CN206560785U - The micro-nano ozone emission-reducing system of waste gas - Google Patents

The micro-nano ozone emission-reducing system of waste gas Download PDF

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Publication number
CN206560785U
CN206560785U CN201720205664.0U CN201720205664U CN206560785U CN 206560785 U CN206560785 U CN 206560785U CN 201720205664 U CN201720205664 U CN 201720205664U CN 206560785 U CN206560785 U CN 206560785U
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ozone
water
micro
gas
pond
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CN201720205664.0U
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Chinese (zh)
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吴正新
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Nanjing Jiayuan New Environmental Technology Co Ltd
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Nanjing Jiayuan New Environmental Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Abstract

The utility model provides a kind of micro-nano ozone emission-reducing system of waste gas, including ventilation duct, air exhauster, lower air conduit, pond and chimney, flue gas enters air exhauster through ventilation duct, it is discharged in lower air conduit and is entered above water face by air exhauster again, flue gas is passed through by smoke stack emission to air from after the bounce-back of the pond water surface, it is provided for spraying the nozzle containing ozone and micro/nano level ozone bubbles water droplet in front of lower air conduit and/or chimney, water in pond enters in filter, and the gas of gas-liquid mixing pump input is oxygenous and ozone.System described in the utility model, by way of the recirculated water containing ozone and ozone bubbles is in the enterprising water-filling drop spray in flow of flue gas path, makes the soot amount in flue gas reduce and de-taste;The cigarette ash dirt of absorption, is partly collected by filter, is partly progressively oxidized in pond and is resolved into carbon dioxide and water, reduces the discharge of waste gas and the removal of the smell of waste gas.

Description

The micro-nano ozone emission-reducing system of waste gas
Technical field
The utility model is related to technical field of waste gas treatment, more particularly to a kind of waste gas micro-nano ozone emission-reducing system.
Background technology
The source of generation of waste gas has a lot, such as can produce waste gas when metal works are heat-treated, but the generation of the waste gas It cannot avoid again, because metal works heat treatment is one of important process of machine-building.The heat treatment on metal works top layer To change the Technology for Heating Processing of its top layer mechanical property, in order to which only heated partses top layer is without making in the incoming workpiece of excessive heat Portion, the thermal source used generally uses highdensity heater.Antirust oiliness thing is often smeared on surface to workpiece in process, is had Machine solvent, and alkalescence or acid.The gasification of various smears and portions under heat oxidation of surface of workpiece during heat treatment, these Vapour is herein collectively referred to as cigarette ash, and soot particulates differ in size, and soot amount is big during heat treatment, produces fast and has peculiar smell, these have Evil even poison gas is discharged outside workshop through smoke discharging pipe.The molecular weight of these cigarette ashes is relatively large, is difficult to fly to high-altitude and disperses, As haze.
The exhaust-gas treatment produced when being heat-treated at present for the processing of waste gas, especially metal works is typically all using activity The mode of charcoal absorption.But, which needs often to change activated carbon, and hardly possible meets the demand of actual job.Electrostatic smoking is small Type operation is feasible, but smoke it is big when then operation it is difficult.With ultraviolet equipment come smoke abatement, equipment volume is big, and effect is limited, and maintenance Maintenance is not easy to.Strict demand with new environmental regulation to smoke evacuation, these harmful or even poisonous flue gases are needed with one The processing mode of innovation is planted to reduce smoke evacuation and de-taste.
Utility model content
Therefore, technical problem to be solved in the utility model is:A kind of micro-nano ozone emission-reducing system of waste gas is provided, To reduce the discharge of waste gas and the removal of exhaust gas smell.
Then, the utility model provides a kind of micro-nano ozone emission-reducing system of waste gas, including:At a kind of flue gas emission reduction Reason system, including:Ventilation duct, air exhauster, lower air conduit, pond and chimney, flue gas enter air exhauster through ventilation duct, then by air exhauster It is discharged in lower air conduit and enters above water face, flue gas is passed through by smoke stack emission to air from after the bounce-back of the pond water surface, in lower air conduit And/or be provided for having adsorbed cigarette at nozzle of the sprinkling containing ozone and micro/nano level ozone bubbles water droplet, nozzle in front of chimney The water droplet of cigarette ash in gas is fallen into pond, and the water in pond enters in water in filter through being placed in the self priming pump outside pond Bulky grain solid thing filter out after enter gas-liquid mixing pump input, the output end of gas-liquid mixing pump connects with pressure adjustment tank Connect, the outlet that water adjusts tank through excess pressure enters the nozzle, and the gas of gas-liquid mixing pump input is oxygenous and ozone.
Wherein, above-mentioned micro-nano ozone emission-reducing system, is also provided with shower room above pond, and nozzle is arranged on spray Interior, the flue gas by nozzles spray is through smoke stack emission into air.
Above-mentioned micro-nano ozone emission-reducing system also includes:Being used for of being connected with gas-liquid mixing pump produces the smelly of oxygen and ozone Oxygen supply equipment.
Pressure adjustment tank top is provided with pressure-regulating valve.
The pressure limit of the pressure-regulating valve is 0.1 Mpa to 0.3 Mpa.
The size of the micro/nano level ozone bubbles is 0.01-1 microns.
Water in the pond contains ozone and micro/nano level ozone bubbles.
Organic matter containing unsaturated hydrogen bond in the flue gas or the oiliness thing containing non-hydrophilic.
The utility model additionally provides a kind of smell of waste gas discharge and removes system, including:Ventilation duct, air exhauster, leeward Pipe, pond and chimney, organic matter of the flue gas containing unsaturated hydrogen bond or the oiliness thing containing non-hydrophilic, enter through ventilation duct and take out Blower fan, then be discharged to by air exhauster in lower air conduit into above water face, flue gas is passed through by smoke stack emission from after the bounce-back of the pond water surface To air, it is provided for spraying the nozzle containing ozone and micro/nano level ozone bubbles water droplet in front of lower air conduit and/or chimney, The water droplet that the organic matter containing unsaturated hydrogen bond in flue gas or the oiliness thing containing non-hydrophilic have been adsorbed at nozzle falls into pond In, removed with the smell for reaching waste gas discharge, the water in pond enters water in filter through being placed in the self priming pump outside pond In bulky grain solid thing filter out after enter gas-liquid mixing pump input, the output end of gas-liquid mixing pump connects with pressure adjustment tank Connect, the outlet that water adjusts tank through excess pressure enters the nozzle, gas-liquid mixing pump input gas is oxygenous and ozone.
Wherein, the size of the micro/nano level ozone bubbles is 0.01-1 microns.
The micro-nano ozone emission-reducing system of waste gas described in the utility model, passes through the recirculated water containing ozone and ozone bubbles The mode of enterprising water-filling drop spray in flow of flue gas path, allow the cigarette ash in flue gas include vapour, unsaturated hydrogen bond it is organic The material such as thing, oiliness thing, the carbon particle of non-hydrophilic is attracted on water droplet, the soot amount in flue gas is reduced and is de-tasted;Inhale Attached cigarette ash dirt, is partly collected by filter, is partly progressively oxidized in pond and is resolved into carbon dioxide and water, reduced The discharge of waste gas and the removal of the smell of waste gas.
Brief description of the drawings
Fig. 1 is the structural representation of the micro-nano ozone emission-reducing system of the waste gas described in the utility model embodiment.
Embodiment
Below, the utility model is described in detail with reference to accompanying drawing.
As shown in figure 1, present embodiments providing a kind of micro-nano ozone emission-reducing system 10 of waste gas, two pairs are largely divided into System, one is structure subsystem, and another is equipment subsystem.The flue gas produced by heat treatment process in workshop, for example It is the flue gas that metal works heat treatment operation is produced, workpiece smear is heated and the cigarette ash in partial oxidation, flue gas contains largely not Saturation hydrogen bond, harmful and have peculiar smell, the organic matter containing unsaturated hydrogen bond in flue gas or the oiliness containing non-hydrophilic Thing.Its arrow flowed in Lu Jingru Fig. 1 passages of flue gas is signified, through ventilation duct 12, crosses air exhauster 14, lower air conduit 16 enters pond 18.Flue gas rebounds to spray chamber 20, then via chimney 22 from the water surface in pond 18 and is discharged into air.This flow of flue gas path is The setting path that workshop smoke discharging is walked.Ventilation duct 12, air exhauster 14, lower air conduit 16, pond 18, spray chamber 20, chimney 22 etc., Range structure subsystem.In addition in Fig. 1, dotted line surrounding portion is equipment subsystem.
Wherein, first jet 46, or the setting second nozzle 50, Huo Zhetong in spray chamber 20 are set in lower air conduit 16 When first jet 46 is being set in the lower air conduit 16 and second nozzle 50 is set in spray chamber 20.
Shower room 20 is provided with the present embodiment Fig. 1, still, shower room 20 can also merge into a single whole with chimney 22, made Realized for chimney.
Water in pond 18 filters out the solids of bulky grain into filter 32 through self priming pump 30, subsequently into gas The fluid input port 35 of liquid mixing pump 34, the gas input 36 of gas-liquid mixing pump 34 is received from the smelly of ozone supplied equipment 38 Oxygen.Ozone supplied equipment 38 can be a set of equipment, including:Air compressor and air water removal device purify air, oxygen Molecular sieve denitrogenates pure oxygen, and partial oxidation is transformed into ozone etc. by high-voltage discharge tube.
In gas-liquid mixing pump 34, the oxygen and ozone that gas input 36 receives are compressed and are mixed into water body, water body Dissolved oxygen amount and molten ozone amount be rapidly reached supersaturation, solubility of the ozone in water is about 10 to 15 times of oxygen molecule, portion Divide unnecessary gas to form micro-nano bubble to be mixed into water body.1 micron of 100 a ten thousandth equivalent to 1 meter, and nanometer is It is millimicron, 1 nanometer equivalent to 1/1000000000th meter.Micro-nano bubble, which represents bubble size distribution, micron order size, also Have close to nano-grade size.The exit of gas-liquid mixing pump 34 connects pressure adjustment tank 40, and its top is connected to pressure regulation Valve 42, water adjusts the outlet of tank 40 through excess pressure, and a part of water 44 flows to lower air conduit 16 by the road, through the spray water of first jet 46 Drop in lower air conduit 16.Another part water 48 is flowed in spray chamber 20 by the road, and water droplet is sprayed through second nozzle 50.
The flue gas produced when workshop is through ventilation duct 12, air exhauster 14, and when reaching lower air conduit 16, the sprinkling of first jet 46 contains The water droplet of dissolved ozone and ozone bubbles, cigarette ash meets water droplet, because the electricity price potential difference of ozone produces absorption, cigarette ash can be sticked to Water drops surface, is subsequently collected in pond.The flue gas of discharge continues to push ahead, and enters spray chamber 20 from the resilience of water face.Together The reason of sample, the water droplet that second nozzle 50 sprays, because the reason containing ozone and ozone bubbles can adsorb cigarette ash, the cigarette after processing Gas, wherein cigarette ash are reduced and aqueous vapor increases, and continuation is discharged to air from chimney 22 forward.Therefore the micro-nano energy of ozone emission-reducing system 10 The cigarette ash and other dirts in flue gas are adsorbed, the direct discharge of cigarette ash is reduced.
As shown in figure 1, the flue gas that ventilation duct 12 is come in is adsorbed substantially across three roads.First of absorption is in first jet The spray region formed at 46, second absorption is, to water face, to be attracted to the water surface in smoke contacts.3rd road absorption be The spray region formed at second nozzle 50.Some cigarette ashes contain unsaturated hydrogen bond, there is peculiar smell.By the absorption in three roads, cigarette is reduced Cigarette ash in gas, including containing unsaturated hydrogen bond, long key oiliness thing and possible sulfide.Therefore micro-nano ozone emission-reducing system 10 It can also go to eliminate the unusual smell while smoke evacuation can be reduced.The present embodiment selection has used above-mentioned three road suction type and its corresponding useless The micro-nano structure of ozone emission-reducing system 10 of gas.It is of course also possible to using only first of the absorption of first jet 46 and water surface absorption Second adsorbs the micro-nano ozone emission-reducing system structure of twice suction type and its corresponding waste gas;The water surface can also be used only Adsorb twice suction type and its corresponding in the road of spray region the 3rd for adsorbing second absorption and being formed at second nozzle 50 The micro-nano ozone emission-reducing system structure of waste gas.
Water in pond 18, can attract the dirt in water because of ozone valency containing negative electricity, particularly there is unsaturated hydrogen bond Cigarette ash easily attract each other.The cigarette ash adsorbed by ozone, during ozone and oxygen molecule decomposition, cigarette ash is from macromolecular shape Formula is broken into small molecule form, and the cigarette ash of small molecule form is further aoxidized, and eventually becomes carbon dioxide and water.To make Easily distribution shift and a variety of different size of dirts form oxidation reaction, recirculated water to bubble containing ozone and oxygen in pond 18 The size distribution for including ozone bubbles is major consideration.The bubble that bubble ratio ozoniferous is constituted with general air, which reacts, lives Property is many by force.When ozone bubbles are 1 grade sizes, bubble can only be stopped the several seconds in pond internal cause buoyancy relation, it is impossible to Obtain in effect ground oxidation reaction.Bubble can be stayed in pond and drifted about in 1-0.1 micron order sizes, and the residence time is about more than ten point Clock.Bubble is in super micron-scale, i.e., close to 0.001 micron order size, and the time drifted about in pond can be rested in theory more Long, but because molecular structure water also polarized, ozone in itself easily accelerates to fail into oxygen molecule, the activity of bubble is reduced.Generally Half-life period of the ozone in water body about at 20 minutes, therefore adjustment ozone bubbles Size Distribution in 0.01-1 micron order sizes, It is preferred that size distribution ranges be 0.05-1 micron order chis, can maintain the reactivity of ozone bubbles, accelerate pollutant in water body Decomposition, and preferable ozone bubbles distribution chi can be had by suitably debugging the pressure-regulating valve 42 for adjusting the top of tank 40 positioned at pressure It is very little, experiment display, the pressure of pressure-regulating valve 42 is in 0.1Mpa to 0.3 Mpa, and scope preferably is 0.1 Mpa to 0.25 Mpa, the ozone bubbles size distribution that this pressure limit is produced can relatively efficiently decompose the dirt in water body.
Micro-nano ozone emission-reducing system 10 described in the utility model embodiment and traditional waste gas wash ratio are compared with advantage is bright It is aobvious.Traditional waste gas washing is one of exhaust gas treatment technology.It is usually used in industrial waste gas such as acid mist, alkali mist and paint exhaust-gas treatment. Micro-nano ozone emission-reducing system 10 can be adsorbed outside above-mentioned acid mist, alkali mist and paint waste gas, can also adsorb non-hydrophilic Cigarette ash, grease-contained flue gas is produced in many industry production processes, because water droplet includes ozone, makes the cigarette ash of original non-hydrophilic It can be adsorbed by water droplet, reach the effect that tradition elution operation does not reach.
The micro-nano ozone emission-reducing system 10 of waste gas described in the utility model embodiment and traditional direct in pond 18 Ozonation aerated comparison is advantageous.Because under certain pressure, temperature, concentration, molten ozone amount is limited in water body, is often far below Absorption and the demand for decomposing cigarette ash.The water droplet of water droplet containing dissolved ozone and ozone bubbles and only dissolved ozone compares, excellent Gesture is obvious.Because the overall electricity price position of ozone bubbles is shown on bubble chamber film, and hydrone polarized itself, this has whole water droplet The electricity price position performance of body is stronger than the water droplet of only dissolved ozone.And ozone is stored in water body with micro-nano bubble form, It can substantially increase to soot-treating capacity, reach traditional directly ozonation aerated effect not reached.
In summary, the micro-nano ozone emission-reducing system 10 of waste gas described in the utility model embodiment, with containing dissolved ozone Sprayed with the water droplet of micro-nano ozone bubbles on flue gas travel path, water droplet adsorbs the cigarette ash and other dirts in flue gas, cigarette Ash can have the organic matter of unsaturated hydrogen bond, the oiliness thing of non-hydrophilic, or an organic solvent, these cigarette ashes and other dirts via Drop collection reaches that emission reduction is de-tasted in pond 18, and is progressively fallen in pond by ozone and oxygen molecule oxidation consumption, final point Solution is into carbon dioxide and water.
The micro-nano ozone emission-reducing system 10 of waste gas described in the utility model embodiment, except suitable for surface of workpiece heat Processing is outer, also suitable for the fume emission of plastic injection manufacturing process.The conventional material of plastic injection technique is formulated with macromolecule The synthetic resin of polymer, filler, plasticizer, stabilizer, colouring agent, lubricant, antioxidant, in addition to above-mentioned auxiliary agent, modeling Fire retardant, foaming agent, antistatic additive etc. can be also added in material, to meet different use requirements.These materials are in process Volatilization and gasification, smell weight and containing a variety of cancer things processed.The micro-nano ozone emission-reducing system 10 of waste gas is also applied to other spray paintings The exhaust-gas treatment of exhaust-gas treatment and medium and small pattern firing equipment.
Preferred embodiment of the present utility model is the foregoing is only, it is all at this not to limit the utility model Within the spirit and principle of utility model, any modification, equivalent substitution and improvements made etc. should be included in the utility model Protection domain within.

Claims (10)

1. a kind of micro-nano ozone emission-reducing system of waste gas, it is characterised in that including:Ventilation duct, air exhauster, lower air conduit, pond And chimney, flue gas enters air exhauster through ventilation duct, then is discharged in lower air conduit and enters above water face by air exhauster, and flue gas is from water Passed through after the bounce-back of water face by smoke stack emission to air, sprinkling is provided in front of lower air conduit and/or chimney and contains ozone and micro- The water droplet that the cigarette ash in flue gas has been adsorbed at the nozzle of nanoscale ozone bubbles water droplet, nozzle is fallen into pond, the water in pond Enter gas-liquid mixing pump through being placed in the self priming pump outside pond into after filtering out the bulky grain solid thing in water in filter Input, the output end of gas-liquid mixing pump is connected with pressure adjustment tank, and the outlet that water adjusts tank through excess pressure enters the nozzle, Gas-liquid mixing pump input gas is oxygenous and ozone.
2. micro-nano ozone emission-reducing system according to claim 1, it is characterised in that shower room is provided with above pond, Nozzle is arranged in spray chamber, and the flue gas by nozzles spray is through smoke stack emission into air.
3. the micro-nano ozone emission-reducing system of the waste gas according to claims 1 or 2, it is characterised in that also including with gas The ozone supplied equipment for being used to produce oxygen and ozone of liquid mixing pump connection.
4. the micro-nano ozone emission-reducing system of the waste gas according to claims 1 or 2, it is characterised in that in pressure adjustment Tank top is provided with pressure-regulating valve.
5. the micro-nano ozone emission-reducing system of waste gas according to claim 4, it is characterised in that the pressure-regulating valve Pressure limit be 0.1 Mpa to 0.3 Mpa.
6. the micro-nano ozone emission-reducing system of the waste gas according to claims 1 or 2, it is characterised in that described micro-nano The size of level ozone bubbles is 0.01-1 microns.
7. the micro-nano ozone emission-reducing system of the waste gas according to claims 1 or 2, it is characterised in that in the pond Water contain ozone and micro/nano level ozone bubbles.
8. the micro-nano ozone emission-reducing system of the waste gas according to claims 1 or 2, it is characterised in that in the flue gas Organic matter containing unsaturated hydrogen bond or the oiliness thing containing non-hydrophilic.
9. a kind of smell of waste gas discharge removes system, it is characterised in that including:Ventilation duct, air exhauster, lower air conduit, pond and Chimney, organic matter of the flue gas containing unsaturated hydrogen bond or the oiliness thing containing non-hydrophilic, enter air exhauster through ventilation duct, then by Air exhauster, which is discharged in lower air conduit, to be entered above water face, and flue gas is passed through from after the bounce-back of the pond water surface by smoke stack emission to air, It is provided for spraying in front of lower air conduit and/or chimney at the nozzle containing ozone and micro/nano level ozone bubbles water droplet, nozzle and inhales The water droplet of the organic matter containing unsaturated hydrogen bond or the oiliness thing containing non-hydrophilic is fallen into pond in attached flue gas, to reach The smell of waste gas discharge is removed, and the water in pond enters the bulky grain in water in filter through being placed in the self priming pump outside pond Solids enters gas-liquid mixing pump input after filtering out, the output end of gas-liquid mixing pump is connected with pressure adjustment tank, and water passes through The outlet of pressure adjustment tank enters the nozzle, gas-liquid mixing pump input gas is oxygenous and ozone.
10. the smell of waste gas discharge according to claim 9 removes system, it is characterised in that the micro/nano level ozone The size of bubble is 0.01-1 microns.
CN201720205664.0U 2017-03-03 2017-03-03 The micro-nano ozone emission-reducing system of waste gas Expired - Fee Related CN206560785U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106853332A (en) * 2017-03-03 2017-06-16 南京嘉源润新环保科技有限公司 The micro-nano ozone emission-reducing system of waste gas

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106853332A (en) * 2017-03-03 2017-06-16 南京嘉源润新环保科技有限公司 The micro-nano ozone emission-reducing system of waste gas

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