CN206680245U - A kind of advanced treatment system of percolate evaporation process tail water - Google Patents

A kind of advanced treatment system of percolate evaporation process tail water Download PDF

Info

Publication number
CN206680245U
CN206680245U CN201720450165.8U CN201720450165U CN206680245U CN 206680245 U CN206680245 U CN 206680245U CN 201720450165 U CN201720450165 U CN 201720450165U CN 206680245 U CN206680245 U CN 206680245U
Authority
CN
China
Prior art keywords
water
water outlet
dioxide solution
evaporation process
outlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201720450165.8U
Other languages
Chinese (zh)
Inventor
张欣
孙承林
王志强
史秋
邹继成
尹宪彪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dalian Guangtaiyuan Environmental Protection Science & Technology Co Ltd
Original Assignee
Dalian Guangtaiyuan Environmental Protection Science & Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dalian Guangtaiyuan Environmental Protection Science & Technology Co Ltd filed Critical Dalian Guangtaiyuan Environmental Protection Science & Technology Co Ltd
Priority to CN201720450165.8U priority Critical patent/CN206680245U/en
Application granted granted Critical
Publication of CN206680245U publication Critical patent/CN206680245U/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The utility model provides a kind of advanced treatment system of percolate evaporation process tail water, and the advanced treatment system of percolate evaporation process tail water includes acid-base accommodation unit, catalytic reaction unit, decomposing hydrogen dioxide solution unit and water unit.The deep treatment method of percolate evaporation process tail water comprises the following steps:High temperature percolate tail water after evaporation process is squeezed into catalytic tower through delivery pump;After catalytic wet hydrogen peroxide oxidation reacts, by catalytic tower upper end overflow to decomposing hydrogen dioxide solution tank;After remnants decomposing hydrogen dioxide solution, by decomposing hydrogen dioxide solution tank upper end overflow to water outlet temporary storage tank;Water outlet in water outlet temporary storage tank squeezes into heat-exchangers of the plate type, heat-exchangers of the plate type Chinese effluent or reuse through booster pump.The utility model deep treatment method can optimize the effluent quality of percolate evaporation process tail water, ensure that water outlet reaches《Consumer waste filling and embedding pollutant catabolic gene standard》Emission request in GB16889 2008.

Description

A kind of advanced treatment system of percolate evaporation process tail water
Technical field
It the utility model is related to wastewater processing technology, more particularly to a kind of depth of percolate evaporation process tail water Reason system.
Background technology
With the fast development of China's industry, urbanization process is constantly accelerated, and municipal refuse total amount is presented rapid growth and become Gesture, annual rate of rise are up to 10%.Sanitation Landfill Technology for Refuse is due to the skill such as its technique is simple, cost is low, management is convenient Art advantage, the at present most commonly used refuse disposal mode of domestic application.Rubbish is during stacking and landfill due to being compacted, fermenting Deng biochemical degradation, while under the seepage effect of rainwater and underground water, a kind of high concentrated organic wastewater is formd, is claimed For percolate.Because percolate complicated component, water quality and quantity fluctuation are big, the reasonable disposal of percolate is always The problem of field of Environment Protection.With《Household refuse landfill sites pollutant catabolic gene standard》(GB16889-2008) promulgation, China pair The processing of percolate proposes more strict requirements.However, from the Practical Project state of the art, traditional garbage filter Liquid treatment technology is most it cannot be guaranteed that the qualified discharge of percolate.Therefore, percolate Tailwater Depth treatment technology is developed, it is right Conventional garbage percolate treating process is upgraded or transformed, and is the necessary behave for ensureing percolate qualified discharge.
MVR evaporation techniques (mechanical vapor recompression technology) are by feat of energy consumption is low, floor space is small, capacity of resisting impact load By force, the applied widely, advantage such as effluent quality is high, is that another new rubbish oozes after biochemistry+embrane method and DTRO embrane methods Filtrate treatment technology.Evaporation is a kind of physical process that volatile composition is separated with nonvolatile element.MVR evaporation process During percolate, water boils from percolate liquid, and heavy metal and the volatility of inorganic matter and most of organic matter compare water It is weak, therefore can be retained in concentrate, only the pollutant such as part volatile hydrocarbon, VFA and ammonia can enter steam, It is ultimately present in condensate liquid.At present, MVR evaporations and gas washing group technology can effectively remove VFA in steam and Ammonia, but the pollutant such as part volatile hydrocarbon is still present in condensate liquid, causes water outlet CODcrDischarge standard can not be met.
At present, the further treatment technique of percolate evaporation process tail water mainly includes:Ion-exchange, UF membrane Method, absorption method and Fenton oxidation method.
Ion-exchange, technique rely on ion exchange resin by the pollutant exchange adsorption in percolate tail water, general Standard water discharge is discharged.However, ion exchange resin is limited in one's ability, treating capacity is low, and the cost of resin reduction is higher, and reduction process In easily cause secondary pollution.
Membrane separation process, the technology mainly carry out Selective Separation, its mechanism through film using selectivity to the composition in water The mainly sieving actoion of film.There are NF membrane, microfiltration membranes, milipore filter and reverse osmosis membrane etc. using more at present.Membrane separation process Technique is simple, floor space is small, high treating effect.However, being found in the application practice of membrane technology, membrane pollution problem causes film Component is frequently changed, and operating cost is very high.In addition, UF membrane can produce substantial amounts of concentrate, concentrate complicated component, if processing It is improper, it will even more serious pollution is brought to environment.
Pollutant is mainly adsorbed to the surface of solids by absorption method, this method using porous type solid matter, and it is useless to reach removal The purpose of water pollutant.Conventional adsorbent includes activated carbon, zeolite, flyash, diatomite etc..Although absorption method is in rubbish Certain effect is obtained in percolate treatment processing, but adsorbent adsorption capacity is limited, and regeneration difficulty is big, and replacement cost is high.In addition, Enriching pollutants are finally simply transferred on adsorbent by absorption method, its thoroughly degraded removal can not easily be formed into secondary dirt Dye.
Fenton oxidation method, mainly with ferrous ion (Fe2+) catalyst is used as, utilize Fe2+And H2O2Chain reaction catalysis Hydroxyl radical free radical of the generation with strong oxidizing property, less toxic or nontoxic small point of small molecule is oxidized to by the organic pollution in waste water Sub- material.This method is applied widely, oxidability is strong and will not cause secondary pollution.It is real with increasing for its engineer applied Many problems are exposed in the running of border.1. sludge quantity is big, processing cost is high;②Fe2+And H2O2The difficult control of ratio is added, is gone out Water easily returns color, remaining H2O2Increase water outlet CODcr;③H2O2It is high to remove complex process, cost;4. treatment effect is unstable.
Utility model content
The purpose of this utility model is, for operating cost existing for prior art is high, treatment effect is unstable, Yi Zao Into technical problems such as secondary pollutions, a kind of advanced treatment system of percolate evaporation process tail water is proposed, the system can expire The increasingly strict discharge standard of sufficient effluent quality.
To achieve the above object, the technical solution adopted in the utility model is:A kind of percolate evaporation process tail water Advanced treatment system, including acid-base accommodation unit, catalytic reaction unit, decomposing hydrogen dioxide solution unit and water unit;
The acid-base accommodation unit includes delivery pump, concentrated sulfuric acid measuring pump, hydrogen peroxide measuring pump, sour blender and inlet flow-patterm It is worth detector, the delivery pump, concentrated sulfuric acid measuring pump and hydrogen peroxide measuring pump are connected by pipeline with sour blender respectively, described Water inlet pH value detector is arranged on sour mixer outlet pipeline, the water inlet pH value detector and concentrated sulfuric acid measuring pump Electricity Federation;
The catalytic reaction unit includes catalytic tower, and the catalytic tower bottom inlet connects with sour mixer outlet It is logical;
The decomposing hydrogen dioxide solution unit includes decomposing hydrogen dioxide solution tank, the decomposing hydrogen dioxide solution pot bottom entrance and catalytic reaction Top of tower outlet;
The water unit includes water outlet temporary storage tank, booster pump, sodium hydroxide measuring pump, alkali blender, the inspection of water outlet pH value Survey instrument and heat-exchangers of the plate type, the water outlet temporary storage tank upper entrance and decomposing hydrogen dioxide solution tank top outlet, the water outlet Temporary storage tank outlet at bottom is connected by booster pump with alkali mixer entrance, and the alkali mixer outlet connects with heat-exchangers of the plate type Logical, the sodium hydroxide measuring pump is connected with alkali mixer entrance, and water outlet pH is provided with the pipeline of the alkali mixer outlet It is worth detector, the water outlet pH value detector and sodium hydroxide measuring pump Electricity Federation.
Using the method for Tthe utility model system advanced treatment of landfill leachate evaporation process tail water, comprise the following steps:
(water inlet specifically described herein is height of the percolate after evaporation process unless otherwise specified for step (1) water inlet Temperature water inlet) mixed with the concentrated sulfuric acid and hydrogen peroxide;
The water inlet that step (1) obtains is squeezed into catalytic tower by step (2), is reacted through catalytic wet hydrogen peroxide oxidation;
The water inlet that step (3) step (2) obtains is through catalytic tower upper end overflow to decomposing hydrogen dioxide solution tank, by the double of remnants Oxygen water decomposition;
The water inlet that step (4) step (3) obtains is through decomposing hydrogen dioxide solution tank upper end overflow to water outlet temporary storage tank;The water outlet is temporary The water outlet deposited in tank squeezes into heat-exchangers of the plate type, the heat-exchangers of the plate type Chinese effluent or reuse through booster pump.
Further, step (1) comprises the following steps:High-temperature inlet water of the percolate after evaporation process is through delivery pump Sour blender is delivered to, the 98%wt concentrated sulfuric acids and hydrogen peroxide that the sour blender will intake and concentrated sulfuric acid measuring pump adds measure The 30%wtH that pump adds2O2Quick mixing, the water inlet pH value is adjusted to 5.5~6.5, water inlet pH value detector feeds back telecommunications The rotating speed of concentrated sulfuric acid measuring pump number is automatically controlled, automatically adjusts the dosage of the 98%wt concentrated sulfuric acids.
Further, step (2) comprises the following steps:Water inlet after being handled by step (1) is entered by catalytic reaction tower bottom Enter, intake uphill process in pass through the first catalyst, the organic pollution in water inlet with state H2O2It is diffused into first catalyst The activated centre of inner surface is adsorbed, H2O2HO is produced under the catalytic action of the first catalyst activity component, HO triggers certainly Oxidative degradation organic matter is reacted by base, catabolite is desorbed from the first catalyst inner surface, is diffused into catalytic tower.
Further, step (3) comprises the following steps:The catalytic wet hydrogen peroxide oxidation of the water inlet through step (2) After reaction, by catalytic tower upper end overflow to decomposing hydrogen dioxide solution tank;The water inlet rises from the decomposing hydrogen dioxide solution pot bottom During, under the catalytic action of the second catalyst, remaining H in water inlet2O2It is decomposed into H2O and O2, avoid H2O2To water outlet CODcrHave an impact.
Further, step (4) comprises the following steps:The water outlet is from decomposing hydrogen dioxide solution tank top overflow to water outlet Temporary storage tank, the water outlet is delivered to alkali blender through booster pump, the alkali blender throws water outlet and sodium hydroxide measuring pump The 20%wt sodium hydroxide solutions added and water outlet quickly mix, and water outlet pH value are adjusted to 6.0~9.0, water outlet pH value detector Feedback electric signal automatically controls the rotating speed of sodium hydroxide measuring pump, automatically adjusts adding for the 20%wt sodium hydroxide solutions Amount;Water outlet enters heat-exchangers of the plate type after the alkali blender, and water outlet carries out heat exchange with low temperature percolate stoste, will Leaving water temperature is reduced to discharge or reuse after normal temperature.
Further, in the step (1), the high-temperature water outlet of percolate evaporation process is directly entered percolate In the advanced treatment system of evaporation process tail water, inflow temperature is 95~100 DEG C.
Further, in the step (2), the ratio of height to diameter of the catalytic tower is 14:1, water inlet air speed be 0.3~ 0.5h-1, 30%wtH2O2Dosage is 2.0~4.0g/L.
Further, in the step (2), first catalyst is heterogeneous catalysis, with Fe3+As activearm Point, the Fe3+Iron ore form is present in first catalyst.
Further, air speed of being intake in the step (3), in the decomposing hydrogen dioxide solution tank is 1.5~2.0h-1, reaction temperature Spend for 95~100 DEG C.
Further, in the step (3), second catalyst is heterogeneous catalysis, and activearm is used as using manganese sand Point.
The advanced treatment system of the utility model percolate evaporation process tail water compared with prior art have with Lower advantage:
1. catalytic wet hydrogen peroxide oxidation technology is applied to the depth of percolate evaporation process tail water first Reason field.
2. the percolate evaporation tail water of high temperature is directly entered advanced treatment system, without cooling device, and meanwhile it is higher Reaction temperature be advantageous to improve catalysis oxidation reaction rate.
3. replacing traditional homogeneous catalyst using heterogeneous catalysis in catalytic wet hydrogen peroxide oxidation reaction, have The features such as catalytic activity is high, stability is good, service life is long low with turnover rate.Heterogeneous catalysis is with ferric iron (Fe3+) replace Fe2+As active component, H is eliminated2O2Oxidation of Fe2+The step of, reduce H2O2Dosage.Wherein Fe3+Mainly in the form of alpha-feooh It is present in catalyst, compared to homogeneous Fe2+Or Fe3+Compare, have reaction pH wider and the higher advantage of Fe clearances.
4. utilizing the heterogeneous catalysis using manganese sand as active component, H is catalyzed2O2H is decomposed under the high temperature conditions2O and O2.H remaining after catalytic wet hydrogen peroxide oxidation reacts is decomposed using this method2O2, not only reaction efficiency is high, reaction condition Warm and operating cost is low, can effectively avoid H2O2Influence to effluent quality.
To sum up, the utility model is using described catalytic wet hydrogen peroxide oxidation technology as percolate evaporation process Tail water handling process, complex technical process existing for traditional advanced treatment process, operating cost height, treatment effect can be overcome The problems such as unstable, further optimize the effluent quality of percolate evaporation process tail water, ensure that water outlet reaches《House refuse Fill pollutant catabolic gene standard》Emission request in GB16889-2008.
Brief description of the drawings
Fig. 1 is the structural representation of the advanced treatment system of the utility model percolate evaporation process tail water.
1. delivery pump in figure;2. concentrated sulfuric acid measuring pump;3. hydrogen peroxide measuring pump;4. sour blender;5. pH value of intaking detection Instrument;6. the first catalyst;7. catalytic tower;8. the second catalyst;9. decomposing hydrogen dioxide solution tank;10. water outlet temporary storage tank;11. increase Press pump;12. sodium hydroxide measuring pump;13. alkali blender;14. water outlet pH value detector;15. heat-exchangers of the plate type.
Embodiment
The utility model is further illustrated with reference to embodiments:
Embodiment 1
The present embodiment discloses a kind of advanced treatment system of percolate evaporation process tail water, its structure as shown in figure 1, Including acid-base accommodation unit, catalytic reaction unit, decomposing hydrogen dioxide solution unit and water unit;
The acid-base accommodation unit includes delivery pump 1, concentrated sulfuric acid measuring pump 2, hydrogen peroxide measuring pump 3, sour blender 4 and entered Water pH value detector 5, the delivery pump 1, concentrated sulfuric acid measuring pump 2 and hydrogen peroxide measuring pump 3 pass through pipeline and sour blender 4 respectively Connection, the water inlet pH value detector 5 are arranged on the sour export pipeline of blender 4, the water inlet pH value detector 5 and the concentrated sulfuric acid The Electricity Federation of measuring pump 2;
The catalytic reaction unit includes catalytic tower 7, and the catalytic tower bottom inlet exports with sour blender 4 Connection;
The decomposing hydrogen dioxide solution unit includes decomposing hydrogen dioxide solution tank 9, and the bottom inlet of decomposing hydrogen dioxide solution tank 9 is anti-with catalysis Answer top of tower outlet;
The water unit includes water outlet temporary storage tank 10, booster pump 11, sodium hydroxide measuring pump 12, alkali blender 13, gone out Water pH value detector 14 and heat-exchangers of the plate type 15, the upper entrance of water outlet temporary storage tank 10 go out with the top of decomposing hydrogen dioxide solution tank 9 Mouth connection, the outlet at bottom of water outlet temporary storage tank 10 are connected by booster pump 11 with the entrance of alkali blender 13, the alkali blender 13 outlets connect with heat-exchangers of the plate type 15, and the sodium hydroxide measuring pump 12 connects with the entrance of alkali blender 13, and the alkali mixes Water outlet pH value detector 14, the water outlet pH value detector 14 and sodium hydroxide measuring pump are provided with the pipeline that clutch 13 exports 12 Electricity Federations.
Method using the present embodiment device advanced treatment of landfill leachate evaporation process tail water comprises the following steps:(1) Acid-base accommodation unit:High-temperature inlet water of the percolate after evaporation process is delivered to sour blender 4, the acid through delivery pump 1 Blender 4 will intake and the 98%wt concentrated sulfuric acids that concentrated sulfuric acid measuring pump 2 adds and the 30%wtH that hydrogen peroxide measuring pump 3 adds2O2 Quick mixing, the water inlet pH value is adjusted to 6, water inlet pH value detector 5 feeds back electric signal and automatically controls the concentrated sulfuric acid meter The rotating speed of pump 2 is measured, automatically adjusts the dosage of the 98%wt concentrated sulfuric acids.The high-temperature water outlet of percolate evaporation process is direct Into in advanced treatment system, inflow temperature is 95 DEG C.
(2) catalytic reaction unit:By step (1) handle after water inlet by the bottom of catalytic tower 7 enter, it is described enter it is waterborne Pass through the first catalyst 6, organic pollution and the H in the water inlet during rising2O2It is diffused into first catalyst 6 The activated centre of inner surface is adsorbed, the H2O2HO is produced under the catalytic action of the active component of the first catalyst 6, HO triggers radical reaction oxidative degradation organic matter, and catabolite is desorbed from the inner surface of the first catalyst 6, is diffused into institute State in catalytic tower 7.The ratio of height to diameter of catalytic tower 7 is 14:1, water inlet air speed is 0.5h-1, 30%wtH2O2Dosage is 3.0g/L.First catalyst 6 is heterogeneous catalysis, with Fe3+As active component, the Fe3+Iron ore form is present in described In first catalyst 6.
(3) decomposing hydrogen dioxide solution unit:The water inlet is after the catalytic wet hydrogen peroxide oxidation reaction of step (2), by institute The upper end overflow of catalytic tower 7 is stated to decomposing hydrogen dioxide solution tank 9.It is described to intake from the bottom uphill process of decomposing hydrogen dioxide solution tank 9 In, under the catalytic action of the second catalyst 8, remaining H in the water inlet2O2It is decomposed into H2O and O2, avoid H2O2To water outlet CODcrHave an impact.Air speed of being intake in decomposing hydrogen dioxide solution tank 9 is 2.0h-1, reaction temperature is 95 DEG C.Second catalyst 8 is non-equal Phase catalyst, active component is used as using manganese sand.
(4) water unit:The water outlet is from the top overflow of decomposing hydrogen dioxide solution tank 9 to water outlet temporary storage tank 10, through supercharging The water outlet is delivered to alkali blender 13 by pump 11, and the alkali blender 13 adds the water outlet and sodium hydroxide measuring pump 12 20%wt sodium hydroxide solutions and the water outlet quickly mix, the water outlet pH value is adjusted to 8.0, water outlet pH value detector 14 feedback electric signals automatically control the rotating speed of the sodium hydroxide measuring pump 12, automatically adjust the 20%wt sodium hydroxide solutions Dosage.The water outlet enters heat-exchangers of the plate type 15, the water outlet and low temperature garbage filter after the alkali blender 13 Liquid stoste carries out heat exchange, and the leaving water temperature is reduced into discharge or reuse after normal temperature.
The advanced treatment system of the present embodiment has that treatment effeciency is high, floor space is small, operating cost is low, simple to operate etc. Feature, can effectively solve the underproof problem of percolate evaporation process tail water water quality, ensure that water outlet reaches《House refuse is filled out Bury pollutant catabolic gene standard》Emission request in GB16889-2008.
Embodiment 2
The advanced treatment system for the percolate evaporation process tail water that the present embodiment uses is same as Example 1, this reality A method for advanced treatment of landfill leachate evaporation process tail water is applied to comprise the following steps:(1) acid-base accommodation unit:Garbage filter High-temperature inlet water of the liquid after evaporation process is delivered to sour blender 4 through delivery pump 1, and the sour blender 4 will intake and the concentrated sulfuric acid The 30%wtH that the 98%wt concentrated sulfuric acids and hydrogen peroxide measuring pump 3 that measuring pump 2 adds add2O2Quick mixing, by the inlet flow-patterm To 5.5, water inlet pH value detector 5 feeds back the rotating speed that electric signal automatically controls the concentrated sulfuric acid measuring pump 2, automatically adjusts for value regulation The dosage of the 98%wt concentrated sulfuric acids.The high-temperature water outlet of percolate evaporation process is directly entered in advanced treatment system, Inflow temperature is 100 DEG C.
(2) catalytic reaction unit:By step (1) handle after water inlet by the bottom of catalytic tower 7 enter, it is described enter it is waterborne Pass through the first catalyst 6, organic pollution and the H in the water inlet during rising2O2It is diffused into first catalyst 6 The activated centre of inner surface is adsorbed, the H2O2HO is produced under the catalytic action of the active component of the first catalyst 6, HO triggers radical reaction oxidative degradation organic matter, and catabolite is desorbed from the inner surface of the first catalyst 6, is diffused into institute State in catalytic tower 7.The ratio of height to diameter of catalytic tower 7 is 14:1, water inlet air speed is 0.5h-1, 30%wtH2O2Dosage is 4.0g/L.First catalyst 6 is heterogeneous catalysis, with Fe3+As active component, the Fe3+Iron ore form is present in described In first catalyst 6.
(3) decomposing hydrogen dioxide solution unit:The water inlet is after the catalytic wet hydrogen peroxide oxidation reaction of step (2), by institute The upper end overflow of catalytic tower 7 is stated to decomposing hydrogen dioxide solution tank 9.It is described to intake from the bottom uphill process of decomposing hydrogen dioxide solution tank 9 In, under the catalytic action of the second catalyst 8, remaining H in the water inlet2O2It is decomposed into H2O and O2, avoid H2O2To water outlet CODcrHave an impact.Air speed of being intake in decomposing hydrogen dioxide solution tank 9 is 2.0h-1, reaction temperature is 100 DEG C.Second catalyst 8 is non- Homogeneous catalyst, active component is used as using manganese sand.
(4) water unit:The water outlet is from the top overflow of decomposing hydrogen dioxide solution tank 9 to water outlet temporary storage tank 10, through supercharging The water outlet is delivered to alkali blender 13 by pump 11, and the alkali blender 13 adds the water outlet and sodium hydroxide measuring pump 12 20%wt sodium hydroxide solutions and the water outlet quickly mix, the water outlet pH value is adjusted to 9.0, water outlet pH value detector 14 feedback electric signals automatically control the rotating speed of the sodium hydroxide measuring pump 12, automatically adjust the 20%wt sodium hydroxide solutions Dosage.The water outlet enters heat-exchangers of the plate type 15, the water outlet and low temperature garbage filter after the alkali blender 13 Liquid stoste carries out heat exchange, and the leaving water temperature is reduced into discharge or reuse after normal temperature.
Finally it should be noted that:Various embodiments above is only to illustrate the technical solution of the utility model, rather than it is limited System;Although the utility model is described in detail with reference to foregoing embodiments, one of ordinary skill in the art should Understand:It can still modify to the technical scheme described in foregoing embodiments, either to which part or whole Technical characteristic carries out equivalent substitution;And these modifications or replacement, the essence of appropriate technical solution is departed from this practicality newly The scope of each embodiment technical scheme of type.

Claims (2)

1. a kind of advanced treatment system of percolate evaporation process tail water, it is characterised in that including acid-base accommodation unit, urge Change reaction member, decomposing hydrogen dioxide solution unit and water unit;
The acid-base accommodation unit includes delivery pump, concentrated sulfuric acid measuring pump, hydrogen peroxide measuring pump, sour blender and water inlet pH value inspection Instrument is surveyed, the delivery pump, concentrated sulfuric acid measuring pump and hydrogen peroxide measuring pump are connected by pipeline with sour blender respectively, the water inlet PH value detector is arranged on sour mixer outlet pipeline, the water inlet pH value detector and concentrated sulfuric acid measuring pump Electricity Federation;
The catalytic reaction unit includes catalytic tower, and the catalytic tower bottom inlet connects with sour mixer outlet;
The decomposing hydrogen dioxide solution unit includes decomposing hydrogen dioxide solution tank, the decomposing hydrogen dioxide solution pot bottom entrance and catalytic reaction tower top Portion's outlet;
The water unit includes water outlet temporary storage tank, booster pump, sodium hydroxide measuring pump, alkali blender, water outlet pH value detector And heat-exchangers of the plate type, the water outlet temporary storage tank upper entrance and decomposing hydrogen dioxide solution tank top outlet, the water outlet are kept in Pot bottom outlet is connected by booster pump with alkali mixer entrance, and the alkali mixer outlet connects with heat-exchangers of the plate type, institute State sodium hydroxide measuring pump to connect with alkali mixer entrance, the detection of water outlet pH value is provided with the pipeline of the alkali mixer outlet Instrument, the water outlet pH value detector and sodium hydroxide measuring pump Electricity Federation.
2. the advanced treatment system of percolate evaporation process tail water according to claim 1, it is characterised in that described to urge The ratio of height to diameter for changing reaction tower is 14:1.
CN201720450165.8U 2017-04-25 2017-04-25 A kind of advanced treatment system of percolate evaporation process tail water Expired - Fee Related CN206680245U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201720450165.8U CN206680245U (en) 2017-04-25 2017-04-25 A kind of advanced treatment system of percolate evaporation process tail water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201720450165.8U CN206680245U (en) 2017-04-25 2017-04-25 A kind of advanced treatment system of percolate evaporation process tail water

Publications (1)

Publication Number Publication Date
CN206680245U true CN206680245U (en) 2017-11-28

Family

ID=60406775

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201720450165.8U Expired - Fee Related CN206680245U (en) 2017-04-25 2017-04-25 A kind of advanced treatment system of percolate evaporation process tail water

Country Status (1)

Country Link
CN (1) CN206680245U (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107032475A (en) * 2017-04-25 2017-08-11 大连广泰源环保科技有限公司 The deep treatment method and system of a kind of percolate evaporation process tail water
TWI663129B (en) * 2018-05-30 2019-06-21 可寧衛股份有限公司 Processing method for wastewater containing volatile organic compounds and wastewater processing system using the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107032475A (en) * 2017-04-25 2017-08-11 大连广泰源环保科技有限公司 The deep treatment method and system of a kind of percolate evaporation process tail water
TWI663129B (en) * 2018-05-30 2019-06-21 可寧衛股份有限公司 Processing method for wastewater containing volatile organic compounds and wastewater processing system using the same

Similar Documents

Publication Publication Date Title
CN104512956B (en) A kind of oil refining sewerage catalytic ozonation deep treatment method and device
CN109928511B (en) Physicochemical-biological coupling nitrogen and phosphorus removal method and reactor based on iron-carbon micro-electrolysis
CN102086075A (en) Deep treatment process of landfill leachate
CN106348456B (en) Creek water pollution superior microorganism original position ecological restoring method
CN105541020A (en) CDI (Capacitive Deionization) based compound type constructed wetland desalination system
CN206680245U (en) A kind of advanced treatment system of percolate evaporation process tail water
CN102674645A (en) Sludge conditioning device and method for conditioning sludge
CN109231656A (en) A kind of catalytic wet oxidation-biochemistry-membrane treatment process of landfill leachate
CN109867413A (en) A kind of chemical industrial park integrated industrial waste water treatment process
CN105417765B (en) A kind of municipal sewage organic carbon enriching and recovering utilizes device and its application method
CN107032521A (en) Advanced treatment system and method after a kind of percolate evaporation gas washing
CN103435181B (en) A kind of efficient process of chemical wastewater biochemical water outlet and reuse method
CN106348441A (en) Carbon-nitrogen separation type bottom incoming water artificial rapid infiltration system and sewage treatment method thereof
CN213141524U (en) Synergistic mixed ozone catalytic oxidation sewage treatment system
CN107032475A (en) The deep treatment method and system of a kind of percolate evaporation process tail water
CN101514062B (en) Method of processing high concentration organic wastewater
CN105692867B (en) A kind of O3 contacted oxidation device for landfill leachate depth efficient process
CN100486921C (en) Method for treating waste water in production of 4,6-dinitro o-sec-butyl phenol
CN203625104U (en) Device for deeply treating oil refining sewage through catalytic ozonation
CN210457807U (en) High-efficient ozone catalytic oxidation advanced treatment unit of printing and dyeing wastewater
CN104326617A (en) Energy-saving deep treatment system and method for non-biodegradable organic wastewater
CN203683328U (en) System for recycling car washing wastewater
CN203033860U (en) Micro-aerobic expansion particle sludge bed- steel slag biological aerated filter sewage treatment system
CN206188490U (en) Handle high concentration organic waste water's device
CN204779236U (en) Coking wastewater's high -efficient low -cost processing system

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20171128

Termination date: 20200425

CF01 Termination of patent right due to non-payment of annual fee