CN206715946U - Liquid fuel reforming reactor - Google Patents

Liquid fuel reforming reactor Download PDF

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Publication number
CN206715946U
CN206715946U CN201720253807.5U CN201720253807U CN206715946U CN 206715946 U CN206715946 U CN 206715946U CN 201720253807 U CN201720253807 U CN 201720253807U CN 206715946 U CN206715946 U CN 206715946U
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China
Prior art keywords
heat
transfer pipe
liquid fuel
reaction tube
reforming reactor
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CN201720253807.5U
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Chinese (zh)
Inventor
梁波
罗景祥
宋孟杰
毛宁
张思龙
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Shenzhen King Technology Co Ltd
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Shenzhen King Technology Co Ltd
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Abstract

The utility model discloses liquid fuel reforming reactor, including heating mantle, first the second heat-transfer pipe of heat-transfer pipe, accelerate reaction tube, heating mantle is sheathed on outside the first heat-transfer pipe and the first heat-transfer pipe is heated, first heat-transfer pipe is sheathed on the outside of the second heat-transfer pipe and heat is transmitted into the second heat-transfer pipe, reaction tube is accelerated to connect and be placed in the first heat-transfer pipe with the second heat-transfer pipe, its internal catalyst filling, second heat-transfer pipe is not provided with charging aperture with the one end for accelerating reaction tube to be connected, first heat-transfer pipe is provided with gas outlet, raw material is in the second heat-transfer pipe and accelerates the gas of reaction inner reaction tube generation to be overflowed into the first heat-transfer pipe and from gas outlet.Liquid fuel reforming reactor provided by the utility model, gasification reaction and the reformation endothermic reaction are merged into a chamber, improve the compactedness of reactor;Make full use of liquid fuel gravity and surface tension so that gas can only be gushed out to exit after gasification, will not flow back, and do not need current-carrying gas.

Description

Liquid fuel reforming reactor
Technical field
It the utility model is related to chemical industry hydrogen producing technology field, more particularly to liquid fuel reforming reactor.
Background technology
With regard to it is current prepare hydrogen source for, in the world, the preparation of hydrogen mostly come from fossil fuels, biomass and Water, technique are mainly electrolytic hydrogen production, are pyrolyzed the methods of hydrogen manufacturing, photochemical hydrogen manufacturing, biological hydrogen production and electrochemistry hydrogen manufacturing.From global hydrogen From the point of view of the situation of production, the conversion of general layout that hydrogen gas production will be presented a variety of hydrogen production process and deposit, wherein natural gas vapor and biology Matter gasification will occupy an leading position.In order to adapt to all kinds of catalytic reactions, and make catalytic reaction more efficient, the design of catalyst is more It is multifarious.
And the gasification reactor that various hydrocarbon fuels can fully gasify is directed to, each major company studies very detailed, and The accreditation in market is obtained.Such as LG Chemical Ltd., international Shell Co. Ltd and Beijing Shen Wu environmental energy scientific & technical corporation etc. Commercialized product is have devised, but is related to less for the gasification reactor of mini reforming reactor.It is and some of Mini reforming reactor use it is complicated, multiple reaction chambers need to be divided realize it is multiple reaction be eventually fabricated gas, having The time is expended when using in the laboratory between in limited time to grow.
Utility model content
Liquid fuel reforming reactor provided by the utility model, solves one in prior art problem or more It is individual.
Liquid fuel reforming reactor provided by the utility model, including heating mantle, first the second heat-transfer pipe of heat-transfer pipe, plus Fast reaction tube;
Heating mantle is sheathed on outside the first heat-transfer pipe and the first heat-transfer pipe is heated, and the first heat-transfer pipe is sheathed on the second biography Heat is simultaneously transmitted to the second heat-transfer pipe by the outside of heat pipe;
Reaction tube is accelerated to connect and be placed in the first heat-transfer pipe with the second heat-transfer pipe, its internal catalyst filling;
Second heat-transfer pipe is not provided with charging aperture with the one end for accelerating reaction tube to be connected, and the first heat-transfer pipe is provided with gas outlet, former Expect that in the second heat-transfer pipe and the gas for accelerating reaction inner reaction tube to generate the first heat-transfer pipe can be entered and overflowed from gas outlet.
Liquid fuel reforming reactor provided by the utility model, gasification reaction and the reformation endothermic reaction are merged into one Chamber, improve the compactedness of reactor;Make full use of liquid fuel gravity and surface tension so that gas can only be to after gasification Exit gushes out, and will not flow back, and do not need current-carrying gas.
In some embodiments, one end sealing closing that reaction tube is not connected with the second heat-transfer pipe is accelerated, its side wall is set There are some through holes.
Overflowed again from through hole in this way, the mixed gas after gasification can enter catalytic inner, the mixing after increase gasification Gas and catalyst fill contact area.
In some embodiments, catalyst is porous catalyst.
In this way, mixed gas can be made to be contacted into catalytic inner with catalyst, increase mixed gas and catalysis again The contact area of agent, improve reaction rate.
In some embodiments, in addition to muff, muff are wrapped in the outside of heating mantle.
So, it is possible to reduce the heat of heating mantle scatters and disappears.
In some embodiments, the second heat-transfer pipe and acceleration reaction tube use refractory ceramics gluing knot.
In this way, the air-tightness between the second heat-transfer pipe and acceleration reaction tube is good, the gas after gasification can be poured in fully Accelerate to contact with catalyst in reaction tube.
In some embodiments, it is connected between heating mantle and the first heat-transfer pipe by packing material.
In this way, heating mantle and the soft connection of the first heat-transfer pipe can be caused, both hard collisions are avoided, while are easy to pacify Dress.
Brief description of the drawings
Fig. 1 is a kind of sectional view of the liquid fuel reforming reactor of embodiment provided by the utility model;
Fig. 2 is a kind of schematic flow sheet of the liquid fuel reforming reactor of embodiment provided by the utility model.
Embodiment
The utility model is further described with reference to Figure of description.
As shown in Figure 1-2, liquid fuel reforming reactor, including heating mantle 1, the first heat-transfer pipe 2, the second heat-transfer pipe 3, plus Fast reaction tube 4.Wherein, heating mantle 1 is sheathed on the outside of the first heat-transfer pipe 2 and the first heat-transfer pipe 2 heated, the first heat-transfer pipe 2 It is sheathed on the outside of the second heat-transfer pipe 3 and heat is transmitted to the second heat-transfer pipe 3, accelerates reaction tube 4 to be connected simultaneously with the second heat-transfer pipe 3 And be placed in the first heat-transfer pipe 2, its internal catalyst filling, the second heat-transfer pipe 3 is not provided with the one end for accelerating reaction tube 4 to be connected Charging aperture 31, the first heat-transfer pipe 2 are provided with gas outlet 21, and raw material is in the second heat-transfer pipe 3 and accelerates the gas that reaction generates in reaction tube 4 Body can enter the first heat-transfer pipe 2 and be overflowed from gas outlet 21.
In the present embodiment, the first heat-transfer pipe 2 and the second heat-transfer pipe 3 can use alundum tube or metal tube, as long as reaching To that can conduct heat and high temperature resistant, do not limit herein.
It is vertical to place during using the reactor, reaction solution is slowly pushed to from charging aperture 31 to the by pushing meanss Two heat-transfer pipes 3, heating mantle 1 are heated at high temperature to the first heat-transfer pipe 2, and the first heat-transfer pipe 2 transfers heat to the second heat-transfer pipe 3.This When, rapid vaporizing volume expands the top liquid fuel that push enters in the second heat-transfer pipe 3 at high temperature, the gaseous mixture after gasification Body pours in upwards to be accelerated in reaction tube 4 and is fully reacted with the catalyst of inside, and the gas generated afterwards enters the first heat transfer Pipe 2 simultaneously overflows from gas outlet 21, is the gas prepared in the gas that gas outlet 21 is collected into.The reactor by gasification reaction and Reform the endothermic reaction merge into a chamber, improve the compactedness of reactor, at the same also make full use of liquid fuel gravity and Surface tension so that gas can only be gushed out to exit after gasification, will not flow back, and do not need current-carrying gas.
Specifically, one end sealing closing for accelerating reaction tube 4 not to be connected with the second heat-transfer pipe 3, in practice, both Refractory ceramics gluing knot can be used, accelerates the side wall of reaction tube 4 to be provided with some through holes.It can so ensure to accelerate reaction tube 4 And the second air-tightness between heat-transfer pipe 3 is good, avoid gas is not sufficiently reactive from just being overflowed from junction so that the gas of generation It is impure, meanwhile, accelerate reaction tube 4 that through hole is set, the surface area that catalyst contacts with mixed gas can be increased.
As preferable embodiment, catalyst can use porous catalyst.Urged in this way, can enter mixed gas Contacted inside agent with catalyst, increase mixed gas and the contact area of catalyst again, improve reaction rate.
Specifically, also including muff 5, muff 5 is wrapped in the outside of heating mantle 1, it is possible to reduce the heat of heating mantle 1 Scatter and disappear, improve the utilization rate of heat.Wherein, muff 5 internally can reach insulation purpose by filling asbestos, not do herein Limitation.
Specifically, it can be connected between the heat-transfer pipe 2 of heating mantle 1 and first by packing material.It can so avoid The hard contact of the heat-transfer pipe 2 of heating mantle 1 and first, is easily installed.
Referring to Fig. 2, the process for using of liquid fuel reforming reactor is described further below, liquid fuel is reformed anti- The raw material that device uses is answered as hydrocarbon fuel, such as alcohols, alkanes, sweet Water Oil Or Gas, said below with ethanol steam hydrogen manufacturing It is bright:
Ethanol and distilled water are mixed by certain volume ratio, pushed liquid fuel using pusher after stirring Into in push pipe 7, pusher can use micro pump, in micro push-in reactor at a slow speed, to avoid push-in from measuring ambassador Vaporizing volume expansion damage reactor.Liquid fuel passes through from silicone tube 6, enters from charging aperture 31 in the second heat-transfer pipe 3, upper strata Liquid fuel into high-temperature region gasify rapidly expansion rise, pour in accelerate the catalytic reaction of reaction tube 4 after enter the first heat-transfer pipe 2 Overflowed from outlet 21.
The above is only some embodiments of the present utility model.For the person of ordinary skill of the art, not On the premise of departing from the utility model creation design, various modifications and improvements can be made, these belong to the utility model Protection domain.

Claims (6)

1. liquid fuel reforming reactor, it is characterised in that including heating mantle (1), the heat-transfer pipe (3) of the first heat-transfer pipe (2) second, Accelerate reaction tube (4);
The heating mantle (1) is sheathed on the first heat-transfer pipe (2) outside and the first heat-transfer pipe (2) is heated, first heat transfer Pipe (2) is sheathed on the outside of the second heat-transfer pipe (3) and heat is transmitted into the second heat-transfer pipe (3);
The acceleration reaction tube (4) is connected with the second heat-transfer pipe (3) and is placed in the first heat-transfer pipe (2), and its internal filling is urged Agent;
Second heat-transfer pipe (3) is not provided with charging aperture (31), first heat-transfer pipe with the one end for accelerating reaction tube (4) to be connected (2) gas outlet (21) are provided with, raw material is in the second heat-transfer pipe (3) and accelerates the gas of reaction generation in reaction tube (4) to enter First heat-transfer pipe (2) simultaneously overflows from gas outlet (21).
2. liquid fuel reforming reactor according to claim 1, it is characterised in that it is described acceleration reaction tube (4) not with The connected one end sealing closing of second heat-transfer pipe (3), its side wall are provided with some through holes.
3. liquid fuel reforming reactor according to claim 2, it is characterised in that the catalyst is porous catalytic Agent.
4. liquid fuel reforming reactor according to claim 2, it is characterised in that also including muff (5), the guarantor Temperature set (5) is wrapped in the outside of heating mantle (1).
5. liquid fuel reforming reactor according to claim 1, it is characterised in that second heat-transfer pipe (3) and add Fast reaction tube (4) uses refractory ceramics gluing knot.
6. liquid fuel reforming reactor according to claim 1, it is characterised in that the heating mantle (1) and first passes Heat pipe is connected between (2) by packing material.
CN201720253807.5U 2017-03-15 2017-03-15 Liquid fuel reforming reactor Active CN206715946U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201720253807.5U CN206715946U (en) 2017-03-15 2017-03-15 Liquid fuel reforming reactor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201720253807.5U CN206715946U (en) 2017-03-15 2017-03-15 Liquid fuel reforming reactor

Publications (1)

Publication Number Publication Date
CN206715946U true CN206715946U (en) 2017-12-08

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201720253807.5U Active CN206715946U (en) 2017-03-15 2017-03-15 Liquid fuel reforming reactor

Country Status (1)

Country Link
CN (1) CN206715946U (en)

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