CN206583877U - A kind of in-situ chemical oxygen demand on-line detector - Google Patents

A kind of in-situ chemical oxygen demand on-line detector Download PDF

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Publication number
CN206583877U
CN206583877U CN201720254089.3U CN201720254089U CN206583877U CN 206583877 U CN206583877 U CN 206583877U CN 201720254089 U CN201720254089 U CN 201720254089U CN 206583877 U CN206583877 U CN 206583877U
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China
Prior art keywords
pump
water sample
detector
sample pretreatment
pool
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Expired - Fee Related
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CN201720254089.3U
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Chinese (zh)
Inventor
林峰
俞国军
胡叶亮
赵洋甬
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Zhejiang Yongxin Testing Technology Co ltd
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Ningbo Keda Environment Technology Co Ltd
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Abstract

The utility model is related to a kind of in-situ chemical oxygen demand on-line detector, including sampling system, pretreatment system and analysis system, pretreatment system includes the water sample pretreatment pool being connected with self priming pump, filter screen is provided with water sample pretreatment pool, the inner chamber of water sample pretreatment pool is divided into upper plenum and lower cavity by filter screen, in lower cavity supersonic generator is provided with positioned at the bottom of water sample pretreatment pool, the bottom of water sample pretreatment pool is provided with the one-level discharge outlet connected with lower cavity, and the side of water sample pretreatment pool is provided with the Municipal secondary effluent mouthful connected with upper plenum;Analysis system includes housing, it is built in the detector of housing, the feed liquor peristaltic pump being connected with detector, the pump housing connection feed liquor pump line and Pump for giving-out pipe of feed liquor peristaltic pump, feed liquor pump line is connected with the upper plenum of water sample pretreatment pool, and Pump for giving-out pipe is connected with detector, and the side of housing is additionally provided with multiple reagent bottles, reagent bottle is connected by Reagent Tube and reagent peristaltic pump with detector, and COD testing efficiency and precision are high.

Description

A kind of in-situ chemical oxygen demand on-line detector
Technical field
The utility model is related to water sample chemical oxygen demand detection instrument, especially a kind of in-situ chemical oxygen demand on-line checking Instrument.
Background technology
COD COD (Chemical Oxygen Demand) is chemically to measure to need to be oxidized in water sample Reducing substances amount.In river pollution and the operational management of industrial wastewater Quality Research and waste water treatment plant, it It is an Organic Pollution parameter that is important and can comparatively fast determining, is often represented with symbol COD.
Recognize in market survey:When testing surface water and waste water, the existing COD on-line detectors of in the market There is fault rate height, the larger defect of test result error compared with standard method in device.Due to long-time non-stop run, water quality The most common failure of COD on-line checking instruments mainly has two:One is pipe breakage, the second is wriggling failure of pump.This is instrument Hidden danger has been buried in the stable operation of device, while adding maintenance cost.To find out its cause, mainly there is two.First, majority is on sale to be set The standby pump line anti-wear performance used is poor, and common pump line is not suitable for long time continuous working, easily ruptures.Second, peristaltic pump Placement location design is unreasonable, and positively fixed type, which is designed, causes wriggling pump water inlet probability to increase.
For test result and standard method error it is larger the problem of, its main cause has two:First, COD has larger Part is present in particle, and the pretreatment system majority of existing equipment has carried out degranulation processing, the representative variation of sample;Its Two, using AAS existing COD online detection instruments more, in practice it has proved that, when low concentration is tested, error is larger.
Utility model content
The purpose of this utility model be in order to solve the defect present in COD on-line checkings instrument in the prior art there is provided A kind of in-situ chemical oxygen demand on-line detector.
To achieve these goals, the technical solution adopted in the utility model is:
A kind of in-situ chemical oxygen demand on-line detector, including sampling system, pretreatment system and analysis system, sampling System includes self priming pump, and self priming pump connection probe tube, the water sucking mouth of probe tube is upward, the end connection filtering grid of probe tube, Filter grid case is below the waterline of water sample;
Pretreatment system includes being provided with filter screen, filter screen in the water sample pretreatment pool being connected with self priming pump, water sample pretreatment pool The inner chamber of water sample pretreatment pool is divided into upper plenum and lower cavity, lower cavity positioned at the bottom of water sample pretreatment pool provided with super Sonic generator, the bottom of water sample pretreatment pool is provided with the one-level discharge outlet connected with lower cavity, the side of water sample pretreatment pool Provided with the Municipal secondary effluent mouthful connected with upper plenum;
Analysis system includes housing, is built in the detector of housing, the feed liquor peristaltic pump being connected with detector, and feed liquor is wriggled The pump housing end connection feed liquor pump line and Pump for giving-out pipe of pump, feed liquor pump line are connected with the upper plenum of water sample pretreatment pool, Pump for giving-out Pipe is connected with detector, and the side of housing is additionally provided with multiple reagent bottles, and reagent bottle passes through Reagent Tube and reagent peristaltic pump and detection Instrument is connected;
The end of the feed liquor pump line is provided with secondary filter core, and the material of secondary filter core is environmentally friendly synthetic fibers filtering Cotton;
The feed liquor peristaltic pump, reagent peristaltic pump, the equal side of waste liquid peristaltic pump.
A kind of above-mentioned in-situ chemical oxygen demand on-line detector, the detector includes digestion system and automatic current potential drips Determine system, digestion system includes the digestion pool of closing, and digestion pool bottom is provided with heating wire, and the side wall of digestion pool is provided with temperature Meter, Automatic Potentiometric Titration System is automatical potentiometric titrimeter, the built-in l ferrous ammonium sulfate solution of automatical potentiometric titrimeter, ferrous sulfate Ammonium salt solution is added dropwise in digestion pool.
A kind of above-mentioned in-situ chemical oxygen demand on-line detector, the top of the digestion pool is provided with Air cooler.
A kind of above-mentioned in-situ chemical oxygen demand on-line detector, the digestion pool is connected by waste liquid peristaltic pump and sewer pipe Connect waste liquid barrel.
A kind of above-mentioned in-situ chemical oxygen demand on-line detector, a pair of reagent bottle and reagent the peristaltic pump quantity 1 Should.
The beneficial effects of the utility model are:The end of the upward water sucking mouth set-up mode of the detector and probe tube connects Take over when grating lattice avoid low water level and suck mud scum, cause system jams;The setting of ultrasonic homogeneity pretreatment system so that Larger particle is broken up in preprocessing process by physical action in water sample, while making pretreated water sample evenly, improves The representativeness of testing sample, while increasing the accuracy of instrument test;Peristaltic pump pump line uses France Saint-Gobain Pharmed BPT Long-life tube replaces common silica gel pump line, and pump line service life can improve more than 5 times, reduce the instrument maintenance frequency;Each is compacted Dynamic pump places design and is changed to side by just putting, it is to avoid peristaltic pump waterlogged damage during leak.
Brief description of the drawings
Fig. 1 is schematic diagram of the present utility model;
Fig. 2 is the schematic diagram of the utility model feed liquor peristaltic pump.
Embodiment
As shown in Figure 1 to Figure 2, a kind of in-situ chemical oxygen demand on-line detector, including sampling system 1, pretreatment system 2 And analysis system 3, sampling system 1 includes self priming pump 11, the connection probe tube 12 of self priming pump 11, the water sucking mouth of probe tube 12 to On, the end connection filtering grid 13 of probe tube 12, filtering grid 13 is located at the waterline of water sample below 14;
Pretreatment system 2 is included in the water sample pretreatment pool 21 being connected with self priming pump 11, water sample pretreatment pool 21 provided with filter Net 22, the inner chamber of water sample pretreatment pool 21 is divided into upper plenum 23 and lower cavity 24, lower cavity 24 by filter screen 22 is located at water sample The bottom of pretreatment pool 21 is provided with supersonic generator 25, and the bottom of water sample pretreatment pool 21 is provided with connected with lower cavity 24 one Level discharge outlet 26, the side of water sample pretreatment pool 21 is provided with the Municipal secondary effluent mouthful 27 connected with upper plenum 23;
Analysis system 3 includes housing 31, is built in the detector of housing 31, the feed liquor peristaltic pump 32 being connected with detector, The pump housing end connection feed liquor pump line 321 and Pump for giving-out pipe 322, feed liquor pump line 321 and water sample pretreatment pool of feed liquor peristaltic pump 32 21 upper plenum 23 is connected, and Pump for giving-out pipe 322 is connected with detector, and the side of housing 31 is additionally provided with multiple reagent bottles 33, reagent Bottle 33 is connected by Reagent Tube 331 and reagent peristaltic pump 332 with detector, and reagent bottle 33 and the quantity of reagent peristaltic pump 332 are one by one Correspondence.
Detector includes digestion system and Automatic Potentiometric Titration System, and digestion system includes the digestion pool 34 of closing, cleared up The bottom of pond 34 is provided with heating wire 35, and the side wall of digestion pool 34 is provided with thermometer 36, and digestion pool 34 passes through the He of waste liquid peristaltic pump 37 Sewer pipe 38 connects waste liquid barrel 39.
Automatic Potentiometric Titration System is automatical potentiometric titrimeter 30, and the built-in iron ammonium sulfate of automatical potentiometric titrimeter 30 is molten Liquid, l ferrous ammonium sulfate solution is added dropwise in digestion pool 34, and the top of digestion pool 34 is provided with Air cooler 341.
Further, the end of feed liquor pump line 321 is provided with secondary filter core 323, and the material of secondary filter core 323 is closed for environmental protection Into fiber filter cotton, feed liquor peristaltic pump 32, reagent peristaltic pump 332, the equal side of waste liquid peristaltic pump 37 place sulphur in reagent bottle 33 Acid, silver sulfate, mercuric sulfate, potassium bichromate solution.
During detection, quantitative water sample is sent into by feed liquor peristaltic pump 32 and reagent peristaltic pump 332 first interior certainly in digestion pool 34 After dynamic mixing addition sulfuric acid, silver sulfate, mercuric sulfate, potassium bichromate, (upper end of digestion pool 34 is using air-cooled within 2 hours for heated backflow Machine 341 prevents the heated effusion of organic matter);Heating is finished, and keeps 60 ° of G or so temperature, by automatical potentiometric titrimeter 30 to clearing up Pond 34 instills iron ammonium sulfate automatically, and the two-wave interpretation potentiometry required using national standard indicates titration end-point.According to electrolysis Fe2+ consumptions calculate COD contents.The analysis process meets《Environmental protection product technical requirements COD (CODCr) water Matter online automatic monitor》, and and national standard method (HJ/T377-2007)《The measure bichromate of water chemical oxygen demand Method》(GB/T 11914-1989) is consistent substantially.
The end connection filtering grid 13 of the upward water sucking mouth set-up mode of the detector and probe tube 12 avoids low Mud scum is sucked during water level, causes system jams;The setting of ultrasonic homogeneity pretreatment system so that larger particle exists in water sample Broken up in preprocessing process by physical action, while making pretreated water sample evenly, improve the representativeness of testing sample, together The accuracy of Shi Zengjia instrument tests;Peristaltic pump pump line replaces ordinary silicon using French Saint-Gobain Pharmed BPT long-life tubes Glue pump line, pump line service life can improve more than 5 times, reduce the instrument maintenance frequency;Each peristaltic pump places design by just putting It is changed to side, it is to avoid peristaltic pump waterlogged damage during leak;Detector includes the digestion pool of closing, and digestion pool bottom is provided with electric heating Silk, the side wall of digestion pool is provided with thermometer, is mixed for water sample with medicine, reacts and provide suitable environment and temperature, just Just post analysis, measurement.
The utility model is not limited to above-mentioned preferred forms, and anyone can draw under enlightenment of the present utility model Other various forms of products, however, make any change in its shape or structure, it is every that there is same as the present application or phase Approximate technical scheme, all falls within protection domain of the present utility model.

Claims (5)

1. a kind of in-situ chemical oxygen demand on-line detector, including sampling system, pretreatment system and analysis system, its feature It is, sampling system includes self priming pump, self priming pump connection probe tube, the water sucking mouth of probe tube is upward, the end connection of probe tube Grid is filtered, filter grid case is below the waterline of water sample;
Pretreatment system is included in the water sample pretreatment pool that be connected with self priming pump, water sample pretreatment pool provided with filter screen, and filter screen is by water The inner chamber of sample pretreatment pool is divided into upper plenum and lower cavity, lower cavity is provided with ultrasonic wave positioned at the bottom of water sample pretreatment pool Generator, the bottom of water sample pretreatment pool is provided with the one-level discharge outlet connected with lower cavity, and the side of water sample pretreatment pool is provided with The Municipal secondary effluent mouthful connected with upper plenum;
Analysis system includes housing, is built in the detector of housing, the feed liquor peristaltic pump being connected with detector, feed liquor peristaltic pump Pump housing end connects feed liquor pump line and Pump for giving-out pipe, and feed liquor pump line is connected with the upper plenum of water sample pretreatment pool, Pump for giving-out pipe and Detector is connected, and the side of housing is additionally provided with multiple reagent bottles, and reagent bottle is connected by Reagent Tube and reagent peristaltic pump with detector Connect;
The end of the feed liquor pump line is provided with secondary filter core, and the material of secondary filter core is environmentally friendly synthetic fibers filter cotton;
The feed liquor peristaltic pump, reagent peristaltic pump, the equal side of waste liquid peristaltic pump.
2. a kind of in-situ chemical oxygen demand on-line detector according to claim 1, it is characterised in that the detector bag Digestion system and Automatic Potentiometric Titration System are included, digestion system includes the digestion pool of closing, and digestion pool bottom is provided with heating wire, disappeared Xie Chi side wall is provided with thermometer, and Automatic Potentiometric Titration System is automatical potentiometric titrimeter, the built-in sulphur of automatical potentiometric titrimeter Sour ferrous iron ammonium salt solution, l ferrous ammonium sulfate solution is added dropwise in digestion pool.
3. a kind of in-situ chemical oxygen demand on-line detector according to claim 2, it is characterised in that the digestion pool Top is provided with Air cooler.
4. a kind of in-situ chemical oxygen demand on-line detector according to claim 2, it is characterised in that the digestion pool leads to Cross waste liquid peristaltic pump and sewer pipe connection waste liquid barrel.
5. a kind of in-situ chemical oxygen demand on-line detector according to claim 1, it is characterised in that the reagent bottle and Reagent peristaltic pump quantity is corresponded.
CN201720254089.3U 2017-03-14 2017-03-14 A kind of in-situ chemical oxygen demand on-line detector Expired - Fee Related CN206583877U (en)

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CN201720254089.3U CN206583877U (en) 2017-03-14 2017-03-14 A kind of in-situ chemical oxygen demand on-line detector

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201720254089.3U CN206583877U (en) 2017-03-14 2017-03-14 A kind of in-situ chemical oxygen demand on-line detector

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109164224A (en) * 2018-09-29 2019-01-08 成都凯天电子股份有限公司 water sample on-line dilution monitor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109164224A (en) * 2018-09-29 2019-01-08 成都凯天电子股份有限公司 water sample on-line dilution monitor
CN109164224B (en) * 2018-09-29 2024-04-30 成都凯天电子股份有限公司 Water sample on-line dilution monitor

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Effective date of registration: 20210908

Address after: 315048 west side of second floor, auxiliary building, No. 299, Xinmei Road, high tech Zone, Ningbo, Zhejiang

Patentee after: Zhejiang Yongxin Testing Technology Co.,Ltd.

Address before: 315000 room 547, No. 5, Lane 999, Yangfan Road, high tech Zone, Ningbo, Zhejiang

Patentee before: NINGBO YIKEDA ENVIRONMENT TECHNOLOGY Co.,Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20171024