CN206456052U - A kind of wear-resisting automotive sunshade panel eyeglass of antibacterial - Google Patents
A kind of wear-resisting automotive sunshade panel eyeglass of antibacterial Download PDFInfo
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- CN206456052U CN206456052U CN201720038281.9U CN201720038281U CN206456052U CN 206456052 U CN206456052 U CN 206456052U CN 201720038281 U CN201720038281 U CN 201720038281U CN 206456052 U CN206456052 U CN 206456052U
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Abstract
The utility model provides the moulding process of a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial and eyeglass, including PC resin layer, and the PC resin layer front is provided with stiffening layer;The stiffening layer front is provided with radiation protective layer;The radiation protective layer front is provided with antibiotic layer;The antibiotic layer front is provided with dyed layer;The PC resin layer reverse side is provided with wearing layer;The wearing layer reverse side is provided with anti-soil layer;The utility model provides a kind of antibacterial wear-resisting automotive sunshade panel eyeglass, with excellent antibacterial functions, wear-resisting functions and good shock resistance and explosion-proof performance;The automotive sunshade panel eyeglass, can ensure human pilot clearly driving vision, filter glare, improve driving comfort and security;In addition, the utility model provides a kind of antibacterial wear-resisting automotive sunshade panel eyeglass, also with radiation proof, UV resistance, oil-stain-preventing function, vdiverse in function, moulding process is simple, style is attractive in appearance, cost performance is high, meets the actual demand of modern human pilot.
Description
Technical field
The utility model is related to automobile eyeglass field, and in particular to a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial.
Background technology
With the fast development of social economy, the continuous improvement of national life level, the vehicles make rapid progress, and automobile is made
For one of main vehicles of modern society, huge numbers of families have been come into.
Meanwhile, with the popularization of automobile, the problem of people run into more and more highlights, thus, present people
It is a simple walking-replacing tool to be no longer regarded as automobile, and how safe driving is related to personal life security problem.
Existing automotive sunshade panel eyeglass, does not often possess good anti-microbial property, and eyeglass is used with prolonged
It is easier the phenomenon for occurring scratching.
Meanwhile, either daytime traveling still travel at night, the eyeglass on automotive sunshade panel can to sunshine or
Secondly the strong light of headlight for vehicles, in the process of moving, due to the interference of the light such as sunshine, allow and drive without what weakening effect
The personnel of sailing feel dazzling, and safety coefficient is than relatively low for human pilot.
Moreover, existing automotive sunshade panel eyeglass, function is relatively simple, does not possess good, radiation proof, UV resistance, prevent
Scrape, the function such as dust-proof, while existing automotive sunshade panel eyeglass can not often ensure good degree of getting a clear view when in use,
Human pilot also easily produces visual fatigue etc. in driving procedure.
Therefore, based on above the problems such as, the utility model is directed to a automotive sunshade panel eyeglass vdiverse in function of research.
The content of the invention
To solve above-mentioned problem, the purpose of this utility model is to provide a kind of antibacterial wear-resisting automotive sunshade panel
Eyeglass, it has excellent antibacterial functions, wear-resisting functions and good shock resistance and explosion-proof performance;A kind of described antibacterial is resistance to
The automotive sunshade panel eyeglass of mill, can ensure human pilot clearly driving vision, filter glare, improve driving comfort and
Security;In addition, a kind of wear-resisting automotive sunshade panel eyeglass of described antibacterial, also with radiation proof, UV resistance, oil-stain-preventing work(
Can, vdiverse in function, moulding process is simple, style is attractive in appearance, cost performance is high, meets the actual demand of modern human pilot.
To reach above-mentioned purpose, the technical solution adopted in the utility model is:
A kind of wear-resisting automotive sunshade panel eyeglass of antibacterial, including PC resin layer, the PC resin layer front are provided with stiffening layer;
The stiffening layer front is provided with radiation protective layer;The radiation protective layer front is provided with antibiotic layer;The antibiotic layer front is provided with coloring
Layer;The PC resin layer reverse side is provided with wearing layer;The wearing layer reverse side is provided with anti-soil layer;The PC resin layer includes following heavy
Amount proportioning raw material:
PC resin:70~80 parts, pentaerythrite:20~30 parts, styrene block copolymer:10~15 parts, 2- ethyl hexyls
Base diphenyl phosphoester:5~10 parts, methacryloxypropyl silane:2~3 parts, maleic anhydride:3~5 parts, barium stearate:2~
3 parts, nano silicon:1~3 part, stabilizer:0.1~1 part, nucleator:0.1~1 part, initiator:0.1~0.5 part, resist
Oxidant:0.1~0.5 part.
The wear-resisting automotive sunshade panel eyeglass of a kind of antibacterial that the utility model is provided, with PC resin layer for basic unit, makes material
Possess the more excellent transparency, chemical stability and weatherability, by the eyeglass of above Material synthesis, can not only make eyeglass phase
There is more preferable definition for ordinary resin, human pilot clearly driving vision is more ensured, moreover, shock resistance is more
It is good, it is non-breakable by hitting, with good explosion prevention function.
Further, the stiffening layer is organosilicon membrane, and the thickness of the stiffening layer is 2~3 μm, by compound to eyeglass
One layer of organosilicon membrane, effectively increases the hardness and scratch resistance capability of eyeglass, also make eyeglass by hit when more not
It is broken, at the same time can also increase by 2% light transmittance and be that the follow-up institute's film plating layer of eyeglass improves more preferable adhesive force.
Further, the radiation protective layer is polyvinyl chloride film, and the thickness of the radiation protective layer is 0.5~1 μm, institute
Stating radiation protective layer can be reflected low frequency radiation and microwave and be absorbed, can effective filter out electromagnetic radiation as waves and ultraviolet,
More healthy driving environment is provided to human pilot.
Further, the antibiotic layer is PP resin film layers, and the thickness of the antibiotic layer is 1~3 μm, the antibiotic layer bag
Include following weight proportion raw material:
PP resins:60~70 parts, SA dibutyl ester:15~25 parts, acetone:10~20 parts, acrylamide:10~15
Part, o-aminophenol:5~8 parts, maleic anhydride:2~3 parts, polyvinyl acetate:1~2 part, 2-ethyl-4-methylimidazole:
0.1~1 part, nano-silver powder:0.1~1 part.
Automobile sun-shading eyeglass described in the utility model can be prevented effectively by the antibiotic layer of above weight proportion Material synthesis
Eyeglass bacteria breed, protects the use eye safety of human pilot.
Further, the dyed layer is polyacrylic resin layer, and the thickness of the dyed layer is 2~3 μm, the coloring
Layer includes following weight proportion raw material:
Polyacrylic resin:50~60 parts, ethyl acrylate:10~20 parts, cyclohexanone:10~15 parts, cross-linking epoxy
Group condensation product:5~10 parts, nano-sized iron oxide:3~6 parts, nano zine oxide:2~3 parts, molybdenum trioxide:1~2 part, pigment
Powder:0.1~1 part, carbon black:0.1~0.5 part.
Dyed layer described in the utility model is polyacrylic resin layer, is synthesized by above weight proportion, with splendid
Light transmittance, see that things clear and natural is true, the dyed layer can effectively filter strong light, under conditions of distance light light irradiation
Dazzling sensation will not be produced, prevent dim eyesight, mitigation kopiopia, the safety driven under the strong light of effective guarantee.
Further, the wearing layer is PET resin layer, and the thickness of the wearing layer is 2~3 μm, and the wearing layer includes
Following weight proportion raw material:
PET resin:40~50 parts, gamma-aminopropyl-triethoxy-silane:10~15 parts, polysiloxanes:2~3 parts, mica
Powder:1~2 part, cyclohexanone:4~6 parts, ethyl acetate:10~15 parts, polypropylene grafted maleic anhydride:0.1~1 part, styrene-
Maleic anhydride multipolymer:0.1~0.5 part.
Wearing layer described in the utility model is PET resin layer, by the wearing layer of above weight proportion Material synthesis, is had
Good Wear-resistant scratch-resistant effect, at the same time, also enhances the impact resistance of whole eyeglass, explosion-proof function.
Further, the anti-soil layer is polyvinyl chloride film, and the thickness of the anti-soil layer is 0.5~1 μm, described anti-
Pollution layer is polyvinyl chloride film, can effectively prevent lens surface from, by oil pollution, keeping the cleannes of minute surface, making whole eyeglass
Look more attractive in appearance and comfortable.
Preferably, in PC resin layer raw material, the stabilizer is organic tin stabilizer, it is easy to resin forming, tool
There is good heat endurance and the transparency, the UV resistance of synthetic resin can be increased by using organic tin stabilizer, prevented
Resin material is decomposed and old saying;The nucleator is double(To tert-butyl benzene epoxide)Sodium phosphate, by using double(To tert-butyl benzene
Epoxide)Sodium phosphate improves the tensile strength and impact strength of PC resin layer as nucleator, improves PC resin layer surface
Finish, contribute to lifting PC resin layer rigidity, crystallization rate, the transparency.
Preferably, in PC resin layer raw material, the initiator is peroxidized t-butyl perbenzoate, the carbon of peroxidating two
One kind in sour diisopropyl ester, TBHP, effectively lifts the reaction efficiency entirely reacted, shortens the reaction time;Institute
Antioxidant is stated for dibutyl hydroxy toluene or tetraethyl resorcinol, with low volatilization, the performance of hydrolysis can be reduced effectively
The oxidized performance of PC resin layer, extends the service life of eyeglass.
In addition, a kind of moulding process of the wear-resisting automotive sunshade panel eyeglass of antibacterial, the moulding process of the PC resin layer includes
Following steps:
(1)Precise is carried out according to each weight proportion raw material of PC resin layer, after the completion of weighing, by each component weight
Amount proportioning raw material is lower in bucket is stirred under vacuum to be stirred under vacuum, and is well mixed, mixing time is 30~50 min;
(2)By step(1)Middle products obtained therefrom obtains PC resin layer, wherein twin-screw extrusion by double screw extruder extrusion
The processing temperature of machine is 240~260 DEG C;
(3)By step(2)Middle products obtained therefrom feeding curing is solidified, and hardening time is 20~30 min;Solidify
Cheng Hou, cooling and shaping.
The moulding process of PC resin layer described in the utility model, moulding process is simple, easy to operate, is adapted to industry metaplasia
Production.
The beneficial effects of the utility model are:
(1)The utility model provides a kind of antibacterial wear-resisting automotive sunshade panel eyeglass, with excellent antibacterial functions, wear-resisting
Function and good shock resistance and explosion-proof performance.
(2)The utility model provides a kind of antibacterial wear-resisting automotive sunshade panel eyeglass, can ensure that human pilot is clearly driven
The visual field is sailed, glare is filtered, driving comfort and security is improved;
(3)The utility model provides a kind of antibacterial wear-resisting automotive sunshade panel eyeglass, also with radiation proof, UV resistance, prevents
Greasy dirt function, vdiverse in function, style is attractive in appearance, cost performance is high, meets the actual demand of modern human pilot, meanwhile, eyeglass into
Type technique is simple, easy to operate, be adapted to industrialization production.
Brief description of the drawings
Fig. 1 is a kind of wear-resisting automotive sunshade panel eyeglass schematic diagram of antibacterial that the utility model is provided;
Wherein, 1 is PC resin layer, and 2 be stiffening layer, and 3 be radiation protective layer, and 4 be antibiotic layer, and 5 be dyed layer, and 6 be wearing layer,
7 be anti-soil layer.
Embodiment
Clear, complete description will be carried out to the technical scheme in the utility model embodiment below, it is clear that described
Embodiment is only a part of embodiment of the utility model, rather than whole embodiments.Based on the implementation in the utility model
Example, the every other embodiment that those of ordinary skill in the art are obtained on the premise of creative work is not made all belongs to
The scope protected in the utility model.
Embodiment one
Referring to Fig. 1, a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial, including PC resin layer 1, the front of PC resin layer 1
Provided with stiffening layer 2;The front of stiffening layer 2 is provided with radiation protective layer 3;The front of radiation protective layer 3 is provided with antibiotic layer 4;It is described anti-
The front of bacterium layer 4 is provided with dyed layer 5;1 reverse side of the PC resin layer is provided with wearing layer 6;The reverse side of wearing layer 6 is provided with anti-soil layer 7;
The PC resin layer 1 includes following weight proportion raw material:
PC resin:75 parts, pentaerythrite:25 parts, styrene block copolymer:10 parts, 2- ethylhexyl diphenylphosphoric acids
Ester:10 parts, methacryloxypropyl silane:2.55 parts, maleic anhydride:4 parts, barium stearate:2 parts, nano silicon:2.8
Part, stabilizer:0.6 part, nucleator:0.1 part, initiator:0.5 part, antioxidant:0.3 part.
The wear-resisting automotive sunshade panel eyeglass of a kind of antibacterial that the utility model is provided, is basic unit with PC resin layer 1, makes material
Possess the more excellent transparency, chemical stability and weatherability, by the eyeglass of above Material synthesis, can not only make eyeglass phase
There is more preferable definition for ordinary resin, human pilot clearly driving vision is more ensured, moreover, shock resistance is more
It is good, it is non-breakable by hitting, with good explosion prevention function.
Further, the stiffening layer 2 is organosilicon membrane, and the thickness of the stiffening layer 2 is 2 μm, by eyeglass compound one
Layer organosilicon membrane, effectively increases the hardness and scratch resistance capability of eyeglass, eyeglass is more difficult when by shock
It is broken, at the same time can also increase by 2% light transmittance and be the more preferable adhesive force of the follow-up institute's film plating layer raising of eyeglass.
Further, the radiation protective layer 3 is polyvinyl chloride film, and the thickness of the radiation protective layer 3 is 0.8 μm, described
Low frequency radiation and microwave can be reflected and be absorbed by radiation protective layer 3, can be effective filtered out electromagnetic radiation as waves and ultraviolet, be given
Human pilot provides more healthy driving environment.
Further, the antibiotic layer 4 is PP resin film layers, and the thickness of the antibiotic layer 4 is 2 μm, and the antibiotic layer 4 is wrapped
Include following weight proportion raw material:
PP resins:65 parts, SA dibutyl ester:20 parts, acetone:10 parts, acrylamide:15 parts, o-aminophenol:6.5
Part, maleic anhydride:2.54 parts, polyvinyl acetate:1.2 part, 2-ethyl-4-methylimidazole:0.6 part, nano-silver powder:0.5 part.
Automobile sun-shading eyeglass described in the utility model can be prevented effectively by the antibiotic layer 4 of above weight proportion Material synthesis
Eyeglass bacteria breed, protects the use eye safety of human pilot.
Further, the dyed layer 5 is polyacrylic resin layer, and the thickness of the dyed layer 5 is 2.5 μm, the coloring
Layer 5 includes following weight proportion raw material:
Polyacrylic resin:50 parts, ethyl acrylate:15 parts, cyclohexanone:12 parts, cross-linking epoxide group condensation product:5
Part, nano-sized iron oxide:4.5 parts, nano zine oxide:2.5 parts, molybdenum trioxide:1 part, pigmented powder:0.1 part, carbon black:0.25 part.
Dyed layer 5 described in the utility model is polyacrylic resin layer, is synthesized by above weight proportion, with splendid
Light transmittance, see that things clear and natural is true, the dyed layer 5 can effectively filter strong light, under conditions of distance light light irradiation
Also dazzling sensation will not be produced, prevent dim eyesight, mitigation kopiopia, the safety driven under the strong light of effective guarantee.
Further, the wearing layer 6 is PET resin layer, and the thickness of the wearing layer 6 is 2 μm, and the wearing layer 6 includes
Following weight proportion raw material:
PET resin:45 parts, gamma-aminopropyl-triethoxy-silane:10 parts, polysiloxanes:2.5 parts, mica powder:1 part, ring
Hexanone:5 parts, ethyl acetate:13 parts, polypropylene grafted maleic anhydride:0.5 part, SMA:0.3
Part.
Wearing layer 6 described in the utility model is PET resin layer, passes through the wearing layer of above weight proportion Material synthesis, tool
There is good Wear-resistant scratch-resistant to act on, at the same time, also enhance the impact resistance of whole eyeglass, explosion-proof function.
Further, the anti-soil layer 7 is polyvinyl chloride film, and the thickness of the anti-soil layer 7 is 0.8 μm, the anti-soil
Layer 7 is polyvinyl chloride film, can effectively prevent lens surface from, by oil pollution, keeping the cleannes of minute surface, making whole eyeglass
Look more attractive in appearance and comfortable.
Preferably, in the PC resin 1 raw material of layer, the stabilizer is organic tin stabilizer, it is easy to resin forming, tool
There is good heat endurance and the transparency, the UV resistance of synthetic resin can be increased by using organic tin stabilizer, prevented
Resin material is decomposed and old saying;The nucleator is double(To tert-butyl benzene epoxide)Sodium phosphate, by using double(To tert-butyl benzene
Epoxide)Sodium phosphate improves the tensile strength and impact strength of PC resin layer 1 as nucleator, improves PC resin 1 table of layer
The finish in face, contributes to 1 rigidity of lifting PC resin layer, crystallization rate, the transparency.
Preferably, in the PC resin 1 raw material of layer, the initiator is peroxidized t-butyl perbenzoate, peroxidating two
One kind in diisopropyl carbonate, TBHP, effectively lifts the reaction efficiency entirely reacted, shortens the reaction time;
The antioxidant is dibutyl hydroxy toluene or tetraethyl resorcinol, and with low volatilization, the performance of hydrolysis can effectively drop
The oxidized performance of low PC resin layer 1, extends the service life of eyeglass.
In addition, a kind of moulding process of the wear-resisting automotive sunshade panel eyeglass of antibacterial, the moulding process of the PC resin layer 1 includes
Following steps:
(1)Precise is carried out according to each weight proportion raw material of PC resin layer 1, after the completion of weighing, by each component
Weight proportion raw material is lower in bucket is stirred under vacuum to be stirred under vacuum, and is well mixed, mixing time is 40 min;
(2)By step(1)Middle products obtained therefrom obtains PC resin layer 1 by double screw extruder extrusion, and wherein twin-screw is squeezed
The processing temperature for going out machine is 250 DEG C;
(3)By step(2)Middle products obtained therefrom feeding curing is solidified, and hardening time is 25 min;After the completion of solidification,
Cooling and shaping.
The moulding process of PC resin layer 1 described in the utility model, moulding process is simple, easy to operate, is adapted to industrialization
Production.
Embodiment two
A kind of wear-resisting automotive sunshade panel eyeglass of antibacterial, including PC resin layer 1, the front of PC resin layer 1 are provided with stiffened
Layer 2;The front of stiffening layer 2 is provided with radiation protective layer 3;The front of radiation protective layer 3 is provided with antibiotic layer 4;The front of antibiotic layer 4
Provided with dyed layer 5;1 reverse side of the PC resin layer is provided with wearing layer 6;The reverse side of wearing layer 6 is provided with anti-soil layer 7;The PC trees
Lipid layer 1 includes following weight proportion raw material:
PC resin:80 parts, pentaerythrite:20 parts, styrene block copolymer:12 parts, 2- ethylhexyl diphenylphosphoric acids
Ester:7 parts, methacryloxypropyl silane:2 parts, maleic anhydride:5 parts, barium stearate:2.5 parts, nano silicon:1 part, surely
Determine agent:0.12 part, nucleator:0.98 part, initiator:0.1 part, antioxidant:0.5 part.
The wear-resisting automotive sunshade panel eyeglass of a kind of antibacterial that the utility model is provided, is basic unit with PC resin layer 1, makes material
Possess the more excellent transparency, chemical stability and weatherability, by the eyeglass of above Material synthesis, can not only make eyeglass phase
There is more preferable definition for ordinary resin, human pilot clearly driving vision is more ensured, moreover, shock resistance is more
It is good, it is non-breakable by hitting, with good explosion prevention function.
Further, the stiffening layer 2 is organosilicon membrane, and the thickness of the stiffening layer 2 is 3 μm, by eyeglass compound one
Layer organosilicon membrane, effectively increases the hardness and scratch resistance capability of eyeglass, eyeglass is more difficult when by shock
It is broken, at the same time can also increase by 2% light transmittance and be the more preferable adhesive force of the follow-up institute's film plating layer raising of eyeglass.
Further, the radiation protective layer 3 is polyvinyl chloride film, and the thickness of the radiation protective layer 3 is 0.5 μm, described
Low frequency radiation and microwave can be reflected and be absorbed by radiation protective layer 3, can be effective filtered out electromagnetic radiation as waves and ultraviolet, be given
Human pilot provides more healthy driving environment.
Further, the antibiotic layer 4 is PP resin film layers, and the thickness of the antibiotic layer 4 is 1 μm, and the antibiotic layer 4 is wrapped
Include following weight proportion raw material:
PP resins:70 parts, SA dibutyl ester:15 parts, acetone:20 parts, acrylamide:12.5 parts, o-aminophenol:5
Part, maleic anhydride:3 parts, polyvinyl acetate:1.6 parts, 2-ethyl-4-methylimidazole:0.2 part, nano-silver powder:1 part.
Automobile sun-shading eyeglass described in the utility model can be prevented effectively by the antibiotic layer 4 of above weight proportion Material synthesis
Eyeglass bacteria breed, protects the use eye safety of human pilot.
Further, the dyed layer 5 is polyacrylic resin layer, and the thickness of the dyed layer 5 is 2 μm, the dyed layer
5 include following weight proportion raw material:
Polyacrylic resin:55 parts, ethyl acrylate:10 parts, cyclohexanone:15 parts, cross-linking epoxide group condensation product:
7.5 parts, nano-sized iron oxide:3 parts, nano zine oxide:3 parts, molybdenum trioxide:1.5 parts, pigmented powder:0.9 part, carbon black:0.5 part.
Dyed layer 5 described in the utility model is polyacrylic resin layer, is synthesized by above weight proportion, with splendid
Light transmittance, see that things clear and natural is true, the dyed layer 5 can effectively filter strong light, under conditions of distance light light irradiation
Also dazzling sensation will not be produced, prevent dim eyesight, mitigation kopiopia, the safety driven under the strong light of effective guarantee.
Further, the wearing layer 6 is PET resin layer, and the thickness of the wearing layer 6 is 2.5 μm, and the wearing layer 6 is wrapped
Include following weight proportion raw material:
PET resin:40 parts, gamma-aminopropyl-triethoxy-silane:13 parts, polysiloxanes:2 parts, mica powder:1.6 parts, ring
Hexanone:6 parts, ethyl acetate:10 parts, polypropylene grafted maleic anhydride:0.1 part, SMA:0.5
Part.
Wearing layer 6 described in the utility model is PET resin layer, passes through the wearing layer 6 of above weight proportion Material synthesis, tool
There is good Wear-resistant scratch-resistant to act on, at the same time, also enhance the impact resistance of whole eyeglass, explosion-proof function.
Further, the anti-soil layer 7 is polyvinyl chloride film, and the thickness of the anti-soil layer 7 is 0.5 μm, the anti-soil
Layer 7 is polyvinyl chloride film, can effectively prevent lens surface from, by oil pollution, keeping the cleannes of minute surface, making whole eyeglass
Look more attractive in appearance and comfortable.
Preferably, in the PC resin 1 raw material of layer, the stabilizer is organic tin stabilizer, it is easy to resin forming, tool
There is good heat endurance and the transparency, the UV resistance of synthetic resin can be increased by using organic tin stabilizer, prevented
Resin material is decomposed and old saying;The nucleator is double(To tert-butyl benzene epoxide)Sodium phosphate, by using double(To tert-butyl benzene
Epoxide)Sodium phosphate improves the tensile strength and impact strength of PC resin layer 1 as nucleator, improves PC resin 1 table of layer
The finish in face, contributes to 1 rigidity of lifting PC resin layer, crystallization rate, the transparency.
Preferably, in the PC resin 1 raw material of layer, the initiator is peroxidized t-butyl perbenzoate, peroxidating two
One kind in diisopropyl carbonate, TBHP, effectively lifts the reaction efficiency entirely reacted, shortens the reaction time;
The antioxidant is dibutyl hydroxy toluene or tetraethyl resorcinol, and with low volatilization, the performance of hydrolysis can effectively drop
The oxidized performance of low PC resin layer 1, extends the service life of eyeglass.
In addition, a kind of moulding process of the wear-resisting automotive sunshade panel eyeglass of antibacterial, the moulding process of the PC resin layer 1 includes
Following steps:
(1)Precise is carried out according to each weight proportion raw material of PC resin layer 1, after the completion of weighing, by each component
Weight proportion raw material is lower in bucket is stirred under vacuum to be stirred under vacuum, and is well mixed, mixing time is 50 min;
(2)By step(1)Middle products obtained therefrom obtains PC resin layer, wherein twin-screw extrusion by double screw extruder extrusion
The processing temperature of machine is 240 DEG C;
(3)By step(2)Middle products obtained therefrom feeding curing is solidified, and hardening time is 30 min;After the completion of solidification,
Cooling and shaping.
The moulding process of PC resin layer 1 described in the utility model, moulding process is simple, easy to operate, is adapted to industrialization
Production.
Embodiment three
A kind of wear-resisting automotive sunshade panel eyeglass of antibacterial, including PC resin layer 1, the front of PC resin layer 1 are provided with stiffened
Layer 2;The front of stiffening layer 2 is provided with radiation protective layer 3;The front of radiation protective layer 3 is provided with antibiotic layer 4;The front of antibiotic layer 4
Provided with dyed layer 5;1 reverse side of the PC resin layer is provided with wearing layer 6;The reverse side of wearing layer 6 is provided with anti-soil layer 7;The PC trees
Lipid layer 1 includes following weight proportion raw material:
PC resin:70 parts, pentaerythrite:30 parts, styrene block copolymer:15 parts, 2- ethylhexyl diphenylphosphoric acids
Ester:5 parts, methacryloxypropyl silane:3 parts, maleic anhydride:3 parts, barium stearate:3 parts, nano silicon:It is 2 parts, stable
Agent:0.95 part, nucleator:0.5 part, initiator:0.3 part, antioxidant:0.1 part.
The wear-resisting automotive sunshade panel eyeglass of a kind of antibacterial that the utility model is provided, is basic unit with PC resin layer 1, makes material
Possess the more excellent transparency, chemical stability and weatherability, by the eyeglass of above Material synthesis, can not only make eyeglass phase
There is more preferable definition for ordinary resin, human pilot clearly driving vision is more ensured, moreover, shock resistance is more
It is good, it is non-breakable by hitting, with good explosion prevention function.
Further, the stiffening layer 2 is organosilicon membrane, and the thickness of the stiffening layer 2 is 2.5 μm, by compound to eyeglass
One layer of organosilicon membrane, effectively increases the hardness and scratch resistance capability of eyeglass, also make eyeglass by hit when more not
It is broken, at the same time can also increase by 2% light transmittance and be that the follow-up institute's film plating layer of eyeglass improves more preferable adhesive force.
Further, the radiation protective layer 3 is polyvinyl chloride film, and the thickness of the radiation protective layer 3 is 1 μm, described anti-
Low frequency radiation and microwave can be reflected and be absorbed by radiating layer 3, can effective filter out electromagnetic radiation as waves and ultraviolet, to driving
Sail personnel and more healthy driving environment is provided.
Further, the antibiotic layer 4 is PP resin film layers, and the thickness of the antibiotic layer 4 is 3 μm, and the antibiotic layer 4 is wrapped
Include following weight proportion raw material:
PP resins:60 parts, SA dibutyl ester:25 parts, acetone:15 parts, acrylamide:10 parts, o-aminophenol:8 parts,
Maleic anhydride:2 parts, polyvinyl acetate:2 parts, 2-ethyl-4-methylimidazole:1 part, nano-silver powder:0.1 part.
Automobile sun-shading eyeglass described in the utility model can be prevented effectively by the antibiotic layer 4 of above weight proportion Material synthesis
Eyeglass bacteria breed, protects the use eye safety of human pilot.
Further, the dyed layer 5 is polyacrylic resin layer, and the thickness of the dyed layer 5 is 3 μm, the dyed layer
5 include following weight proportion raw material:
Polyacrylic resin:60 parts, ethyl acrylate:20 parts, cyclohexanone:10 parts, cross-linking epoxide group condensation product:10
Part, nano-sized iron oxide:6 parts, nano zine oxide:2 parts, molybdenum trioxide:2 parts, pigmented powder:0.52 part, carbon black:0.1 part.
Dyed layer 5 described in the utility model is polyacrylic resin layer, is synthesized by above weight proportion, with splendid
Light transmittance, see that things clear and natural is true, the dyed layer 5 can effectively filter strong light, under conditions of distance light light irradiation
Also dazzling sensation will not be produced, prevent dim eyesight, mitigation kopiopia, the safety driven under the strong light of effective guarantee.
Further, the wearing layer 6 is PET resin layer, and the thickness of the wearing layer 6 is 3 μm, and the wearing layer 6 includes
Following weight proportion raw material:
PET resin:50 parts, gamma-aminopropyl-triethoxy-silane:15 parts, polysiloxanes:3 parts, mica powder:2 parts, hexamethylene
Ketone:4 parts, ethyl acetate:15 parts, polypropylene grafted maleic anhydride:1 part, SMA:0.1 part.
Wearing layer 6 described in the utility model is PET resin layer, passes through the wearing layer 6 of above weight proportion Material synthesis, tool
There is good Wear-resistant scratch-resistant to act on, at the same time, also enhance the impact resistance of whole eyeglass, explosion-proof function.
Further, the anti-soil layer 7 is polyvinyl chloride film, and the thickness of the anti-soil layer 7 is 1 μm, the anti-soil layer
7 be polyvinyl chloride film, can effectively prevent lens surface from, by oil pollution, keeping the cleannes of minute surface, seeing whole eyeglass
It is more attractive in appearance and comfortable up.
Preferably, in the PC resin 1 raw material of layer, the stabilizer is organic tin stabilizer, it is easy to resin forming, tool
There is good heat endurance and the transparency, the UV resistance of synthetic resin can be increased by using organic tin stabilizer, prevented
Resin material is decomposed and old saying;The nucleator is double(To tert-butyl benzene epoxide)Sodium phosphate, by using double(To tert-butyl benzene
Epoxide)Sodium phosphate improves the tensile strength and impact strength of PC resin layer 1 as nucleator, improves PC resin 1 table of layer
The finish in face, contributes to 1 rigidity of lifting PC resin layer, crystallization rate, the transparency.
Preferably, in the PC resin 1 raw material of layer, the initiator is peroxidized t-butyl perbenzoate, peroxidating two
One kind in diisopropyl carbonate, TBHP, effectively lifts the reaction efficiency entirely reacted, shortens the reaction time;
The antioxidant is dibutyl hydroxy toluene or tetraethyl resorcinol, and with low volatilization, the performance of hydrolysis can effectively drop
The oxidized performance of low PC resin layer 1, extends the service life of eyeglass.
In addition, a kind of moulding process of the wear-resisting automotive sunshade panel eyeglass of antibacterial, the moulding process of the PC resin layer 1 includes
Following steps:
(1)Precise is carried out according to each weight proportion raw material of PC resin layer 1, after the completion of weighing, by each component
Weight proportion raw material is lower in bucket is stirred under vacuum to be stirred under vacuum, and is well mixed, mixing time is 30 min;
(2)By step(1)Middle products obtained therefrom obtains PC resin layer, wherein twin-screw extrusion by double screw extruder extrusion
The processing temperature of machine is 260 DEG C;
(3)By step(2)Middle products obtained therefrom feeding curing is solidified, and hardening time is 20 min;After the completion of solidification,
Cooling and shaping.
The moulding process of PC resin layer 1 described in the utility model, moulding process is simple, easy to operate, is adapted to industrialization
Production.
The utility model provides a kind of antibacterial wear-resisting automotive sunshade panel eyeglass, with excellent antibacterial functions, wear-resisting work(
Energy and well shock resistance and explosion-proof performance.A kind of wear-resisting automotive sunshade panel eyeglass of described antibacterial, can ensure driver
Member's clearly driving vision, filters glare, improves driving comfort and security;Furthermore, the utility model provides a kind of
The wear-resisting automotive sunshade panel eyeglass of antibacterial, also with radiation proof, UV resistance, oil-stain-preventing function, vdiverse in function, style is attractive in appearance, property
Valency meets the actual demand of modern human pilot than high, meanwhile, the moulding process of eyeglass is simple, easy to operate, be adapted to industrialization
Production.
It should be noted that above example is only unrestricted to illustrate the technical solution of the utility model.Although ginseng
The utility model is described in detail according to preferred embodiment, it will be understood by those within the art that, can be to hair
Bright technical scheme is modified or equivalent substitution, and without departing from the scope of technical solutions of the utility model, it all should cover
In right of the present utility model.
Claims (7)
1. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial, it is characterised in that including PC resin layer, the PC resin layer front is set
There is stiffening layer;
The stiffening layer front is provided with radiation protective layer;
The radiation protective layer front is provided with antibiotic layer;
The antibiotic layer front is provided with dyed layer;
The PC resin layer reverse side is provided with wearing layer;
The wearing layer reverse side is provided with anti-soil layer.
2. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial according to claim 1, it is characterised in that the stiffening layer is
Organosilicon membrane, the thickness of the stiffening layer is 2~3 μm.
3. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial according to claim 1, it is characterised in that the radiation protective layer
For polyvinyl chloride film, the thickness of the radiation protective layer is 0.5~1 μm.
4. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial according to claim 1, it is characterised in that the antibiotic layer is
PP resin film layers, the thickness of the antibiotic layer is 1~3 μm.
5. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial according to claim 1, it is characterised in that the dyed layer
For polyacrylic resin layer, the thickness of the dyed layer is 2~3 μm.
6. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial according to claim 1, it is characterised in that the wearing layer is
PET resin layer, the thickness of the wearing layer is 2~3 μm.
7. a kind of wear-resisting automotive sunshade panel eyeglass of antibacterial according to claim 1, it is characterised in that the anti-soil layer is
Polyvinyl chloride film, the thickness of the anti-soil layer is 0.5~1 μm.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2019100189A1 (en) * | 2017-11-21 | 2019-05-31 | 苏州鑫河镜业有限公司 | Antimicrobial wear-resistant automobile sunshield mirror and mirror forming process |
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Cited By (1)
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WO2019100189A1 (en) * | 2017-11-21 | 2019-05-31 | 苏州鑫河镜业有限公司 | Antimicrobial wear-resistant automobile sunshield mirror and mirror forming process |
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