CN206553407U - Antifog corrosion-resistant energy-saving film for civilian ship bridge glass - Google Patents
Antifog corrosion-resistant energy-saving film for civilian ship bridge glass Download PDFInfo
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- CN206553407U CN206553407U CN201720217123.XU CN201720217123U CN206553407U CN 206553407 U CN206553407 U CN 206553407U CN 201720217123 U CN201720217123 U CN 201720217123U CN 206553407 U CN206553407 U CN 206553407U
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- 239000011521 glass Substances 0.000 title claims abstract description 58
- 230000007797 corrosion Effects 0.000 title claims abstract description 34
- 238000005260 corrosion Methods 0.000 title claims abstract description 34
- 239000010410 layer Substances 0.000 claims abstract description 172
- 239000010408 film Substances 0.000 claims abstract description 83
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 23
- 238000005485 electric heating Methods 0.000 claims abstract description 21
- 239000012528 membrane Substances 0.000 claims abstract description 21
- 239000000758 substrate Substances 0.000 claims abstract description 18
- 239000002346 layers by function Substances 0.000 claims abstract description 8
- 239000010409 thin film Substances 0.000 claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 40
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 34
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 27
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 27
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 22
- -1 polytetrafluoroethylene Polymers 0.000 claims description 21
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 16
- 239000010936 titanium Substances 0.000 claims description 16
- 229910052719 titanium Inorganic materials 0.000 claims description 16
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 11
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 11
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- RHZWSUVWRRXEJF-UHFFFAOYSA-N indium tin Chemical compound [In].[Sn] RHZWSUVWRRXEJF-UHFFFAOYSA-N 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Laminated Bodies (AREA)
Abstract
The utility model discloses a kind of antifog corrosion-resistant energy-saving film for civilian ship bridge glass, the corrosion-resistant anti-fog thin film stealthy for ship bridge glass includes bridge substrate of glass (0), the bridge substrate of glass (0) includes A faces and B faces, different functional film systems are respectively arranged with the A faces and B faces, A faces are electric heating energy-saving membrane system, B faces are hydrophobic membrane system, and the electric heating energy-saving membrane system is followed successively by electric heating energy-saving functional layer and corrosion-resistant hydrophobic film layer from inside to outside by bridge substrate of glass (0).The utility model possesses outstanding electric heating anti-fog performance, energy-efficient performance, decay resistance and hydrophobic performance, and membrane system adhesive force is strong, and dense uniform, color are soft.
Description
Technical field
The utility model is related to bridge glass film manufacturing technology field, and in particular to one kind is used for civilian ship bridge glass
The antifog corrosion-resistant energy-saving film of glass.
Background technology
Civilian ship is long-term to work on sea and surface navigation, with humidity, salt content is high the characteristics of, due to high latitude
Temperature change with low latitudes is larger, often brings fogging phenomenon, has a strong impact on navigation safety, meanwhile, infrared ray on sea,
Ultraviolet brings injury to staff, electronic component in cabin.Effectively improve control visible ray, infrared ray, the energy of ultraviolet
Power, has larger help to the craftmanship of ship personnel and part, so as to save ship energy loss, improves life comfort level.
Finally, humidity and salinity height have higher corrosion-resistant requirement to membrane system, it is necessary to assure enough life-spans.Therefore, inside and outside glass
Surface coats one or more layers nesa coating, meets enough daylighting demands, realizes that antifog, energy-conservation, corrosion-resistant etc. are comprehensive
It is required that the problem of turning into urgent need to resolve.
At present, a kind of good antifog corrosion-resistant energy-saving film for civilian ship bridge glass of anti-fog energy-saving is lacked.
Utility model content
The purpose of this utility model be in view of the above-mentioned problems, provide a kind of anti-fog energy-saving it is good be used for civilian ship bridge glass
The antifog corrosion-resistant energy-saving film of glass.
To reach above-mentioned purpose, the utility model employs following technical proposal：It is of the present utility model a kind of for civilian
The antifog corrosion-resistant energy-saving film of ship bridge glass, the corrosion-resistant anti-fog thin film stealthy for ship bridge glass includes
Bridge substrate of glass, the bridge substrate of glass includes being respectively arranged with different functions on A faces and B faces, the A faces and B faces
Membrane system, A faces are electric heating energy-saving membrane system, and B faces are hydrophobic membrane system, and the electric heating energy-saving membrane system is by bridge substrate of glass by introversion
It is followed successively by electric heating energy-saving functional layer and corrosion-resistant hydrophobic film layer outside；Described hydrophobic membrane system by bridge substrate of glass from inside to outside
It is followed successively by the second silicon oxide layer, the second indium tin oxide layer and outer polytetrafluoroethylene floor.
Further, the A is towards being inner side in ship bridge glass, the B towards being outside outside ship bridge glass,
The electric heating energy-saving functional layer be followed successively by from inside to outside the first silicon oxide layer, the first indium tin oxide layer, the first layer of titanium metal and
Titanium nitride layer, the thickness of the first silicon oxide layer film layer is 10~20nm, and the thickness of the first indium tin oxide layer film layer is
50~100nm, the thickness of the first layer of titanium metal film layer is 6~8nm, the thickness of the titanium nitride layer film layer for 30~
50nm。
Further, the corrosion-resistant hydrophobic layer is followed successively by silicon nitride layer, the second silicon oxide layer and cohesion four from inside to outside
PVF layer, the thickness of the silicon nitride layer film layer is 30~60nm, the thickness of the second silicon oxide layer film layer for 10~
30nm, the thickness of the film layer of the interior polytetrafluoroethylene floor is 35~55nm.
Further, the thickness of the film layer of second silicon oxide layer is 10~20nm, second indium tin oxide layer
The thickness of film layer is 25~65nm, and the thickness of the outer polytetrafluoroethylene floor film layer is 35~55nm.
Beneficial effect：The utility model possesses outstanding electric heating anti-fog performance, energy-efficient performance, decay resistance and hydrophobic
Performance, membrane system adhesive force is strong, and dense uniform, color are soft, even compact, can improve the clean-up performance of glass.
Compared with prior art, the utility model has the following advantages that：
(1) the utility model A faces internal layer realizes low resistance by the use of the materials such as tin indium oxide, Titanium, titanium nitride
Heating function, effectively can be heated to glass, with outstanding fog removal performance, meanwhile, using Titanium and indium tin oxide layer
With reference to control infrared ray enters, and realizes energy-saving effect, infrared reflection rate is more than 73%, it is seen that light transmission rate is up to 83%
More than.
(2) the utility model A faces outer layer uses titanium nitride, silicon nitride, silica, polytetrafluoroethylene (PTFE), has film layer excellent
Elegant corrosion resistance, for the protection to internal layer electric heating energy-saving film layer, meanwhile, there can be certain hydrophobic performance in outer layer, it is right
Anti-fog function plays certain booster action, it is ensured that rainy day, the navigation safety in greasy weather.
(3) the utility model B faces combine silica, tin indium oxide, polytetrafluoroethylene (PTFE) and have realized outside hydrophobic function, can
The navigation visual field of greasy weather, rainy day are effectively improved, further improves navigation safety, and improve spatter property.Glass both sides water contact angle
Up to more than 110 degree.
(4) normal/cruise state is combined, outermost layer coating hydrophobic layer is not only advantageous to solve film layer anti-fog function, simultaneously
Also the clean-up performance of glass can be improved.Polytetrafluoroethylene (PTFE), tin indium oxide, titanium nitride, silica, the metal of the utility model use
Titanium etc. belongs to rub resistance resistant material, is favorably improved the corrosion resistance of whole film layer, improves service life.By
Line or off-line coated technology are sequentially depositing multi-layer transparent in the bridge clear glass both sides of civilian ship according to above design requirement
Film layer, integrates the cut-off for realizing infrared ray and ultraviolet, the high-permeability energy of visible ray, low resistance characteristic, using hydrophobic film layer
Performance easy to clean is realized, with reference to electric heating anti-fog function, the common multifunctionality for completing film layer.Above film layer uses corrosion-resistant material
Material, and corrosion-resistant film layer raising decay resistance is combined, increase service life.
(5) on the basis of enough light transmittances are ensured, the method that film combination is plated using glass two sides effectively combines metal
Nitride, oxide, with reference to matching relationship between the materials such as polytetrafluoroethylene (PTFE), it is comprehensive realize civilian bridge electric heating anti-fog,
Corrosion-resistant, energy-conservation, the two-sided function such as hydrophobic, film have the advantages that adhesive force is strong, color is soft, energy-efficient performance good.
Brief description of the drawings
Fig. 1 is a kind of antifog corrosion-resistant energy-saving film of civilian ship bridge glass of the present utility model；
Wherein, 0 bridge substrate of glass, to A faces, the silicon oxide layers of 1-11 first, the indium tin oxide layers of 1-12 first, 1-13 first
Layer of titanium metal, 1-14 titanium nitride layers, 1-21 silicon nitride layers, the silicon oxide layers of 1-22 second, polytetrafluoroethylene floor in 1-23, to B faces,
The outer polytetrafluoroethylene floor of the silicon oxide layers of 2-11 the 3rd, the indium tin oxide layers of 2-12 second, 2-13.
Embodiment
It is new to this practicality below with reference to accompanying drawing to make the purpose of this utility model, technical scheme and advantage clearer
The embodiment of type is described in further detail.
Embodiment 1
A kind of antifog corrosion-resistant energy-saving film for civilian ship bridge glass of the present utility model, it is described to be used for ship
The stealthy corrosion-resistant anti-fog thin film of bridge glass includes bridge substrate of glass 0, and the bridge substrate of glass 0 includes A faces and B faces,
Different functional film systems are respectively arranged with the A faces and B faces, A faces are electric heating energy-saving membrane system, and B faces are hydrophobic membrane system, described
Electric heating energy-saving membrane system is followed successively by electric heating energy-saving functional layer and corrosion-resistant hydrophobic film layer from inside to outside by bridge substrate of glass 0；
Described hydrophobic membrane system is followed successively by the second silicon oxide layer 2-11, the second indium tin oxide layer 2- from inside to outside by bridge substrate of glass 0
12 and outer polytetrafluoroethylene floor 2-13.
The A towards being inner side in ship bridge glass, the B towards being outside outside ship bridge glass, the electricity plus
Thermal center energy functional layer is followed successively by the first silicon oxide layer 1-11, the first indium tin oxide layer 1-12, the first layer of titanium metal 1- from inside to outside
13 and titanium nitride layer 1-14, the thickness of the first silicon oxide layer 1-11 film layers is 10nm, the first indium tin oxide layer 1-12
The thickness of film layer is 100nm, and the thickness of the first layer of titanium metal 1-13 film layers is 6nm, the titanium nitride layer 1-14 film layers
Thickness is 40nm.
The corrosion-resistant hydrophobic layer is followed successively by silicon nitride layer 1-21, the second silicon oxide layer 1-22 and interior polytetrafluoro from inside to outside
Pvdf layer 1-23, the thickness of the silicon nitride layer 1-21 film layers is 30nm, and the thickness of the second silicon oxide layer 1-22 film layers is
30nm, the thickness of the film layer of the interior polytetrafluoroethylene floor 1-23 is 35nm.
Described hydrophobic membrane system is followed successively by the second silicon oxide layer 2-11, the second indium tin oxide layer 2-12 and outer poly- from inside to outside
Tetrafluoroethene layer 2-13, the thickness of the film layer of the second silicon oxide layer 2-11 is 15nm, the second indium tin oxide layer 2-12
The thickness of film layer is 25nm, and the thickness of the outer polytetrafluoroethylene floor 2-13 film layers is 45nm.
Embodiment 2
The difference of embodiment 2 and embodiment 1 is：It is of the present utility model a kind of for the antifog of civilian ship bridge glass
Corrosion-resistant energy-saving film, the corrosion-resistant anti-fog thin film stealthy for ship bridge glass includes bridge substrate of glass 0, described
A is towards being inner side in ship bridge glass, and the B is towards being outside, the electric heating energy-saving functional layer outside ship bridge glass
The first silicon oxide layer 1-11, the first indium tin oxide layer 1-12, the first layer of titanium metal 1-13 and titanium nitride layer are followed successively by from inside to outside
1-14, the thickness of the first silicon oxide layer 1-11 film layers is 16nm, and the thickness of the first indium tin oxide layer 1-12 film layers is
50nm, the thickness of the first layer of titanium metal 1-13 film layers is 7nm, and the thickness of the titanium nitride layer 1-14 film layers is 30nm.
The thickness of the silicon nitride layer 1-21 film layers is 60nm, and the thickness of the second silicon oxide layer 1-22 film layers is
10nm, the thickness of the film layer of the interior polytetrafluoroethylene floor 1-23 is 55nm.
The thickness of the film layer of the second silicon oxide layer 2-11 is 10nm, the thickness of the second indium tin oxide layer 2-12 film layers
Spend for 45nm, the thickness of the outer polytetrafluoroethylene floor 2-13 film layers is 35nm.
Embodiment 3
The difference of embodiment 3 and embodiment 1 is：It is of the present utility model a kind of for the antifog of civilian ship bridge glass
Corrosion-resistant energy-saving film, the A is towards being inner side in ship bridge glass, and the B is towards being outside, institute outside ship bridge glass
State electric heating energy-saving functional layer and be followed successively by the first silicon oxide layer 1-11, the first indium tin oxide layer 1-12, the first metal from inside to outside
Titanium layer 1-13 and titanium nitride layer 1-14, the thickness of the first silicon oxide layer 1-11 film layers is 20nm, first tin indium oxide
The thickness of layer 1-12 film layers is 80nm, and the thickness of the first layer of titanium metal 1-13 film layers is 8nm, the titanium nitride layer 1-14 films
The thickness of layer is 50nm.
The thickness of the silicon nitride layer 1-21 film layers is 50nm, and the thickness of the second silicon oxide layer 1-22 film layers is
20nm, the thickness of the film layer of the interior polytetrafluoroethylene floor 1-23 is 45nm.
Described hydrophobic membrane system is followed successively by the second silicon oxide layer 2-11, the second indium tin oxide layer 2-12 and outer poly- from inside to outside
Tetrafluoroethene layer 2-13, the thickness of the film layer of the second silicon oxide layer 2-11 is 20nm, the second indium tin oxide layer 2-12
The thickness of film layer is 65nm, and the thickness of the outer polytetrafluoroethylene floor 2-13 film layers is 55nm.
Although more having used bridge substrate of glass 0, the first silicon oxide layer 1-11, the first indium tin oxide layer 1- herein
12nd, the first layer of titanium metal 1-13, titanium nitride layer 1-14, silicon nitride layer 1-21, the second silicon oxide layer 1-22, interior polytetrafluoroethylene floor
The terms such as 1-23, the 3rd silicon oxide layer 2-11, the second indium tin oxide layer 2-12, outer polytetrafluoroethylene floor 2-13, but be not precluded from
Use the possibility of other terms.It is used for the purpose of more easily describing and explaining of the present utility model using these terms
Matter；Any additional limitation is construed as all to disagree with the utility model spirit.
Specific embodiment described herein is only to the utility model spirit explanation for example.The utility model institute
Category those skilled in the art can make various modifications or supplement or using similar to described specific embodiment
Mode substitute, but without departing from spirit of the present utility model or surmount scope defined in appended claims.
Claims (4)
1. a kind of antifog corrosion-resistant energy-saving film for civilian ship bridge glass, it is characterised in that：It is described to be used for ship warship
The stealthy corrosion-resistant anti-fog thin film of bridge glass includes bridge substrate of glass (0), and the bridge substrate of glass (0) includes A faces and B
Different functional film systems are respectively arranged with face, the A faces and B faces, A faces are electric heating energy-saving membrane system, and B faces are hydrophobic membrane system,
The electric heating energy-saving membrane system is followed successively by electric heating energy-saving functional layer and corrosion-resistant hydrophobic from inside to outside by bridge substrate of glass (0)
Film layer；Described hydrophobic membrane system is followed successively by the second silicon oxide layer (2-11), the second oxidation from inside to outside by bridge substrate of glass (0)
Indium tin layer (2-12) and outer polytetrafluoroethylene floor (2-13).
2. the antifog corrosion-resistant energy-saving film according to claim 1 for civilian ship bridge glass, it is characterised in that：
The A is towards being inner side in ship bridge glass, and the B is towards being outside, the electric heating energy-saving work(outside ship bridge glass
Ergosphere is followed successively by the first silicon oxide layer (1-11), the first indium tin oxide layer (1-12), the first layer of titanium metal (1-13) from inside to outside
With titanium nitride layer (1-14), the thickness of the first silicon oxide layer (1-11) film layer is 10~20nm, first tin indium oxide
The thickness of layer (1-12) film layer is 50~100nm, and the thickness of the first layer of titanium metal (1-13) film layer is 6~8nm, the nitrogen
The thickness for changing titanium layer (1-14) film layer is 30~50nm.
3. the antifog corrosion-resistant energy-saving film according to claim 1 for civilian ship bridge glass, it is characterised in that：
The corrosion-resistant hydrophobic layer is followed successively by silicon nitride layer (1-21), the second silicon oxide layer (1-22) and interior polytetrafluoroethylene (PTFE) from inside to outside
Layer (1-23), the thickness of silicon nitride layer (1-21) film layer is 30~60nm, the second silicon oxide layer (1-22) film layer
Thickness is 10~30nm, and the thickness of the film layer of the interior polytetrafluoroethylene floor (1-23) is 35~55nm.
4. the antifog corrosion-resistant energy-saving film for civilian ship bridge glass according to any one of claims 1 to 3, its
It is characterised by：The thickness of the film layer of second silicon oxide layer (2-11) is 10~20nm, the second indium tin oxide layer (2-
12) thickness of film layer is 25~65nm, and the thickness of outer polytetrafluoroethylene floor (2-13) film layer is 35~55nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201720217123.XU CN206553407U (en) | 2017-03-07 | 2017-03-07 | Antifog corrosion-resistant energy-saving film for civilian ship bridge glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201720217123.XU CN206553407U (en) | 2017-03-07 | 2017-03-07 | Antifog corrosion-resistant energy-saving film for civilian ship bridge glass |
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| Publication Number | Publication Date |
|---|---|
| CN206553407U true CN206553407U (en) | 2017-10-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201720217123.XU Expired - Fee Related CN206553407U (en) | 2017-03-07 | 2017-03-07 | Antifog corrosion-resistant energy-saving film for civilian ship bridge glass |
Country Status (1)
| Country | Link |
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| CN (1) | CN206553407U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106854043A (en) * | 2017-03-07 | 2017-06-16 | 郑州航空工业管理学院 | For the antifog corrosion-resistant energy-saving film and preparation method of civilian ship bridge glass |
-
2017
- 2017-03-07 CN CN201720217123.XU patent/CN206553407U/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106854043A (en) * | 2017-03-07 | 2017-06-16 | 郑州航空工业管理学院 | For the antifog corrosion-resistant energy-saving film and preparation method of civilian ship bridge glass |
| CN106854043B (en) * | 2017-03-07 | 2023-04-28 | 郑州航空工业管理学院 | Antifog corrosion-resistant energy-saving film for civil ship bridge glass and preparation method thereof |
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