CN206692723U - A kind of rub resistance erosion resistance coating material - Google Patents

A kind of rub resistance erosion resistance coating material Download PDF

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Publication number
CN206692723U
CN206692723U CN201720260059.3U CN201720260059U CN206692723U CN 206692723 U CN206692723 U CN 206692723U CN 201720260059 U CN201720260059 U CN 201720260059U CN 206692723 U CN206692723 U CN 206692723U
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CN
China
Prior art keywords
layer
titanium
thickness
coating material
oxide layer
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Expired - Fee Related
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CN201720260059.3U
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Chinese (zh)
Inventor
黄现虎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Haideman New Material Co Ltd
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Jiangsu Haideman New Material Co Ltd
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Priority to CN201720260059.3U priority Critical patent/CN206692723U/en
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Expired - Fee Related legal-status Critical Current
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Abstract

The utility model discloses a kind of rub resistance erosion resistance coating material, the rub resistance erosion resistance coating material includes metal base substrate (0), and the metal base substrate (0) is followed successively by layer of titanium metal (1), silicon oxide layer (2), zirconium nitride titanium layer (3), the first chromium oxide layer (4), titanium dioxide layer (5), zirconium nitride titanium layer (6), the second chromium oxide layer (7), zirconium nitride titanium layer (8) and (9) from inside to outside.The utility model possesses higher hardness, outstanding fluid erosion prevention and crocking resistance, dense uniform, and color is soft.

Description

A kind of rub resistance erosion resistance coating material
Technical field
It the utility model is related to metal base manufacturing technology field, and in particular to a kind of rub resistance erosion resistance coating material.
Background technology
Since 18th century of Christian era, Treatment of Metal Surface become either research and develop or application it is upper, pole paid attention to and Widely used technology, its main contents are the technologies such as plating and anodic corrosion protection, and through researching and developing improvement all the year round, such treatment technology is Quite ripe, its finished product function tends to meet customer requirement and quality is good, but the limitation of seriously polluted and base material is it all the time Maximum bottleneck.
Titanium deoxid film has high polarization resistance, and polarization resistance more then represents more corrosion-resistant, contributes to metal base Corrosion inhibition, but titanium deoxid film has a high characteristic of refractive index, wherein rutile-type crystallization refractive index about 2.71, anatase titanium dioxide Refractive index about 2.55 is crystallized, therefore, titanium deoxid film has larger reflection and the ability for scattering light and influences metal base Outward appearance.
The method for preparing CoPt thin magnetic films the most frequently used at present is magnetron sputtering method.Argon ion is accelerated and bombarded by negative electrode Cathode target surface, target material surface atom sputtering is out deposited and forms film on the surface of the substrate.By changing unlike material The target sputtering time different with control, can be to obtain the film of unlike material and different-thickness.Magnetron sputtering method has plated film Layer and the advantages that adhesion of base material is strong, film plating layer is fine and close, uniform.With metal, alloy, low-valent metal compound or semiconductor material Material is used as target cathode, thin with gas particle reaction generation compound in sputter procedure or in substrate surface deposits film forming procedure Film, here it is reaction magnetocontrol sputtering.Reaction magnetocontrol sputtering is widely used in the production in enormous quantities of compound film.
The problem of fluid erosion prevention rub resistance of present metal base, is urgently to be resolved hurrily, and at present, lacking one kind has fluid erosion prevention antifriction Wipe the good rub resistance erosion resistance coating material of performance.
Utility model content
The purpose of this utility model is in view of the above-mentioned problems, providing a kind of rub resistance good with fluid erosion prevention crocking resistance Erosion resistance coating material.
To reach above-mentioned purpose, the utility model employs following technical proposal:A kind of rub resistance of the present utility model is resistance to Erosion coating material, the rub resistance erosion resistance coating material include metal base substrate, and the metal base substrate is by introversion It is followed successively by layer of titanium metal, silicon oxide layer, zirconium nitride titanium layer, the first chromium oxide layer, titanium dioxide layer, zirconium nitride titanium layer and second outside Chromium oxide layer.
Further, the thickness of the layer of titanium metal is 12~30nm, and the thickness of the silicon oxide layer is 6~15nm, institute The thickness for stating zirconium nitride titanium layer is 4~12nm, and the thickness of first chromium oxide layer is 6~10nm.
Further, the thickness of the titanium dioxide layer is 10~18nm, the thickness of the zirconium nitride titanium layer for 6~ 10nm, the thickness of second chromium oxide layer is 6~12nm.
Further, the material of the metal base substrate is aluminium.
Beneficial effect:The utility model possesses higher hardness, outstanding fluid erosion prevention and crocking resistance, dense uniform, Color is soft.
Compared with prior art, the utility model has the following advantages that:
(1) the utility model membrane system is formed using layer of titanium metal and metal nitride, and layer of titanium metal is used for transition and improved Membranous layer binding force, metal nitride possess higher hardness, rub resistance and decay resistance.
(2) the utility model improves film layer fluid erosion prevention, crocking resistance, without obvious boundary between each layer, using gradient Variation Features, tenor, film layer structure graded between each tunic layer element, and nitrogen content also changes in gradient.
(3) the utility model film layer outermost layer is chromium nitride zirconium aluminium titanium film, can improve overall film layer fluid erosion prevention performance, While crocking resistance, possesses low coefficient of friction, film layer coefficient of friction is less than 49, improves fluid erosion prevention of the present utility model Ability.
Brief description of the drawings
Fig. 1 is the schematic diagram of rub resistance erosion resistance coating material of the present utility model;
Wherein, 0 metal base substrate, 1 layer of titanium metal, 2 silicon oxide layers, 3 zirconium nitride titanium layers, 4 first chromium oxide layers, 5 two Titanium oxide layer, 6 zirconium nitride titanium layers, 7 second chromium oxide layers.
Embodiment
It is new to this practicality below with reference to accompanying drawing to make the purpose of this utility model, technical scheme and advantage clearer The embodiment of type is described in further detail.
Embodiment 1
A kind of rub resistance erosion resistance coating material of the present utility model, the rub resistance erosion resistance coating material include metal Base material substrate 0, the metal base substrate 0 are followed successively by layer of titanium metal 1, silicon oxide layer 2, zirconium nitride titanium layer 3, first from inside to outside Chromium oxide layer 4, titanium dioxide layer 5, the chromium oxide layer 7 of zirconium nitride titanium layer 6 and second.
The thickness of the layer of titanium metal 1 is 12nm, and the thickness of the silicon oxide layer 2 is 15nm, the zirconium nitride titanium layer 3 Thickness is 8nm, and the thickness of first chromium oxide layer 4 is 6nm.
The thickness of the titanium dioxide layer 5 is 10nm, and the thickness of the zirconium nitride titanium layer 6 is 8nm, second chromium oxide The thickness of layer 7 is 6nm.
The material of the metal base substrate 0 is aluminium.
Embodiment 2
The difference of embodiment 2 and embodiment 1 is:A kind of rub resistance erosion resistance coating material of the present utility model, it is described The thickness of layer of titanium metal 1 is 18nm, and the thickness of the silicon oxide layer 2 is 6nm, and the thickness of the zirconium nitride titanium layer 3 is 4nm, institute The thickness for stating the first chromium oxide layer 4 is 10nm.
The thickness of the titanium dioxide layer 5 is 15nm, and the thickness of the zirconium nitride titanium layer 6 is 6nm, second chromium oxide The thickness of layer 7 is 10nm.
Embodiment 3
The difference of embodiment 3 and embodiment 1 is:A kind of rub resistance erosion resistance coating material of the present utility model, it is described The thickness of layer of titanium metal 1 is 30nm, and the thickness of the silicon oxide layer 2 is 8nm, and the thickness of the zirconium nitride titanium layer 3 is 12nm, institute The thickness for stating the first chromium oxide layer 4 is 9nm.
The thickness of the titanium dioxide layer 5 is 18nm, and the thickness of the zirconium nitride titanium layer 6 is 10nm, second oxidation The thickness of layers of chrome 7 is 12nm.
Although metal base substrate 0, layer of titanium metal 1, silicon oxide layer 2, zirconium nitride titanium layer 3, have more been used herein The terms such as chromous oxide layer 4, titanium dioxide layer 5, zirconium nitride titanium layer 6, the second chromium oxide layer 7, zirconium nitride titanium layer 8,9, but not Exclude the possibility using other terms.It is of the present utility model just for the sake of more easily describing and explaining using these terms Essence;Any additional limitation is construed as all to disagree with the utility model spirit.
Specific embodiment described herein is only to the utility model spirit explanation for example.The utility model institute Category those skilled in the art can make various modifications or supplement to described specific embodiment or using similar Mode substitute, but without departing from spirit of the present utility model or surmount scope defined in appended claims.

Claims (4)

  1. A kind of 1. rub resistance erosion resistance coating material, it is characterised in that:The rub resistance erosion resistance coating material includes Metal Substrate Material substrate (0), the metal base substrate (0) are followed successively by layer of titanium metal (1), silicon oxide layer (2), zirconium nitride titanium layer from inside to outside (3), the first chromium oxide layer (4), titanium dioxide layer (5), zirconium nitride titanium layer (6) and the second chromium oxide layer (7).
  2. 2. rub resistance erosion resistance coating material according to claim 1, it is characterised in that:The thickness of the layer of titanium metal (1) To spend for 12~30nm, the thickness of the silicon oxide layer (2) is 6~15nm, and the thickness of the zirconium nitride titanium layer (3) is 4~12nm, The thickness of first chromium oxide layer (4) is 6~10nm.
  3. 3. rub resistance erosion resistance coating material according to claim 2, it is characterised in that:The titanium dioxide layer (5) Thickness is 10~18nm, and the thickness of the zirconium nitride titanium layer (6) is 6~10nm, and the thickness of second chromium oxide layer (7) is 6 ~12nm.
  4. 4. rub resistance erosion resistance coating material according to claim 3, it is characterised in that:The metal base substrate (0) Material be aluminium.
CN201720260059.3U 2017-03-16 2017-03-16 A kind of rub resistance erosion resistance coating material Expired - Fee Related CN206692723U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201720260059.3U CN206692723U (en) 2017-03-16 2017-03-16 A kind of rub resistance erosion resistance coating material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201720260059.3U CN206692723U (en) 2017-03-16 2017-03-16 A kind of rub resistance erosion resistance coating material

Publications (1)

Publication Number Publication Date
CN206692723U true CN206692723U (en) 2017-12-01

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106811728A (en) * 2017-03-16 2017-06-09 江苏海德曼新材料股份有限公司 A kind of rub resistance erosion resistance coating material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106811728A (en) * 2017-03-16 2017-06-09 江苏海德曼新材料股份有限公司 A kind of rub resistance erosion resistance coating material and preparation method thereof

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CF01 Termination of patent right due to non-payment of annual fee
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Granted publication date: 20171201

Termination date: 20210316