CN206872744U - A kind of system that natural gas is prepared using wind energy - Google Patents

A kind of system that natural gas is prepared using wind energy Download PDF

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Publication number
CN206872744U
CN206872744U CN201720239538.7U CN201720239538U CN206872744U CN 206872744 U CN206872744 U CN 206872744U CN 201720239538 U CN201720239538 U CN 201720239538U CN 206872744 U CN206872744 U CN 206872744U
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carbon dioxide
hydrogen
wind energy
methanation reaction
electrolytic water
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CN201720239538.7U
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姜鑫
乔佳
丁斌
王勋
郭保玲
朱瑞娟
王倩微
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Beijing Gas Group Co Ltd
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Beijing Gas Group Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/70Wind energy
    • Y02E10/72Wind turbines with rotation axis in wind direction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight

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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The utility model discloses a kind of system that natural gas is prepared using wind energy, it includes:Wind power generation plant, electrolytic water device, carbon dioxide collecting device and methanation reaction device;Wind power generation plant is used to wind energy being converted to electric energy;Electrolytic water device is used for electrolysis water and generates oxygen and hydrogen;Carbon dioxide collecting device is used to collect carbon dioxide;The carbon dioxide that methanation reaction device is provided using hydrogen caused by electrolytic water device and carbon dioxide collecting device produces methane as raw material and generates vapor.The system can make full use of the electrolysis production oxygen and hydrogen of green wind energy progress water, simultaneously GHG carbon dioxide is collected using carbon dioxide collecting device, fuel methane and water byproduct steam are further generated by the chemical reaction of hydrogen and carbon dioxide in methanation reaction device, the chemical energy for converting wind energy into cleaning is realized, while atmosphere pollution and greenhouse effects caused by avoiding carbon dioxide.

Description

A kind of system that natural gas is prepared using wind energy
Technical field
The utility model belongs to clean energy technology field, is using what wind energy prepared natural gas more particularly to a kind of System.
Background technology
Carbon dioxide is greenhouse gases common in air, is a kind of gaseous compound, carbon and its chemistry of oxygen reaction generation Formula is CO2, a carbon dioxide molecule is made up of two oxygen atoms and a carbon atom covalent bond.Global warming it is main Reason is that the mankind have largely used fossil fuel since a nearly century(Such as coal, oil), give off substantial amounts of CO2Etc. a variety of Greenhouse gases.Because these greenhouse gases have the permeability of height to the visible ray from solar radiation, and to earth reflection Long-wave radiation out has the absorbability of height, that is, " greenhouse effects " often said, causes global warming.The whole world becomes It warm consequence, can redistribute Global Precipitation amount, glacier and frozen soil ablation, sea level rise, both endangers natural ecosystem The balance of system, more threaten food supply and the living environment of the mankind.
Carbon dioxide is one of carbon source that reserves are the abundantest on the earth.With the increasingly depleted of petroleum resources, in addition to The serious ecological and environmental problem caused by carbon dioxide are largely discharged in air, by greenhouse gases CO2It is changed into high added value Chemical products turn into domestic and international industry and academia research and discuss focus.
One of method of existing processing carbon dioxide is to seal up for safekeeping, and the carbon dioxide that the mankind discharge is caught and concentrated Come, carry out geological storage or deep-sea is sealed up for safekeeping, the global warming for solving to trigger by greenhouse gases threatens.In addition carbon dioxide Plant gas fertilizer and fruit and vegetable fresh-keeping agent can also be used as, as the raw material of fire extinguisher, industrially can soda ash processed, urea, carbonated drink etc., two The finished product dry ice of carbonoxide can make refrigerant, the food that preservation easily degenerates, it may also be used for rain making;In greenhouse production, Conventional carbon dioxide is as fertilizer.But above-mentioned existing method is respectively provided with the shortcomings that cost is high and the consumption energy is big, it is also necessary to enters One step develops new Sustainable type way of disposing of CO2.
Utility model content
The purpose of this utility model is to provide a kind of system that natural gas is prepared using wind energy, has to solve existing method There is the problem of cost is high and the consumption energy is big.
The technical scheme that the utility model solves above-mentioned technical problem is as follows:It is a kind of to be using what wind energy prepared natural gas System, it includes:Wind power generation plant, electrolytic water device, carbon dioxide collecting device and methanation reaction device;
The wind power generation plant is used to wind energy being converted to electric energy;The electrolytic water device is used for electrolysis water and generates oxygen Gas and hydrogen;The carbon dioxide collecting device is used to collect carbon dioxide;The methanation reaction device is with electrolytic water device The carbon dioxide that caused hydrogen and carbon dioxide collecting device provide produces methane for raw material and generates vapor.
The system that the utility model prepares natural gas using wind energy as described above, further, the wind power generation plant Connected by the power injection interface of power transmission line and electrolytic water device, hydrogen caused by the negative electrode of the electrolytic water device passes through hydrogen Gas is exported and hydrogen transfer tube is transmitted to the hydrogen inlet of methanation reaction device.
The system that the utility model prepares natural gas using wind energy as described above, further, the carbon dioxide collection The gas delivery port of device is connected by carbon dioxide transmission pipe with the carbon dioxide entrance of methanation reaction device.
The system that the utility model prepares natural gas using wind energy as described above, further, the methanation reaction dress Put and connect including hydrogen inlet, carbon dioxide entrance and mixed gas outlet, the hydrogen outlet of the hydrogen inlet and electrolytic water device Logical, carbon dioxide entrance connects with the gas delivery port of carbon dioxide collecting device.
The system that the utility model prepares natural gas using wind energy as described above, further, the system also include mixing Air separation, the air inlet of the mixed gas separation device connect with the mixed gas outlet of methanation reaction device, for inciting somebody to action Methane, vapor in gaseous mixture are separated and exported respectively.
The system that the utility model prepares natural gas using wind energy as described above, further, the system also include backwater Pipe, the steam outlet of the return pipe connection mixed gas separation device and the water supplement port of electrolytic water device.
The system that the utility model prepares natural gas using wind energy as described above, further, the system also include being used for The molecular sieve of carbon dioxide and water is filtered out, the molecular sieve is arranged on the connection of methanation reaction device and mixed gas separation device On pipeline.Further, the molecular sieve is 4A molecular sieves or 13X molecular sieves.
The system that the utility model prepares natural gas using wind energy as described above, further, the system also include dioxy Change Carbon stock device, the carbon dioxide storage device is used to store the carbon dioxide from carbon dioxide collecting device, and will The carbon dioxide of storage is delivered to methanation reaction device.
The beneficial effects of the utility model are:
Green wind energy can be made full use of to carry out the electrolysis production oxygen and hydrogen of water, while filled using carbon dioxide collection Collection GHG carbon dioxide is put, is further generated in methanation reaction device by the chemical reaction of hydrogen and carbon dioxide Fuel methane and water byproduct steam, realize the chemical energy for converting wind energy into cleaning, while avoid carbon dioxide and cause Atmosphere pollution and greenhouse effects.In addition, in the technical scheme of mixed gas separation device and return pipe is set, can be to reaction The vapor of generation is reused, and adds the Operating ettectiveness of system.
Brief description of the drawings
By the detailed description made in conjunction with the following drawings, of the present utility model above-mentioned and/or other aspects and advantage will Becoming more apparent upon and be easier to understand, these accompanying drawings are simply schematical, are not intended to limit the utility model, wherein:
Fig. 1 is a kind of system schematic that natural gas is prepared using wind energy of embodiment of the utility model;
Fig. 2 is the system schematic that natural gas is prepared using wind energy of the utility model another kind embodiment;
Fig. 3 is the system operation schematic flow sheet that natural gas is prepared using wind energy.
In accompanying drawing, the list of parts representated by each label is as follows:
1st, wind power generation plant, 2, electrolytic water device, 3, carbon dioxide collecting device, 4, methanation reaction device, 5, oxygen Gas transfer tube, 6, mixed gas pipeline, 7, filling pipe, 8, carbon dioxide transmission pipe, 9, mixed gas separation device, 10, return pipe.
Embodiment
Hereinafter, the embodiment of the system of the present utility model that natural gas is prepared using wind energy is described with reference to the accompanying drawings.
The embodiment recorded herein is specific embodiment of the present utility model, of the present utility model for illustrating Design, is explanatory and exemplary, should not be construed as the limit to the utility model embodiment and the scope of the utility model System.In addition to the embodiment recorded herein, those skilled in the art can also be based on the application claims and specification institute is public The content opened includes doing using the embodiment to recording herein using obvious other technical schemes, these technical schemes Go out the technical scheme of any obvious substitutions and modifications.
The accompanying drawing of this specification is schematic diagram, aids in illustrating design of the present utility model, it is schematically indicated each several part Shape and its correlation.It note that for the ease of clearly showing the structure of each part of the utility model embodiment, respectively Do not drawn between accompanying drawing according to identical ratio.Identical reference marker is used to represent identical part.
Fig. 1 shows a kind of system that natural gas is prepared using wind energy of embodiment of the utility model, and it includes:Wind-power electricity generation Device 1, electrolytic water device 2, carbon dioxide collecting device 3 and methanation reaction device 4;
Wind power generation plant 1 is used to wind energy being converted to electric energy;Electrolytic water device 2 is used for electrolysis water and generates oxygen and hydrogen Gas;Carbon dioxide collecting device 3 is used to collect the carbon dioxide that combustion of fossil fuel is produced;Methanation reaction device 4 is with electricity The carbon dioxide that hydrogen and carbon dioxide collecting device 3 caused by solution water installations 2 provide produces methane for raw material and generates water steaming Gas, reaction equation CO2+4H2→CH4+2H2O △ H298K=-165.0KJ/mol.Wind power generation plant 1 passes through power transmission line It is connected with the power injection interface of electrolytic water device 2, hydrogen caused by the negative electrode of electrolytic water device 2 passes through hydrogen outlet and hydrogen Transfer tube is transmitted to the hydrogen inlet of methanation reaction device 4.Oxygen caused by the anode of electrolytic water device 2 passes through oxygen outlet Export and utilize with oxygen transmission pipe 5.The gas delivery port of carbon dioxide collecting device 3 passes through carbon dioxide transmission pipe 8 and methane Change the carbon dioxide entrance connection of reaction unit 4.
The principle and mistake of methane are prepared with reference to Fig. 3 systems for illustrating to prepare natural gas using wind energy using above-described embodiment Journey:
It is prepared by the first step, hydrogen:By electrical energy transportation caused by wind power plant into electrolytic water device, in the work of electric current Under, hydrone is decomposed, and produces hydrogen and oxygen in the negative electrode and anode of electrolytic water device respectively, and gas is received respectively Collection, wherein oxygen is utilized as product, and hydrogen then enters methanation reaction device as next step reaction raw materials.
Second step, carbon dioxide collection:Separated, collected using carbon dioxide collecting device, purifying carbon dioxide, as first The raw material of alkanisation enters methanation reaction device.
3rd step, methanation:Hydrogen and carbon dioxide are sent into methanation reaction device according to certain reaction ratio, The two reaction generation methane and vapor in the presence of HTHP catalyst.
The system embodiment of natural gas is prepared using wind energy a kind of, methanation reaction device 4 includes hydrogen inlet, two Carbonoxide entrance and mixed gas outlet, hydrogen inlet connect with the hydrogen outlet of electrolytic water device 2, carbon dioxide entrance and dioxy Change the gas delivery port connection of carbon collection device 3.
Fig. 2 shows the system that natural gas is prepared using wind energy of second of embodiment of the utility model, and it includes:Wind-force is sent out Electric installation 1, electrolytic water device 2, carbon dioxide collecting device 3 and methanation reaction device 4;
Wind power generation plant 1 is used to wind energy being converted to electric energy;Electrolytic water device 2 is used for electrolysis water and generates oxygen and hydrogen Gas;Carbon dioxide collecting device 3 is used to collect the carbon dioxide that combustion of fossil fuel is produced;Methanation reaction device 4 is with electricity The carbon dioxide that hydrogen and carbon dioxide collecting device 3 caused by solution water installations 2 provide produces methane for raw material and generates water steaming Gas;Wind power generation plant 1 is connected by power transmission line with the power injection interface of electrolytic water device 2, the negative electrode production of electrolytic water device 2 Raw hydrogen is transmitted to the hydrogen inlet of methanation reaction device 4 by hydrogen outlet and hydrogen transfer tube.Electrolytic water device 2 Oxygen caused by anode is utilized by oxygen outlet and the output of oxygen transmission pipe 5.The gas delivery port of carbon dioxide collecting device 3 Connected by carbon dioxide transmission pipe 8 with the carbon dioxide entrance of methanation reaction device 4;Mixed gas separation device 9, gaseous mixture The air inlet of separator 9 is connected with the mixed gas outlet of methanation reaction device 4 by mixed gas pipeline 6, for that will mix Close the methane in gas, vapor is separated and exported respectively;Return pipe 10, the water that return pipe 10 connects mixed gas separation device 9 steam Gas exports and the water supplement port of electrolytic water device 2, or return pipe 10 connects steam outlet and the electrolysis of mixed gas separation device 9 The filling pipe 7 of water installations 2.
By isolation technics, methane and vapor are separated, can be recycled after water vapor condensation, methane is as product Output, can also produce CNG or LNG product.
Prepare the system embodiment of natural gas using wind energy a kind of, the system also include being used for filtering out carbon dioxide and The molecular sieve of water, molecular sieve are arranged on the connecting line of methanation reaction device 4 and mixed gas separation device 9;In such as Fig. 1 institutes In the embodiment shown, connecting line is mixed gas pipeline 6.Further, molecular sieve is 4A molecular sieves or 13X molecular sieves.
The system embodiment of natural gas is prepared using wind energy a kind of, the system also includes carbon dioxide storage device, Carbon dioxide storage device is used to store the carbon dioxide from carbon dioxide collecting device 3, and the carbon dioxide of storage is defeated Deliver to methanation reaction device 4.It can be delayed using carbon dioxide storage device for the carbon dioxide collection of system and using providing Function is rushed, it is unnecessary when the carbon dioxide that carbon dioxide collecting device is collected into exceedes the disposal ability of methanation reaction device Carbon dioxide be stored in carbon dioxide storage device, stopped transport for carbon dioxide collecting device or carry out dioxy when collecting insufficient Change carbon supplement.
Each technical characteristic of above-mentioned disclosure is not limited to disclosed and further feature combination, and those skilled in the art are also Other combinations between each technical characteristic can be carried out according to the purpose of invention, are defined by the purpose for realizing the utility model.

Claims (6)

  1. A kind of 1. system that natural gas is prepared using wind energy, it is characterised in that including:Wind power generation plant, electrolytic water device, two Carbonoxide collection device and methanation reaction device;
    The wind power generation plant is used to wind energy being converted to electric energy;The electrolytic water device be used for electrolysis water and generate oxygen and Hydrogen;The carbon dioxide collecting device is used to collect carbon dioxide;The methanation reaction device is produced with electrolytic water device Hydrogen and the carbon dioxide that provides of carbon dioxide collecting device produce methane for raw material and generate vapor;
    The wind power generation plant is connected by the power injection interface of power transmission line and electrolytic water device, the electrolytic water device Hydrogen caused by negative electrode is transmitted to the hydrogen inlet of methanation reaction device by hydrogen outlet and hydrogen transfer tube;
    The gas delivery port of the carbon dioxide collecting device passes through carbon dioxide transmission pipe and the dioxy of methanation reaction device Change the connection of carbon entrance;
    The methanation reaction device includes hydrogen inlet, carbon dioxide entrance and mixed gas outlet, the hydrogen inlet and electricity The hydrogen outlet connection of water installations is solved, carbon dioxide entrance connects with the gas delivery port of carbon dioxide collecting device.
  2. 2. the system according to claim 1 that natural gas is prepared using wind energy, it is characterised in that also including mixed gas separation Device, the air inlet of the mixed gas separation device connect with the mixed gas outlet of methanation reaction device, for by gaseous mixture In methane, vapor separate and export respectively.
  3. 3. the system according to claim 2 that natural gas is prepared using wind energy, it is characterised in that also including return pipe, institute State the steam outlet of return pipe connection mixed gas separation device and the water supplement port of electrolytic water device, or return pipe connection mixing The steam outlet of air separation and the filling pipe of electrolytic water device.
  4. 4. the system according to claim 2 that natural gas is prepared using wind energy, it is characterised in that also include being used to filter out two The molecular sieve of carbonoxide and water, the molecular sieve are arranged on the connecting line of methanation reaction device and mixed gas separation device On.
  5. 5. the system according to claim 4 that natural gas is prepared using wind energy, it is characterised in that the molecular sieve is 4A points Son sieve or 13X molecular sieves.
  6. 6. the system that natural gas is prepared using wind energy according to claim any one of 1-5, it is characterised in that also including two Carbonoxide storage device, the carbon dioxide storage device are used to store the carbon dioxide from carbon dioxide collecting device, and The carbon dioxide of storage is delivered to methanation reaction device.
CN201720239538.7U 2017-03-13 2017-03-13 A kind of system that natural gas is prepared using wind energy Active CN206872744U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109943373A (en) * 2018-05-07 2019-06-28 北京建筑大学 A kind of energy conversion and storage method based on electric gas producing technology
CN110305704A (en) * 2019-05-23 2019-10-08 东南大学 A kind of coupling new energy low energy consumption realization CO2The system and method for capturing and utilizing
CN110467949A (en) * 2019-06-27 2019-11-19 泉州市燃气有限公司 A kind of natural gas production synthesizer and its production technology
JP2020033284A (en) * 2018-08-29 2020-03-05 株式会社日立製作所 Methane production system
CN115069173A (en) * 2022-06-08 2022-09-20 安徽理工大学 Molecular sieve catalytic reduction carbon dioxide device

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109943373A (en) * 2018-05-07 2019-06-28 北京建筑大学 A kind of energy conversion and storage method based on electric gas producing technology
JP2020033284A (en) * 2018-08-29 2020-03-05 株式会社日立製作所 Methane production system
JP7014690B2 (en) 2018-08-29 2022-02-01 株式会社日立製作所 Methane production system
CN110305704A (en) * 2019-05-23 2019-10-08 东南大学 A kind of coupling new energy low energy consumption realization CO2The system and method for capturing and utilizing
CN110467949A (en) * 2019-06-27 2019-11-19 泉州市燃气有限公司 A kind of natural gas production synthesizer and its production technology
CN115069173A (en) * 2022-06-08 2022-09-20 安徽理工大学 Molecular sieve catalytic reduction carbon dioxide device

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