CN206692592U - One kind is packed for Antistatic type pre-coating film - Google Patents

One kind is packed for Antistatic type pre-coating film Download PDF

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Publication number
CN206692592U
CN206692592U CN201720285527.2U CN201720285527U CN206692592U CN 206692592 U CN206692592 U CN 206692592U CN 201720285527 U CN201720285527 U CN 201720285527U CN 206692592 U CN206692592 U CN 206692592U
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layer
film
base material
thickness
coating
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Inventor
赵斌
张涛
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Shandong Kangzheng New Materials Co., Ltd.
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BEIJING KANGDEXIN FUNCTION MATERIAL Co Ltd
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Abstract

The utility model discloses one kind to be packed for Antistatic type pre-coating film, includes successively from top to down:One anti-static function layer;One base material;One hot melt adhesive layer;One adhesion promoting layer or a digital layer.By being coated with anti-static function layer in base material side, the sheet resistance on top layer is less than 1010Ω, electrostatic field is not more than ± 3kv, and antistatic property is not influenceed by ambient temperature and humidity, and persistence is no less than 6 months.Meanwhile anti-static function layer at 120 DEG C without adhesion phenomenon, can tolerate the processes such as hydrothermal aging, extrusion Compound Machining, overlay film, no precipitation, stable performance.In addition, surface tension is not less than 42dyne, printing packaging process after gold stamping grade can be met.Existing product is contrasted, this pre-coating film has the advantages that simple in construction, multiple functional, effect is lasting.

Description

One kind is packed for Antistatic type pre-coating film
Technical field
A kind of printed apcksging material is the utility model is related to, more precisely, being a kind of Antistatic type pre-coating film.
Background technology
Coating technique not only can provide protective effect to printed matter, extend its service life, can also improve printed matter Appearance, be widely used in books and periodicals, food, tobacco and wine, medicine etc. packaging on.Coating technique is divided into i.e. film coating technique With pre-coating film coating technique, wherein compared to i.e. film coating technique, pre-coating film coating technique has environmentally friendly, safe, behaviour The features such as work is convenient, energy-efficient, excellent performance.The printed matters such as paper publication thing, packing material pass through pre-coating film overlay film after-vision Effect is good, bright in luster.
But pre-coating film is since volume production in 2013, the problem of film roll electrostatic is big, receives cutting worker and customer always Complaint.Although taking the measure in cutting link installation ion blower, it is quiet to effectively reduce the surface cut before rolling out factory Electricity, but be the failure to change the physical property of material in itself.Therefore remain to experience larger electrostatic after client's uncoiling, particularly cover as During some relatively thin paper such as 128gsm, 157gsm, the phenomenon of Electrostatic Absorption clearly, have a strong impact on follow-up two-sided overlay film, The normal production of cross cutting or paste box process.
Utility model content
The utility model is mainly to solve the technical problem present in prior art, so as to provide a kind of Antistatic type precoating Film.
Above-mentioned technical problem of the present utility model is mainly what is be addressed by following technical proposals:
The utility model discloses a kind of Antistatic type pre-coating film, include successively from top to down:
One anti-static function layer;
One base material;
One hot melt adhesive layer;
One adhesion promoting layer or a digital layer.
As the utility model preferred embodiment,
Described anti-static function layer is Antistatic type anti-scratch layer or soft tactile layer;
Described base material is biaxially oriented polyester film or BON biaxially oriented nylon film or bidirectional stretching polypropylene film;
Described hot melt adhesive layer is ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-acrylic acid One of which in copolymer, ethylene-methyl acrylate copolymer and low density polyethylene (LDPE).
As the utility model preferred embodiment, described anti-static function layer includes:
Antistatic additive, 0.1-5 mass parts
Functional coating, 100 mass parts
Wherein, described antistatic additive is at least one in cationic surface active agent, anionic interfacial agent Kind;Described functional coating is wherein one in solvent-borne type scratch-resistant coating, water-based scratch-resistant coating, water-based soft feel coating Kind.
As the utility model preferred embodiment, the thickness of the Antistatic type functional layer is 0.001~5 μm, described The thickness of base material be 10~30 μm, the thickness of described hot melt adhesive layer is 10~35 μm, the thickness of the adhesion promoting layer or digital layer Spend for 0.05~0.3 μm, the coating dry weight of described adhesion promoting layer is between 0.05~0.5g/ ㎡.
As the utility model preferred embodiment, the sheet resistance of described anti-static function layer is 105~109Ω, it is quiet Electric field is -3~+3kv, and surface tension is not less than 42dyne.
The invention also discloses a kind of production method of Antistatic type pre-coating film as the aforementioned, step is included:
Step a, substrate layer unreels:Base material is placed on unreeling machine and unreeled by air-expanding shaft, is spread out;
Step b, the sided corona treatment of base material:The base material of expansion is sent into corona processor, to the one of its functional layer to be coated Face carries out sided corona treatment, so that its surface tension >=38dyne;
Step c, it is coated with anti-static function layer:The base material being corona treated come out from corona processor, is applied into first The functional coating for the addition antistatic additive being placed in the first coating pan is coated on the corona of base material by cloth rewinder roll, the first applicator roll Handle on surface so that anti-static function layer is combined with base material, and the film with reference to after enters drying channel and carries out drying and processing;
Step d, composite hot melt glue-line:By the extruder extruding and hot melting glue-line of composite production line, in the compound work of production line Ozone generator is provided with position, ozone is produced and by the curtain coating of ozonizer injection to the PUR of extrusion by ozone generator Place, while the base material for being combined with anti-static function layer of drying is delivered to multi-procedure by the nip roller of production line, and with The PUR for being cast to multi-procedure position extrudes combination by nip roller, forms composite membrane, then by chill roll cooling treatment;
Step e, it is coated with adhesion promoting layer:The film sent from chill roll enters the second applicator roll, and the second applicator roll will be put Put the auxiliary element 0.1%~10% of polyaminoester emulsion and content of solid content in the second coating pan 5%~50% On the surface of the hot melt adhesive layer of mixture coated thin film, it is set to be combined with film, the film then in conjunction with after enters drying channel Carry out drying and processing;
Step f, finished product is wound:The pre-coating film machined is wound by winder.
As the utility model preferred embodiment, the thickness of the Antistatic type functional layer is 0.001~5 μm, described The thickness of base material be 10~30 μm, the thickness of described hot melt adhesive layer is 10~35 μm, the thickness of the adhesion promoting layer or digital layer Spend for 0.05~0.3 μm, the coating dry weight of described adhesion promoting layer is between 0.05~0.5g/ ㎡.
Antistatic type pre-coating film of the present utility model has advantages below:By being coated with anti-static function in base material side Layer, the sheet resistance on surface is 105~109Ω, electrostatic field are -3~+3kv, and surface tension is not less than 42dyne, and antistatic behaviour It can not be influenceed by ambient temperature and humidity, persistence is no less than 6 months, while is resistant to the works such as hydrothermal aging, extrusion Compound Machining, overlay film Sequence, no precipitation, stable performance.In addition, by being coated with adhesion promoting layer in hot melt adhesive layer side, can improve pre-coating film and printed matter it Between cementability, thus, the bonding force of pre-coating film is far longer than common pre-coating film, be suitably applied postprocessing working procedures requirement, Moistened surface tension force is low and printing of the more difficult overlay film under high speed.Contrast existing product, this pre-coating film have it is simple in construction, Multiple functional, the advantages that adhesive property is high.
Brief description of the drawings
, below will be to embodiment in order to illustrate more clearly of the utility model embodiment or technical scheme of the prior art Or the required accompanying drawing used is briefly described in description of the prior art, it should be apparent that, drawings in the following description are only It is some embodiments of the utility model, for those of ordinary skill in the art, is not paying the premise of creative work Under, other accompanying drawings can also be obtained according to these accompanying drawings.
Fig. 1 is the dimensional structure diagram of Antistatic type pre-coating film of the present utility model;
Wherein:01st, base material;02nd, anti-static function layer;03rd, hot melt adhesive layer;04th, adhesion promoting layer;05th, digital layer.
Embodiment
Preferred embodiment of the present utility model is described in detail below in conjunction with the accompanying drawings, so that the advantages of the utility model It can be easier to be readily appreciated by one skilled in the art with feature, it is apparent clear and definite so as to be made to the scope of protection of the utility model Define.
As shown in figure 1, the Antistatic type pre-coating film, from top to down successively comprising an anti-static function layer 02, a base material 01, One hot melt adhesive layer 03,04 or one digital layer 05 of an adhesion promoting layer.
The base material 01 is biaxially oriented polyester film or BON biaxially oriented nylon film or bidirectional stretching polypropylene film.This is anti- Electrostatic function layer 02 is Antistatic type anti-scratch layer or soft tactile layer.The anti-static function layer 02 includes:
Antistatic additive, 0.1-5 mass parts
Functional coating, 100 mass parts
Wherein, the antistatic additive is at least one of cationic surface active agent, anionic interfacial agent;Should Functional coating is one kind in solvent-borne type scratch-resistant coating, water-based scratch-resistant coating, water-based soft feel coating.
The hot melt adhesive layer 03 is that ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-acrylic acid are common At least one of polymers, ethylene-methyl acrylate copolymer and low density polyethylene (LDPE).
The adhesion promoting layer 04 be solid content 5%~50% polyaminoester emulsion and solids content 0.1%~10% it is auxiliary The mixture of co-ingredients, auxiliary element include levelling agent and adhesion promoters.
The thickness of the Antistatic type functional layer 02 is 0.001~5 μm, and the thickness of the base material 01 is 10~30 μm, the hot melt The thickness of glue-line 03 is 10~35 μm, and the thickness of the adhesion promoting layer 04 or digital layer 05 is 0.05~0.3 μm, the adhesion promoting layer 04 Dry weight is coated between 0.05~0.5g/ ㎡.
The sheet resistance of the anti-static function layer 02 is 105~109Ω, electrostatic field are -3~+3kv, and surface tension is not less than 42dyne。
By being coated with Antistatic type functional layer, in addition to the properties for maintaining former functional layer, surface in the side of base material 01 The sheet resistance of layer can be down to 1010Below and persistence is good, and is resistant to the processes such as hydrothermal aging, extrusion Compound Machining, overlay film, Without precipitation, stable performance.By being coated with adhesion promoting layer 04 or digital layer 05 in the side of hot melt adhesive layer 03, pre-coating film and print can be improved Cementability between brush product, the bonding force of this pre-coating film is far longer than common pre-coating film, be suitably applied postprocessing working procedures It is required that, moistened surface tension force is low and printing of the more difficult overlay film under high speed.
According to some preferred embodiments of the present utility model, the thickness of base material 01 is 12~20 μm, anti-static function layer 02 Thickness be 0.01~5 μm, the thickness of hot melt adhesive layer 03 is 12~25 μm, the thickness of adhesion promoting layer 04 or digital layer for 0.05~ 0.1μm
Further the utility model is illustrated below by a comparative example and two embodiments.
Comparative example
It is 1400mm matt Biaxially oriented polypropylene (BOPP) scratch resistance pre-coating film for comparative example using width, to according to this The pre-coating film of utility model embodiment is described in detail.
As shown in figure 1, Biaxially oriented polypropylene (BOPP) scratch resistance pre-coating film, by base material 01, scratch resistance functional layer 02, heat Melt layer 03 forms, and base material 01, scratch resistance functional layer 02 are identical with the width of hot melt adhesive layer 03.Wherein base material 01 is double using matt To stretched polypropene film (BOPP), width 1420mm, thickness is 15 μm;Scratch resistance functional layer 02 uses solvent-borne type scratch resistance Coating, its solid content being coated with are 30~35%, and the width of coating is 1420mm, and thickness is 3~5 μm;Hot melt adhesive layer 03 uses Ethene-vinyl acetate (EVA) copolymer, compound width are 1420mm, and thickness is 13 μm.Manufacture the thickness for the pre-coating film completed About 31~33 μm.
According to the utility model, the producer of matt Biaxially oriented polypropylene (BOPP) scratch resistance pre-coating film of comparative example one Method, comprise the following steps:
Step a, substrate layer unreel:Thickness is placed on unreeling machine for 15 μm of bidirectional stretching polypropylene films (BOPP) and led to Cross air-expanding shaft to unreel, spread out;
Step b, the sided corona treatment of base material:Matt bidirectional stretching polypropylene film (BOPP) base material of expansion is sent into corona Processor, sided corona treatment is carried out to the one side of its functional layer to be coated, so that its surface tension >=38dyne;
Step C, it is coated with scratch resistance functional layer:The Biaxially oriented polypropylene being corona treated come out from corona processor is thin Film (BOPP) base material, into the first applicator roll, the first applicator roll will be placed on the painting of the first coating pan internal solvent type scratch-resistant coating Cloth makes scratch resistance functional layer be combined with bidirectional stretching polypropylene film (BOPP) base material on the corona treated surface of base material, knot Film after conjunction enters drying channel and carries out drying and processing, and the thickness of the scratch resistance functional layer after drying is 3~5 μm;
Step d, composite hot melt glue-line:Extrude extruder extrusion ethene-vinyl acetate (EVA) copolymer of composite production line PUR, ozone generator is provided with the multi-procedure of production line, ozone is produced by ozone generator and passes through ozonizer It is blown at the curtain coating of the PUR of extrusion, while drying is combined with Antistatic type scratch resistance by the nip roller of production line Bidirectional stretching polypropylene film (BOPP) film of layer is delivered to multi-procedure, and with being cast to the PUR at multi-procedure position Extruded and combined by nip roller, form composite membrane, then (temperature is 20 DEG C) processing, the thickness of hot melt adhesive layer are cooled down by chill roll For 13 μm;
Step e, finished product winding:The pre-coating film machined is wound by winder, the coiled material after winding is pre- Film both sides of the edge are accumulative to cut away 20mm, and final products width is 1400mm, and thickness is 31~33 μm, thickness deviation≤2 μm.
Embodiment one
So that width is 1400mm matt Biaxially oriented polypropylene (BOPP) Antistatic type scratch resistance pre-coating film as an example, to root It is described in detail according to the pre-coating film of the utility model embodiment.
As shown in figure 1, matt Biaxially oriented polypropylene (BOPP) Antistatic type scratch resistance pre-coating film is by base material 01, antistatic Type functional layer 02, hot melt adhesive layer 03 form, and base material 01, Antistatic type functional layer 02, the width of hot melt adhesive layer 03 are identical.
Wherein base material 01 is 12 μm using matt bidirectional stretching polypropylene film (BOPP), width 1420mm, thickness;It is anti- Electrostatic functional layer 02 is matched as the mass parts of antistatic additive 1, scratch resistance using the solvent-borne type scratch-resistant coating of addition antistatic additive The mass parts of coating 100, wherein antistatic additive are quaternaries cation type antistatic additive, and scratch-resistant coating is:What it was coated with consolidates Content is 30~35%, and the width of coating is 1420mm, and thickness is 5 μm;Hot melt adhesive layer 03 is using ethene-vinyl acetate (EVA) Copolymer, compound width are 1420mm, and thickness is 10 μm.The thickness for manufacturing the pre-coating film completed is about 27 μm.
According to the utility model, matt Biaxially oriented polypropylene (BOPP) Antistatic type scratch resistance pre-coating film of embodiment one Production method, comprise the following steps:
Step a, substrate layer unreel:It is that 15 μm of matt bidirectional stretching polypropylene films (BOPP) are placed in unreeling machine by thickness On unreeled by air-expanding shaft, spread out;
Step b, the sided corona treatment of base material:Bidirectional stretching polypropylene film (BOPP) base material of expansion is sent into sided corona treatment Device, sided corona treatment is carried out to the one side of its functional layer to be coated, so that its surface tension >=
38dyne;
Step c, it is coated with antistatic scratch resistance functional layer:The biaxial tension being corona treated come out from corona processor gathers Polypropylene film (BOPP) base material, into the first applicator roll, the first applicator roll is antistatic by the addition being placed in the first coating pan The solvent-borne type scratch-resistant coating of agent is coated on the corona treated surface of base material, makes Antistatic type scratch resistance functional layer and two-way drawing Polypropylene stretched film (BOPP) base material combines, and the film with reference to after enters drying channel and carries out drying and processing, anti-quiet after drying The thickness of electric type functional layer is 3~5 μm;
Step d, composite hot melt glue-line:Extrude extruder extrusion ethene-vinyl acetate (EVA) copolymer of composite production line PUR, ozone generator is provided with the multi-procedure of production line, ozone is produced by ozone generator and passes through ozonizer It is blown at the curtain coating of the PUR of extrusion, while drying is combined with Antistatic type scratch resistance by the nip roller of production line Bidirectional stretching polypropylene film (BOPP) film of layer is delivered to multi-procedure, and with being cast to the PUR at multi-procedure position Extruded and combined by nip roller, form composite membrane, then (temperature is 20 DEG C) processing, the thickness of hot melt adhesive layer are cooled down by chill roll For 13 μm;
Step e, finished product winding:The pre-coating film machined is wound by winder, the coiled material after winding is pre- Film both sides of the edge are accumulative to cut away 20mm, and final products width is 1400mm, and thickness is 31~33 μm, thickness deviation≤2 μm.
Embodiment two
Exemplified by matt Biaxially oriented polypropylene (BOPP) Antistatic type by width for 1400mm viscosifies scratch resistance pre-coating film, Pre-coating film according to the utility model embodiment is described in detail.
As shown in figure 1, matt Biaxially oriented polypropylene (BOPP) Antistatic type viscosifies scratch resistance pre-coating film by base material 01, anti- Electrostatic functional layer 02, hot melt adhesive layer 03 and adhesion promoting layer 04 form, base material 01, Antistatic type functional layer 02, hot melt adhesive layer 03 It is identical with the width of adhesion promoting layer 04.
Wherein base material 01 is 15 μm using matt bidirectional stretching polypropylene film (BOPP), width 1420mm, thickness;It is anti- For electrostatic functional layer 02 using the solvent-borne type scratch-resistant coating of addition type antistatic additive, antistatic additive is quaternaries cation type Antistatic additive, the solid content of its coating fluid is 30~35%, and the width of coating is 1420mm, and thickness is 0.001 μm;Hot melt adhesive layer 03 uses ethene-vinyl acetate (EVA) copolymer, and compound width is 1420mm, and thickness is 13 μm.Adhesion promoting layer 04 uses to be contained admittedly Measure 5%~50% polyaminoester emulsion and solids content 0.1%~10% auxiliary element mixture, auxiliary element bag Include levelling agent, adhesion promoters, the thickness of adhesion promoting layer is 0.3 μm, the coating dry weight of adhesion promoting layer 04 0.05~0.5g/ ㎡ it Between.The thickness for manufacturing the pre-coating film completed is about 31~33 μm.
According to the utility model, matt Biaxially oriented polypropylene (BOPP) Antistatic type thickening scratch resistance of embodiment two is pre- The production method of film, comprises the following steps:
Step a, substrate layer unreel:It is that 15 μm of matt bidirectional stretching polypropylene films (BOPP) are placed in unreeling machine by thickness On unreeled by air-expanding shaft, spread out;
Step b, the sided corona treatment of base material:Matt bidirectional stretching polypropylene film (BOPP) base material of expansion is sent into corona Processor, sided corona treatment is carried out to the one side of its functional layer to be coated, so that its surface tension >=38dyne;
Step c, it is coated with antistatic scratch resistance functional layer:The biaxial tension being corona treated come out from corona processor gathers Polypropylene film (BOPP) base material, into the first applicator roll, the first applicator roll is antistatic by the addition being placed in the first coating pan The solvent-borne type scratch-resistant coating of agent is coated on the corona treated surface of base material, makes Antistatic type scratch resistance functional layer and two-way drawing Polypropylene stretched film (BOPP) base material combines, and the film with reference to after enters drying channel and carries out drying and processing, anti-quiet after drying The thickness of electric type functional layer is 3~5 μm;
Step d, composite hot melt glue-line:Extrude extruder extrusion ethene-vinyl acetate (EVA) copolymer of composite production line PUR, ozone generator is provided with the multi-procedure of production line, ozone is produced by ozone generator and passes through ozonizer It is blown at the curtain coating of the PUR of extrusion, while drying is combined with Antistatic type scratch resistance by the nip roller of production line Bidirectional stretching polypropylene film (BOPP) film of layer is delivered to multi-procedure, and with being cast to the PUR at multi-procedure position Extruded and combined by nip roller, form composite membrane, then (temperature is 20 DEG C) processing, the thickness of hot melt adhesive layer are cooled down by chill roll For 13 μm;
Step e, it is coated with adhesion promoting layer:The film sent from chill roll enters the second applicator roll, and the second applicator roll will be put Put the auxiliary element 0.1%~10% of polyaminoester emulsion and content of solid content in the second coating pan 5%~50% On the hot melt adhesive layer surface of mixture coated thin film, it is set to be combined with film, the film then in conjunction with after enters into drying channel Row drying and processing, the thickness of the adhesion promoting layer after drying is 0.3 μm, and the coating dry weight of adhesion promoting layer increases between 0.05~0.5g/ ㎡ Auxiliary element in adhesion coating includes levelling agent, adhesion promoters;
Step f, finished product is wound:The pre-coating film machined is wound by winder, the coiled material after winding is pre- Film both sides of the edge are accumulative to cut away 20mm, and final products width is 1400mm, and thickness is 31~33 μm, thickness deviation≤2 μm.
Following table is the performance test data of above-mentioned comparative example and embodiment.
Table one
Comparative example Embodiment one Embodiment two
Sheet resistance (Ω) >1013 108~9 109
Surface tension (dyne) 36 54 54
Peel off force value (N/15mm) 6.2 6.3 7.1 film breakage
Sheet resistance (Ω) after aging >1013 109 109
Surface tension (dyne) after aging 36 50 50
Force value (N/15mm) is peeled off after aging 4.9 4.8 4.5 film breakage
According to the pre-coating film of the utility model embodiment, by being coated with anti-static function layer, the table on top layer in base material side Surface resistance is less than 1010Ω, electrostatic field is not more than ± 3kv, and antistatic property is not influenceed by ambient temperature and humidity, and persistence is no less than 6 months.Meanwhile anti-static function layer at 120 DEG C without adhesion phenomenon, can tolerate hydrothermal aging, extrusion Compound Machining, overlay film etc. Process, no precipitation, stable performance.In addition, surface tension is not less than 42dyne, printing packaging process after gold stamping grade can be met.It is right Than existing product, this pre-coating film has the advantages that simple in construction, multiple functional, effect is lasting.
This is not limited to, any change or replacement expected without creative work, should all be covered in the utility model Protection domain within.Therefore, the scope of protection of the utility model should be determined by the scope of protection defined in the claims.

Claims (2)

1. a kind of Antistatic type pre-coating film, is included successively from top to down:
One anti-static function layer (02);
One base material (01);
One hot melt adhesive layer (03);
One adhesion promoting layer (04) or a digital layer (05), the thickness of the Antistatic type functional layer (02) is 0.001~5 μm, described The thickness of base material (01) be 10~30 μm, the thickness of described hot melt adhesive layer (03) is 10~35 μm, the adhesion promoting layer (04) Or the thickness of digital layer (05) is 0.05~0.3 μm, the coating dry weight of described adhesion promoting layer (04) or digital layer (05) is 0.05 Between~0.5g/ ㎡.
2. Antistatic type pre-coating film according to claim 1, it is characterised in that
Described anti-static function layer (02) is Antistatic type anti-scratch layer or soft tactile layer;
Described base material (01) is biaxially oriented polyester film or BON biaxially oriented nylon film or bidirectional stretching polypropylene film;
Described hot melt adhesive layer (03) is ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-acrylic acid One of which in copolymer, ethylene-methyl acrylate copolymer and low density polyethylene (LDPE).
CN201720285527.2U 2017-03-22 2017-03-22 One kind is packed for Antistatic type pre-coating film Active CN206692592U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108774473A (en) * 2018-06-19 2018-11-09 河北乐成新材料科技有限公司 A kind of Antistatic type pre-coating film and preparation method thereof
CN109306234A (en) * 2018-09-05 2019-02-05 纳琳威纳米科技南通有限公司 A kind of antistatic coated film of long-acting type and preparation method thereof
CN109651971A (en) * 2019-01-31 2019-04-19 开平市齐裕胶粘制品科技有限公司 A kind of wear-resisting matt sense of touch tacky film and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108774473A (en) * 2018-06-19 2018-11-09 河北乐成新材料科技有限公司 A kind of Antistatic type pre-coating film and preparation method thereof
CN109306234A (en) * 2018-09-05 2019-02-05 纳琳威纳米科技南通有限公司 A kind of antistatic coated film of long-acting type and preparation method thereof
CN109651971A (en) * 2019-01-31 2019-04-19 开平市齐裕胶粘制品科技有限公司 A kind of wear-resisting matt sense of touch tacky film and preparation method thereof
CN109651971B (en) * 2019-01-31 2023-04-18 开平市齐裕胶粘制品科技有限公司 Wear-resistant matte touch adhesive film and preparation method thereof

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