CN206456052U - A kind of wear-resisting automotive sunshade panel eyeglass of antibacterial - Google Patents

A kind of wear-resisting automotive sunshade panel eyeglass of antibacterial Download PDF

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Publication number
CN206456052U
CN206456052U CN201720038281.9U CN201720038281U CN206456052U CN 206456052 U CN206456052 U CN 206456052U CN 201720038281 U CN201720038281 U CN 201720038281U CN 206456052 U CN206456052 U CN 206456052U
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China
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layer
eyeglass
wear
parts
sunshade panel
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Chinese (zh)
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杨晓燕
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Suzhou Xin River Mirror Co Ltd
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Suzhou Xin River Mirror Co Ltd
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Abstract

The utility model provides the moulding process of a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial and eyeglass, including PC resin layer, and the PC resin layer front is provided with stiffening layer;The stiffening layer front is provided with radiation protective layer;The radiation protective layer front is provided with antibiotic layer;The antibiotic layer front is provided with dyed layer;The PC resin layer reverse side is provided with wearing layer;The wearing layer reverse side is provided with anti-soil layer;The utility model provides a kind of antibacterial wear-resisting automotive sunshade panel eyeglass, with excellent antibacterial functions, wear-resisting functions and good shock resistance and explosion-proof performance;The automotive sunshade panel eyeglass, can ensure human pilot clearly driving vision, filter glare, improve driving comfort and security;In addition, the utility model provides a kind of antibacterial wear-resisting automotive sunshade panel eyeglass, also with radiation proof, UV resistance, oil-stain-preventing function, vdiverse in function, moulding process is simple, style is attractive in appearance, cost performance is high, meets the actual demand of modern human pilot.

Description

A kind of wear-resisting automotive sunshade panel eyeglass of antibacterial
Technical field
The utility model is related to automobile eyeglass field, and in particular to a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial.
Background technology
With the fast development of social economy, the continuous improvement of national life level, the vehicles make rapid progress, and automobile is made For one of main vehicles of modern society, huge numbers of families have been come into.
Meanwhile, with the popularization of automobile, the problem of people run into more and more highlights, thus, present people It is a simple walking-replacing tool to be no longer regarded as automobile, and how safe driving is related to personal life security problem.
Existing automotive sunshade panel eyeglass, does not often possess good anti-microbial property, and eyeglass is used with prolonged It is easier the phenomenon for occurring scratching.
Meanwhile, either daytime traveling still travel at night, the eyeglass on automotive sunshade panel can to sunshine or Secondly the strong light of headlight for vehicles, in the process of moving, due to the interference of the light such as sunshine, allow and drive without what weakening effect The personnel of sailing feel dazzling, and safety coefficient is than relatively low for human pilot.
Moreover, existing automotive sunshade panel eyeglass, function is relatively simple, does not possess good, radiation proof, UV resistance, prevent Scrape, the function such as dust-proof, while existing automotive sunshade panel eyeglass can not often ensure good degree of getting a clear view when in use, Human pilot also easily produces visual fatigue etc. in driving procedure.
Therefore, based on above the problems such as, the utility model is directed to a automotive sunshade panel eyeglass vdiverse in function of research.
The content of the invention
To solve above-mentioned problem, the purpose of this utility model is to provide a kind of antibacterial wear-resisting automotive sunshade panel Eyeglass, it has excellent antibacterial functions, wear-resisting functions and good shock resistance and explosion-proof performance;A kind of described antibacterial is resistance to The automotive sunshade panel eyeglass of mill, can ensure human pilot clearly driving vision, filter glare, improve driving comfort and Security;In addition, a kind of wear-resisting automotive sunshade panel eyeglass of described antibacterial, also with radiation proof, UV resistance, oil-stain-preventing work( Can, vdiverse in function, moulding process is simple, style is attractive in appearance, cost performance is high, meets the actual demand of modern human pilot.
To reach above-mentioned purpose, the technical solution adopted in the utility model is:
A kind of wear-resisting automotive sunshade panel eyeglass of antibacterial, including PC resin layer, the PC resin layer front are provided with stiffening layer; The stiffening layer front is provided with radiation protective layer;The radiation protective layer front is provided with antibiotic layer;The antibiotic layer front is provided with coloring Layer;The PC resin layer reverse side is provided with wearing layer;The wearing layer reverse side is provided with anti-soil layer;The PC resin layer includes following heavy Amount proportioning raw material:
PC resin:70~80 parts, pentaerythrite:20~30 parts, styrene block copolymer:10~15 parts, 2- ethyl hexyls Base diphenyl phosphoester:5~10 parts, methacryloxypropyl silane:2~3 parts, maleic anhydride:3~5 parts, barium stearate:2~ 3 parts, nano silicon:1~3 part, stabilizer:0.1~1 part, nucleator:0.1~1 part, initiator:0.1~0.5 part, resist Oxidant:0.1~0.5 part.
The wear-resisting automotive sunshade panel eyeglass of a kind of antibacterial that the utility model is provided, with PC resin layer for basic unit, makes material Possess the more excellent transparency, chemical stability and weatherability, by the eyeglass of above Material synthesis, can not only make eyeglass phase There is more preferable definition for ordinary resin, human pilot clearly driving vision is more ensured, moreover, shock resistance is more It is good, it is non-breakable by hitting, with good explosion prevention function.
Further, the stiffening layer is organosilicon membrane, and the thickness of the stiffening layer is 2~3 μm, by compound to eyeglass One layer of organosilicon membrane, effectively increases the hardness and scratch resistance capability of eyeglass, also make eyeglass by hit when more not It is broken, at the same time can also increase by 2% light transmittance and be that the follow-up institute's film plating layer of eyeglass improves more preferable adhesive force.
Further, the radiation protective layer is polyvinyl chloride film, and the thickness of the radiation protective layer is 0.5~1 μm, institute Stating radiation protective layer can be reflected low frequency radiation and microwave and be absorbed, can effective filter out electromagnetic radiation as waves and ultraviolet, More healthy driving environment is provided to human pilot.
Further, the antibiotic layer is PP resin film layers, and the thickness of the antibiotic layer is 1~3 μm, the antibiotic layer bag Include following weight proportion raw material:
PP resins:60~70 parts, SA dibutyl ester:15~25 parts, acetone:10~20 parts, acrylamide:10~15 Part, o-aminophenol:5~8 parts, maleic anhydride:2~3 parts, polyvinyl acetate:1~2 part, 2-ethyl-4-methylimidazole: 0.1~1 part, nano-silver powder:0.1~1 part.
Automobile sun-shading eyeglass described in the utility model can be prevented effectively by the antibiotic layer of above weight proportion Material synthesis Eyeglass bacteria breed, protects the use eye safety of human pilot.
Further, the dyed layer is polyacrylic resin layer, and the thickness of the dyed layer is 2~3 μm, the coloring Layer includes following weight proportion raw material:
Polyacrylic resin:50~60 parts, ethyl acrylate:10~20 parts, cyclohexanone:10~15 parts, cross-linking epoxy Group condensation product:5~10 parts, nano-sized iron oxide:3~6 parts, nano zine oxide:2~3 parts, molybdenum trioxide:1~2 part, pigment Powder:0.1~1 part, carbon black:0.1~0.5 part.
Dyed layer described in the utility model is polyacrylic resin layer, is synthesized by above weight proportion, with splendid Light transmittance, see that things clear and natural is true, the dyed layer can effectively filter strong light, under conditions of distance light light irradiation Dazzling sensation will not be produced, prevent dim eyesight, mitigation kopiopia, the safety driven under the strong light of effective guarantee.
Further, the wearing layer is PET resin layer, and the thickness of the wearing layer is 2~3 μm, and the wearing layer includes Following weight proportion raw material:
PET resin:40~50 parts, gamma-aminopropyl-triethoxy-silane:10~15 parts, polysiloxanes:2~3 parts, mica Powder:1~2 part, cyclohexanone:4~6 parts, ethyl acetate:10~15 parts, polypropylene grafted maleic anhydride:0.1~1 part, styrene- Maleic anhydride multipolymer:0.1~0.5 part.
Wearing layer described in the utility model is PET resin layer, by the wearing layer of above weight proportion Material synthesis, is had Good Wear-resistant scratch-resistant effect, at the same time, also enhances the impact resistance of whole eyeglass, explosion-proof function.
Further, the anti-soil layer is polyvinyl chloride film, and the thickness of the anti-soil layer is 0.5~1 μm, described anti- Pollution layer is polyvinyl chloride film, can effectively prevent lens surface from, by oil pollution, keeping the cleannes of minute surface, making whole eyeglass Look more attractive in appearance and comfortable.
Preferably, in PC resin layer raw material, the stabilizer is organic tin stabilizer, it is easy to resin forming, tool There is good heat endurance and the transparency, the UV resistance of synthetic resin can be increased by using organic tin stabilizer, prevented Resin material is decomposed and old saying;The nucleator is double(To tert-butyl benzene epoxide)Sodium phosphate, by using double(To tert-butyl benzene Epoxide)Sodium phosphate improves the tensile strength and impact strength of PC resin layer as nucleator, improves PC resin layer surface Finish, contribute to lifting PC resin layer rigidity, crystallization rate, the transparency.
Preferably, in PC resin layer raw material, the initiator is peroxidized t-butyl perbenzoate, the carbon of peroxidating two One kind in sour diisopropyl ester, TBHP, effectively lifts the reaction efficiency entirely reacted, shortens the reaction time;Institute Antioxidant is stated for dibutyl hydroxy toluene or tetraethyl resorcinol, with low volatilization, the performance of hydrolysis can be reduced effectively The oxidized performance of PC resin layer, extends the service life of eyeglass.
In addition, a kind of moulding process of the wear-resisting automotive sunshade panel eyeglass of antibacterial, the moulding process of the PC resin layer includes Following steps:
(1)Precise is carried out according to each weight proportion raw material of PC resin layer, after the completion of weighing, by each component weight Amount proportioning raw material is lower in bucket is stirred under vacuum to be stirred under vacuum, and is well mixed, mixing time is 30~50 min;
(2)By step(1)Middle products obtained therefrom obtains PC resin layer, wherein twin-screw extrusion by double screw extruder extrusion The processing temperature of machine is 240~260 DEG C;
(3)By step(2)Middle products obtained therefrom feeding curing is solidified, and hardening time is 20~30 min;Solidify Cheng Hou, cooling and shaping.
The moulding process of PC resin layer described in the utility model, moulding process is simple, easy to operate, is adapted to industry metaplasia Production.
The beneficial effects of the utility model are:
(1)The utility model provides a kind of antibacterial wear-resisting automotive sunshade panel eyeglass, with excellent antibacterial functions, wear-resisting Function and good shock resistance and explosion-proof performance.
(2)The utility model provides a kind of antibacterial wear-resisting automotive sunshade panel eyeglass, can ensure that human pilot is clearly driven The visual field is sailed, glare is filtered, driving comfort and security is improved;
(3)The utility model provides a kind of antibacterial wear-resisting automotive sunshade panel eyeglass, also with radiation proof, UV resistance, prevents Greasy dirt function, vdiverse in function, style is attractive in appearance, cost performance is high, meets the actual demand of modern human pilot, meanwhile, eyeglass into Type technique is simple, easy to operate, be adapted to industrialization production.
Brief description of the drawings
Fig. 1 is a kind of wear-resisting automotive sunshade panel eyeglass schematic diagram of antibacterial that the utility model is provided;
Wherein, 1 is PC resin layer, and 2 be stiffening layer, and 3 be radiation protective layer, and 4 be antibiotic layer, and 5 be dyed layer, and 6 be wearing layer, 7 be anti-soil layer.
Embodiment
Clear, complete description will be carried out to the technical scheme in the utility model embodiment below, it is clear that described Embodiment is only a part of embodiment of the utility model, rather than whole embodiments.Based on the implementation in the utility model Example, the every other embodiment that those of ordinary skill in the art are obtained on the premise of creative work is not made all belongs to The scope protected in the utility model.
Embodiment one
Referring to Fig. 1, a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial, including PC resin layer 1, the front of PC resin layer 1 Provided with stiffening layer 2;The front of stiffening layer 2 is provided with radiation protective layer 3;The front of radiation protective layer 3 is provided with antibiotic layer 4;It is described anti- The front of bacterium layer 4 is provided with dyed layer 5;1 reverse side of the PC resin layer is provided with wearing layer 6;The reverse side of wearing layer 6 is provided with anti-soil layer 7; The PC resin layer 1 includes following weight proportion raw material:
PC resin:75 parts, pentaerythrite:25 parts, styrene block copolymer:10 parts, 2- ethylhexyl diphenylphosphoric acids Ester:10 parts, methacryloxypropyl silane:2.55 parts, maleic anhydride:4 parts, barium stearate:2 parts, nano silicon:2.8 Part, stabilizer:0.6 part, nucleator:0.1 part, initiator:0.5 part, antioxidant:0.3 part.
The wear-resisting automotive sunshade panel eyeglass of a kind of antibacterial that the utility model is provided, is basic unit with PC resin layer 1, makes material Possess the more excellent transparency, chemical stability and weatherability, by the eyeglass of above Material synthesis, can not only make eyeglass phase There is more preferable definition for ordinary resin, human pilot clearly driving vision is more ensured, moreover, shock resistance is more It is good, it is non-breakable by hitting, with good explosion prevention function.
Further, the stiffening layer 2 is organosilicon membrane, and the thickness of the stiffening layer 2 is 2 μm, by eyeglass compound one Layer organosilicon membrane, effectively increases the hardness and scratch resistance capability of eyeglass, eyeglass is more difficult when by shock It is broken, at the same time can also increase by 2% light transmittance and be the more preferable adhesive force of the follow-up institute's film plating layer raising of eyeglass.
Further, the radiation protective layer 3 is polyvinyl chloride film, and the thickness of the radiation protective layer 3 is 0.8 μm, described Low frequency radiation and microwave can be reflected and be absorbed by radiation protective layer 3, can be effective filtered out electromagnetic radiation as waves and ultraviolet, be given Human pilot provides more healthy driving environment.
Further, the antibiotic layer 4 is PP resin film layers, and the thickness of the antibiotic layer 4 is 2 μm, and the antibiotic layer 4 is wrapped Include following weight proportion raw material:
PP resins:65 parts, SA dibutyl ester:20 parts, acetone:10 parts, acrylamide:15 parts, o-aminophenol:6.5 Part, maleic anhydride:2.54 parts, polyvinyl acetate:1.2 part, 2-ethyl-4-methylimidazole:0.6 part, nano-silver powder:0.5 part.
Automobile sun-shading eyeglass described in the utility model can be prevented effectively by the antibiotic layer 4 of above weight proportion Material synthesis Eyeglass bacteria breed, protects the use eye safety of human pilot.
Further, the dyed layer 5 is polyacrylic resin layer, and the thickness of the dyed layer 5 is 2.5 μm, the coloring Layer 5 includes following weight proportion raw material:
Polyacrylic resin:50 parts, ethyl acrylate:15 parts, cyclohexanone:12 parts, cross-linking epoxide group condensation product:5 Part, nano-sized iron oxide:4.5 parts, nano zine oxide:2.5 parts, molybdenum trioxide:1 part, pigmented powder:0.1 part, carbon black:0.25 part.
Dyed layer 5 described in the utility model is polyacrylic resin layer, is synthesized by above weight proportion, with splendid Light transmittance, see that things clear and natural is true, the dyed layer 5 can effectively filter strong light, under conditions of distance light light irradiation Also dazzling sensation will not be produced, prevent dim eyesight, mitigation kopiopia, the safety driven under the strong light of effective guarantee.
Further, the wearing layer 6 is PET resin layer, and the thickness of the wearing layer 6 is 2 μm, and the wearing layer 6 includes Following weight proportion raw material:
PET resin:45 parts, gamma-aminopropyl-triethoxy-silane:10 parts, polysiloxanes:2.5 parts, mica powder:1 part, ring Hexanone:5 parts, ethyl acetate:13 parts, polypropylene grafted maleic anhydride:0.5 part, SMA:0.3 Part.
Wearing layer 6 described in the utility model is PET resin layer, passes through the wearing layer of above weight proportion Material synthesis, tool There is good Wear-resistant scratch-resistant to act on, at the same time, also enhance the impact resistance of whole eyeglass, explosion-proof function.
Further, the anti-soil layer 7 is polyvinyl chloride film, and the thickness of the anti-soil layer 7 is 0.8 μm, the anti-soil Layer 7 is polyvinyl chloride film, can effectively prevent lens surface from, by oil pollution, keeping the cleannes of minute surface, making whole eyeglass Look more attractive in appearance and comfortable.
Preferably, in the PC resin 1 raw material of layer, the stabilizer is organic tin stabilizer, it is easy to resin forming, tool There is good heat endurance and the transparency, the UV resistance of synthetic resin can be increased by using organic tin stabilizer, prevented Resin material is decomposed and old saying;The nucleator is double(To tert-butyl benzene epoxide)Sodium phosphate, by using double(To tert-butyl benzene Epoxide)Sodium phosphate improves the tensile strength and impact strength of PC resin layer 1 as nucleator, improves PC resin 1 table of layer The finish in face, contributes to 1 rigidity of lifting PC resin layer, crystallization rate, the transparency.
Preferably, in the PC resin 1 raw material of layer, the initiator is peroxidized t-butyl perbenzoate, peroxidating two One kind in diisopropyl carbonate, TBHP, effectively lifts the reaction efficiency entirely reacted, shortens the reaction time; The antioxidant is dibutyl hydroxy toluene or tetraethyl resorcinol, and with low volatilization, the performance of hydrolysis can effectively drop The oxidized performance of low PC resin layer 1, extends the service life of eyeglass.
In addition, a kind of moulding process of the wear-resisting automotive sunshade panel eyeglass of antibacterial, the moulding process of the PC resin layer 1 includes Following steps:
(1)Precise is carried out according to each weight proportion raw material of PC resin layer 1, after the completion of weighing, by each component Weight proportion raw material is lower in bucket is stirred under vacuum to be stirred under vacuum, and is well mixed, mixing time is 40 min;
(2)By step(1)Middle products obtained therefrom obtains PC resin layer 1 by double screw extruder extrusion, and wherein twin-screw is squeezed The processing temperature for going out machine is 250 DEG C;
(3)By step(2)Middle products obtained therefrom feeding curing is solidified, and hardening time is 25 min;After the completion of solidification, Cooling and shaping.
The moulding process of PC resin layer 1 described in the utility model, moulding process is simple, easy to operate, is adapted to industrialization Production.
Embodiment two
A kind of wear-resisting automotive sunshade panel eyeglass of antibacterial, including PC resin layer 1, the front of PC resin layer 1 are provided with stiffened Layer 2;The front of stiffening layer 2 is provided with radiation protective layer 3;The front of radiation protective layer 3 is provided with antibiotic layer 4;The front of antibiotic layer 4 Provided with dyed layer 5;1 reverse side of the PC resin layer is provided with wearing layer 6;The reverse side of wearing layer 6 is provided with anti-soil layer 7;The PC trees Lipid layer 1 includes following weight proportion raw material:
PC resin:80 parts, pentaerythrite:20 parts, styrene block copolymer:12 parts, 2- ethylhexyl diphenylphosphoric acids Ester:7 parts, methacryloxypropyl silane:2 parts, maleic anhydride:5 parts, barium stearate:2.5 parts, nano silicon:1 part, surely Determine agent:0.12 part, nucleator:0.98 part, initiator:0.1 part, antioxidant:0.5 part.
The wear-resisting automotive sunshade panel eyeglass of a kind of antibacterial that the utility model is provided, is basic unit with PC resin layer 1, makes material Possess the more excellent transparency, chemical stability and weatherability, by the eyeglass of above Material synthesis, can not only make eyeglass phase There is more preferable definition for ordinary resin, human pilot clearly driving vision is more ensured, moreover, shock resistance is more It is good, it is non-breakable by hitting, with good explosion prevention function.
Further, the stiffening layer 2 is organosilicon membrane, and the thickness of the stiffening layer 2 is 3 μm, by eyeglass compound one Layer organosilicon membrane, effectively increases the hardness and scratch resistance capability of eyeglass, eyeglass is more difficult when by shock It is broken, at the same time can also increase by 2% light transmittance and be the more preferable adhesive force of the follow-up institute's film plating layer raising of eyeglass.
Further, the radiation protective layer 3 is polyvinyl chloride film, and the thickness of the radiation protective layer 3 is 0.5 μm, described Low frequency radiation and microwave can be reflected and be absorbed by radiation protective layer 3, can be effective filtered out electromagnetic radiation as waves and ultraviolet, be given Human pilot provides more healthy driving environment.
Further, the antibiotic layer 4 is PP resin film layers, and the thickness of the antibiotic layer 4 is 1 μm, and the antibiotic layer 4 is wrapped Include following weight proportion raw material:
PP resins:70 parts, SA dibutyl ester:15 parts, acetone:20 parts, acrylamide:12.5 parts, o-aminophenol:5 Part, maleic anhydride:3 parts, polyvinyl acetate:1.6 parts, 2-ethyl-4-methylimidazole:0.2 part, nano-silver powder:1 part.
Automobile sun-shading eyeglass described in the utility model can be prevented effectively by the antibiotic layer 4 of above weight proportion Material synthesis Eyeglass bacteria breed, protects the use eye safety of human pilot.
Further, the dyed layer 5 is polyacrylic resin layer, and the thickness of the dyed layer 5 is 2 μm, the dyed layer 5 include following weight proportion raw material:
Polyacrylic resin:55 parts, ethyl acrylate:10 parts, cyclohexanone:15 parts, cross-linking epoxide group condensation product: 7.5 parts, nano-sized iron oxide:3 parts, nano zine oxide:3 parts, molybdenum trioxide:1.5 parts, pigmented powder:0.9 part, carbon black:0.5 part.
Dyed layer 5 described in the utility model is polyacrylic resin layer, is synthesized by above weight proportion, with splendid Light transmittance, see that things clear and natural is true, the dyed layer 5 can effectively filter strong light, under conditions of distance light light irradiation Also dazzling sensation will not be produced, prevent dim eyesight, mitigation kopiopia, the safety driven under the strong light of effective guarantee.
Further, the wearing layer 6 is PET resin layer, and the thickness of the wearing layer 6 is 2.5 μm, and the wearing layer 6 is wrapped Include following weight proportion raw material:
PET resin:40 parts, gamma-aminopropyl-triethoxy-silane:13 parts, polysiloxanes:2 parts, mica powder:1.6 parts, ring Hexanone:6 parts, ethyl acetate:10 parts, polypropylene grafted maleic anhydride:0.1 part, SMA:0.5 Part.
Wearing layer 6 described in the utility model is PET resin layer, passes through the wearing layer 6 of above weight proportion Material synthesis, tool There is good Wear-resistant scratch-resistant to act on, at the same time, also enhance the impact resistance of whole eyeglass, explosion-proof function.
Further, the anti-soil layer 7 is polyvinyl chloride film, and the thickness of the anti-soil layer 7 is 0.5 μm, the anti-soil Layer 7 is polyvinyl chloride film, can effectively prevent lens surface from, by oil pollution, keeping the cleannes of minute surface, making whole eyeglass Look more attractive in appearance and comfortable.
Preferably, in the PC resin 1 raw material of layer, the stabilizer is organic tin stabilizer, it is easy to resin forming, tool There is good heat endurance and the transparency, the UV resistance of synthetic resin can be increased by using organic tin stabilizer, prevented Resin material is decomposed and old saying;The nucleator is double(To tert-butyl benzene epoxide)Sodium phosphate, by using double(To tert-butyl benzene Epoxide)Sodium phosphate improves the tensile strength and impact strength of PC resin layer 1 as nucleator, improves PC resin 1 table of layer The finish in face, contributes to 1 rigidity of lifting PC resin layer, crystallization rate, the transparency.
Preferably, in the PC resin 1 raw material of layer, the initiator is peroxidized t-butyl perbenzoate, peroxidating two One kind in diisopropyl carbonate, TBHP, effectively lifts the reaction efficiency entirely reacted, shortens the reaction time; The antioxidant is dibutyl hydroxy toluene or tetraethyl resorcinol, and with low volatilization, the performance of hydrolysis can effectively drop The oxidized performance of low PC resin layer 1, extends the service life of eyeglass.
In addition, a kind of moulding process of the wear-resisting automotive sunshade panel eyeglass of antibacterial, the moulding process of the PC resin layer 1 includes Following steps:
(1)Precise is carried out according to each weight proportion raw material of PC resin layer 1, after the completion of weighing, by each component Weight proportion raw material is lower in bucket is stirred under vacuum to be stirred under vacuum, and is well mixed, mixing time is 50 min;
(2)By step(1)Middle products obtained therefrom obtains PC resin layer, wherein twin-screw extrusion by double screw extruder extrusion The processing temperature of machine is 240 DEG C;
(3)By step(2)Middle products obtained therefrom feeding curing is solidified, and hardening time is 30 min;After the completion of solidification, Cooling and shaping.
The moulding process of PC resin layer 1 described in the utility model, moulding process is simple, easy to operate, is adapted to industrialization Production.
Embodiment three
A kind of wear-resisting automotive sunshade panel eyeglass of antibacterial, including PC resin layer 1, the front of PC resin layer 1 are provided with stiffened Layer 2;The front of stiffening layer 2 is provided with radiation protective layer 3;The front of radiation protective layer 3 is provided with antibiotic layer 4;The front of antibiotic layer 4 Provided with dyed layer 5;1 reverse side of the PC resin layer is provided with wearing layer 6;The reverse side of wearing layer 6 is provided with anti-soil layer 7;The PC trees Lipid layer 1 includes following weight proportion raw material:
PC resin:70 parts, pentaerythrite:30 parts, styrene block copolymer:15 parts, 2- ethylhexyl diphenylphosphoric acids Ester:5 parts, methacryloxypropyl silane:3 parts, maleic anhydride:3 parts, barium stearate:3 parts, nano silicon:It is 2 parts, stable Agent:0.95 part, nucleator:0.5 part, initiator:0.3 part, antioxidant:0.1 part.
The wear-resisting automotive sunshade panel eyeglass of a kind of antibacterial that the utility model is provided, is basic unit with PC resin layer 1, makes material Possess the more excellent transparency, chemical stability and weatherability, by the eyeglass of above Material synthesis, can not only make eyeglass phase There is more preferable definition for ordinary resin, human pilot clearly driving vision is more ensured, moreover, shock resistance is more It is good, it is non-breakable by hitting, with good explosion prevention function.
Further, the stiffening layer 2 is organosilicon membrane, and the thickness of the stiffening layer 2 is 2.5 μm, by compound to eyeglass One layer of organosilicon membrane, effectively increases the hardness and scratch resistance capability of eyeglass, also make eyeglass by hit when more not It is broken, at the same time can also increase by 2% light transmittance and be that the follow-up institute's film plating layer of eyeglass improves more preferable adhesive force.
Further, the radiation protective layer 3 is polyvinyl chloride film, and the thickness of the radiation protective layer 3 is 1 μm, described anti- Low frequency radiation and microwave can be reflected and be absorbed by radiating layer 3, can effective filter out electromagnetic radiation as waves and ultraviolet, to driving Sail personnel and more healthy driving environment is provided.
Further, the antibiotic layer 4 is PP resin film layers, and the thickness of the antibiotic layer 4 is 3 μm, and the antibiotic layer 4 is wrapped Include following weight proportion raw material:
PP resins:60 parts, SA dibutyl ester:25 parts, acetone:15 parts, acrylamide:10 parts, o-aminophenol:8 parts, Maleic anhydride:2 parts, polyvinyl acetate:2 parts, 2-ethyl-4-methylimidazole:1 part, nano-silver powder:0.1 part.
Automobile sun-shading eyeglass described in the utility model can be prevented effectively by the antibiotic layer 4 of above weight proportion Material synthesis Eyeglass bacteria breed, protects the use eye safety of human pilot.
Further, the dyed layer 5 is polyacrylic resin layer, and the thickness of the dyed layer 5 is 3 μm, the dyed layer 5 include following weight proportion raw material:
Polyacrylic resin:60 parts, ethyl acrylate:20 parts, cyclohexanone:10 parts, cross-linking epoxide group condensation product:10 Part, nano-sized iron oxide:6 parts, nano zine oxide:2 parts, molybdenum trioxide:2 parts, pigmented powder:0.52 part, carbon black:0.1 part.
Dyed layer 5 described in the utility model is polyacrylic resin layer, is synthesized by above weight proportion, with splendid Light transmittance, see that things clear and natural is true, the dyed layer 5 can effectively filter strong light, under conditions of distance light light irradiation Also dazzling sensation will not be produced, prevent dim eyesight, mitigation kopiopia, the safety driven under the strong light of effective guarantee.
Further, the wearing layer 6 is PET resin layer, and the thickness of the wearing layer 6 is 3 μm, and the wearing layer 6 includes Following weight proportion raw material:
PET resin:50 parts, gamma-aminopropyl-triethoxy-silane:15 parts, polysiloxanes:3 parts, mica powder:2 parts, hexamethylene Ketone:4 parts, ethyl acetate:15 parts, polypropylene grafted maleic anhydride:1 part, SMA:0.1 part.
Wearing layer 6 described in the utility model is PET resin layer, passes through the wearing layer 6 of above weight proportion Material synthesis, tool There is good Wear-resistant scratch-resistant to act on, at the same time, also enhance the impact resistance of whole eyeglass, explosion-proof function.
Further, the anti-soil layer 7 is polyvinyl chloride film, and the thickness of the anti-soil layer 7 is 1 μm, the anti-soil layer 7 be polyvinyl chloride film, can effectively prevent lens surface from, by oil pollution, keeping the cleannes of minute surface, seeing whole eyeglass It is more attractive in appearance and comfortable up.
Preferably, in the PC resin 1 raw material of layer, the stabilizer is organic tin stabilizer, it is easy to resin forming, tool There is good heat endurance and the transparency, the UV resistance of synthetic resin can be increased by using organic tin stabilizer, prevented Resin material is decomposed and old saying;The nucleator is double(To tert-butyl benzene epoxide)Sodium phosphate, by using double(To tert-butyl benzene Epoxide)Sodium phosphate improves the tensile strength and impact strength of PC resin layer 1 as nucleator, improves PC resin 1 table of layer The finish in face, contributes to 1 rigidity of lifting PC resin layer, crystallization rate, the transparency.
Preferably, in the PC resin 1 raw material of layer, the initiator is peroxidized t-butyl perbenzoate, peroxidating two One kind in diisopropyl carbonate, TBHP, effectively lifts the reaction efficiency entirely reacted, shortens the reaction time; The antioxidant is dibutyl hydroxy toluene or tetraethyl resorcinol, and with low volatilization, the performance of hydrolysis can effectively drop The oxidized performance of low PC resin layer 1, extends the service life of eyeglass.
In addition, a kind of moulding process of the wear-resisting automotive sunshade panel eyeglass of antibacterial, the moulding process of the PC resin layer 1 includes Following steps:
(1)Precise is carried out according to each weight proportion raw material of PC resin layer 1, after the completion of weighing, by each component Weight proportion raw material is lower in bucket is stirred under vacuum to be stirred under vacuum, and is well mixed, mixing time is 30 min;
(2)By step(1)Middle products obtained therefrom obtains PC resin layer, wherein twin-screw extrusion by double screw extruder extrusion The processing temperature of machine is 260 DEG C;
(3)By step(2)Middle products obtained therefrom feeding curing is solidified, and hardening time is 20 min;After the completion of solidification, Cooling and shaping.
The moulding process of PC resin layer 1 described in the utility model, moulding process is simple, easy to operate, is adapted to industrialization Production.
The utility model provides a kind of antibacterial wear-resisting automotive sunshade panel eyeglass, with excellent antibacterial functions, wear-resisting work( Energy and well shock resistance and explosion-proof performance.A kind of wear-resisting automotive sunshade panel eyeglass of described antibacterial, can ensure driver Member's clearly driving vision, filters glare, improves driving comfort and security;Furthermore, the utility model provides a kind of The wear-resisting automotive sunshade panel eyeglass of antibacterial, also with radiation proof, UV resistance, oil-stain-preventing function, vdiverse in function, style is attractive in appearance, property Valency meets the actual demand of modern human pilot than high, meanwhile, the moulding process of eyeglass is simple, easy to operate, be adapted to industrialization Production.
It should be noted that above example is only unrestricted to illustrate the technical solution of the utility model.Although ginseng The utility model is described in detail according to preferred embodiment, it will be understood by those within the art that, can be to hair Bright technical scheme is modified or equivalent substitution, and without departing from the scope of technical solutions of the utility model, it all should cover In right of the present utility model.

Claims (7)

1. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial, it is characterised in that including PC resin layer, the PC resin layer front is set There is stiffening layer;
The stiffening layer front is provided with radiation protective layer;
The radiation protective layer front is provided with antibiotic layer;
The antibiotic layer front is provided with dyed layer;
The PC resin layer reverse side is provided with wearing layer;
The wearing layer reverse side is provided with anti-soil layer.
2. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial according to claim 1, it is characterised in that the stiffening layer is Organosilicon membrane, the thickness of the stiffening layer is 2~3 μm.
3. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial according to claim 1, it is characterised in that the radiation protective layer For polyvinyl chloride film, the thickness of the radiation protective layer is 0.5~1 μm.
4. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial according to claim 1, it is characterised in that the antibiotic layer is PP resin film layers, the thickness of the antibiotic layer is 1~3 μm.
5. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial according to claim 1, it is characterised in that the dyed layer For polyacrylic resin layer, the thickness of the dyed layer is 2~3 μm.
6. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial according to claim 1, it is characterised in that the wearing layer is PET resin layer, the thickness of the wearing layer is 2~3 μm.
7. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial according to claim 1, it is characterised in that the anti-soil layer is Polyvinyl chloride film, the thickness of the anti-soil layer is 0.5~1 μm.
CN201720038281.9U 2017-01-13 2017-01-13 A kind of wear-resisting automotive sunshade panel eyeglass of antibacterial Expired - Fee Related CN206456052U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019100189A1 (en) * 2017-11-21 2019-05-31 苏州鑫河镜业有限公司 Antimicrobial wear-resistant automobile sunshield mirror and mirror forming process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019100189A1 (en) * 2017-11-21 2019-05-31 苏州鑫河镜业有限公司 Antimicrobial wear-resistant automobile sunshield mirror and mirror forming process

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