CN206772649U - The sampler of electrolyte in liquid energy-storage system - Google Patents

The sampler of electrolyte in liquid energy-storage system Download PDF

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Publication number
CN206772649U
CN206772649U CN201720704182.XU CN201720704182U CN206772649U CN 206772649 U CN206772649 U CN 206772649U CN 201720704182 U CN201720704182 U CN 201720704182U CN 206772649 U CN206772649 U CN 206772649U
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electrolyte
peristaltic pump
storage tank
suction pipe
liquid
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荣明林
张华民
邹毅
宋玉波
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Dalian Rongke Power Co Ltd
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Dalian Rongke Power Co Ltd
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Abstract

The sampler of electrolyte in liquid energy-storage system, belongs to liquid energy-storage field, opens the problem of manhole direct sample causes for solving due to reserving sample tap on operation pipeline, or in storage device, technical essential is:Including electrolyte storage tank, peristaltic pump and sampling bottle, the surface of its body of electrolyte storage tank has preformed hole, and suction pipe is inserted inside electrolyte storage tank by preformed hole, and the suction inlet of suction pipe is located under electrolysis liquid surface, and suction pipe is communicated in peristaltic pump, peristaltic pump connects with sampling bottle.Effect is:By peristaltic pump to sample extraction, the mode of this indirect manual sampling is no longer limited by storage device height, and sampling mode is by peristaltic pump pumps, manually participates in less, and sealing is preferable.

Description

The sampler of electrolyte in liquid energy-storage system
Technical field
The utility model belongs to liquid energy-storage field, is related to a kind of sampler of electrolyte in liquid energy-storage system.
Background technology
In liquid energy-storage running, analysis need to be sampled to the chemical property of electrolyte, the electrolysis in storage device Liquid is for Main Analysis object, it is necessary to take liquid to electrolyte, and at present, sampling mode mainly includes several lower two kinds:
Mode one:Sample tap is reserved on energy-storage system operation pipeline, sample is accessed from sample tap;
This kind of sampling mode has the disadvantage that:
A. sample tap position determines when designing energy storage system pipeline, the later stage sample position be not easy to change.Due to electrolysis Liquid when energy-storage system is run chemical property can real-time change, electrolyte and storing up electricity solution chemistry in storage device in pipeline It is not consistent, thus the electrolye analysis result that such a sampling mode takes out has limitation.
B. because sampling analysis has real-time, therefore before every sub-sampling, the electrolysis of residual before need to discharging at sample tap Liquid, to reduce entrained electrolyte error to caused by analysis result.Sample only needs 5-10ml capacity, but lifting rate exists every time 0.5-1L, it is 100-200 times of sample size, and the electrolyte discharged is respectively formed wastes, increase operating cost.
C. electrolyte easily crystallizes in static pipeline, so as to block sample tap:
When a) per sub-sampling, electrolyte is influenceed by the sample tap blocked, easily causes electrolyte splash, causes electrolyte unrestrained Take, increase operating cost.
B) such as sample tap is cleared up before sampling, then additionally increases the job costs of sampling personnel;And Subsampling mouth Stopping state is serious, need to change sample tap, increases maintenance cost.
When D. sampling, it is limited to sample tap and valve opening size, sampling amount is difficult to control, and the sample having more forms wave Take, increase operating cost.
Mode two:The manhole of energy-accumulating medium storage device is opened, is directly contained from storage device and takes sample;
This kind of sampling mode has the disadvantage that:
A. such a mode can only use in small-sized storage device, as storage device highly be more than 1.2 meters, Ci Zhongfang Formula will be no longer applicable.
B. sample number it is more when, frequently open the manhole of storage device, by the work of great increase sampling personnel into This, reduces operating efficiency, while will also influence the sealing of storage device.
Except this, above two sampling mode also has the disadvantage that simultaneously:
When A. sampling, it can not accomplish that electrolyte liquid and air are completely isolated, easily cause electrolyte liquid by air oxygen Change, cause its chemical property to change, impact analysis result accuracy.
B. it when energy-storage system is run, will make troubles to sampling work, thus generally enter under energy-storage system halted state Row sampling work.
Utility model content
In order to solve due to operation pipeline on reserve sample tap, or storage device open manhole direct sample cause Above-mentioned problems, the utility model uses following technical scheme:
The sampler of electrolyte in a kind of liquid energy-storage system, including electrolyte storage tank, peristaltic pump and sampling bottle, it is described The surface of its body of electrolyte storage tank has preformed hole, and suction pipe is inserted inside electrolyte storage tank by preformed hole, the suction inlet position of suction pipe Under electrolysis liquid surface, and suction pipe is communicated in peristaltic pump, and peristaltic pump connects with sampling bottle.
Further, hand-operated valve is installed on the suction pipe between described preformed hole and peristaltic pump.
Further, described electrolyte storage tank includes anolyte liquid storage tank and cathode electrolyte storage tank, peristaltic pump tool There is a double pump head, the pump head all the way of the suction pipe connection in anolyte liquid storage tank, suction pipe connection in cathode electrolyte storage tank pump all the way Head, each pump head connect a sampling bottle, and the inert gas for sealing is carried in sampling bottle.
Further, peristaltic pump has external communication interface, and the electric power system of peristaltic pump is connected to battery management system (BMS)。
Further, the suction inlet of suction pipe is located at 1/3 or so under electrolysis liquid surface.
Further, the working flow of the peristaltic pump is 0.0016-500ml/ minutes, and suction pipe internal diameter is 0.8-7.9mm, Tubing length is 0.1-2m.
Further, described peristaltic pump is between anolyte liquid storage tank and cathode electrolyte storage tank, and places high Degree is substantially contour with electrolysis liquid surface, and preformed hole is located at the upper surface of electrolyte storage tank.
Beneficial effect:The utility model improves prior art, and thief hole is not reserved on operation pipeline, and selects storing Device aperture, and the mode of this indirect manual sampling, storage device height is no longer limited by sample extraction by peristaltic pump Degree, and sampling mode is by peristaltic pump pumps, manually participates in less, and sealing is preferable, and the analysis result of sample has reliability.Cause The resorption function of peristaltic pump, the electrolyte remained after sampling can resorption need not carry out discharge opeing into storage device, during lower sub-sampling Operation, thus not because discharge opeing and caused by electrolyte waste.In peristaltic pump suction pipe will not entrained electrolyte, therefore will not be because of electrolyte Crystallization cause sampling line to block.The working flow of peristaltic pump can be set, therefore the sample size per sub-sampling can be controlled accurately, be subtracted Electrolyte wastes caused by when sampling less.Inert gas shielding is carried in sampling bottle, can make electrolyte liquid and air completely every From.Not by energy-storage system state limit during wriggling pump work, i.e., no matter whether energy-storage system stops, and sampling work can be carried out. Peristaltic pump double pump head can be sampled work simultaneously, save both positive and negative polarity sample time, sampling equipment independently of energy-storage system, thus Energy-storage system will not be had undesirable effect.
Brief description of the drawings
Fig. 1 is the structural representation of the sampler of electrolyte in liquid energy-storage system described in the utility model.
Wherein:1. suction pipe, 2. preformed holes, 3. peristaltic pumps, 4. hand-operated valves, 5. anolyte liquid storage tanks, 6. electrolyte liquid Storage tank, 7. sampling bottles.
Embodiment
Embodiment:The sampler of electrolyte in a kind of liquid energy-storage system, including electrolyte storage tank, peristaltic pump 3 and take Sample bottle 7, the surface of its body of electrolyte storage tank have preformed hole 2, and suction pipe 1 is inserted inside electrolyte storage tank by preformed hole 2, The suction inlet of suction pipe 1 is located under electrolysis liquid surface, and suction pipe 1 is communicated in peristaltic pump 3, and peristaltic pump 3 connects with sampling bottle 7.Described is pre- Box out and hand-operated valve 4 is installed on the suction pipe 1 between 2 and peristaltic pump 3.Described electrolyte storage tank includes anolyte liquid storage tank 5 With cathode electrolyte storage tank 6, peristaltic pump 3 has a double pump head, and the suction pipe 1 in anolyte liquid storage tank 5 connects pump head all the way, negative pole Suction pipe 1 in electrolyte storage tank 6 connects pump head all the way, and each pump head connects a sampling bottle 7, and is carried in sampling bottle 7 for close The inert gas of envelope.Peristaltic pump 3 has external communication interface, and the electric power system of peristaltic pump 3 is connected to battery management system.Inhale The suction inlet of pipe 1 is located at 1/3 or so under electrolysis liquid surface.The working flow of the peristaltic pump 3 is 0.0016-500ml/ minutes, is inhaled The internal diameter of pipe 1 is 0.8-7.9mm, and the length of suction pipe 1 is 0.1-2m.Described peristaltic pump 3 is located at anolyte liquid storage tank 5 and negative electricity Between solving liquid storage tank 6, and placing height is substantially contour with electrolysis liquid surface, and preformed hole 2 is located at the upper surface of electrolyte storage tank.
In one embodiment, using semi-automatic extraction and can resorption peristaltic pump, electrolyte is taken out from storage device Take or resorption (such as electrolyte storage tank) into storage device.The working flow of peristaltic pump is 0.0016-500ml/ minutes, in suction pipe Footpath is 0.8-7.9mm, and tubing length can select 0.1-2m as needed, and the putting position that need not be fixed of peristaltic pump is, it is necessary to make Peristaltic pump is placed into suitable location (needing 22OV power supplys) by the used time.Peristaltic pump have start and stop, it is positive and negative, at full speed, speed governing, The functions such as state memorization (power-failure memory).Peristaltic pump is manually operable, while carries external communication interface, can connect battery management System (BMS) remote control.The form of double pump head can be selected in peristaltic pump, and electrolyte both positive and negative polarity only needs to share a peristaltic pump Progress samples simultaneously.In the energy-storage system design phase, in electrolyte positive/negative storage tank top preformed hole, hole upper end should install hand Dynamic valve (normal off status) is in order to seal, and concrete operation method is as follows during sampling:
(1) according to sampling needs, the hand-operated valve of positive/negative preformed hole upper end is opened;
(2) one end of the suction pipe of peristaltic pump is inserted and is placed in below liquid level of electrolyte from preformed hole, due to energy storage During system operation, both positive and negative polarity electrolyte liquid level can be offset, and can be inserted to the suction inlet of suction pipe at 1/3 under liquid level, ensure peristaltic pump Electrolyte can be extracted out at work;
(3) operating personnel place the sample bottle with inert gas seal in the other end of suction pipe;
(4) suction pipe is put at Peristaltic pump head;
(5) it is positive (extraction state) to set peristaltic pump, according to taking liquid measure to set suitable flow and the startup that is powered, then may be used Realize the extraction work of sample;
(6) entertain after taking fully enough samples, stop peristaltic pump, suction pipe is taken out from sample bottle, sample bottle is sealed;
(7) peristaltic pump is switched into reverse (resorption state) and started, by the electrolyte resorption remained in suction pipe to storage tank In;
(8) in suction pipe after noresidue electrolyte, stop peristaltic pump, peristaltic pump is powered off, and suction pipe is taken out from preformed hole;
(9) hand-operated valve at reserved opening is closed, sampling work is completed.
It is described above, the only preferable embodiment of the invention, but the protection domain of the invention is not This is confined to, any one skilled in the art is in the technical scope that the invention discloses, according to the present invention The technical scheme of creation and its inventive concept are subject to equivalent substitution or change, should all cover the invention protection domain it It is interior.

Claims (7)

1. the sampler of electrolyte in a kind of liquid energy-storage system, it is characterised in that including electrolyte storage tank, peristaltic pump (3) With sampling bottle (7), the surface of its body of electrolyte storage tank has preformed hole (2), and suction pipe (1) inserts electricity by preformed hole (2) Solve inside liquid storage tank, the suction inlet of suction pipe (1) be located under electrolysis liquid surface, and suction pipe (1) is communicated in peristaltic pump (3), peristaltic pump (3) and Sampling bottle (7) connects.
2. the sampler of electrolyte in liquid energy-storage system as claimed in claim 1, it is characterised in that described preformed hole (2) hand-operated valve (4) is installed on the suction pipe (1) between peristaltic pump (3).
3. the sampler of electrolyte in liquid energy-storage system as claimed in claim 1, it is characterised in that described electrolyte Storage tank includes anolyte liquid storage tank (5) and cathode electrolyte storage tank (6), and peristaltic pump (3) has double pump head, anode electrolyte storage Suction pipe (1) connection pump head all the way in tank (5), suction pipe (1) connection in cathode electrolyte storage tank (6) pump head all the way, each pump Head one sampling bottle of connection (7), and the inert gas for sealing is carried in sampling bottle (7).
4. the sampler of electrolyte in liquid energy-storage system as claimed in claim 1, it is characterised in that peristaltic pump (3) has There is external communication interface, and the electric power system of peristaltic pump (3) is connected to battery management system.
5. the sampler of electrolyte in liquid energy-storage system as claimed in claim 1, it is characterised in that the suction of suction pipe (1) Mouth is located at 1/3 or so under electrolysis liquid surface.
6. the sampler of electrolyte in liquid energy-storage system as claimed in claim 1, it is characterised in that the peristaltic pump (3) working flow is 0.0016-500ml/ minutes, and suction pipe (1) internal diameter is 0.8-7.9mm, and suction pipe (1) length is 0.1-2m.
7. the sampler of electrolyte in liquid energy-storage system as claimed in claim 3, it is characterised in that described peristaltic pump (3) between anolyte liquid storage tank (5) and cathode electrolyte storage tank (6), and placing height is substantially contour with electrolysis liquid surface, Preformed hole (2) is located at the upper surface of electrolyte storage tank.
CN201720704182.XU 2017-06-16 2017-06-16 The sampler of electrolyte in liquid energy-storage system Active CN206772649U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201720704182.XU CN206772649U (en) 2017-06-16 2017-06-16 The sampler of electrolyte in liquid energy-storage system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201720704182.XU CN206772649U (en) 2017-06-16 2017-06-16 The sampler of electrolyte in liquid energy-storage system

Publications (1)

Publication Number Publication Date
CN206772649U true CN206772649U (en) 2017-12-19

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

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CN (1) CN206772649U (en)

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