CN206295780U - A kind of pouring-in simultaneous SO_2 and NO removal mercury removal device - Google Patents

A kind of pouring-in simultaneous SO_2 and NO removal mercury removal device Download PDF

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Publication number
CN206295780U
CN206295780U CN201621430913.8U CN201621430913U CN206295780U CN 206295780 U CN206295780 U CN 206295780U CN 201621430913 U CN201621430913 U CN 201621430913U CN 206295780 U CN206295780 U CN 206295780U
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China
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gas
mass flow
mercury
flow controller
generating unit
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Expired - Fee Related
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CN201621430913.8U
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Chinese (zh)
Inventor
罗津晶
毛中建
杨新宇
侯丽君
田闰枫
张晓舒
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Xiamen Bairui Environmental Protection Technology Co Ltd
Xiamen University
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Xiamen Bairui Environmental Protection Technology Co Ltd
Xiamen University
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Abstract

A kind of pouring-in simultaneous SO_2 and NO removal mercury removal device, is related to the desulphurization denitration removal of mercury.Pouring-in simultaneous SO_2 and NO removal mercury removal device is provided with coal-fired flue-gas generating unit, vapor generating unit, plasma generating unit, gas mixing units and detection unit.Coal-fired flue-gas generating unit is provided with O2、NO、SO2And N2Gas cylinder and Hg0Osmos tube and thermostat water bath;Vapor generating unit is made up of thermostat water bath, Drexel bottle;Plasma generating unit is provided with power supply and plasma reactor;Gas mixing units are provided with gas mixer chamber;Detection unit is provided with flue gas analyzer and mercury vapourmeter.The pouring-in simultaneous SO_2 and NO removal method for removing hydrargyrum uses pouring-in simultaneous SO_2 and NO removal mercury removal device.Can easily and fast, stabilization produce active particle, and due to using it is pouring-in flue gas system introduce active particle, the corrosion and loss of flue gas composition article on plasma reactor according can be avoided.

Description

A kind of pouring-in simultaneous SO_2 and NO removal mercury removal device
Technical field
The utility model is related to the desulphurization denitration removal of mercury, more particularly, to a kind of pouring-in simultaneous SO_2 and NO removal mercury removal device.
Background technology
The existing coal group of motors level of China falls behind, and gross coal consumption rate is high, and flue dust, sulphur are contained in the flue gas that coal burning is produced Oxide (SOx), nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2) and the air such as poisonous heavy metal element it is dirty Dye thing, the balance that these materials can not only destroy air causes environmental pollution, and health can be caused harm.
SO2And NOxCan form secondary with other materials in environment under physics, chemistry or biological factor after entering air Pollutant, causes acid rain and photochemical fog etc. to pollute, and causes even more serious harm.It is big that current China has become the world three First of Acid Rain Zone, to health, building, lake and ecological environment cause greatly harm to acid rain;And photochemical fog In specific geographical position, the meteorological condition of inversion and unfavorable diffusion is run into, then easily cause zonal ozone and granular pattern Pollution so that regional air quality degradation.
Mercury belongs to trace element, with very strong toxicity.Although content of the mercury in coal is relatively low, due to CHINESE COAL Charcoal consumption is big, and total emission volumn is very big, and mercury is volatile, and under the effect of bioaccumulation and amplification, mercury can be in food Concentration higher is enriched in the organism of thing chain higher level, so as to bring serious harm to biological and health.
The principle of corona treatment pollutant is that under DC Electric Field, a large amount of the taking that electric discharge is produced can electron bombardment Contaminant molecule, makes its ionization, dissociates and excite, so as to trigger the physical and chemical reaction of a series of complex so that macromolecular Pollutant is changed into simple small molecule safe material, or poisonous and harmful substance is changed into the low harmful thing of nontoxic or low toxicity Matter, finally enables pollutant degrade and removes.Plasma flue gas purifying technology has been applied to nitrogen oxides and sulfur dioxide Purification process, and achieve good effect.
At this stage due to factors such as technology or costs, dedusting, desulphurization and denitration and demercuration are past in domestic and international flue gases purification Toward being respectively completed in multiple independent systems, existing integrated treatment technology is not also due to the reason such as technology treatment effect It is highly desirable.In order to reduce the cost of gas cleaning, the new technology and new technology that exploitation multiple pollutant is removed simultaneously turn into flue gas New development trend in purification techniques field.
(Chen Tianbing, Wu Jianjun, Korea Spro's first industry pollutions that caused by coal burning present situation and its Treatment process summary coals, 2006,15 such as Chen Tianbing (2):1~4) report pollution that caused by coal burning present situation and its Treatment process summary.Cheng Ke etc. (Cheng Ke, Wang Yan, Xue Zhigang, Tian Hong, easily Roc《Fossil-fuel power plant atmospheric pollutant emission standard》Implement the influence Research of Environmental Sciences to coal-burning power plant's Mercury In The Air emission reduction .2015,28(9):1369~1374) report《Fossil-fuel power plant atmospheric pollutant emission standard》Implementation subtracts to coal-burning power plant's Mercury In The Air The influence of row.
The content of the invention
The purpose of this utility model is to provide a kind of pouring-in simultaneous SO_2 and NO removal mercury removal device.
The utility model is provided with coal-fired flue-gas generating unit, vapor generating unit, plasma generating unit, gas and mixes Close unit and detection unit.
The coal-fired flue-gas generating unit is provided with O2Gas cylinder, NO gas cylinders, SO2Gas cylinder, N2Gas cylinder, Hg0Osmos tube and flue gas are sent out Raw thermostat water bath;
There is thermostat water bath, Drexel bottle and connecting line by vapor and constitute in the vapor generating unit;
The plasma generating unit is provided with high voltage power supply and plasma reactor;
The gas mixing units are made up of gas mixer chamber (can use column glass container) and connecting line, and periphery twines There is heating tape;
The detection unit is provided with flue gas analysis unit (flue gas analyzer) and Hg0Analytic unit (mercury vapourmeter);
Vapor is produced by the Drexel bottle equipped with water being positioned in vapor generation thermostat water bath, is connected with Drexel bottle The stripping carrier gas O of constant flow rate2
The O2Cylinder outlet is respectively equipped with an O2Gas mass flow controller and the 2nd O2Gas mass flow controller, The NO cylinder outlets are provided with NO gas mass flow controllers, the SO2Cylinder outlet is provided with SO2Gas mass flow controller, institute State N2Cylinder outlet is provided with a N2Gas mass flow controller and the 2nd N2Gas mass flow controller;
First O2Gas mass flow controller output end and Drexel bottle connect plasma reactor, the 2nd O2Gas mass flow Controller output end connects Drexel bottle, and Drexel bottle is located at vapor to be occurred in thermostat water bath, the output of NO gas mass flow controller End, SO2Gas mass flow controller output end, a N2Gas mass flow controller output end and Hg0Osmos tube output end is distinguished Connect gas mixer chamber, the 2nd N2Gas mass flow controller output termination Hg0Osmos tube, Hg0Osmos tube is located at flue gas and constant temperature occurs In water-bath, the output end of gas mixer chamber connects flue gas analyzer, mercury vapourmeter and exhaust gas processing device respectively.
KCl bottles and tube furnace can be sequentially provided with the import of mercury vapourmeter.
The method for carrying out the pouring-in simultaneous SO_2 and NO removal removal of mercury using the utility model is as follows:
1) flow of mass flow controller is respectively set to O2 400 1#、O2 100 2#、SO2 80、NO 66、N2 854, unit is mL/min;
2) open flue gas and thermostat water bath occurs, open N2Gas cylinder, makes Hg0Osmos tube is in constant bath temperature 57.5 DEG C, the stabilization 2h under constant flow rate 0.2L/min carrier gas strippings obtains the mercury release rate of stabilization;
3) steam evaporator is opened, it is produced the aqueous O of steady concentration2, open temperature control box and set its temperature as 140 DEG C, heating tape is set to be stably held in 140 DEG C;
4) O is opened2Gas cylinder and mass flow controller and valve, O2Enter plasma reactor (plasma with vapor Reactor according is closed), the flow of gas mixer chamber is entered by pump control, mix in gas mixing room with simulated flue gas component It is even, by flue gas analysis unit (flue gas analyzer) and Hg0Flue gas composition concentration in analytic unit (mercury vapourmeter) detecting system (NO, SO2) and Hg0Concentration, if surveyed Hg0Concentration is 50 μ g/m3, then step 5 can be carried out), otherwise wait for Hg0Osmos tube stabilization;
5) high voltage power supply is opened, regulation voltage makes O to 5kV2With vapor by produced after plasma discharge reaction Active particle reacted in gas mixing room by with simulated flue gas component, by flue gas analyzer and mercury vapourmeter detecting system NO、SO2And Hg0Concentration, after measured result contrast, you can obtain the active oxidation particle of ion precursor reactant generation for NO, SO2 And Hg0Oxidation efficiency;
6) flue gas absorbs Hg respectively by KCl solution and NaOH alkali lye2+After sour gas, by flue gas analyzer and survey mercury The pollutant concentration of instrument inspection system outlet, draws the efficiency of the system desulphurization denitration removal of mercury.
The beneficial effects of the utility model are:Can easily and fast, stabilization generation active particle, and due to using note Enter formula and introduce active particle in flue gas system, the corrosion and loss of flue gas composition article on plasma reactor according can be avoided.This practicality It is new that O is introduced in discharge system2And vapor, electric discharge atmosphere it is pure, be conducive to electric discharge to carry out, and produce active particle group Into controllable with concentration, OH, O, O are mainly produced3Deng with the active particle compared with strong oxidizing property, be conducive to the oxidation of mixed flue gas.
The active particle that discharge system is produced is via injection mode and fully compositional simulation coal-fired flue-gas in gas mixing units Mixing, and realized to NO, SO by equipment such as flue gas analyzer and mercury vapourmeters2And Hg0Real-time monitoring.System design is convenient real With, pipeline using acidproof, high temperature resistant (<200 DEG C) material.
Brief description of the drawings
Fig. 1 is the structure composition schematic diagram of the utility model embodiment.
Specific embodiment
Referring to Fig. 1, the utility model is provided with coal-fired flue-gas generating unit, vapor generating unit 2, plasma and list occurs Unit, gas mixing units and detection unit.
The coal-fired flue-gas generating unit is provided with O2Gas cylinder 11, NO gas cylinders 12, SO2Gas cylinder 13, N2Gas cylinder 14, Hg0Osmos tube 16 and flue gas occur thermostat water bath 17;
There is thermostat water bath 21, Drexel bottle 22 and connecting line by vapor and constitute in the vapor generating unit;
The plasma generating unit is provided with high voltage power supply 31 and plasma reactor 32;
The gas mixing units are made up of gas mixer chamber 4 (can use column glass container) and connecting line, periphery It is tied with heating tape;
The detection unit is provided with flue gas analysis unit (flue gas analyzer 51) and Hg0Analytic unit (mercury vapourmeter 52);
Vapor is produced by the Drexel bottle 22 equipped with water being positioned in vapor generation thermostat water bath 21, Drexel bottle 22 Inside it is connected with the stripping carrier gas O of constant flow rate2
The O2The outlet of gas cylinder 11 is respectively equipped with an O2The O of gas mass flow controller 111 and the 2nd2Gas mass flow control Device processed 112, the outlet of NO gas cylinders 12 is provided with NO gas mass flow controller 121, the SO2The outlet of gas cylinder 13 is provided with SO2Makings Amount flow controller 131, the N2The outlet of gas cylinder 14 is provided with a N2The N of gas mass flow controller 141 and the 2nd2Gas quality stream Amount controller 142;
First O2The output end of gas mass flow controller 111 and Drexel bottle 22 connect plasma reactor 32, the 2nd O2Makings The amount output termination Drexel bottle 22 of flow controller 112, Drexel bottle 22 is located at vapor to be occurred in thermostat water bath 21, NO makings amounts The output end of flow controller 121, SO2The output end of gas mass flow controller 131, a N2Gas mass flow controller 141 is exported End and Hg0The output end of osmos tube 16 connects gas mixer chamber 4, the 2nd N respectively2The output termination of gas mass flow controller 142 Hg0Ooze Saturating pipe 16, Hg0Osmos tube 16 is located at flue gas to be occurred in thermostat water bath 17, the output end difference cigarette receiving qi leel of gas mixer chamber 4 Analyzer 51, mercury vapourmeter 52 and exhaust gas processing device 55.
KCl bottles 53 and tube furnace 54 can be sequentially provided with the import of mercury vapourmeter 52.
The method for carrying out the pouring-in simultaneous SO_2 and NO removal removal of mercury using the utility model is as follows:
1) flow of mass flow controller is respectively set to O2 400 1#、O2 100 2#、SO2 80、NO 66、N2 854, unit is mL/min;
2) open flue gas and thermostat water bath occurs, open N2Gas cylinder, makes Hg0Osmos tube is in constant bath temperature 57.5 DEG C, the stabilization 2h under constant flow rate 0.2L/min carrier gas strippings obtains the mercury release rate of stabilization;
3) steam evaporator is opened, it is produced the aqueous O of steady concentration2, open temperature control box and set its temperature as 140 DEG C, heating tape is set to be stably held in 140 DEG C;
4) O is opened2Gas cylinder and mass flow controller and valve, O2Enter plasma reactor (plasma with vapor Reactor according is closed), the flow of gas mixer chamber is entered by pump (see the mark A in Fig. 1) control, with simulated flue gas component in gas It is well mixed in body mixing chamber, by flue gas analysis unit (flue gas analyzer 51) and Hg0Analytic unit (mercury vapourmeter 52) detection system Flue gas composition concentration (NO, SO in system2) and Hg0Concentration, if surveyed Hg0Concentration is 50 μ g/m3, then step 5 can be carried out), otherwise etc. Treat Hg0Osmos tube stabilization;
5) high voltage power supply is opened, regulation voltage makes O to 5kV2With vapor by produced after plasma discharge reaction Active particle reacted in gas mixing room by with simulated flue gas component, by flue gas analyzer and mercury vapourmeter detecting system NO、SO2And Hg0Concentration, after measured result contrast, you can obtain the active oxidation particle of ion precursor reactant generation for NO, SO2 And Hg0Oxidation efficiency;
6) flue gas absorbs Hg respectively by KCl solution and NaOH alkali lye2+After sour gas, by flue gas analyzer and survey mercury The pollutant concentration of instrument inspection system outlet, draws the efficiency of the system desulphurization denitration removal of mercury.
1. each part is assembled into the device of the complete pouring-in simultaneous SO_2 and NO removal removal of mercury by Fig. 1, is used in the system To solution be matching while using.
2. producing simulation coal-fired flue-gas (the 50 μ g/m3Hg at 140 DEG C containing typical concentration component0, 9% moisture, 300ppm NO、300ppm SO2) as a example by, operate as follows:
The flow of mass flow controller shown in Fig. 1 is respectively set to (unit by 3:mL/min)O2 400 1#、O2 100 2#、SO2 80、NO 66、N2 854。
4. water-bath is opened, N is opened2, mercury osmos tube is in 57.5 DEG C constant of bath temperature, in constant flow rate Stabilization 2h obtains the mercury release rate of stabilization under 0.2L/min carrier gas strippings.Steam evaporator is opened, it is produced steady concentration Aqueous O2.Open temperature control box and set its temperature as 140 DEG C, heating tape is stably held in 140 DEG C.
5. O is opened2Gas cylinder and mass flow controller and valve, O2Enter plasma reactor (plasma with vapor Reactor according is closed), the flow of route 1 is entered by pump control, extract 450mL/min, remaining 50mL/min route vias 1 and mould out Intend flue gas composition (1L/min) to be well mixed in mixing chamber, flue gas composition concentration (NO and SO in detecting system2) and Hg0Concentration. If surveyed Hg0Concentration is 50 μ g/m3, then next step can be carried out, otherwise wait mercury pipe stabilization.
6. turn on the power, slow regulation voltage makes O to 5kV2With vapor by produced after plasma discharge reaction Active particle fully reacted in mixing chamber with simulated flue gas component (1L/min) by route 1, by flue gas analyzer and survey mercury NO, SO in instrument detecting system2And Hg0Concentration.By with 2.3 in measured result contrasted, you can obtain ion precursor reactant generation Active oxidation particle for NO, SO2And Hg0Oxidation efficiency.
7. flue gas absorbs Hg respectively by KCl solution and NaOH alkali lye in system2+After sour gas, by flue gas analyzer The pollutant concentration exported with mercury vapourmeter inspection system, draws the efficiency of the system desulphurization denitration removal of mercury.

Claims (3)

1. a kind of pouring-in simultaneous SO_2 and NO removal mercury removal device, it is characterised in that be provided with coal-fired flue-gas generating unit, vapor hair Raw unit, plasma generating unit, gas mixing units and detection unit;
The coal-fired flue-gas generating unit is provided with O2Gas cylinder, NO gas cylinders, SO2Gas cylinder, N2Gas cylinder, Hg0Osmos tube and flue gas occur permanent Warm water bath;
There is thermostat water bath, Drexel bottle and connecting line by vapor and constitute in the vapor generating unit;
The plasma generating unit is provided with high voltage power supply and plasma reactor;
The gas mixing units are made up of gas mixer chamber and connecting line, and periphery is tied with heating tape;
The detection unit is provided with flue gas analyzer and mercury vapourmeter;
Vapor is produced by the Drexel bottle equipped with water being positioned in vapor generation thermostat water bath, is connected with Drexel bottle constant The stripping carrier gas O of flow2
The O2Cylinder outlet is respectively equipped with an O2Gas mass flow controller and the 2nd O2Gas mass flow controller, it is described NO cylinder outlets are provided with NO gas mass flow controllers, the SO2Cylinder outlet is provided with SO2Gas mass flow controller, the N2 Cylinder outlet is provided with a N2Gas mass flow controller and the 2nd N2Gas mass flow controller;First O2Gas mass flow control Device output end processed and Drexel bottle connect plasma reactor, the 2nd O2The output termination Drexel bottle of gas mass flow controller, gas washing Bottle is located at vapor to be occurred in thermostat water bath, NO gas mass flow controllers output end, SO2Gas mass flow controller is exported End, a N2Gas mass flow controller output end and Hg0Osmos tube output end connects gas mixer chamber, the 2nd N respectively2Makings amount Flow controller output termination Hg0Osmos tube, Hg0Osmos tube is located at flue gas to be occurred in thermostat water bath, the output of gas mixer chamber End connects flue gas analyzer, mercury vapourmeter and exhaust gas processing device respectively.
2. as claimed in claim 1 a kind of pouring-in simultaneous SO_2 and NO removal mercury removal device, it is characterised in that in the import of mercury vapourmeter It is sequentially provided with KCl bottles and tube furnace.
3. as claimed in claim 1 a kind of pouring-in simultaneous SO_2 and NO removal mercury removal device, it is characterised in that the gas mixer chamber Periphery is tied with heating tape.
CN201621430913.8U 2016-12-23 2016-12-23 A kind of pouring-in simultaneous SO_2 and NO removal mercury removal device Expired - Fee Related CN206295780U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106492601A (en) * 2016-12-23 2017-03-15 厦门大学 A kind of pouring-in simultaneous SO_2 and NO removal method for removing hydrargyrum
CN109647124A (en) * 2018-11-19 2019-04-19 华中科技大学 A kind of plasma flame method lead occurs and adsorption reaction integral system and method
CN113354016A (en) * 2021-05-06 2021-09-07 浦恩远 Water sample mercury vapor stripping and concentrating device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106492601A (en) * 2016-12-23 2017-03-15 厦门大学 A kind of pouring-in simultaneous SO_2 and NO removal method for removing hydrargyrum
CN109647124A (en) * 2018-11-19 2019-04-19 华中科技大学 A kind of plasma flame method lead occurs and adsorption reaction integral system and method
CN113354016A (en) * 2021-05-06 2021-09-07 浦恩远 Water sample mercury vapor stripping and concentrating device

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Granted publication date: 20170704