CN206521300U - It is a kind of can the light of online recycling iron catalyst help Fenton wastewater treatment equipment - Google Patents

It is a kind of can the light of online recycling iron catalyst help Fenton wastewater treatment equipment Download PDF

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Publication number
CN206521300U
CN206521300U CN201720186974.2U CN201720186974U CN206521300U CN 206521300 U CN206521300 U CN 206521300U CN 201720186974 U CN201720186974 U CN 201720186974U CN 206521300 U CN206521300 U CN 206521300U
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China
Prior art keywords
activator
light
water inlet
staving
delivery port
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CN201720186974.2U
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周健
王磊
李星桥
李锦景
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Suzhou Zhanqing Environment Protection Technology Co Ltd
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Suzhou Zhanqing Environment Protection Technology Co Ltd
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  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

It is a kind of can the light of online recycling iron catalyst help Fenton wastewater treatment equipment, Fenton reactor, iron ion activator and iron ion separator are helped including light, iron ion activator includes activator staving, activator water inlet, activator mud refluxing opening and activator delivery port are set on activator staving, activator water inlet is provided with threeway, one termination waste water, one end connects activator staving, and the other end connects activator dosing mouth;Activator delivery port, which connects light, to be helped on the water inlet and connecting line of Fenton reactor and is provided with intake pump;Iron ion separator includes pipe-line mixer, the import of pipe-line mixer connects light and helps the delivery port of Fenton reactor and alkali lye dosing mouth is provided with connecting line, the water inlet of the outlet connection hydrocyclone of pipe-line mixer, the top of hydrocyclone is system delivery port, bottom is mud discharging mouth, and mud discharging mouth is connected by pipeline with activator mud refluxing opening;The present apparatus improves treatment effeciency, reduces system dimension, and can save medicament and equipment.

Description

It is a kind of can the light of online recycling iron catalyst help Fenton wastewater treatment equipment
Technical field
The utility model belongs to environmental protection industry (epi), is related to technical field of waste water processing, more particularly to one kind can online recycling iron The light of catalyst helps Fenton wastewater treatment equipment.
Background technology
Fenton reagent method is a kind of effective ways for handling high-concentration hardly-degradable industrial organic waste water, be swift in response because of it, The features such as mild condition such as reaction temperature and pressure and be widely used.Because the core of Fenton's reaction passes through for hydrogen peroxide Ferrous ion inspires hydroxyl radical free radical, and the reaction needs substantial amounts of ferrous ion to participate in.Therefore the reaction needs to add largely Ferrous iron, on the other hand also result in more sludge and produce.
Light helps Fenton process to be a kind of new high-level oxidation technology developed based on Fenton reagent method, and its general principle is except logical Crossing ferrous ion excites hydrogen peroxide to produce outside hydroxyl radical free radical, can also directly excite hydrogen peroxide to produce hydroxyl free with ultraviolet light Base directly results in organic matter scission of link.Because ferric ion rapidly can will be reduced into ferrous iron by ultraviolet light, therefore greatly Add the potential available ferrous amount of reaction system greatly.Therefore light helps Fenton reactor to greatly improve organic wastewater Degradation rate, and reduce the yield of sludge, reactor volume is substantially reduced, and this causes light to help Fenton reactor as mould Block, integrated product are possibly realized.
But light helps Fenton process to still need to add more ferrous ion, this causes aftertreatment device larger, processing cost It is higher, the modularization of the technique and integrated application are limited to a certain extent.Iron cement is reclaimed using the method for sequence batch examination The equipment that uses of method it is larger, and recoverys must be shut down, organic efficiency and recovery quality are relatively low.At present in processing iron cement Also without related online recycling device application in field.
The content of the invention
In order to overcome the shortcoming of above-mentioned prior art, the purpose of this utility model be to provide one kind can online recycling iron urge The light of agent helps Fenton wastewater treatment equipment, and iron ion in light Fenton can be achieved and is recycled online, sequence batch examination is overcome The deficiency of recovery, greatly increases treatment effeciency, saves reagent cost and Treatment of Sludge cost.
To achieve these goals, the technical solution adopted in the utility model is:
It is a kind of can the light of online recycling iron catalyst help Fenton wastewater treatment equipment, including light to help Fenton reactor 1, iron Ion activation device and iron ion separator, wherein:
The iron ion activator includes setting activator water inlet 7, activator on activator staving 5, activator staving 5 Mud refluxing opening 8 and activator delivery port 9, activator water inlet 7 are provided with threeway, and one terminates waste water, and one end connects activator staving 5, the other end connects activator dosing mouth 6;Activator delivery port 9, which connects light, to be helped and is set on the water inlet and connecting line of Fenton reactor 1 It is equipped with intake pump 11;
The iron ion separator includes pipe-line mixer 3, and the import of pipe-line mixer 3 connects light and helps Fenton reactor 1 Delivery port and alkali lye dosing mouth 2 is provided with connecting line, the water inlet of the outlet connection hydrocyclone 4 of pipe-line mixer 3 Mouthful, the top of hydrocyclone 4 is system delivery port 10, and bottom is mud discharging mouth, and mud discharging mouth passes through pipeline and the activator mud Refluxing opening 8 is connected.
The light helps Fenton reactor 1 to use stainless steel cavity, built-in low-pressure lamp or middle pressure uviol lamp.
The water inlet of the hydrocyclone 4 is in side.
The activator staving 5 is sealed cylindrical, and interior setting dividing plate is mixed.
The hydrocyclone 4 is in the top of activator staving 5.
Compared with prior art, the beneficial effects of the utility model are:
The present apparatus employs the mode of light Fenton reactor combination online recycling iron ion, and treatment effeciency has been significantly greatly increased, Reduce the size of reactor.Online iron ion recovery system in device eliminates sludge treating system, reduces whole system The size of system.Therefore the device realizes integrated and modularized design.
The online recycling of iron ion is realized in the present apparatus, iron ion energy repetitive cycling is used, save ferrous sulfate medicament More than 90% is added, the equipment such as sludge compressor are saved.
Brief description of the drawings
Fig. 1 is the utility model structural representation (front view).
Fig. 2 is the utility model structural representation (top view).
Fig. 3 is the utility model structural representation (axonometric drawing).
Embodiment
Describe embodiment of the present utility model in detail with reference to the accompanying drawings and examples.
As shown in Figure 1, Figure 2, Figure 3 shows, it is a kind of can online recycling iron catalyst light help Fenton wastewater treatment equipment include three Individual unit:Light helps Fenton reactor 1, iron ion activator and iron ion separator.
Wherein:
Light helps Fenton reactor 1 to use stainless steel cavity, built-in low-pressure lamp or middle pressure uviol lamp.
Iron ion activator includes activator staving 5, and activator staving 5 is sealed cylindrical, and interior setting dividing plate is mixed. It is provided with three interfaces:Activator water inlet 7, activator mud refluxing opening 8 and activator delivery port 9, activator water inlet 7 are set Threeway is equipped with, a termination waste water, one end connects activator staving 5, and the other end is activator dosing mouth 6, accesses acid adding pump;Activator Delivery port 9, which connects light, to be helped intake pump 11 is provided with the water inlet and connecting line of Fenton reactor 1.
Iron ion separator includes pipe-line mixer 3, and the import of pipe-line mixer 3 connects the water outlet that light helps Fenton reactor 1 Mouthful and be provided with alkali lye dosing mouth 2 on connecting line, the water inlet of the outlet connection hydrocyclone 4 of pipe-line mixer 3, water The water inlet of power cyclone 4 is in side.The top of hydrocyclone 4 is system delivery port 10, and bottom is mud discharging mouth, and mud discharging mouth leads to Piping is connected with activator mud refluxing opening 8.Hydrocyclone 4 is easy to sludge reflux in the top of activator staving 5.
Above whole system is fixed together by framework 12.
The course of work of the present utility model:
Waste water, hydrogen peroxide and the activated device water inlet 7 of sulfuric acid enter iron ion activator, while from iron ion separator The iron cement separated enters iron ion activator by activator mud refluxing opening 8, after being mixed in iron ion activator, passes through Activator delivery port 9 flows out.Outflow water is further mixed by intake pump 11, and is pumped into light and is helped in Fenton reactor 1.Containing molten Solution property iron ion, the organic wastewater of hydrogen peroxide are helped in Fenton reactor 1 in light and are progressively degraded, and are discharged finally by delivery port. Then the alkali lye with addition is mixed in the pipe-line mixer 3 of iron ion separator, is then progressively separated in hydrocyclone 4 Out, the tail water containing a small amount of iron ion is discharged by the system delivery port 10 of iron ion separator upper end, and the iron sludge of concentration leads to The mud discharging mouth for crossing lower end is again introduced into iron ion activator.

Claims (5)

1. it is a kind of can the light of online recycling iron catalyst help Fenton wastewater treatment equipment, including light to help Fenton reactor (1), it is special Levy and be, in addition to iron ion activator and iron ion separator, wherein:
The iron ion activator includes setting activator water inlet (7), activation on activator staving (5), activator staving (5) Device mud refluxing opening (8) and activator delivery port (9), activator water inlet (7) are provided with threeway, and one terminates waste water, and one end is taken over a job Change device staving (5), the other end connects activator dosing mouth (6);Activator delivery port (9) connects the water inlet that light helps Fenton reactor (1) Intake pump (11) is provided with mouth and connecting line;
The iron ion separator includes pipe-line mixer (3), and the import of pipe-line mixer (3) connects light and helps Fenton reactor (1) Delivery port and alkali lye dosing mouth (2) is provided with connecting line, the outlet of pipe-line mixer (3) connection hydrocyclone (4) water inlet, the top of hydrocyclone (4) is system delivery port (10), and bottom is mud discharging mouth, mud discharging mouth by pipeline with Activator mud refluxing opening (8) connection.
2. according to claim 1 can the light of online recycling iron catalyst help Fenton wastewater treatment equipment, it is characterised in that institute Stating light helps Fenton reactor (1) to use stainless steel cavity, built-in low-pressure lamp or middle pressure uviol lamp.
3. according to claim 1 can the light of online recycling iron catalyst help Fenton wastewater treatment equipment, it is characterised in that institute The water inlet of hydrocyclone (4) is stated in side.
4. according to claim 1 can the light of online recycling iron catalyst help Fenton wastewater treatment equipment, it is characterised in that institute Activator staving (5) is stated for sealed cylindrical, interior setting dividing plate is mixed.
5. according to claim 1 can the light of online recycling iron catalyst help Fenton wastewater treatment equipment, it is characterised in that institute State top of the hydrocyclone (4) in activator staving (5).
CN201720186974.2U 2017-02-28 2017-02-28 It is a kind of can the light of online recycling iron catalyst help Fenton wastewater treatment equipment Active CN206521300U (en)

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CN201720186974.2U CN206521300U (en) 2017-02-28 2017-02-28 It is a kind of can the light of online recycling iron catalyst help Fenton wastewater treatment equipment

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CN201720186974.2U CN206521300U (en) 2017-02-28 2017-02-28 It is a kind of can the light of online recycling iron catalyst help Fenton wastewater treatment equipment

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675543A (en) * 2018-06-27 2018-10-19 江苏苏宁新技术应用研究所 A kind of low consumption catalytic separation device and waste water treatment system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675543A (en) * 2018-06-27 2018-10-19 江苏苏宁新技术应用研究所 A kind of low consumption catalytic separation device and waste water treatment system
CN108675543B (en) * 2018-06-27 2023-10-31 北京市惠全成环境治理工程有限责任公司 Low-consumption catalytic separation device and wastewater treatment system

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