CN206364024U - Domestic glass based on 3D printing Nano diamond transparent thin-film battery - Google Patents

Domestic glass based on 3D printing Nano diamond transparent thin-film battery Download PDF

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Publication number
CN206364024U
CN206364024U CN201621261751.XU CN201621261751U CN206364024U CN 206364024 U CN206364024 U CN 206364024U CN 201621261751 U CN201621261751 U CN 201621261751U CN 206364024 U CN206364024 U CN 206364024U
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China
Prior art keywords
nano diamond
glass
layer
diamond transparent
printing
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Expired - Fee Related
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CN201621261751.XU
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Chinese (zh)
Inventor
魏舒怡
丁振伟
张秀霞
张立龙
马晓旋
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North Minzu University
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North Minzu University
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00—Integration of renewable energy sources in buildings
    • Y02B10/10—Photovoltaic [PV]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/547—Monocrystalline silicon PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Photovoltaic Devices (AREA)

Abstract

A kind of Domestic glass based on 3D printing Nano diamond transparent thin-film battery of the utility model, including glass, and glass is successively set on close to the anode layer of indoor, p-type Nano diamond transparent membrane, PN junction layer, N-type Nano diamond transparent membrane and negative electrode layer；Glass is provided with vacuum gap at least provided with one layer between adjacent glass.Its Nano diamond transparent thin-film battery by being positioned close to indoor, while window translucency is ensured, solar energy is utilized, not only save the extra space-consuming of solar panel, and utilize the setting of home window, sufficiently solar energy is absorbed, the energy spending of each family is saved；And the protection to Nano diamond transparent thin-film battery can be realized by the vacuum gap of adjacent glass part, stabilization and life-span that it is used is improved；And the setting based on 3D printing, disclosure satisfy that the glass of various different shapes and size, carry out personalized customization, strong adaptability.

Description

Domestic glass based on 3D printing Nano diamond transparent thin-film battery
Technical field
The utility model be related to it is a kind of can utilize solar energy Domestic glass, specially based on 3D printing Nano diamond The Domestic glass of transparent thin-film battery.
Background technology
Solar cell is prepared using the semiconductor silicon material of tetravalence mostly at present, the process highly energy-consuming of preparation, height Pollution.But diamond is also tetravalence, the laboratory that present people have grasped prepare Nano diamond method low power consuming, It is pollution-free, so the diamond manually prepared is commonly used in clothes, on shoes and hats.Diamond has high heat conductance, high rigidity, height The excellent physical property such as disruptive field intensity, low-friction coefficient, low-k and broad stopband and electronics and hole high mobility, And have good optical transmissibility and chemical stability, make diamond be expected to turn into high temperature with complex environment in optics, acoustics, machine The semi-conducting material that the field such as tool and semiconductor has broad application prospects.Boron impurity is mixed in diamond thin, can be with The p-type diamond thin with excellent conductive performance is obtained, is a kind of splendid semi-conducting material.Nano diamond transparent membrane It is the laminated film formed by Nano diamond crystal grain and amorphous carbon crystal boundary, it is except the excellent properties with conventional PCD Outside, also with surface continuous and derivable, specific surface area is big the features such as.Boron impurity is mixed in Nano diamond transparent membrane, it is expected to Prepare with the p-type conductivity more excellent than boron doped microcrystalline diamond thin can film, in nano electron device and There is preferable application prospect in terms of electrochemical electrode.
In existing domestic solar collection, the cell panel of large area uniform specification generally is installed to gather too on roof Positive energy, but this method price is high and efficiency is average.Disclosed solar energy glass, is inhaled using coating in the prior art Light is transferred in the solar cell of glass edge with different wave length after receiving sunshine, although use transparent material Light transmittance is unaffected, but its stability is poor, and the path that light passes through is longer, and efficiency is low, and only proposes conception at present, only Only exist in the level of theoretical research.
Utility model content
For problems of the prior art, the utility model provides a kind of based on 3D printing Nano diamond thin transparent The Domestic glass of film battery, it can make full use of the solar energy being irradiated within doors, be not take up exceptional space, and not reduce printing opacity Rate, transformation efficiency is high, it is ensured that can carry out the utilization and conversion of solar energy according to demand while illumination within doors.
The utility model is to be achieved through the following technical solutions：
Based on the Domestic glass of 3D printing Nano diamond transparent thin-film battery, including glass, and it is successively set on glass Glass is close to the anode layer of indoor, p-type Nano diamond transparent membrane, PN junction layer, N-type Nano diamond transparent membrane and negative pole Layer；Described glass is provided with vacuum gap at least provided with one layer between adjacent glass.
It is preferred that, described glass uses double layer glass, and outermost layer glass is disposed with just on indoor Pole layer, p-type Nano diamond transparent membrane, PN junction layer, N-type Nano diamond transparent membrane and negative electrode layer.
It is preferred that, described glass using three layers of double glazing, outermost layer and intermediate layer glass on indoor successively It is provided with anode layer, p-type Nano diamond transparent membrane, PN junction layer, N-type Nano diamond transparent membrane and negative electrode layer.
It is preferred that, also cladding is provided with the encapsulated layer using flexible poly-vinegar film on negative electrode layer.
It is preferred that, anode layer uses Ti/SnO2Membrane electrode, negative electrode layer uses ZnO/Al transparent membrane electrodes, anode layer With positive wire and negative wire are respectively arranged with negative electrode layer.
It is preferred that, negative wire uses the aluminium film being made up of 3D printing equipment；Positive wire is used and set by 3D printing The ito thin film prepared.
It is preferred that, described p-type Nano diamond transparent membrane and N-type Nano diamond transparent membrane are used by 3D printing The Nano diamond transparent membrane that equipment is made.
Compared with prior art, the utility model has following beneficial technique effect：
Domestic glass described in the utility model, by the Nano diamond transparent membrane electricity for being positioned close to indoor Pond, while window translucency is ensured, is utilized to solar energy, not only saves the occupancy of solar panel additionally empty Between, and using the setting of home window, sufficiently solar energy is absorbed, save the energy spending of each family；And And the protection to Nano diamond transparent thin-film battery can be realized by the vacuum gap of adjacent glass part, improve what it was used The stable and life-span；And the setting based on 3D printing, disclosure satisfy that the glass of various different shapes and size, it is personalized fixed to carry out System, improves its adaptability.
Further, by the setting of multiple glazing, and the inside of side outside window is positioned close to, can be to the sun It can carry out repeatedly most directly utilizing and absorbing；Using the setting of encapsulated layer, Nano diamond transparent membrane preferably ensure that The combination stability and reliability of battery and glass.
Further, can be more preferable by setting the positive wire and negative wire that can be obtained with 3D printing equipment The overall structure of Domestic glass is improved, solar energy utilization ratio is improved.
Brief description of the drawings
Fig. 1 is the preparation process block diagram described in the utility model example.
Fig. 2 is Nano diamond transparent membrane thermal sintering curve map described in the utility model example.
Fig. 3 is the 3D modeling figure to glass described in the utility model example.
Fig. 4 is the structural representation of the Domestic glass of double layer hollow described in the utility model example.
In figure：Glass 1, anode layer 2, p-type Nano diamond transparent membrane 3, PN junction layer 4, N-type Nano diamond thin transparent Film 5, negative electrode layer 6, vacuum gap 7.
Embodiment
The utility model is described in further detail with reference to specific embodiment, described is to the utility model Explanation rather than restriction.
A kind of Domestic glass based on 3D printing Nano diamond transparent thin-film battery of the utility model, including glass 1, with And glass 1 is successively set on close to the anode layer 2 of indoor, p-type Nano diamond transparent membrane 3, PN junction layer 4, N-type nanogold Hard rock transparent membrane 5 and negative electrode layer 6；Described glass 1 is provided with vacuum gap 7 at least provided with one layer between adjacent glass 1. Wherein, p-type Nano diamond transparent membrane 3 and N-type Nano diamond transparent membrane 5 are using the nanometer being made up of 3D printing equipment Diamond transparent membrane.
Specifically, the family expenses glass based on 3D printing Nano diamond transparent thin-film battery that the utility model is preferably obtained Glass, using double layer hollow structure, as shown in figure 4, be vacuum gap 7 in the middle of layer glass 1, it is close on outermost glass 1 Indoor sets gradually anode layer 2, p-type Nano diamond transparent membrane 3, PN junction layer 4, the and of N-type Nano diamond transparent membrane 5 Negative electrode layer 6.P-type Nano diamond transparent membrane 3 and N-type Nano diamond transparent membrane 5 are made up of 3D printing equipment.Can also Anode layer 2, p-type nanometer are disposed with indoor using using three layers of double glazing, outermost layer and intermediate layer glass Diamond transparent membrane 3, PN junction layer 4, N-type Nano diamond transparent membrane 5 and negative electrode layer 6.
Wherein, also cladding is provided with the encapsulated layer using flexible poly-vinegar film on negative electrode layer 6.Anode layer 2 uses Ti/SnO2It is thin Membrane electrode, negative electrode layer 6 uses and is respectively arranged with positive wire ITO on ZnO/Al transparent membrane electrodes, anode layer 2 and negative electrode layer 6 Film and negative wire aluminium film.
When prepared by the utility model, specifically, as shown in figure 1, for 3D printing Nano diamond transparent membrane solar energy Battery, first has to take industrialized three steps clean method to clean used glass：
Cleaning in the first step, acetone soln：Glass is put into equipped with ultrasound source and acetone soln with mechanical arm Cleaned in tank, mechanical arm there are plc controls to have three cylinders, and at least three suckers of robot section, sucker Passage be connected with vavuum pump, make sucker produce negative pressure firmly adsorb in glass surface.And ultrasound source take 20KHz~ 40KHz is to prevent shatter glass, 5~10mins of scavenging period, acetone soln concentration 10~30%.
Cleaning in second step, ethanol solution：The glass cleaned with acetone soln is put into body automatically through mechanical arm The ethanol solution that product concentration is 95~98%, and tank is also provided with ultrasound source, ultrasound source take 20KHz~40KHz with Prevent shatter glass, 5~10mins of scavenging period.
Cleaning in 3rd step, deionized water：Mechanical arm is automatically put glass equipped with ultrasonic wave and deionized water into In tank, ultrasound source takes 20KHz~40KHz to prevent shatter glass, and deionized water temperature is 25~35 DEG C, scavenging period For 20~30mins.
Secondly, the processing of solar cell positive plate and lead is carried out.
Ti/SnO is prepared using czochralski method2Electrode is used as the positive pole of solar cell, electrode reflection light transmittance and optical lens Light preferably, and can also improve energy conversion efficiency.Using titanium as base material, tin halides solid powder is added to citric acid-ethanol and mixed Heating stirring in liquid is closed, base material is put into lift in solution and smeared, is dried after taking-up, drying temperature is 120~160 DEG C, High temperature sintering is being carried out, sintering temperature is 450~550 DEG C, repeated multiple times just to can be made into solar cell positive pole.
Utilize the positive plate of the 3D printing technique controllable preparation Nano diamond transparent membrane solar cell of intelligence manufacture Lead, prepares ito thin film as the pole plate lead of positive pole on positive pole.
Again, three-dimensional data is set up according to the shape of the different types of glass of the different sizes of different home, utilizes industrial 3D Printer professional software sets up 3D mathematical models, and glass different types of for different sizes carries out accurate measurement, according to institute Obtain data and carry out 3D modeling.This example carries out 3D modeling, such as Fig. 3 using long and a width of 30cm and 20cm, thickness for 1.5cm glass It is shown.Due to carry out the manufacture of ito film by matrix of glass, the thickness of ito film, the rear degree of general ito thin film are also considered For 1~100nm.
Then, according to the 3D modeling of glass, the solar cell of the Nano diamond transparent membrane of different structure is carried out 3D printing preparation method,
The P, N-type Nano diamond transparent membrane are made using 3D printing equipment, temperature curve such as Fig. 2 when it is sintered It is shown.It is preferred that use share a kind of many work box sand mold 3D printing equipment of Group Plc utility model.
Using acetone as carbon source, B2H6For boron source, boron concentration is 500~5000ppm, using work box sand mold 3D printing equipment Acetone dissolved with boron source is injected in reative cell, 600~700 DEG C of reaction temperature, 5~6 hours reaction time, made on substrate It is standby to obtain the boron dopen Nano diamond transparent membrane precursor that thickness is 1~15nm, vacuum annealing, 30 at 800~1200 DEG C ~60 minutes, described p-type Nano diamond transparent membrane is made, many work box sand mold 3D printing equipment are recycled in nanogold Implantation dosage is 1 × 10 in hard rock transparent membrane15cm-2Phosphonium ion, and in 900 DEG C of vacuum annealings 30 minutes, obtain N-type nanometer Diamond transparent membrane.Phosphonium ion is carried out with anemostat after annealing and diffuse to form PN junction layer, obtain nanometer identical with glass shape Diamond transparent membrane, i.e. cell substrate.
4th, carry out negative plate processing, it is preferred that using shared Group Plc utility model based on FDM 3D printing equipment prepare negative plate.
Negative plate is prepared using the 3D printing equipment based on FDM, first using cell substrate as substrate, successively with acetone, ethanol Substrate is cleaned with deionized water ultrasonic wave, substrate is dried up with nitrogen, magnetron sputtering reative cell is sent into；Magnetron sputtering reative cell is taken out very It is empty to 9.0 × 10-4After Pa, substrate is heated to 100 DEG C, and adjusting argon flow amount makes air pressure reach 6Pa, is entered using pure Al as target Row magnetron sputtering, it is 100W, sputtering time 4min to control sputtering power, and the thick Al films of 258nm are obtained on substrate；Spend from Sub- water, which cleans above-mentioned sputtering, the substrate of Al films, and substrate then is heated into 200~400 DEG C, the spray of 3D printing equipment is used Head is passed through oxygen and carries Zn (HCH2CH3)2Argon gas, wherein the ratio between argon gas and oxygen flow be 1：100, jet velocity is 6s/50g~6s/100g, obtains the thick films of 500nm in the substrate for having Al films, then uses high pure nitrogen purgative gas, take out base Piece；Under oxygen atmosphere, 30min is made annealing treatment in 400 DEG C of substrates to being loaded with film, the ZnO/ under different preparation temperatures is obtained Al transparent membrane electrodes.
The pole plate lead of standby negative pole is controlled using 3D printing equipment；Using the nanometer aluminum more inexpensive than silver nanoparticle level powder Powder.Nanoscale aluminium powder and solvent are pressed 1：30 ratio mixing, then Ultrasonic Heating scattered 3 as a child obtain slurry, then by its Prepared by 3D printing on hull cell surface, laser sintering and moulding.
Finally, the method for packing based on 3D printing Nano diamond transparent thin-film battery on Domestic glass, according to difference The different packaging technology of family's different types of Glass Design of difference size.
Choose different sizes and different types of glass, positive pole and Nano diamond transparent thin-film battery, Nano diamond The thickness of transparent thin-film battery is 0.5mm；Nano diamond transparent thin-film battery will be chosen to fix, ready carve is taken out Knife, cut is marked on the surface of Nano diamond transparent thin-film battery along direction anyhow；Flexible poly-vinegar film is by positive pole and receives Rice diamond transparent thin-film battery is wrapped on glass successively, and the film that flexible poly-vinegar film is had more by edge is by positive pole and nanometer Diamond transparent thin-film battery glue seals into closed cavity；The component that flexible poly-vinegar film is wrapped is put into 3D equipment by laminating packaging Laminating packaging is carried out, the thin melting of glue is vacuumized before the film of melting is not contracted, lower room is carried out and vacuumizes, upper air bag fills Gas, makes glass press positive pole and Nano diamond transparent thin-film battery, then will be cooled to less than 70 DEG C of solar module Carry out heat laminated encapsulation.

Claims (7)

1. the Domestic glass based on 3D printing Nano diamond transparent thin-film battery, it is characterised in that including glass (1), and It is successively set on anode layer (2), p-type Nano diamond transparent membrane (3), PN junction layer (4), N-type of the glass (1) close to indoor Nano diamond transparent membrane (5) and negative electrode layer (6)；Described glass (1) is at least provided with one layer, and adjacent glass is set between (1) It is equipped with vacuum gap (7).
2. the Domestic glass according to claim 1 based on 3D printing Nano diamond transparent thin-film battery, its feature exists In described glass (1) uses double layer glass, and outermost layer glass is disposed with anode layer (2), P on indoor Type Nano diamond transparent membrane (3), PN junction layer (4), N-type Nano diamond transparent membrane (5) and negative electrode layer (6).
3. the Domestic glass according to claim 1 based on 3D printing Nano diamond transparent thin-film battery, its feature exists In described glass (1) is using three layers of double glazing, and outermost layer and intermediate layer glass are disposed with positive pole on indoor Layer (2), p-type Nano diamond transparent membrane (3), PN junction layer (4), N-type Nano diamond transparent membrane (5) and negative electrode layer (6).
4. the Domestic glass according to claim 1 based on 3D printing Nano diamond transparent thin-film battery, its feature exists In also cladding is provided with the encapsulated layer using flexible poly-vinegar film on negative electrode layer (6).
5. the Domestic glass according to claim 1 based on 3D printing Nano diamond transparent thin-film battery, its feature exists In anode layer (2) uses Ti/SnO2Membrane electrode, negative electrode layer (6) use ZnO/Al transparent membrane electrodes, anode layer (2) and bear Positive wire and negative wire are respectively arranged with pole layer (6).
6. the Domestic glass according to claim 1 based on 3D printing Nano diamond transparent thin-film battery, its feature exists In negative wire uses the aluminium film being made up of 3D printing equipment；Positive wire is thin using the ITO being made up of 3D printing equipment Film.
7. the Domestic glass according to claim 1 based on 3D printing Nano diamond transparent thin-film battery, its feature exists In described p-type Nano diamond transparent membrane (3) and N-type Nano diamond transparent membrane (5) are using by 3D printing equipment system Into Nano diamond transparent membrane.
CN201621261751.XU 2016-11-21 2016-11-21 Domestic glass based on 3D printing Nano diamond transparent thin-film battery Expired - Fee Related CN206364024U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201621261751.XU CN206364024U (en) 2016-11-21 2016-11-21 Domestic glass based on 3D printing Nano diamond transparent thin-film battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201621261751.XU CN206364024U (en) 2016-11-21 2016-11-21 Domestic glass based on 3D printing Nano diamond transparent thin-film battery

Publications (1)

Publication Number Publication Date
CN206364024U true CN206364024U (en) 2017-07-28

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Application Number Title Priority Date Filing Date
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Granted publication date: 20170728

Termination date: 20201121