CN206624670U - Ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device - Google Patents
Ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device Download PDFInfo
- Publication number
- CN206624670U CN206624670U CN201720328662.0U CN201720328662U CN206624670U CN 206624670 U CN206624670 U CN 206624670U CN 201720328662 U CN201720328662 U CN 201720328662U CN 206624670 U CN206624670 U CN 206624670U
- Authority
- CN
- China
- Prior art keywords
- wastewater treatment
- carrier
- waste water
- treatment case
- catalytic oxidation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Catalysts (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
It the utility model is related to a kind of ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device, belong to organic wastewater decoloration device field, including wastewater treatment case, wastewater treatment case two sides set water inlet, delivery port respectively, wastewater treatment case upper wall sets perpendicular carrier of photocatalyst plate respectively with bottom wall, and carrier of photocatalyst plate is interspersed to form water stream channel.The utility model is decolourized using the oxidation of ultrasonic wave metal salting liquid cooperative photocatalysis to industrial organic waste water, good decolorizing effect, at the same the utility model using hollow glass plate as carrier of photocatalyst, scribble TiO outside carrier of photocatalyst2Photochemical catalyst thin layer, carrier of photocatalyst inside are provided with LED uviol lamps as light source, and light is evenly distributed, and penetration power is strong, and energy resource consumption is low, while the utility model is compact-sized, saves space, waste water and photochemical catalyst contact area are big, enhance decolorizing effect.
Description
Technical field
A kind of ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device is the utility model is related to, belongs to organic wastewater and decolourizes to fill
Put field.
Background technology
Colourity is deep before industrial organic waste water is arranged outside, it is more difficult to decolourize, traditional biological decolouring method treatment effect is not satisfactory,
Chemical precipitation and Bubble-floating Method are also very limited to this kind of waste water decoloring effect, and photocatalytic oxidation is at present increasingly by people's weight
Depending on a kind of high-level oxidation technology.So-called light-catalyzed reaction, refer to a kind of chemical reaction carried out under the catalytic action of light, profit
With photocatalysts such as titanium dioxide, in the presence of ultraviolet light, organic matter is progressively oxidized to low molecule intermediate product most
Throughout one's life into CO2、H2O etc. reaches the purpose of decolouring, and CN200920106910.2 discloses a kind of continuous type Treatment by Photocatalysis Oxidation and given up
The device of water, including casing, there is a water inlet pipe and an outlet pipe；Quartzy pillar, the box house is laid in, the quartzy pillar
Uviol lamp dividing plate is inside equiped with, located at the box house, at least one runner is formed in the casing；Catalyst carrier, it is fixed
On the cabinet wall and the dividing plate, catalyst is consolidated with the catalyst carrier, can efficiently utilize photochemical catalyst and luminous energy
Handle waste water.But its shortcoming is：Color degree of dyeing waste water is high, and ultraviolet light penetration power is low, influences the utilization of luminous energy；Light source is lamp
Pillar designs, not only space-consuming, and light irradiation is uneven, influences catalytic oxidation effect.
Ultrasonic technology is increasingly becoming one of numerous environmentalists' focus of attention in recent years.At organic wastewater decolouring
During reason, the cavitation of ultrasonic wave has very strong degradation capability to organic matter, and degradation speed is quickly, ultrasonic air bubble
Collapse caused by high-energy be enough break chemical bonds, cavitation bubble collapse produces hydroxy (OH) and hydrogen-based (H), same to organic matter
Generation oxidation reaction, harmful organic substance in water body can be transformed into CO2、H2O, inorganic ions or than the former easy drop of organic matter small toxicity
The organic matter of solution, so as to reach the purpose of decolouring.
In addition, research shows, Mn2+、Cu2+Plasma energy greatly reduces the luminous intensity required for original photochemical catalytic oxidation,
Preferably solve the problems such as fluorescent tube needed for original photochemical catalytic oxidation is more, and efficiency is low, and electrisity consumption is big, therefore use and contain Mn2+、
Cu2+The research that plasma carries out concerted catalysis oxidation turns into recent research emphasis.Meanwhile for carrier of photocatalyst, because
Glass is cheap and easy to get, has good translucency, is easy to be designed to variously-shaped, also result in the attention of researcher.
Utility model content
The utility model purpose is to provide a kind of ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device, utilizes ultrasound
Ripple-metal salt solution cooperative photocatalysis oxidation is decolourized to industrial organic waste water, good decolorizing effect, while the utility model is adopted
With hollow glass plate as carrier of photocatalyst, TiO is scribbled outside carrier of photocatalyst2Photochemical catalyst thin layer, photochemical catalyst carry
Internal portion is provided with LED uviol lamps as light source, and light is evenly distributed, and penetration power is strong, and energy resource consumption is low, while the utility model knot
Structure is compact, saves space, waste water and photochemical catalyst contact area are big, enhance decolorizing effect.
Ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device described in the utility model, including wastewater treatment case, waste water
Treatment box two sides set water inlet, delivery port respectively, and wastewater treatment case upper wall sets perpendicular photochemical catalyst respectively with bottom wall
Carrier board, carrier of photocatalyst plate are interspersed to form water stream channel, and carrier of photocatalyst plate is hollow glass harden structure, and light is urged
Agent carrier board scribbles TiO on outer surface2Photochemical catalyst thin layer, carrier of photocatalyst plate inwall are stained with some LED uviol lamps
Band, several LED uviol lamps are evenly distributed with LED ultraviolet lamp belts；Material storage container is set outside wastewater treatment case, on wastewater treatment case
Some shower nozzles parallel with carrier of photocatalyst plate are set between the adjacent carrier of photocatalyst plate of wall, shower nozzle passes through wastewater treatment case
Upper wall is connected by pipeline with the outlet pipe of material storage container bottom, and booster pump is set on the pipeline that shower nozzle is connected with wastewater treatment case；It is useless
Water treatment case lower box sets some supersonic generators, the ultrasonic wave efferent duct of supersonic generator and wastewater treatment bottom wall
It is connected.
Flowmeter is also set on the pipeline that shower nozzle is connected with wastewater treatment case, is easy to the liquid inventory to being pumped into wastewater treatment case
Monitored in real time.
Agitating device is set in material storage container, solution in material storage container can be stirred, be prevented from precipitating or flocculate.
Inlet valve is also set on the pipeline that shower nozzle is connected with wastewater treatment case.
The distance between each adjacent carrier of photocatalyst plate is 1-3cm, and carrier of photocatalyst harden structure is compact, increases useless
The contact area of water and photochemical catalyst, extend flowing time of the waste water in wastewater treatment case.
The industrial organic waste water for process pretreatment that water inlet flows into.
Reflective aluminium foil is posted on wastewater treatment chamber interior wall, it can be light to shine after the light on wastewater treatment chamber interior wall reflects
Catalyst provides light source, improves the utilization rate of ultraviolet light.
The solution of metalline is stored in material storage container, further, it is preferable to the solution of manganese containing salt or mantoquita.
The utility model compared with prior art, has the advantages that.
The utility model is decolourized using ultrasonic wave-metal salt solution cooperative photocatalysis oxidation to industrial organic waste water,
Good decolorizing effect, at the same the utility model using hollow glass plate as carrier of photocatalyst, scribbled outside carrier of photocatalyst
TiO2Photochemical catalyst thin layer, LED uviol lamps being provided with inside carrier of photocatalyst as light source, the light penetration power that is evenly distributed is strong,
Energy resource consumption is low, while the utility model is compact-sized, saves space, waste water and photochemical catalyst contact area are big, enhance de-
Color effect.
Brief description of the drawings
Fig. 1, the example structure schematic diagram of the utility model one；
Carrier of photocatalyst plate sectional view in Fig. 2, Fig. 1.
In figure：1st, water inlet 2, wastewater treatment case 3, material storage container 4, agitating device 5, booster pump 6, flowmeter 7, shower nozzle 8, go out
The mouth of a river 9, carrier of photocatalyst plate 10, LED ultraviolet lamp belts 11, inlet valve 12, ultrasonic wave efferent duct 13, supersonic generator.
Embodiment
The utility model is described further with reference to embodiment and Figure of description.
As shown in Figure 1-2, ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device described in the utility model, including waste water
Treatment box 2, the two sides of wastewater treatment case 2 set water inlet 1, delivery port 8 respectively, the upper wall of wastewater treatment case 2 and bottom wall set respectively with
Its vertical carrier of photocatalyst plate 9, carrier of photocatalyst plate 9 are interspersed to form water stream channel, and carrier of photocatalyst plate 9 is
Hollow glass harden structure, carrier of photocatalyst plate 9 scribble TiO on outer surface2Photochemical catalyst thin layer, in carrier of photocatalyst plate 9
Wall is stained with some LED ultraviolet lamp belts 10, and several LED uviol lamps are evenly distributed with LED ultraviolet lamp belts 10；Wastewater treatment case
Material storage container 3 is set outside 2, the solution containing mantoquita, the adjacent carrier of photocatalyst of the upper wall of wastewater treatment case 2 are stored in material storage container 3
Set some shower nozzles 7 parallel with carrier of photocatalyst plate 9 between plate 9, shower nozzle 7 through the upper wall of wastewater treatment case 2 by pipeline with
The outlet pipe of the bottom of material storage container 3 is connected, and booster pump 5 is set on the pipeline that shower nozzle 7 is connected with wastewater treatment case 2；The case of wastewater treatment case 2
Body bottom sets some supersonic generators 13, the phase of ultrasonic wave efferent duct 12 of supersonic generator 13 and the bottom wall of wastewater treatment case 2
Even.
Flowmeter 6 is also set on the pipeline that shower nozzle 7 is connected with wastewater treatment case 2.
Agitating device 4 is set in material storage container 3.
Inlet valve 11 is also set on the pipeline that shower nozzle 7 is connected with wastewater treatment case 2.
The distance between each adjacent carrier of photocatalyst plate 9 is 2cm.
The industrial organic waste water for process pretreatment that water inlet 1 flows into.
Reflective aluminium foil is posted on the inwall of wastewater treatment case 2.
The solution of manganese containing salt is stored in material storage container 3.
When the present embodiment is implemented, the power of regulation supersonic generator 13 is 1-1.5Kw, supersonic frequency 30-50KHz,
Simultaneously in order to improve decolorizing effect, hydrogen peroxide can be added into material storage container 3, utilize UV/Mn2+Concerted catalysis hydrogen peroxide oxidation aids in
Decolourize, improve decolorizing effect.
The utility model is decolourized using ultrasonic wave-metal salt solution cooperative photocatalysis oxidation to industrial organic waste water,
Good decolorizing effect, at the same the utility model using hollow glass plate as carrier of photocatalyst, scribbled outside carrier of photocatalyst
TiO2Photochemical catalyst thin layer, LED uviol lamps being provided with inside carrier of photocatalyst as light source, the light penetration power that is evenly distributed is strong,
Energy resource consumption is low, while the utility model is compact-sized, saves space, waste water and photochemical catalyst contact area are big, enhance de-
Color effect.
Claims (8)
1. a kind of ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device, including wastewater treatment case (2), wastewater treatment case (2) two
Side sets water inlet (1), delivery port (8) respectively, it is characterised in that：Wastewater treatment case (2) upper wall is set respectively with bottom wall to hang down with it
Straight carrier of photocatalyst plate (9), carrier of photocatalyst plate (9) are interspersed to form water stream channel, carrier of photocatalyst plate (9)
For hollow glass harden structure, TiO is scribbled on carrier of photocatalyst plate (9) outer surface2Photochemical catalyst thin layer, carrier of photocatalyst plate
(9) inwall is stained with some LED ultraviolet lamp belts (10), and several LED uviol lamps are evenly distributed with LED ultraviolet lamp belts (10)；
Material storage container (3) is set outside wastewater treatment case (2), set between the adjacent carrier of photocatalyst plate (9) of wastewater treatment case (2) upper wall with
The parallel some shower nozzles (7) of carrier of photocatalyst plate (9), shower nozzle (7) pass through pipeline and storing through wastewater treatment case (2) upper wall
The outlet pipe of pond (3) bottom is connected, and booster pump (5) is set on the pipeline that shower nozzle (7) is connected with wastewater treatment case (2)；Wastewater treatment
Case (2) lower box sets some supersonic generators (13), the ultrasound of supersonic generator (13) and wastewater treatment case (2) bottom wall
Ripple efferent duct (12) is connected.
2. ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device according to claim 1, it is characterised in that：Shower nozzle (7)
Flowmeter (6) is also set on the pipeline being connected with wastewater treatment case (2).
3. ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device according to claim 1, it is characterised in that：Material storage container
(3) agitating device (4) is set in.
4. ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device according to claim 1, it is characterised in that：Shower nozzle (7)
Inlet valve (11) is also set on the pipeline being connected with wastewater treatment case (2).
5. ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device according to claim 1, it is characterised in that：Each adjacent light
The distance between catalyst carrier plate (9) is 1-3cm.
6. ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device according to claim 1, it is characterised in that：Water inlet
(1) industrial organic waste water for process pretreatment flowed into.
7. ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device according to claim 1, it is characterised in that：Wastewater treatment
Reflective aluminium foil is posted on case (2) inwall.
8. ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device according to claim 1, it is characterised in that：Material storage container
(3) solution of metalline is stored in.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201720328662.0U CN206624670U (en) | 2017-03-30 | 2017-03-30 | Ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201720328662.0U CN206624670U (en) | 2017-03-30 | 2017-03-30 | Ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN206624670U true CN206624670U (en) | 2017-11-10 |
Family
ID=60206426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201720328662.0U Expired - Fee Related CN206624670U (en) | 2017-03-30 | 2017-03-30 | Ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN206624670U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109264907A (en) * | 2018-10-29 | 2019-01-25 | 南京高正农用化工有限公司 | A kind of photocatalysis treatment device of pesticide organic wastewater |
| CN111807498A (en) * | 2020-07-31 | 2020-10-23 | 山东大学 | Integrated antibiotic wastewater degradation device combining hydrodynamic cavitation and photocatalysis |
-
2017
- 2017-03-30 CN CN201720328662.0U patent/CN206624670U/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109264907A (en) * | 2018-10-29 | 2019-01-25 | 南京高正农用化工有限公司 | A kind of photocatalysis treatment device of pesticide organic wastewater |
| CN109264907B (en) * | 2018-10-29 | 2024-03-19 | 南京高正农用化工有限公司 | Photocatalysis treatment device for pesticide organic wastewater |
| CN111807498A (en) * | 2020-07-31 | 2020-10-23 | 山东大学 | Integrated antibiotic wastewater degradation device combining hydrodynamic cavitation and photocatalysis |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN206624672U (en) | Cooperative photocatalysis oxidized waste water decoloration device | |
| CN102241422B (en) | Circulating closed ammonia nitrogen stripping system | |
| CN205740607U (en) | The photocatalysis coupled device of ultrasound wave for treatment of Organic Wastewater | |
| CN102730906B (en) | Combined apparatus for advanced treatment of high concentration organic waste water | |
| CN204874211U (en) | A synthesize processing apparatus for high salt industrial waste water that contains | |
| CN105130046B (en) | Plasma and ultrasound and the tandem type water treatment facilities of catalytic association | |
| CN206624670U (en) | Ultrasonic synergistic photochemical catalytic oxidation waste water decoloring device | |
| CN105060395A (en) | Water treatment device combining multiple physical methods | |
| CN108217832A (en) | A kind of refractory wastewater equipment | |
| CN205382045U (en) | Degradation system of aquatic antibiotic | |
| CN104445507B (en) | A kind of ns high voltage pulse discharge plasma works in coordination with titanium dioxide degradable dyeing waste water device and method | |
| CN203855437U (en) | Submerged photo-catalytic reactor | |
| CN108689456A (en) | Double catalyst purifying apparatus and double catalyst food purification equipments | |
| CN202482101U (en) | Light-catalyzed reaction device for water treatment | |
| CN209338302U (en) | A kind of photocatalytic water treatment device | |
| CN210874762U (en) | UV micro-nano waste gas treatment device | |
| CN208617458U (en) | A kind of photocatalysis oxidation treatment waste water device | |
| CN102329033A (en) | Independent-aeration high-voltage pulse discharging water treatment reactor and sewage treatment method thereof | |
| CN101137583A (en) | Method for treating liquids | |
| CN208200447U (en) | A kind of refractory wastewater equipment | |
| CN104993164B (en) | Photocatalytic reduction of carbon oxide and photocatalytic fuel cell coupling electricity production system | |
| CN207507263U (en) | A kind of VOCs treatment catalytic unit | |
| CN110550804A (en) | industrial wastewater circulating treatment and purification device for ozone oxidation and use method | |
| CN105311899A (en) | Photo oxidation and catalysis deodorization waste gas treatment device | |
| CN206156799U (en) | Light catalytic oxidation waste water reaction system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20171110 Termination date: 20190330 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |