaction for the pulverized coal pyrolysis stove provides thermal source;The mixed spray stove of the oxygen coal is adopted With the hot method next life electricity production stone of oxygen, its side wall is provided with charging aperture and injection mouth, Jiao of the charging aperture and the pulverized coal pyrolysis stove Charcoal outlet connection, the injection mouth are connected with the oxygen valve group and the breeze blowing tank respectively.
Inventor has found that the utility model provides a kind of calcium carbide furnace system of blowing oxygen and heat integration, should Calcium carbide furnace system carries out calcium carbide production using the mixed spray stove of oxygen coal, and the mixed spray stove of the oxygen coal utilizes high temperature and energy caused by oxygen coal injection Carbon dust and pulverized limestone is set to synthesize in calcium carbide, with traditional calcium carbide production technology and provide the mode of heating of heat not all of electric energy Together, heat caused by oxygen coal combustion can be made full use of to substitute part or all of electric energy, calcium carbide is solved and produce asking for high power consumption Topic;Caused pyrolysis coke is heat-fed as the raw material for producing calcium carbide, and by pyrolysis coke and lime stone by the use of in pulverized coal pyrolysis stove Into the mixed spray stove of oxygen coal as raw materials for production, heat utilization ratio is improved, reduces production cost;Produced using the mixed spray stove of oxygen coal Flue gas have that gas flow is big, temperature is high(Flue gas exit temperature is up to 1500 DEG C -1700 DEG C)And CO content in smoke is high Feature, as the coal pyrolysis in pulverized coal pyrolysis stove after the flue gas is mixed with pyrogenic steam caused by pyrolysis in pulverized coal pyrolysis stove Thermal source, the part of waste heat for realizing flue gas and pyrogenic steam fully recycle, and the upgrading for solving the problems, such as low-order coal utilizes, drop Low production cost;Using pyrogenic steam caused by pyrolysis in pulverized coal pyrolysis stove oil, the gas of high-quality are obtained by condensation, purification Product, waste recovery is realized, produce new benefit, reduce cost indirectly.
The calcium carbide furnace system of blowing oxygen and heat integration provided by the utility model, including solid mixer, powder Coal heat decomposition stove and the mixed spray stove of oxygen coal, the solid mixer, for feed coal and lime stone to be well mixed;The pulverized coal pyrolysis Stove is connected with the solid mixer, for the well mixed feed coal and the lime stone to be carried out into pyrolysis processing;Enter One step, using the solid mixture of the feed coal and the lime stone as raw material, passed through in the pulverized coal pyrolysis furnace interior Cross heating carry out pyrolytic reaction, pyrolysis temperature at 850 DEG C -1100 DEG C, obtained after pyrolysis processing upgraded coal and lime stone and Pyrolysis gas;The mixed spray stove of the oxygen coal is connected with the pulverized coal pyrolysis stove, for by after the pulverized coal pyrolysis stove pyrolysis processing Solid product(That is upgraded coal and lime stone)It is discharged into the mixed spray stove of the oxygen coal, calcium carbide is produced using the hot method of oxygen.
According to specific embodiment of the utility model, the mixed spray stove of the oxygen coal, for will be pyrolyzed through the pulverized coal pyrolysis stove Solid product after processing(That is upgraded coal and lime stone)As raw material, stone is produced electricity using oxygen hot method next life.Further, in institute State in the mixed spray stove of oxygen coal, using solid mixer and pulverized coal pyrolysis stove as feedstock pre-processing system, obtain upgraded coal and lime The solid mixture of stone, using oxygen valve group and breeze blowing tank as thermal source feed system, passes through oxygen and coal as raw material Powder burns in stove provides heat for reaction, produces electricity stone using oxygen hot method next life, obtains calcium carbide and high-temperature flue gas.The oxygen coal mixes The side wall for spraying stove is provided with charging aperture, injection mouth, offgas outlet and discharging opening, Jiao of the charging aperture and the pulverized coal pyrolysis stove Charcoal outlet connection, for by the solid product in the pulverized coal pyrolysis stove after pyrolysis processing(That is upgraded coal and lime stone)Discharge Into the mixed spray stove of the oxygen coal, the solid product prepares calcium carbide in the mixed spray stove of the oxygen coal as raw material using the hot method of oxygen;Institute State injection mouth to be connected with the oxygen valve group and the breeze blowing tank respectively, by oxygen and coal dust in the mixed spray stove of the oxygen coal Interior burning, chemical reaction is carried out between upgraded coal and lime stone heat is provided;The offgas outlet and the gas mixer Entrance connects, for high-temperature flue gas caused by the mixed spray stove of the oxygen coal to be discharged into the gas mixer;The discharging opening It is connected with calcium carbide holding vessel, is collected, stores for caused calcium carbide to be discharged into the calcium carbide holding vessel.
According to specific embodiment of the utility model, calcium carbide furnace system provided by the utility model also includes oxygen coal gun, institute Oxygen valve group and the breeze blowing tank are stated, the oxygen valve group is connected with the oxygen coal gun, for by the oxygen valve group Oxygen spray into the oxygen coal gun;The breeze blowing tank connects with the oxygen coal gun, for by the breeze blowing tank Coal dust spray into the oxygen coal gun;The oxygen coal gun is connected with the mixed spray stove of the oxygen coal, for that will come from the oxygen valve group Oxygen and coal dust from the breeze blowing tank spray into simultaneously in the mixed spray stove of oxygen coal, oxygen and coal dust is mixed in the oxygen coal Spray in stove and burn, heat is provided for reaction as thermal source.The oxygen coal gun includes:Muzzle, oxygen intake and coal powder entrance, it is described Oxygen intake is connected with the oxygen valve group, and the coal powder entrance is connected with the outlet of the breeze blowing tank, the muzzle with The injection mouth connection of the mixed spray furnace sidewall of the oxygen coal.Further, the lance head of the oxygen coal gun could be arranged to angle in The oblique hole structure of heart aggregation, when oxygen and coal dust by it is interior be set to the muzzle that inclined hole is distributed and spray after, occur to spray between air-flow Mutually impact and collision, be advantageous to strengthen the mixing between oxygen and coal dust so that burning is more abundant, there is provided more heats.
According to specific embodiment of the utility model, the structure type of the pulverized coal pyrolysis stove is not particularly limited, as long as It can be used in the solid mixture of the feed coal and the lime stone carrying out pyrolysis processing.Further, the powder Coal heat decomposition stove can be fluid bed or down-flow fluidized bed using ECT fast pyrolysis reactor, can be by big in stove after being passed through in order to hot gas Grain solid, which is blown afloat, to be come so that bulky grain solid is suspended among the fluid of motion, can more fully carry out pyrolytic reaction.According to Some specific embodiments of the utility model, the pulverized coal pyrolysis stove include charging aperture, coke export, pyrolysis gas outlet and pyrolysis Gas entrance, the charging aperture of the pulverized coal pyrolysis stove are connected with the discharging opening of the solid mixer, for the institute that will be well mixed State feed coal and the lime stone carries out pyrolysis processing;Further, the feed coal and the lime stone are as raw material, in institute State pulverized coal pyrolysis furnace interior and carry out pyrolytic reaction by heating, pyrolysis temperature obtains at 850 DEG C -1100 DEG C after pyrolysis processing Upgraded coal and lime stone and pyrolysis smoke;The coke export is connected with the mixed spray stove of the oxygen coal, for the fine coal is warm The solid mixture of upgraded coal and lime stone caused by solution furnace interior emits, and is added in the mixed spray stove of the oxygen coal, described Solid mixture is used as the raw material of production calcium carbide;The pyrolysis gas outlet is connected with the cyclone dust collectors, for by the powder Pyrolysis smoke caused by inside coal heat decomposition stove gives off, and enters and purified treatment is carried out in the cyclone dust collectors;The pyrolysis The outlet connection of gas entrance and gas mixer, high-temperature gas is provided by the gas mixer for the pulverized coal pyrolysis stove, The high-temperature gas is used as the thermal source that the pulverized coal pyrolysis furnace interior carries out pyrolysis processing.The charging aperture of the pulverized coal pyrolysis stove and The set location of coke export is not particularly limited, as long as can successfully be inputted the material and be discharged to the fine coal heat Solve in stove;Preferably, the charging aperture of the pulverized coal pyrolysis stove is arranged at the top of furnace wall, and coke export is arranged on the bottom of furnace wall Portion, in order to which the material can utilize the Gravitational sliding of its own, add residence time of the material in stove so that Pyrolytic reaction carries out more abundant.
According to specific embodiment of the utility model, the type of the solid mixer is not particularly limited, as long as can The feed coal and the lime stone are thoroughly mixed to uniformly.Preferably, the solid mixer can be Mixer, can be by being sufficiently stirred the feed coal and the lime stone, and guarantee is well mixed between the two.
The calcium carbide furnace system of blowing oxygen and heat integration provided by the utility model, including cyclone dust collectors, oil Gas condensing unit, the pyrolysis gentle body blender of air purifying apparatus so that caused pyrolysis gas is via rotation in the pulverized coal pyrolysis stove Wind deduster, oil gas condensation device, pyrolysis air purifying apparatus are separated successively, purified treatment, obtain tar product and clean Hot gas, the tar product be used for store, the clean hot gas be passed into the gas mixer be used for and institute Flue gas caused by stating the mixed spray stove of oxygen coal is mixed, and the pyrolytic reaction for the pulverized coal pyrolysis stove provides thermal source.
According to specific embodiment of the utility model, the heat of the inlet end of the cyclone dust collectors and the pulverized coal pyrolysis stove Vent one's spleen and export connection, for the pyrolysis gas to be carried out into dust removal process, remove the SS contained in the pyrolysis gas, Obtain high-temperature gas;The outlet side of the cyclone dust collectors is connected with the oil gas condensation device, for by above-mentioned removing dust High-temperature gas after reason is passed into the oil gas condensation device and carries out Oil-gas Separation, using the method for condensation process, obtains Jiao Oil product and cleaner gas;The pyrolysis air purifying apparatus is connected with the oil gas condensation device, for by the oil gas The relatively clean gas discharged in condensing unit carries out purified treatment, obtains clean gas.Further, the pyrolysis gas purification Device includes the different unit modules such as desulfurization unit, deamination unit, de- benzene unit, de- naphthalene unit, respectively that the oil gas is cold The relatively clean gas discharged in solidifying device carries out the corresponding purified treatments such as desulfurization, deamination, de- benzene, de- naphthalene, has obtained totally Gas.
According to specific embodiment of the utility model, the entrance of the gas mixer purifies with the pyrolysis gas respectively to be filled Put and connected with the offgas outlet of the mixed spray stove of the oxygen coal, the outlet of the gas mixer and the pyrolysis gas of the pulverized coal pyrolysis stove Entrance connects, for the gas of the pyrolysis air purifying apparatus discharge and flue gas caused by the mixed spray stove of the oxygen coal to be mixed Close, the pyrolytic reaction for the pulverized coal pyrolysis stove provides thermal source.By controlling the intake of two kinds of different gas of said temperature, The gas mixer can be mixed to above two gas and adjust temperature, be obtained lower than the ash fusion point ST temperature of coal At least 100 DEG C of mixed gas.Thus, have that gas flow is big, temperature is high using flue gas caused by the mixed spray stove of oxygen coal(Exhanst gas outlet Temperature is up to 1500 DEG C -1700 DEG C)The characteristics of, make after the flue gas is mixed with pyrogenic steam caused by pyrolysis in pulverized coal pyrolysis stove For the coal pyrolysis thermal source in pulverized coal pyrolysis stove, the part of waste heat for realizing flue gas and pyrogenic steam is fully recycled, solved The problem of upgrading of low-order coal utilizes, reduces production cost.
The cyclic process that heat energy provided by the utility model recycles is as follows:Feed coal and stone in the pulverized coal pyrolysis stove Lime stone passes through pyrolysis processing, and the pyrolysis temperature in stove is 850 DEG C -1100 DEG C, generates high temperature pyrolysis gas, the high temperature pyrolysis gas The pulverized coal pyrolysis stove is discharged from pyrolysis gas outlet, carries out dust removal process via cyclone dust collectors successively, oil gas condensation device enters Row condensation process, pyrolysis air purifying apparatus carry out purified treatment, obtain the clean gas of low temperature, the clean gas enters described In gas mixer;Meanwhile the mixed upgraded coal sprayed in stove of the oxygen coal and lime stone produce calcium carbide by the hot method of oxygen, also produce High-temperature flue gas has been given birth to, the high-temperature flue gas is discharged via the offgas outlet of the mixed spray stove of the oxygen coal, and temperature is 1500 DEG C -1700 DEG C, Enter in the gas mixer.Due to the gas mixer entrance respectively with the pyrolysis air purifying apparatus and described The offgas outlet connection of the mixed spray stove of oxygen coal so that the clean gas of the pyrolysis air purifying apparatus discharge and the mixed spray stove of the oxygen coal Caused high-temperature flue gas, which is entered in the gas mixer, is mixed and is adjusted temperature, the different two kinds of gases warp of temperature Mixed gas is obtained after being mixed by the gas mixer, the temperature of the mixed gas is lower at least than the ash fusion point ST temperature of coal 100℃.The outlet of the gas mixer is connected with the pyrolysis gas entrance of the pulverized coal pyrolysis stove, and the mixed gas is passed through Into the pulverized coal pyrolysis stove, the pyrolytic reaction for the pulverized coal pyrolysis stove provides thermal source.
Inventor has found that the utility model provides a kind of calcium carbide furnace system of blowing oxygen and heat integration, should Calcium carbide furnace system carries out calcium carbide production using the mixed spray stove of oxygen coal, and the mixed spray stove of the oxygen coal utilizes high temperature and energy caused by oxygen coal injection Carbon dust and pulverized limestone is set to synthesize in calcium carbide, with traditional calcium carbide production technology and provide the mode of heating of heat not all of electric energy Together, heat caused by oxygen coal combustion can be made full use of to substitute part or all of electric energy, calcium carbide is solved and produce asking for high power consumption Topic;Caused pyrolysis coke is heat-fed as the raw material for producing calcium carbide, and by pyrolysis coke and lime stone by the use of in pulverized coal pyrolysis stove Into the mixed spray stove of oxygen coal as raw materials for production, heat utilization ratio is improved, reduces production cost;Produced using the mixed spray stove of oxygen coal Flue gas have that gas flow is big, temperature is high(Flue gas exit temperature is up to 1500 DEG C -1700 DEG C)And CO content in smoke is high Feature, as the coal pyrolysis in pulverized coal pyrolysis stove after the flue gas is mixed with pyrogenic steam caused by pyrolysis in pulverized coal pyrolysis stove Thermal source, the part of waste heat for realizing flue gas and pyrogenic steam fully recycle, and the upgrading for solving the problems, such as low-order coal utilizes, drop Low production cost;Using pyrogenic steam caused by pyrolysis in pulverized coal pyrolysis stove oil, the gas of high-quality are obtained by condensation, purification Product, waste recovery is realized, produce new benefit, reduce cost indirectly.
According to one side of the present utility model, the utility model provides a kind of comprehensive using above-mentioned blowing oxygen and heat energy The production technology of the calcium carbide furnace system utilized is closed, is comprised the following steps:
(1)Feed coal and lime stone are added in solid mixer, carry out mixed processing.
According to specific embodiment of the utility model, the solid mixer, for by the feed coal and the lime Stone is uniformly mixed.The particle diameter and mixed proportion of the feed coal and the lime stone are not particularly limited, as long as can be Pyrolytic reaction is carried out after well mixed.The feed coal particle diameter is 0.5-5mm, limestone particle size 0.5-5mm, is advantageous to The contact mixing in millimeter rank is carried out between the feed coal and the lime stone;The feed coal is carried out with the lime stone The mixed proportion of mixing is that feed coal/lime stone is 1.05-1.2 so that the feed coal is with the lime stone via the powder Coal heat decomposition stove carries out pyrolysis processing, can obtain upgraded coal and lime stone that mixed proportion is more beneficial for producing calcium carbide.
(2)Raw material after blended processing is sent into pulverized coal pyrolysis stove, carries out pyrolysis processing, obtain pyrolysis gas, upgraded coal and Lime stone.
According to specific embodiment of the utility model, the pulverized coal pyrolysis stove, it is connected with the solid mixer, for inciting somebody to action The solid mixture of the feed coal and the lime stone carries out pyrolysis processing.Further, the feed coal and described Lime stone carries out pyrolytic reaction, with the mixing in gas mixer in the pulverized coal pyrolysis furnace interior as raw material by heating For gas as thermal source, pyrolysis temperature obtains upgraded coal and lime stone and pyrolysis at 850 DEG C -1100 DEG C after pyrolysis processing Gas.Further, the pulverized coal pyrolysis stove can be fluid bed or down-flow fluidized bed using ECT fast pyrolysis reactor, in order to which hot gas is passed through The bulky grain solid in stove can be blown afloat and afterwards so that bulky grain solid is suspended among the fluid of motion, can be more abundant Carry out pyrolytic reaction.
According to specific embodiment of the utility model, the pulverized coal pyrolysis stove includes charging aperture, coke export, pyrolysis gas and gone out Mouth and pyrolysis gas entrance, the charging aperture of the pulverized coal pyrolysis stove are connected with the discharging opening of the solid mixer, for that will mix The uniform feed coal and the lime stone carry out pyrolysis processing;The coke export is connected with the mixed spray stove of the oxygen coal, is used Emitted in by the solid mixture of upgraded coal and lime stone caused by the pulverized coal pyrolysis furnace interior, be added to the oxygen coal In mixed spray stove, the solid mixture is used as the raw material of production calcium carbide;The pyrolysis gas outlet is connected with the cyclone dust collectors, For pyrolysis smoke caused by the pulverized coal pyrolysis furnace interior to be discharged into cyclone dust collectors;The pyrolysis gas entrance mixes with gas The outlet connection of clutch, provides high-temperature gas, the high-temperature gas is used as institute by gas mixer for the pulverized coal pyrolysis stove State the thermal source that pulverized coal pyrolysis furnace interior carries out pyrolysis processing.Preferably, the charging aperture of the pulverized coal pyrolysis stove is arranged on furnace wall top Portion, coke export are arranged on the bottom of furnace wall, in order to which the material can utilize the Gravitational sliding of its own, add described Residence time of the material in stove so that pyrolytic reaction carries out more abundant.
(3)It is pyrolyzed obtained upgraded coal and is sent into the mixed spray stove of oxygen coal as raw material with lime stone, meanwhile, using from oxygen valve The oxygen of group and the coal dust from breeze blowing tank are sprayed onto thermal source of the burning as reaction in the mixed spray stove of the oxygen coal, using oxygen heat Method, obtain calcium carbide and flue gas.
According to specific embodiment of the utility model, the mixed spray stove of the oxygen coal, it is connected with the pulverized coal pyrolysis stove, is used for By the solid product after the pulverized coal pyrolysis stove pyrolysis processing(That is upgraded coal and lime stone)As raw material, using the hot method of oxygen come Produce calcium carbide.Further, in the mixed spray stove of the oxygen coal, the upgraded coal that is gone out with the pulverized coal pyrolysis fire grate and lime stone are consolidated Body mixture burns as raw material, by oxygen and coal dust in stove provides heat for reaction, using the hot method next life electricity production stone of oxygen, Calcium carbide and high-temperature flue gas are obtained, the temperature of the high-temperature flue gas is 1500 DEG C -1700 DEG C.Set in the side wall of the mixed spray stove of the oxygen coal There are charging aperture, injection mouth, offgas outlet and discharging opening, the charging aperture to be connected with the coke export of the pulverized coal pyrolysis stove, use In by the solid product in the pulverized coal pyrolysis stove after pyrolysis processing(That is upgraded coal and lime stone)The oxygen coal is discharged into mix Spray in stove, the solid product prepares calcium carbide in the mixed spray stove of the oxygen coal as raw material using the hot method of oxygen;The injection mouth difference It is connected, is burnt by oxygen and coal dust in the mixed spray stove of the oxygen coal, to carry with the oxygen valve group and the breeze blowing tank Chemical reaction is carried out between matter coal and lime stone heat is provided;The offgas outlet is connected with the entrance of the gas mixer, is used It is discharged into by high-temperature flue gas caused by the mixed spray stove of the oxygen coal in the gas mixer, the tail gas of the mixed spray stove of the oxygen coal goes out The high-temperature flue gas at mouthful is 1500 DEG C -1700 DEG C;The discharging opening is connected with calcium carbide holding vessel, for by caused calcium carbide It is discharged into the calcium carbide holding vessel and is collected, stores.
According to specific embodiment of the utility model, calcium carbide furnace system provided by the utility model also includes oxygen coal gun, institute Oxygen valve group and the breeze blowing tank are stated, the oxygen valve group is connected with the oxygen coal gun, for by the oxygen valve group Oxygen spray into the oxygen coal gun;The breeze blowing tank connects with the oxygen coal gun, for by the breeze blowing tank Coal dust spray into the oxygen coal gun;The oxygen coal gun is connected with the mixed spray stove of the oxygen coal, can be utilized and is arranged in the oxygen coal The oxygen coal gun of mixed spray stove injection mouth sprays into the oxygen from oxygen valve group and the coal dust from breeze blowing tank simultaneously, make oxygen and Coal dust is burnt in the mixed spray stove of the oxygen coal, and heat is provided for reaction.The oxygen coal gun includes:Muzzle, oxygen intake and coal dust Entrance, the oxygen intake are connected with the oxygen valve group, and the coal powder entrance is connected with the outlet of the breeze blowing tank, institute The injection mouth that muzzle is stated with the mixed spray furnace sidewall of the oxygen coal is connected.Further, the lance head of the oxygen coal gun could be arranged to The oblique hole structure that angle is assembled to center, when oxygen and coal dust by it is interior be set to the muzzle that inclined hole is distributed and spray after, spray Mutual impact and collision between air-flow, be advantageous to strengthen the mixing between oxygen and coal dust.
(4)Step(2)In obtained pyrolysis gas handled what is obtained via oil gas condensation device, pyrolysis air purifying apparatus Net pyrolysis gas.
According to specific embodiment of the utility model, pyrogenic steam is successively via cyclone dust collectors caused by pulverized coal pyrolysis stove Carry out dust removal process, oil gas condensation device progress condensation process, pyrolysis air purifying apparatus and carry out purified treatment, obtain clean gas Body, it is passed into the gas mixer and is mixed, the part of heat energy of pyrolysis processing is carried out as pulverized coal pyrolysis stove;Wherein, Pyrogenic steam caused by pulverized coal pyrolysis stove enters oil gas condensation device and carries out condensation process, obtains coal tar;A pyrolysis gas part Circulation is mixed as pyrolysis thermal source with high-temperature flue gas caused by the mixed spray stove of oxygen coal.
The purification process of pyrolysis gas provided by the utility model is as follows:Feed coal and lime stone in the pulverized coal pyrolysis stove By pyrolysis processing, the pyrolysis temperature in stove is 850 DEG C -1100 DEG C, generates high temperature pyrolysis gas, and the high temperature pyrolysis gas are from heat Vent one's spleen to export and discharge the pulverized coal pyrolysis stove, carried out successively via cyclone dust collectors progress dust removal process, oil gas condensation device cold Solidifying processing, pyrolysis air purifying apparatus carry out purified treatment, obtain the clean gas of low temperature, the clean gas enters the gas In blender.
(5)By step(4)In obtained net pyrolysis gas and step(3)In obtained flue gas enter in gas mixer Trip temperature regulation is handled, and then the mixed gas after temperature adjustment is sent in the pulverized coal pyrolysis stove as pyrolysis thermal source, to stove Interior raw material carries out pyrolysis processing.
According to specific embodiment of the utility model, the entrance of the gas mixer purifies with the pyrolysis gas respectively to be filled Put and connected with the offgas outlet of the mixed spray stove of the oxygen coal, the outlet of the gas mixer and the pyrolysis gas of the pulverized coal pyrolysis stove Entrance connects, for the gas of the pyrolysis air purifying apparatus discharge and flue gas caused by the mixed spray stove of the oxygen coal to be mixed Close, the pyrolytic reaction for the pulverized coal pyrolysis stove provides thermal source.By controlling the intake of two kinds of different gas of said temperature, The gas mixer carries out temperature adjustment to above two gas, obtains than the ash fusion point ST temperature of coal lower at least 100 DEG C Mixed gas.Thus, have that gas flow is big, temperature is high using flue gas caused by the mixed spray stove of oxygen coal(Flue gas exit temperature is reachable 1500℃-1700℃)The characteristics of, as fine coal heat after the flue gas is mixed with pyrogenic steam caused by pyrolysis in pulverized coal pyrolysis stove The coal pyrolysis thermal source in stove is solved, the part of waste heat for realizing flue gas and pyrogenic steam fully recycles, and solves low-order coal The problem of upgrading utilizes, reduces production cost.
The cyclic process that heat energy provided by the utility model recycles is as follows:Feed coal and stone in the pulverized coal pyrolysis stove Lime stone passes through pyrolysis processing, and the pyrolysis temperature in stove is 850 DEG C -1100 DEG C, generates high temperature pyrolysis gas, the high temperature pyrolysis gas The pulverized coal pyrolysis stove is discharged from pyrolysis gas outlet, carries out dust removal process via cyclone dust collectors successively, oil gas condensation device enters Row condensation process, pyrolysis air purifying apparatus carry out purified treatment, obtain the clean gas of low temperature, the clean gas enters described In gas mixer;Meanwhile the mixed upgraded coal sprayed in stove of the oxygen coal and lime stone produce calcium carbide by the hot method of oxygen, also produce High-temperature flue gas has been given birth to, the high-temperature flue gas is discharged via the offgas outlet of the mixed spray stove of the oxygen coal, and temperature is 1500 DEG C -1700 DEG C, Enter in the gas mixer.Due to the gas mixer entrance respectively with the pyrolysis air purifying apparatus and described The offgas outlet connection of the mixed spray stove of oxygen coal so that the clean gas of the pyrolysis air purifying apparatus discharge and the mixed spray stove of the oxygen coal Caused high-temperature flue gas is entered in the gas mixer and mixed, and two kinds of different gases of temperature mix via the gas The mixed gas obtained after clutch regulation, the temperature of the mixed gas are lower than the ash fusion point ST temperature of coal at least 100 DEG C.It is described The outlet of gas mixer is connected with the pyrolysis gas entrance of the pulverized coal pyrolysis stove, and the mixed gas is passed into the fine coal In pyrolysis oven, the pyrolytic reaction for the pulverized coal pyrolysis stove provides thermal source.
According to specific embodiment of the utility model, the electricity of blowing oxygen and heat integration provided by the utility model Stone furnace system, calcium carbide, the final product such as institute of table 3 of the calcium carbide furnace system are produced as raw materials for production using feed coal and lime stone Show.Wherein, the lime stone uses quick lime, and the component CaO more than 90% is contained in the quick lime(By mass percentage Calculate), the feed coal uses low-order coal, and the main character of the low-order coal is as shown in table 1.By the raw material that particle diameter is 0.5-5mm Coal is mixed with particle diameter 0.5-5mm lime stones, and mixed proportion is feed coal(That is fine coal):It is 1 that lime, which is pressed,:1.05.Will mixing Raw material afterwards, which is sent into pulverized coal pyrolysis stove, carries out pyrolysis processing, to be pyrolyzed the clean gas of air purifying apparatus discharge and the oxygen coal High-temperature flue gas caused by mixed spray stove provides energy as thermal source for pyrolysis, and pyrolysis temperature obtains upgraded coal and lime at 900 DEG C Stone and pyrolysis gas.Upgraded coal caused by pyrolysis and lime stone enter the raw material as production calcium carbide, oxygen in the mixed spray stove of oxygen coal The thermal source of being used as production calcium carbide is sprayed into the mixed spray stove of oxygen coal with coal dust by oxygen coal gun, and specific injection amount is as shown in table 3, passes through coal Powder and oxygen combustion produce high-temperature flue gas, the flue-gas temperature when high-temperature flue gas is in the offgas outlet of electric arc furnaces at 1600 DEG C, It with the pyrolysis gas Jing Guo purified treatment mixed in gas mixer, obtains mixed gas, the mixed gas Temperature is 1100 DEG C.Also, pyrogenic steam caused by pulverized coal pyrolysis stove carries out dust removal process, oil gas via cyclone dust collectors successively Condensing unit carries out condensation process, pyrolysis air purifying apparatus carries out purified treatment, obtains clean gas, is passed into the gas and mixes Mixed in clutch, the part of heat energy of pyrolysis processing is carried out as pulverized coal pyrolysis stove;Wherein, it is pyrolyzed caused by pulverized coal pyrolysis stove Steam enters oil gas condensation device and carries out condensation process, obtains coal tar;The circulation of a pyrolysis gas part produces with the mixed spray stove of oxygen coal High-temperature flue gas mixing as pyrolysis thermal source.Finally, the mixed spray stove of oxygen coal uses the hot method of oxygen, obtains calcium carbide and high-temperature flue gas, product The gas forming amount 267L/kg of calcium carbide, calcium carbonate content 72.1%.
The main character of the low-order coal of table 1
Project Unit Numerical value Remarks
Quan Shui % 3.5 As-received
Fixed carbon % 62.2 Butt
Volatile matter % 37 Butt
Ash content % 7 Butt
The product that the calcium carbide furnace system of table 2 obtains
Product Yield %(Coal base)
Solid product 67.4
Tar 2.7
Coal gas 25.3
It is pyrolyzed water 4.6
The injection amount of the oxygen of table 3 and coal dust
It is blown carbon dust amount(kg/h) Injecting oxygen amount(Nm3/h)
1500 1200
Inventor has found that the utility model provides a kind of calcium carbide furnace system of blowing oxygen and heat integration, should Calcium carbide furnace system carries out calcium carbide production using the mixed spray stove of oxygen coal, and the mixed spray stove of the oxygen coal utilizes high temperature and energy caused by oxygen coal injection Carbon dust and pulverized limestone is set to synthesize in calcium carbide, with traditional calcium carbide production technology and provide the mode of heating of heat not all of electric energy Together, heat caused by oxygen coal combustion can be made full use of to substitute part or all of electric energy, calcium carbide is solved and produce asking for high power consumption Topic;Caused pyrolysis coke is heat-fed as the raw material for producing calcium carbide, and by pyrolysis coke and lime stone by the use of in pulverized coal pyrolysis stove Into the mixed spray stove of oxygen coal as raw materials for production, heat utilization ratio is improved, reduces production cost;Produced using the mixed spray stove of oxygen coal Flue gas have that gas flow is big, temperature is high(Flue gas exit temperature is up to 1500 DEG C -1700 DEG C)And CO content in smoke is high Feature, as the coal pyrolysis in pulverized coal pyrolysis stove after the flue gas is mixed with pyrogenic steam caused by pyrolysis in pulverized coal pyrolysis stove Thermal source, the part of waste heat for realizing flue gas and pyrogenic steam fully recycle, and the upgrading for solving the problems, such as low-order coal utilizes, drop Low production cost;Using pyrogenic steam caused by pyrolysis in pulverized coal pyrolysis stove oil, the gas of high-quality are obtained by condensation, purification Product, waste recovery is realized, produce new benefit, reduce cost indirectly.
Calcium carbide furnace system provided by the utility model is described in detail above, embodiment pair used herein The principle and embodiment of the application is set forth, and the explanation of above example is only intended to help and understands the present processes And its core concept;Meanwhile for those of ordinary skill in the art, according to the thought of the application, in embodiment and There will be changes in application, in summary, this specification content should not be construed as the limitation to the application.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means specific features, structure, material or the spy for combining the embodiment or example description Point is contained at least one embodiment or example of the present utility model.In this manual, to the schematic table of above-mentioned term State and be necessarily directed to identical embodiment or example.Moreover, specific features, structure, material or the feature of description can be with Combined in an appropriate manner in any one or more embodiments or example.In addition, in the case of not conflicting, this area Technical staff the different embodiments or example and the feature of different embodiments or example described in this specification can be entered Row combines and combination.
Although embodiment of the present utility model has been shown and described above, it is to be understood that above-described embodiment is Exemplary, it is impossible to it is interpreted as to limitation of the present utility model, one of ordinary skill in the art is in the scope of the utility model It is interior above-described embodiment to be changed, changed, replaced and modification.

Claims (5)

1. the calcium carbide furnace system of a kind of blowing oxygen and heat integration, it is characterised in that including solid mixer, fine coal heat Solve stove, cyclone dust collectors, oil gas condensation device, pyrolysis air purifying apparatus, gas mixer, the mixed spray stove of oxygen coal, oxygen valve group and Breeze blowing tank, wherein:
The pulverized coal pyrolysis stove is connected with the solid mixer;
The inlet end of the cyclone dust collectors is connected with the pyrolysis gas outlet of the pulverized coal pyrolysis stove, and the cyclone dust collectors go out Gas end is connected with the oil gas condensation device;
The pyrolysis air purifying apparatus is connected with the oil gas condensation device;
Offgas outlet of the entrance of the gas mixer respectively with the pyrolysis air purifying apparatus and the mixed spray stove of the oxygen coal connects Connect, the outlet of the gas mixer is connected with the pyrolysis gas entrance of the pulverized coal pyrolysis stove;
The side wall of the mixed spray stove of the oxygen coal is provided with charging aperture and injection mouth, the coke of the charging aperture and the pulverized coal pyrolysis stove Outlet connection, the injection mouth are connected with the oxygen valve group and the breeze blowing tank respectively.
2. a kind of calcium carbide furnace system of blowing oxygen and heat integration as claimed in claim 1, it is characterised in that also wrap Oxygen coal gun is included, including:Muzzle, oxygen intake and coal powder entrance, the muzzle and the injection mouth of the mixed spray furnace sidewall of the oxygen coal connect Connect, the oxygen intake is connected with the oxygen valve group, and the coal powder entrance is connected with the outlet of the breeze blowing tank.
3. a kind of calcium carbide furnace system of blowing oxygen and heat integration as claimed in claim 2, it is characterised in that described The lance head of oxygen coal gun is the oblique hole structure that angle is assembled to center.
4. the calcium carbide furnace system of a kind of blowing oxygen and heat integration as described in claim any one of 1-3, its feature It is, the pulverized coal pyrolysis stove is fluid bed or down-flow fluidized bed using ECT fast pyrolysis reactor;The pyrolysis air purifying apparatus includes desulfurization Unit, deamination unit, de- benzene unit, de- naphthalene unit.
5. the calcium carbide furnace system of a kind of blowing oxygen and heat integration as described in claim any one of 1-3, its feature It is, in addition to calcium carbide holding vessel, it is connected with the discharging opening of the mixed spray stove of the oxygen coal.
CN201720608166.0U 2017-05-27 2017-05-27 A kind of calcium carbide furnace system of blowing oxygen and heat integration Expired - Fee Related CN206886686U (en)

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