CN204874211U - A synthesize processing apparatus for high salt industrial waste water that contains - Google Patents

A synthesize processing apparatus for high salt industrial waste water that contains Download PDF

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Publication number
CN204874211U
CN204874211U CN201520642070.7U CN201520642070U CN204874211U CN 204874211 U CN204874211 U CN 204874211U CN 201520642070 U CN201520642070 U CN 201520642070U CN 204874211 U CN204874211 U CN 204874211U
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pond
baf
catalyzed oxidation
clean water
oxidation pond
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贺明和
凌二锁
吴盼盼
吕佩嵘
徐知雄
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ZHONGHAI ASPHALT (TAIZHOU) CO Ltd
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ZHONGHAI ASPHALT (TAIZHOU) CO Ltd
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Abstract

The utility model discloses a synthesize processing apparatus for high salt industrial waste water that contains, treatment process includes catalytic oxidation pool, oxidation stability pond, the biochemical BAF pond in back, clean water basin, dilutes and synthesize jar, preliminary treatment one -level BAF pond, preliminary treatment second grade BAF pond and outlet water pool based on a special processing apparatus, this special use processing apparatus, catalytic oxidation pool, oxidation stability pond, the biochemical BAF pond in back and clean water basin loop through back end transmission pipeline and connect, outlet water pool and catalytic oxidation pool are connected to inside the catalytic oxidation pool through the inlet channel, catalytic oxidation pool fills with the fixed bed form has ozone catalytic particle, it is provided with charge door and agitator to dilute comprehensive jar, ozone catalytic particle comprises activated aluminium oxide granule, cupric oxide, titanium dioxide, polyethylene glycol, polyvinyl alcohol. The utility model discloses with the oxidation of macromolecule difficult degradation organic matter for the easy biochemical organic matter of micro molecule, and then the biochemistry nature of using water improves.

Description

For the Integrated Processing Unit of high saliferous trade effluent
Technical field
The utility model relates to a kind of Integrated Processing Unit for high saliferous trade effluent, belongs to technical field of waste water processing.
Background technology
At present, the treatment process for phenolic wastewater mainly contains extraction process, absorption method, chemical oxidization method, biochemical treatment process etc.Extraction process energy consumption is high, extraction agent easily occurs and residues in follow-up waste water, affect follow-up treating processes; Absorption method is simple to operate, be suitable for containing the lower waste water of phenol amount, but equipment one-time investment is comparatively large, and adsorbent reactivation difficulty; Though chemical method can be oxidized except phenol, direct oxidation working cost is higher.
Summary of the invention
The utility model object is to provide a kind of Integrated Processing Unit for high saliferous trade effluent, this Integrated Processing Unit working cost being used for high saliferous trade effluent is low, simple to operate, stable, and obtain the object of efficient degradation organic pollutant, the petroleum chemical industry height saline sewage advanced treatment under low cost and qualified discharge can be realized.
For achieving the above object, the technical solution adopted in the utility model is: a kind of Integrated Processing Unit for high saliferous trade effluent, comprise catalyzed oxidation pond, oxidation-stabilized pond, rear biochemical BAF pond, clean water basin, dilute comprehensive tank, pretreated primary BAF pond, pre-treatment secondary BAF pond and outlet sump, the comprehensive tank of described dilution, pretreated primary BAF pond, pre-treatment secondary BAF pond is connected by leading portion transfer conduit successively with outlet sump, described catalyzed oxidation pond, oxidation-stabilized pond, rear biochemical BAF pond is connected by back segment transfer conduit successively with clean water basin, it is inner that described outlet sump and catalyzed oxidation pond are connected to catalyzed oxidation pond by inlet channel,
It is inner that one ozonizer is connected to catalyzed oxidation pond by gas pipeline, described clean water basin are provided with prosopyle, posticum, the prosopyle of described clean water basin is connected by back segment transfer conduit with rear biochemical BAF pond, described clean water basin are connected to a backwashing pump one end, it is inner that this backwashing pump the other end is connected to catalyzed oxidation pond, rear biochemical BAF pond by back segment reflux line, described catalyzed oxidation pond is filled with ozone catalytic particle with fixed bed form, and the comprehensive tank of described dilution is provided with charging opening and agitator.
The technical scheme improved further in technique scheme is as follows:
As preferably, a dividing plate is provided with vertically in described catalyzed oxidation pond, thus catalyzed oxidation pond is divided into left and right chamber, described catalyzed oxidation pond lower horizontal is provided with a sieve plate, the lower end of this dividing plate is installed to the upper surface of sieve plate, and described ozone catalytic particle to be positioned at above sieve plate and to be positioned at dividing plate both sides.
As preferably, also comprise the backwash settling tank, leading portion supernatant liquid pool and the pre-treatment backwashing pump that connect successively, described backwash settling tank is connected to pretreated primary BAF pond, pre-treatment secondary BAF pond by the first pipeline, second pipe, and described pre-treatment backwashing pump is connected to pretreated primary BAF pond, pre-treatment secondary BAF pond by leading portion reflux line.
As preferably, described ozonizer is connected to the bottom in catalyzed oxidation pond by gas pipeline.
Because technique scheme is used, the utility model compared with prior art has following advantages and effect:
The utility model is used for the Integrated Processing Unit of high saliferous trade effluent, macromole hardly degraded organic substance is oxidized to the easy biochemical organism of small molecules by it, and then the biochemical of water outlet is improved, by rear biochemical internal recycle BAF system, mineralising is carried out to the organism in water again, improve high saliferous phenolic wastewater advanced treatment effect; Secondly, improve the tolerance to high saliferous phenolic wastewater, make in the catalytic oxidation treatment process to saline sewage, the hydroxyl radical free radical that catalyst ozone generation is active, keeps good effect to the removal of waste water COD, decolouring, de-stench, degraded toxic pollutant and the biodegradability that improves waste water.
Accompanying drawing explanation
Accompanying drawing 1 is for the utility model is for the Integrated Processing Unit structural representation of high saliferous trade effluent.
In above accompanying drawing: 1, catalyzed oxidation pond; 2, oxidation-stabilized pond; 3, rear biochemical BAF pond; 4, clean water basin; 41, prosopyle; 42, posticum; 51, leading portion transfer conduit; 52, back segment transfer conduit; 6, lift pump; 7, inlet channel; 8, ozonizer; 9, gas pipeline; 10, back segment reflux line; 11, backwashing pump; 12, ozone catalytic particle; 15, pretreated primary BAF pond; 16, pre-treatment secondary BAF pond; 17, outlet sump; 18, comprehensive tank is diluted; 181, charging opening; 182, agitator; 19, backwash settling tank; 201, the first pipeline; 202, backwash settling tank; 21, leading portion supernatant liquid pool; 22, pre-treatment backwashing pump; 23, leading portion reflux line.
Embodiment
Below in conjunction with embodiment, the utility model is further described:
Embodiment: a kind of Integrated Processing Unit for high saliferous trade effluent, comprise catalyzed oxidation pond 1, oxidation-stabilized pond 2, rear biochemical BAF pond 3, clean water basin 4, dilute comprehensive tank 18, pretreated primary BAF pond 15, pre-treatment secondary BAF pond 16 and outlet sump 17, the comprehensive tank 18 of described dilution, pretreated primary BAF pond 15, pre-treatment secondary BAF pond 16 are connected by leading portion transfer conduit 51 successively with outlet sump 17
Described catalyzed oxidation pond 1, oxidation-stabilized pond 2, rear biochemical BAF pond 3 are connected by back segment transfer conduit 52 successively with clean water basin 4, and it is inner that described outlet sump 17 and catalyzed oxidation pond 1 are connected to catalyzed oxidation pond 1 by inlet channel 7,
It is inner that one ozonizer 8 is connected to catalyzed oxidation pond 1 by gas pipeline 9, described clean water basin 4 are provided with prosopyle 41, posticum 42, the prosopyle 41 of described clean water basin 4 is connected by back segment transfer conduit 52 with rear biochemical BAF pond 3, described clean water basin 4 are connected to backwashing pump 11 one end, it is inner that this backwashing pump 11 the other end is connected to catalyzed oxidation pond 1, rear biochemical BAF pond 3 by back segment reflux line 10, described catalyzed oxidation pond 1 is filled with ozone catalytic particle 12 with fixed bed form, and the comprehensive tank 18 of described dilution is provided with charging opening 181 and agitator 182.
A dividing plate 13 is provided with vertically in above-mentioned catalyzed oxidation pond 1, thus catalyzed oxidation pond is divided into left and right chamber, described catalyzed oxidation pond 1 lower horizontal is provided with a sieve plate 14, the lower end of this dividing plate 13 is installed to the upper surface of sieve plate 14, and described ozone catalytic particle 12 to be positioned at above sieve plate 14 and to be positioned at dividing plate 13 both sides.
Also comprise the backwash settling tank 19, leading portion supernatant liquid pool 21 and the pre-treatment backwashing pump 22 that connect successively, described backwash settling tank 19 is connected to pretreated primary BAF pond 15, pre-treatment secondary BAF pond 16 by the first pipeline 201, second pipe 201, and described pre-treatment backwashing pump 22 is connected to pretreated primary BAF pond 15, pre-treatment secondary BAF pond 16 by leading portion reflux line 23.
Above-mentioned ozonizer 8 is connected to the bottom in catalyzed oxidation pond 1 by gas pipeline 9.
The utility model is used for the Integrated Processing Unit of high saliferous trade effluent, and working process is as follows, comprises the steps:
(1) high saliferous phenolic wastewater squeezes into internal recycle BAF system by pump, and sewage promotes along aeration tube, then through biological bed, forms cycling stream.The flow velocity of packing layer inside reaches 20 ~ 30m/h, improve the mass transfer velocity between microbial film and aqueous phase, improve treatment efficiency and the impact resistance of reactor, the air water short circuit phenomenon simultaneously preventing the channel directly formed packing layer aeration to cause occurs.By pretreated BAF system can degrade by biochemical component to high saliferous phenolic wastewater, thus reduce bio-chemical effluent COD;
(2) biochemical pre-treatment water outlet gravity flow enters catalytic ozonation, rear biochemical internal recycle BAF coupling technique treatment system, first this system utilizes ozone to carry out catalytic oxidation, utilize ozone oxidation part refractory organic, make larger molecular organics be oxidized to small organic molecule, the biodegradability of pre-treatment water outlet can be improved simultaneously;
(3) catalytic ozonation water outlet enters rear biochemical internal recycle BAF advanced treatment system, and this biochemical reaction tank utilizes the mushroom of domestication to carry out biological degradation to the small organic molecule of ozone oxidation water outlet, and water outlet COD is reduced further.
Above-described embodiment, only for technical conceive of the present utility model and feature are described, its object is to person skilled in the art can be understood content of the present utility model and implement according to this, can not limit protection domain of the present utility model with this.All equivalences done according to the utility model spirit change or modify, and all should be encompassed within protection domain of the present utility model.

Claims (4)

1. the Integrated Processing Unit for high saliferous trade effluent, it is characterized in that: comprise catalyzed oxidation pond (1), oxidation-stabilized pond (2), rear biochemical BAF pond (3), clean water basin (4), dilute comprehensive tank (18), pretreated primary BAF pond (15), pre-treatment secondary BAF pond (16) and outlet sump (17), the comprehensive tank of described dilution (18), pretreated primary BAF pond (15), pre-treatment secondary BAF pond (16) and outlet sump (17) are connected by leading portion transfer conduit (51) successively;
Described catalyzed oxidation pond (1), oxidation-stabilized pond (2), rear biochemical BAF pond (3) and clean water basin (4) are connected by back segment transfer conduit (52) successively, and it is inner that described outlet sump (17) and catalyzed oxidation pond (1) are connected to catalyzed oxidation pond (1) by inlet channel (7);
It is inner that one ozonizer (8) is connected to catalyzed oxidation pond (1) by gas pipeline (9), described clean water basin (4) are provided with prosopyle (41), posticum (42), the prosopyle (41) of described clean water basin (4) is connected by back segment transfer conduit (52) with rear biochemical BAF pond (3), described clean water basin (4) are connected to a backwashing pump (11) one end, this backwashing pump (11) the other end is connected to catalyzed oxidation pond (1) by back segment reflux line (10), rear biochemical BAF pond (3) is inner, described catalyzed oxidation pond (1) is filled with ozone catalytic particle (12) with fixed bed form, the comprehensive tank of described dilution (18) is provided with charging opening (181) and agitator (182).
2. the Integrated Processing Unit for high saliferous trade effluent according to claim 1, it is characterized in that: in described catalyzed oxidation pond (1), be provided with a dividing plate (13) vertically, thus catalyzed oxidation pond is divided into left and right chamber, described catalyzed oxidation pond (1) lower horizontal is provided with a sieve plate (14), the lower end of this dividing plate (13) is installed to the upper surface of sieve plate (14), and described ozone catalytic particle (12) is positioned at sieve plate (14) top and is positioned at dividing plate (13) both sides.
3. the Integrated Processing Unit for high saliferous trade effluent according to claim 1, it is characterized in that: also comprise the backwash settling tank (19), leading portion supernatant liquid pool (21) and the pre-treatment backwashing pump (22) that connect successively, described backwash settling tank (19) is connected to pretreated primary BAF pond (15), pre-treatment secondary BAF pond (16) by the first pipeline (201), second pipe (201), and described pre-treatment backwashing pump (22) is connected to pretreated primary BAF pond (15), pre-treatment secondary BAF pond (16) by leading portion reflux line (23).
4. the Integrated Processing Unit for high saliferous trade effluent according to claim 1, is characterized in that: described ozonizer (8) is connected to the bottom of catalyzed oxidation pond (1) by gas pipeline (9).
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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105481177A (en) * 2015-12-27 2016-04-13 苏州科环环保科技有限公司 Low-consumption nitrification and denitrification coal chemical wastewater advanced treatment device
CN105541012A (en) * 2015-12-27 2016-05-04 苏州科环环保科技有限公司 Sewage nitrogen and phosphorus removal device with internal circulating biological aerated filter
CN105541011A (en) * 2015-12-27 2016-05-04 苏州科环环保科技有限公司 High nitrogen and phosphorus wastewater overall disposal system with efficient hydrolytic tank
CN105601035A (en) * 2015-12-27 2016-05-25 苏州科环环保科技有限公司 Water treatment equipment for up-to-standard discharge of high concentrated organic wastewater
CN107344797A (en) * 2016-05-04 2017-11-14 苏州科环环保科技有限公司 Advanced treatment process for gas station phenol water
CN107344793A (en) * 2016-05-04 2017-11-14 苏州科环环保科技有限公司 Comprehensive processing technique for high saliferous phenol-containing wastewater
CN107673546A (en) * 2016-08-01 2018-02-09 苏州科环环保科技有限公司 Coal gasification phenol water pollution-free circular treatment method
CN107673543A (en) * 2016-08-01 2018-02-09 苏州科环环保科技有限公司 The processing method of phenol wastewater
CN107673542A (en) * 2016-08-01 2018-02-09 苏州科环环保科技有限公司 The processing method of gas generator water containing phenol
CN107673544A (en) * 2016-08-01 2018-02-09 苏州科环环保科技有限公司 The processing method of high salt organic wastewater containing phenol
CN107673547A (en) * 2016-08-01 2018-02-09 苏州科环环保科技有限公司 Novel process for treating phenol water from gas station
CN107759003A (en) * 2016-08-17 2018-03-06 苏州科环环保科技有限公司 High-salt wastewater cyclic utilization system
CN107758984A (en) * 2016-08-17 2018-03-06 苏州科环环保科技有限公司 Handling process for coal gas producer phenol water
CN107758994A (en) * 2016-08-17 2018-03-06 苏州科环环保科技有限公司 Advanced treatment process for gas station phenol water

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105481177A (en) * 2015-12-27 2016-04-13 苏州科环环保科技有限公司 Low-consumption nitrification and denitrification coal chemical wastewater advanced treatment device
CN105541012A (en) * 2015-12-27 2016-05-04 苏州科环环保科技有限公司 Sewage nitrogen and phosphorus removal device with internal circulating biological aerated filter
CN105541011A (en) * 2015-12-27 2016-05-04 苏州科环环保科技有限公司 High nitrogen and phosphorus wastewater overall disposal system with efficient hydrolytic tank
CN105601035A (en) * 2015-12-27 2016-05-25 苏州科环环保科技有限公司 Water treatment equipment for up-to-standard discharge of high concentrated organic wastewater
CN107344797A (en) * 2016-05-04 2017-11-14 苏州科环环保科技有限公司 Advanced treatment process for gas station phenol water
CN107344793A (en) * 2016-05-04 2017-11-14 苏州科环环保科技有限公司 Comprehensive processing technique for high saliferous phenol-containing wastewater
CN107673546A (en) * 2016-08-01 2018-02-09 苏州科环环保科技有限公司 Coal gasification phenol water pollution-free circular treatment method
CN107673543A (en) * 2016-08-01 2018-02-09 苏州科环环保科技有限公司 The processing method of phenol wastewater
CN107673542A (en) * 2016-08-01 2018-02-09 苏州科环环保科技有限公司 The processing method of gas generator water containing phenol
CN107673544A (en) * 2016-08-01 2018-02-09 苏州科环环保科技有限公司 The processing method of high salt organic wastewater containing phenol
CN107673547A (en) * 2016-08-01 2018-02-09 苏州科环环保科技有限公司 Novel process for treating phenol water from gas station
CN107759003A (en) * 2016-08-17 2018-03-06 苏州科环环保科技有限公司 High-salt wastewater cyclic utilization system
CN107758984A (en) * 2016-08-17 2018-03-06 苏州科环环保科技有限公司 Handling process for coal gas producer phenol water
CN107758994A (en) * 2016-08-17 2018-03-06 苏州科环环保科技有限公司 Advanced treatment process for gas station phenol water

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