CN206530370U - Using the Brayton Cycle system of supercritical carbon dioxide - Google Patents

Using the Brayton Cycle system of supercritical carbon dioxide Download PDF

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CN206530370U
CN206530370U CN201720083907.8U CN201720083907U CN206530370U CN 206530370 U CN206530370 U CN 206530370U CN 201720083907 U CN201720083907 U CN 201720083907U CN 206530370 U CN206530370 U CN 206530370U
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temperature regenerator
regenerator
boiler
outlet
high temperature
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徐钢
白子为
薛小军
张国强
杨勇平
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North China Electric Power University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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Abstract

The utility model discloses a kind of Brayton Cycle system for the use supercritical carbon dioxide for belonging to power station energy-saving field, the circulatory system is main to be made up of boiler hearth heating surface, heated surface at the end of boiler, air preheater, boiler back end ductwork, cycle fluid bypass duct, high temperature regenerator, middle temperature regenerator, cryogenic regenerator, working medium turbine, high temperature compressor, a cold pressing mechanism of qi and cooler.By the way that boiler hearth heating surface is rearranged, the bypass of high temperature regenerator is set, so as to match newly-designed supercritical carbon dioxide cycle heat exchange demand;Improve cycle efficieny;Improve low-temperature flue gas utility;Improve air preheater caloric receptivity distribution, the design heat exchange amount for being optimized to correspondence air preheater in being circulated substantially with coal-fired steam is identical;Using a cold compression technology, cycle efficieny is improved, the heat exchange for optimizing cooler is interval, is allowed to match with water-cooling system.In addition the system architecture is simple, and operational efficiency is high, there is preferable application prospect in engineering.

Description

采用超临界二氧化碳的布雷顿循环系统Brayton cycle system using supercritical carbon dioxide

技术领域technical field

本实用新型属于电站节能领域,特别涉及一种采用超临界二氧化碳的布雷顿循环系统。The utility model belongs to the field of power station energy saving, in particular to a Brayton cycle system using supercritical carbon dioxide.

背景技术Background technique

超临界二氧化碳(S-CO2)布雷顿循环是以处于超临界状态的二氧化碳(临界压力7.38MPa,临界温度31.05℃)为工质,采用布雷顿循环原理实现能量转换的一种循环方式。The supercritical carbon dioxide (S-CO 2 ) Brayton cycle is a cycle mode in which carbon dioxide in a supercritical state (critical pressure 7.38MPa, critical temperature 31.05°C) is used as the working medium, and the principle of Brayton cycle is used to realize energy conversion.

采用超临界流体作为循环工质,是为了利用流体在超临界点附近的高密度、低黏性等优势,降低压气机耗功、提高循环效率。而且超临界二氧化碳具有无毒、储量丰富、成本低、性能稳定、密度大、临界温度和压力相对低等特点,被认为最佳循环工质之一。当前大规模使用的蒸汽动力循环相比,超临界二氧化碳布雷顿循环高温(一般高于400℃)下的能量转换效率更高,且其系统紧凑,设备体积小(涡轮系统和冷却设备的体积仅相当于蒸汽系统对应设备体积的十分之一),易于模块化建设,具备良好的潜在经济性;与常规气体布雷顿循环相比,其压缩过程参数位于工质临界点附近的特点使得压缩功耗显著降低,循环效率明显提高。The use of supercritical fluid as the circulating working medium is to take advantage of the advantages of high density and low viscosity of the fluid near the supercritical point to reduce the power consumption of the compressor and improve the cycle efficiency. Moreover, supercritical carbon dioxide has the characteristics of non-toxicity, abundant reserves, low cost, stable performance, high density, relatively low critical temperature and pressure, and is considered one of the best circulating working fluids. Compared with the steam power cycle currently used on a large scale, the supercritical carbon dioxide Brayton cycle has higher energy conversion efficiency at high temperature (generally higher than 400°C), and its system is compact and the equipment volume is small (the volume of the turbine system and cooling equipment is only It is equivalent to one tenth of the corresponding equipment volume of the steam system), which is easy to be modularized and has good potential economy; compared with the conventional gas Brayton cycle, its compression process parameters are located near the critical point of the working medium, making the compression work The consumption is significantly reduced and the cycle efficiency is significantly improved.

超临界二氧化碳在二十世纪六十年代被提出作为动力循的工质,然而当时由于技术限制,没有得到普遍应用。近年来,随着技术水平的提高,超临界二氧化碳在核反应堆方面的应用得到了国内外学者及研究机构的广泛关注和研究,其与塔式太阳能吸热器结合也广泛开展,然而对于目前占据最主要发电方式的燃煤锅炉,超临界二氧化碳在其中的应用却发展较为缓慢。Supercritical carbon dioxide was proposed as a working fluid in the power cycle in the 1960s, but it was not widely used due to technical limitations at that time. In recent years, with the improvement of technology level, the application of supercritical carbon dioxide in nuclear reactors has been widely concerned and researched by scholars and research institutions at home and abroad, and its combination with tower solar heat absorbers has also been widely carried out. Coal-fired boilers are the main power generation methods, but the application of supercritical carbon dioxide in them develops relatively slowly.

大型火电机组的节能减排是中国的重要能源战略。为适应电力市场的快速发展和节能减排的巨大压力,我们迫切需要寻找新的途径来提高电厂的效率,这已成为各电厂日益重视的课题。Energy conservation and emission reduction of large thermal power units is an important energy strategy in China. In order to adapt to the rapid development of the electricity market and the huge pressure of energy conservation and emission reduction, we urgently need to find new ways to improve the efficiency of power plants, which has become a topic that every power plant pays more and more attention to.

实用新型内容Utility model content

本实用新型的目的是针对现有技术的不足,提出了一种采用超临界二氧化碳的布雷顿循环系统,其特征在于:对锅炉炉膛受热面进行重新设计,在锅炉尾部烟道中依次布置锅炉尾部受热面4和空气预热器3;锅炉炉膛受热面1出口与工质透平5入口相连,工质透平5出口与高温回热器6连接,高温回热器6与中温回热器7相连,中温回热器7与低温回热器8相连,低温回热器8出口分别与高温压气机9和第一凝汽器12相连,高温压气机9出口与中温回热器7和低温回热器8之间通过管路15连接,在高温回热器6和中温回热器7之间通过管路14连接,在高温回热器6和中温回热器7之间的管路14上再连接高温回热器旁路 16,高温回热器旁路16经过锅炉尾部受热面4与高温回热器6出口一同汇入到锅炉炉膛受热面1;第一凝汽器12出口与第一间冷压气机10相连,第一间冷压气机10出口与第二凝汽器13相连,第二凝汽器13出口与第二间冷压气机11相连,第二间冷压气机11出口与低温回热器8相连。The purpose of this utility model is to address the deficiencies in the prior art and propose a Brayton cycle system using supercritical carbon dioxide, which is characterized in that: the heating surface of the boiler furnace is redesigned, and the boiler tail is arranged sequentially in the boiler tail flue to receive heat Surface 4 and air preheater 3; the outlet of boiler furnace heating surface 1 is connected to the inlet of working medium turbine 5, the outlet of working medium turbine 5 is connected to high temperature regenerator 6, and the high temperature regenerator 6 is connected to medium temperature regenerator 7 , the medium-temperature regenerator 7 is connected to the low-temperature regenerator 8, the outlet of the low-temperature regenerator 8 is connected to the high-temperature compressor 9 and the first condenser 12, and the outlet of the high-temperature compressor 9 is connected to the medium-temperature regenerator 7 and the low-temperature regenerator The regenerators 8 are connected by a pipeline 15, the high temperature regenerator 6 and the medium temperature regenerator 7 are connected by a pipeline 14, and the pipeline 14 between the high temperature regenerator 6 and the medium temperature regenerator 7 is further Connect the high temperature regenerator bypass 16, the high temperature regenerator bypass 16 flows into the boiler furnace heating surface 1 through the boiler tail heating surface 4 and the high temperature regenerator 6 outlet together; the first condenser 12 outlet and the first room The cold compressor 10 is connected, the outlet of the first cold compressor 10 is connected with the second condenser 13, the outlet of the second condenser 13 is connected with the second cold compressor 11, and the outlet of the second cold compressor 11 is connected with the low temperature Regenerator 8 is connected.

所述在高温回热器6和中温回热器7之间设置高温回热器旁路16,其入口温度为320℃,出口温度为470℃,从而有效利用了350℃-500℃的低温烟气热量,提高了系统循环效率。The high-temperature regenerator bypass 16 is set between the high-temperature regenerator 6 and the medium-temperature regenerator 7, the inlet temperature is 320°C, and the outlet temperature is 470°C, thereby effectively utilizing the low-temperature smoke at 350°C-500°C Gas heat, improve the system cycle efficiency.

所述两个间冷压气机的间冷压缩,提高了循环系统的循环效率,使冷却器的换热温度维持在30℃-80℃之间,与水冷系统温度匹配良好。The intercooling compression of the two intercooling compressors improves the circulation efficiency of the circulation system and maintains the heat exchange temperature of the cooler between 30° C. and 80° C., which is well matched with the temperature of the water cooling system.

所述锅炉尾部烟道依次布置锅炉尾部受热面4和空气预热器3,使该循环中空气预热器换热烟气范围在100℃-350℃,换热量基本与燃煤蒸汽循环中对应空气预热器的设计换热量相同,从而优化了空预器的传热特性。The flue at the tail of the boiler is arranged in sequence with the heating surface 4 at the tail of the boiler and the air preheater 3, so that the heat exchange range of the air preheater in this cycle is 100°C-350°C, and the heat transfer is basically the same as that in the coal-fired steam cycle. The design heat transfer capacity of the corresponding air preheater is the same, thus optimizing the heat transfer characteristics of the air preheater.

本实用新型的有益效果为:The beneficial effects of the utility model are:

1.该系统在高温回热器外设置了高温回热器旁路,部分来自于中温回热器的工质直接进入到锅炉尾部烟道中吸收低温烟气热量,最后与高温回热器出口的工质混合,一同汇入到锅炉炉膛受热面中。这一旁路优化了系统结构,改善了锅炉低温烟气的吸收性能,吸收了350℃-500℃之间烟气热量,提高了系统循环效率。1. The system has a high-temperature regenerator bypass outside the high-temperature regenerator. Part of the working fluid from the medium-temperature regenerator directly enters the tail flue of the boiler to absorb the heat of low-temperature flue gas, and finally connects with the outlet of the high-temperature regenerator. The working fluids are mixed and flow into the heating surface of the boiler furnace together. This bypass optimizes the system structure, improves the absorption performance of the low-temperature flue gas of the boiler, absorbs the heat of the flue gas between 350°C and 500°C, and improves the cycle efficiency of the system.

2.将锅炉炉膛受热面重新布置,以匹配新设计的超临界二氧化碳循环换热特性,使得换热高效紧凑,并保证了锅炉的稳定运行。2. Rearrange the heating surface of the boiler furnace to match the heat transfer characteristics of the newly designed supercritical carbon dioxide cycle, making the heat transfer efficient and compact, and ensuring the stable operation of the boiler.

3.该系统采用间冷压缩技术,不仅提高了系统循环效率,也优化了冷凝器的换热温度范围,使之与水冷系统互匹配。3. The system adopts intercooling compression technology, which not only improves the cycle efficiency of the system, but also optimizes the heat transfer temperature range of the condenser to match it with the water cooling system.

4.该系统无再热循环,简化了控制系统与炉膛布置,具有进一步效率提升空间,在工程上会有很好的应用前景。如控制系统足够先进,可通过加设再热循环进一步提升本系统效果。4. The system has no reheating cycle, which simplifies the control system and furnace layout, has room for further efficiency improvement, and has a good application prospect in engineering. If the control system is advanced enough, the effect of the system can be further improved by adding a reheat cycle.

5.该系统布置方案适用性广,可根据机组参数以及冷却方式的不同,决定是否采用间冷压缩。5. The system layout scheme has wide applicability, and it can be decided whether to use intercooling compression according to the parameters of the unit and the cooling method.

附图说明Description of drawings

图1为超临界二氧化碳布雷顿循环系统示意图。Figure 1 is a schematic diagram of a supercritical carbon dioxide Brayton cycle system.

具体实施方式detailed description

本实用新型提出一种采用超临界二氧化碳的布雷顿循环系统。下面结合附图和实例予以说明。The utility model proposes a Brayton cycle system using supercritical carbon dioxide. The following will be described in conjunction with the accompanying drawings and examples.

如图1所示为超临界二氧化碳布雷顿循环系统示意图,本实用新型对锅炉炉膛受热面进行重新设计,在锅炉尾部烟道中依次布置锅炉尾部受热面4和空气预热器3;锅炉炉膛受热面1出口与工质透平5入口相连,工质透平5出口与高温回热器6连接,高温回热器6与中温回热器7相连,中温回热器7与低温回热器8相连,低温回热器8出口分别与高温压气机9和第一凝汽器12相连,高温压气机9出口与中温回热器7和低温回热器8之间通过管路15连接,在高温回热器6和中温回热器7 之间通过管路14连接,在高温回热器6和中温回热器7之间的管路14上再连接高温回热器旁路16,高温回热器旁路16经过锅炉尾部受热面4与高温回热器6出口一同汇入到锅炉炉膛受热面1;从而使锅炉炉膛受热面与新设计的超临界二氧化碳循环匹配,优化了受热面布置,保证了锅炉的高效运行。As shown in Figure 1, it is a schematic diagram of the supercritical carbon dioxide Brayton cycle system. The utility model redesigns the boiler furnace heating surface, and arranges the boiler tail heating surface 4 and the air preheater 3 in sequence in the boiler tail flue; the boiler furnace heating surface The outlet of 1 is connected to the inlet of working fluid turbine 5, the outlet of working fluid turbine 5 is connected to high temperature regenerator 6, the high temperature regenerator 6 is connected to medium temperature regenerator 7, and the medium temperature regenerator 7 is connected to low temperature regenerator 8 , the outlet of the low-temperature regenerator 8 is connected to the high-temperature compressor 9 and the first condenser 12 respectively, and the outlet of the high-temperature compressor 9 is connected to the medium-temperature regenerator 7 and the low-temperature regenerator 8 through a pipeline 15. The heater 6 and the medium temperature regenerator 7 are connected through a pipeline 14, and the high temperature regenerator bypass 16 is connected to the pipeline 14 between the high temperature regenerator 6 and the medium temperature regenerator 7, and the high temperature regenerator The bypass 16 flows into the boiler furnace heating surface 1 through the boiler tail heating surface 4 and the outlet of the high-temperature regenerator 6; thus, the boiler furnace heating surface matches the newly designed supercritical carbon dioxide cycle, optimizes the layout of the heating surface, and ensures efficient operation of the boiler.

所述循环系统的第一凝汽器12出口与第一间冷压气机10相连,第一间冷压气机10出口与第二凝汽器13相连,第二凝汽器13出口与第二间冷压气机11相连,第二间冷压气机11出口与低温回热器8相连,即两个间冷压气机采用间冷压缩技术,提高了循环系统的循环效率,使冷却器的换热温度维持在30℃-80℃之间,与水冷系统温度匹配良好。The outlet of the first condenser 12 of the circulation system is connected with the first intercooler compressor 10, the outlet of the first intercooler compressor 10 is connected with the second condenser 13, and the outlet of the second condenser 13 is connected with the second intercooler. The cold compressor 11 is connected, and the outlet of the second inter-cooled compressor 11 is connected with the low-temperature regenerator 8, that is, the two inter-cooled compressors adopt the inter-cooled compression technology, which improves the circulation efficiency of the circulation system and makes the heat exchange temperature of the cooler It is maintained between 30°C and 80°C, which matches well with the temperature of the water cooling system.

所述在高温回热器6和中温回热器7之间设置高温回热器旁路16,其入口温度为320℃,出口温度为470℃,从而有效利用了350℃-500℃的低温烟气热量,提高了系统循环效率。The high-temperature regenerator bypass 16 is set between the high-temperature regenerator 6 and the medium-temperature regenerator 7, the inlet temperature is 320°C, and the outlet temperature is 470°C, thereby effectively utilizing the low-temperature smoke at 350°C-500°C Gas heat, improve the system cycle efficiency.

所述锅炉尾部烟道依次布置锅炉尾部受热面4和空气预热器3,使该循环中空气预热器换热烟气范围在100℃-350℃,换热量基本与燃煤蒸汽循环中对应空气预热器的设计换热量相同,从而优化了空预器的传热特性。The flue at the tail of the boiler is arranged in sequence with the heating surface 4 at the tail of the boiler and the air preheater 3, so that the heat exchange range of the air preheater in this cycle is 100°C-350°C, and the heat transfer is basically the same as that in the coal-fired steam cycle. The design heat transfer capacity of the corresponding air preheater is the same, thus optimizing the heat transfer characteristics of the air preheater.

本实用新型首次提出了在超临界二氧化碳布雷顿循环系统中设置高温回热器旁路,一部分中温回热器出口工质直接进入到之后的的高温回热器;另一部分中温回热器出口工质先进入到炉膛尾部换热面吸热,从而吸收炉膛尾部余热,减少空气预热器设计时不必要的吸热,并提高了系统循环效率。最终达到了充分合理利用锅炉中烟气温度分布,分级利用烟气能量,在保证超临界二氧化碳布雷顿循环高效的同时,合理有效的将系统与燃煤锅炉耦合起来,解决了尾部低温烟气无法高效合理利用,超规格布置空气预热器吸热量的问题。同时,本发明可根据需要灵活布置(多级)再热循环与间冷压缩,使得整体超临界二氧化碳布雷顿循环在工程实际中的应用前景大幅提高,可实施性显著。The utility model proposes for the first time that a high-temperature regenerator bypass is set in the supercritical carbon dioxide Brayton cycle system, and a part of the medium-temperature regenerator outlet directly enters the subsequent high-temperature regenerator; another part of the medium-temperature regenerator outlet works The mass first enters the heat exchange surface at the end of the furnace to absorb heat, thereby absorbing the waste heat at the end of the furnace, reducing unnecessary heat absorption during the design of the air preheater, and improving the cycle efficiency of the system. Finally, the temperature distribution of the flue gas in the boiler is fully and reasonably utilized, and the energy of the flue gas is utilized in stages. While ensuring the high efficiency of the supercritical carbon dioxide Brayton cycle, the system is reasonably and effectively coupled with the coal-fired boiler, which solves the problem that the tail low-temperature flue gas cannot Efficient and reasonable use, the problem of heat absorption of the air preheater arranged beyond the specification. At the same time, the present invention can flexibly arrange (multi-stage) reheating cycle and intercooling compression according to needs, so that the application prospect of the overall supercritical carbon dioxide Brayton cycle in engineering practice is greatly improved, and the implementability is remarkable.

Claims (4)

1. a kind of Brayton Cycle system of use supercritical carbon dioxide, it is characterised in that:To boiler hearth heating surface (1) weight New design, heated surface at the end of boiler (4) and air preheater (3) are sequentially arranged in boiler back end ductwork (2);Boiler furnace is heated Face (1) outlet is connected with working medium turbine (5) entrance, and working medium turbine (5) outlet is connected with high temperature regenerator (6), high temperature regenerator (6) it is connected with middle temperature regenerator (7), middle temperature regenerator (7) is connected with cryogenic regenerator (8), cryogenic regenerator (8) outlet difference It is connected with high temperature compressor (9) and the first condenser (12), high temperature compressor (9) outlet is returned with middle temperature regenerator (7) and low temperature Connected between hot device (8) by pipeline (15), between high temperature regenerator (6) and middle temperature regenerator (7) by pipeline (14) even Connect, high temperature regenerator bypass (16) is reconnected on the pipeline (14) between high temperature regenerator (6) and middle temperature regenerator (7), it is high Warm regenerator bypass (16) by heated surface at the end of boiler (4) and high temperature regenerator (6) outlet be together imported into boiler furnace by Hot face (1);First condenser (12) is exported to be connected with being cold-pressed mechanism of qi (10) between first, and mechanism of qi (10) outlet and the are cold-pressed between first Two condensers (13) are connected, and the second condenser (13) outlet is connected with being cold-pressed mechanism of qi (11) between second, and mechanism of qi is cold-pressed between second (11) outlet is connected with cryogenic regenerator (8).
2. the Brayton Cycle system of supercritical carbon dioxide is used according to claim 1, it is characterised in that:It is described in height High temperature regenerator bypass (16) is set between warm regenerator (6) and middle temperature regenerator (7), and its inlet temperature is 320 DEG C, outlet temperature Spend for 470 DEG C, so as to be effectively utilized 350 DEG C -500 DEG C of low-temperature flue gas heat, improve system circulation efficiency.
3. the Brayton Cycle system of supercritical carbon dioxide is used according to claim 1, it is characterised in that:It is described two Between cold pressing mechanism of qi use between cold compression, improve the cycle efficieny of the circulatory system, make cooler heat-exchange temperature maintain 30 DEG C- It is good with water-cooling system Temperature Matching between 80 DEG C.
4. the Brayton Cycle system of supercritical carbon dioxide is used according to claim 1, it is characterised in that:The boiler Back-end ductwork is sequentially arranged heated surface at the end of boiler (4) and air preheater (3), makes air preheater heat exchange flue gas in the circulation Scope is at 100 DEG C -350 DEG C, and the design heat exchange amount of correspondence air preheater is identical during heat exchange amount is circulated with coal-fired steam substantially, from And optimize the heat-transfer character of air preheater.
CN201720083907.8U 2017-01-22 2017-01-22 Using the Brayton Cycle system of supercritical carbon dioxide Expired - Fee Related CN206530370U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106870037A (en) * 2017-01-22 2017-06-20 华北电力大学 A kind of supercritical carbon dioxide Brayton Cycle system
CN108005744A (en) * 2017-12-26 2018-05-08 华北电力大学 Supercritical CO2The machine furnace cooling of circulation can recycle and power generation and heat supply integral system
CN111442284A (en) * 2020-04-07 2020-07-24 安徽楚江高新电材有限公司 Oxygen supplementing and preheating device of incinerator
CN113623039A (en) * 2021-09-17 2021-11-09 西安热工研究院有限公司 Air-carbon dioxide combined cycle power generation system and method
CN108425711B (en) * 2018-03-27 2023-06-06 哈尔滨电气股份有限公司 Three-turbine coaxial supercritical carbon dioxide cycle power generation system for gas turbine waste heat recovery

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106870037A (en) * 2017-01-22 2017-06-20 华北电力大学 A kind of supercritical carbon dioxide Brayton Cycle system
CN108005744A (en) * 2017-12-26 2018-05-08 华北电力大学 Supercritical CO2The machine furnace cooling of circulation can recycle and power generation and heat supply integral system
CN108005744B (en) * 2017-12-26 2023-08-29 华北电力大学 Integrated heat supply method for recovery of cold energy and power generation in a supercritical CO2 cycle
CN108425711B (en) * 2018-03-27 2023-06-06 哈尔滨电气股份有限公司 Three-turbine coaxial supercritical carbon dioxide cycle power generation system for gas turbine waste heat recovery
CN111442284A (en) * 2020-04-07 2020-07-24 安徽楚江高新电材有限公司 Oxygen supplementing and preheating device of incinerator
CN113623039A (en) * 2021-09-17 2021-11-09 西安热工研究院有限公司 Air-carbon dioxide combined cycle power generation system and method

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