CN206242627U - A kind of nana intelligent thermal-insulation window film - Google Patents
A kind of nana intelligent thermal-insulation window film Download PDFInfo
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- CN206242627U CN206242627U CN201620984315.9U CN201620984315U CN206242627U CN 206242627 U CN206242627 U CN 206242627U CN 201620984315 U CN201620984315 U CN 201620984315U CN 206242627 U CN206242627 U CN 206242627U
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Abstract
The utility model is related to a kind of nana intelligent thermal-insulation window film, and it is by anti-scratch layer（1）, polyester film or makrolon film base material（2‑1）, the heat-insulated glue-line of intelligence（3）, the polyester film with the coat of metal or the makrolon film base material with the coat of metal（2‑2）, ultraviolet-resistant pressure-sensitive adhesive layer（4）And mould release membrance（5）Constitute；Anti-scratch layer（1）With reference in polyester film or makrolon film base material（2‑1）A surface on, the heat-insulated glue-line of intelligence（3）With reference in polyester film or makrolon film base material（2‑1）Another surface on, the polyester film with the coat of metal or the makrolon film base material with the coat of metal（2‑2）Metal coating surface in the heat-insulated glue-line of intelligence（3）Outer surface, ultraviolet-resistant pressure-sensitive adhesive layer（4）In the polyester film with the coat of metal or the makrolon film base material with the coat of metal（2‑2）Another surface on, mould release membrance（5）In ultraviolet-resistant pressure-sensitive adhesive layer（4）Outer surface.This fenestrated membrane has compared with low-E and compared with high visible light transmissivity.
Description
Technical field
The utility model is specifically related to a kind of nana intelligent thermal-insulation window film, is particularly suitable for being pasted onto the glass surface of building
Or the glass surface of automobile.
Background technology
According to statistics, building energy consumption accounts for 1/3rd of social total energy consumption, and building forms are buildings goes along with sb. to guard him
Important component in structure, research has shown that, forms energy loss accounts for the 50% of whole building thing building enclosure energy loss
Left and right.Forms and curtain wall transformation are the keys of building energy-saving, there was only two kinds to the method for existing building glass green transformation
Selection：One is that original glass of dismantling changes energy-saving glass, and two is to stick thermal isolation film for building to original glass.Torn open in method one
Fall the generation that original glass not only results in substantial amounts of building waste, and change the relatively costly of energy-saving glass；In method two
Using the method for adhering film to glass, sunshade can be greatly reduced in the case of not changing original clear glass outward appearance, keeping daylighting high
Coefficient, is decreased obviously building electricity consumption.
Thermal-insulation window film on the market at present, can play good infrared ray barriers function, but to winter, it is desirable to
Solar energy gets in and brings heat, and current thermal isolation film can not accomplish；The use of automobile is more and more universal, and in state
Inside almost each car can all paste automobile heat insulation fenestrated membrane, and automobile heat insulation fenestrated membrane is used as having heat-insulated, UV resistance, attractive in appearance, anti-dazzle concurrently
Deng multipotency in the product of one, its heat-insulating and energy-saving function is increasingly taken seriously, but there is also a problem, in the car temperature compared with
When low, thermal isolation film has also intercepted the heat in the sun can not be into the car.
Application No. 201210019446.x Chinese patents disclose a kind of intelligent temperature control energy-conservation composite film-stuck, the intelligent temperature
Control energy-conservation composite film-stuck can realize cold and hot bidirectional modulation, so as to reach the effect that winter is warming, summer is heat-insulated.But its product knot
Basement membrane in structure is common basement membrane, therefore, radiance is higher, has in the environment of heating equipment for winter and occurs that heat radiation is big
Heat losses are caused, the weather of northern cold summer heat is not particularly suited for.
The Chinese patent of Application No. 200810033032.6 discloses a kind of intelligent heat-insulating film and preparation method thereof, but
Its structure is single layer structure, and weatherability cannot ensure that coating there is also problem, wear-resisting scratch resistance in the adhesive force of substrate surface
Can be poor, while in actual applications can also there is problem in its construction.
The Chinese patent of Application No. 201410568704.9 discloses the preparation method of temperature control fenestrated membrane and temperature control fenestrated membrane, and it is adopted
It is dry coating method i.e. magnetron sputtering method, is repeatedly sputtered on flexible parent metal, complex manufacturing, high cost, while
Adhesive force of its coating on base material cannot ensure that the temperature control fenestrated membrane cannot be used, it is necessary to carry out gluing just again directly against glass
Can paste on glass and use.
The content of the invention
The purpose of this utility model is：A kind of nana intelligent thermal-insulation window film is provided, with relatively low radiance and higher
Visible light transmissivity, has good heat insulation effect in the case where daylighting is not influenceed；It can also be according to environment temperature simultaneously
Height, automatically optionally intercept or pass through infrared ray rejection rate, apply on automobile and glass of building, reach every
The effect of thermal center energy.
Realizing the technical scheme of the utility model purpose is：A kind of nana intelligent thermal-insulation window film, it is by anti-scratch layer, gathers
Ester film or makrolon film base material, the heat-insulated glue-line of intelligence, the polyester film with the coat of metal or the poly- carbonic acid with the coat of metal
Ester film base material, ultraviolet-resistant pressure-sensitive adhesive layer and mould release membrance are constituted, and each layer is complex as a whole；
The anti-scratch layer ultraviolet light polymerization combine on a surface of polyester film or makrolon film base material, intelligence every
Hot glue layer heat cure is combined on another surface of polyester film or makrolon film base material, polyester film with the coat of metal or
The metal coating surface of the makrolon film base material with the coat of metal is compounded in the outer surface of the heat-insulated glue-line of intelligence, ultraviolet-resistant
Pressure-sensitive adhesive layer heat cure is combined in the another of the polyester film with the coat of metal or the makrolon film base material with the coat of metal
On individual surface, mould release membrance is compounded in the outer surface of ultraviolet-resistant pressure-sensitive adhesive layer.
In the above-mentioned technical solutions, at the polyester film or makrolon film base material are surfaces by sided corona treatment or chemistry
The transparent polyester film or makrolon film base material of reason, or dyeing polyester film or makrolon film base material or be primary colors gather
Ester film or makrolon film base material, or ultraviolet-resistant polyester film or makrolon film base material, or aluminized polyester film or
Makrolon film base material, or magnetron sputtering polyester film or makrolon film base material.
In the above-mentioned technical solutions, the polyester film with the coat of metal or the polycarbonate membrane base with the coat of metal
The coat of metal of material is attached on a surface of polyester film or makrolon film base material by magnetron sputtering.
In the above-mentioned technical solutions, the nana intelligent thermal-insulation window film thickness is 50~444 μm, wherein, anti-scratch layer
Thickness is 1~5 μm；The thickness of polyester film or makrolon film base material is 12~175 μm；The thickness of the heat-insulated glue-line of nana intelligent is
6~25 μm；The thickness of the polyester film with the coat of metal or the makrolon film base material with the coat of metal is 12~175 μm；
The thickness of ultraviolet-resistant pressure-sensitive adhesive layer is 6~25 μm；The thickness of mould release membrance is 19~39 μm.
In the above-mentioned technical solutions, the polyester film or makrolon film base material and polyester film or band with the coat of metal
There is the thickness of the makrolon film base material of the coat of metal identical or difference.
It is of the present utility model to have the technical effect that：The utility model nana intelligent thermal-insulation window film has composite construction, it be by
Anti-scratch layer, polyester film or makrolon film base material, the heat-insulated glue-line of intelligence, the polyester film with the coat of metal or with metal-plated
The makrolon film base material of layer, ultraviolet-resistant pressure-sensitive adhesive layer and mould release membrance are constituted and each layer is complex as a whole, and each layer has mutual
Synergy；In the heat-insulated glue-line of intelligence in the utility model nana intelligent thermal-insulation window film containing an appropriate number of nana intelligent every
Hot material, the material is undergone phase transition in temperature uncomfortable less than human body, and the infrared ray allowed in the sun is passed through, and improves indoor environment
Temperature, and when temperature is higher, effectively intercept ultrared transmission, reach heat-insulated effect；Adopted in the utility model simultaneously
Polyester film with the coat of metal or the relatively low radiance of the makrolon film base material with the coat of metal, show it with heat
It is few to there is heat exchange in the form of radiation and environment, with preferable heat preservation and insulation, is warmed oneself area in north of china in winter, can be by
Heat radiation stays within, and reaches the effect of insulation stabilization；The utility model also has scratch resistance wear-resisting functions simultaneously.Additionally, this
The preparation method of the nana intelligent thermal-insulation window film of utility model is simple to operation, is firmly combined between each layer, using very convenient,
When using, after outermost mould release membrance is peeled off, the glass surface of automotive window, building is pasted onto, i.e., with relatively low spoke
The effect of rate and visible light transmissivity higher is penetrated, there is good heat insulation effect in the case where daylighting is not influenceed；While its
Automatically can also optionally intercept or pass through infrared ray according to the height of environment temperature, apply in automobile and building
On glass, the effect of heat-insulating and energy-saving is reached.
Brief description of the drawings
Fig. 1 is a kind of structural representation of nana intelligent thermal-insulation window film of the present utility model.
Specific embodiment
The utility model is further described in detail below in conjunction with drawings and Examples, but it is not limited.
Embodiment is raw materials used, unless otherwise indicated, is commercially available industrial goods, commercially available by commercial channel.
As shown in figure 1, a kind of nana intelligent thermal-insulation window film, it is by anti-scratch layer 1, polyester film or makrolon film base material
It is 2-1, the heat-insulated glue-line 3 of intelligence, the polyester film with the coat of metal or the makrolon film base material 2-2 with the coat of metal, ultraviolet
Intercept pressure-sensitive adhesive layer 4 and mould release membrance 5 is constituted, and each layer is complex as a whole；
The ultraviolet light polymerization of the anti-scratch layer 1 is combined on a surface of polyester film or makrolon film base material 2-1, intelligence
The heat cure of energy heat-insulated glue-line 3 is combined on another surface of polyester film or makrolon film base material 2-1, with the coat of metal
The metal coating surface of polyester film or the makrolon film base material 2-2 with the coat of metal is compounded in the outer of the heat-insulated glue-line 3 of intelligence
Surface, the heat cure of ultraviolet-resistant pressure-sensitive adhesive layer 4 is combined in the polyester film with the coat of metal or the poly- carbonic acid with the coat of metal
On another surface of ester film base material 2-2, mould release membrance 5 is compounded in the outer surface of ultraviolet-resistant pressure-sensitive adhesive layer 4.
In nana intelligent thermal-insulation window film, the polyester film or makrolon film base material 2-1 are surfaces by sided corona treatment
Or chemically treated transparent polyester film or makrolon film base material, or dyeing polyester film or makrolon film base material or
It is primary colors polyester film or makrolon film base material, or ultraviolet-resistant polyester film or makrolon film base material, or aluminize
Polyester film or makrolon film base material, or magnetron sputtering polyester film or makrolon film base material.
In nana intelligent thermal-insulation window film, the polyester film with the coat of metal or the makrolon with the coat of metal
The coat of metal of film base material 2-2 is attached on a surface of polyester film or makrolon film base material by magnetron sputtering.
In nana intelligent thermal-insulation window film, the nana intelligent thermal-insulation window film thickness is 50~444 μm, wherein, scratch resistance
The thickness of layer 1 is 1~5 μm；The thickness of polyester film or makrolon film base material 2-1 is 12~175 μm；The heat-insulated glue-line of nana intelligent
3 thickness is 6~25 μm；The thickness of the polyester film with the coat of metal or the makrolon film base material 2-2 with the coat of metal
It is 12~175 μm；The thickness of ultraviolet-resistant pressure-sensitive adhesive layer 4 is 6~25 μm；The thickness of mould release membrance 5 is 19~39 μm.
In nana intelligent thermal-insulation window film, the polyester film or makrolon film base material 2-1 and poly- with the coat of metal
The thickness of ester film or the makrolon film base material 2-2 with the coat of metal is identical or difference.
Embodiment 1 ~ 3 prepares nana intelligent thermal-insulation window film A ~ C
Concrete operations are as follows：
（A）Prepare raw material
1. base material is prepared
Thickness is 23 μm of transparent polyester film base material 2-1；Prepare the polyester film base with the coat of metal that thickness is 23 μm
Material 2-2, one surface has the silver metal layer of magnetron sputtering；Prepare the mould release membrance 5 that thickness is 23 μm；
2. the mixed material for forming anti-scratch layer 1 is prepared
In mass ratio it is 1：1 prepares scraping-resistant agent and solvent ethyl acetate, and the two well mixed being obtained is formed into wearing layer
Mixed material, saves backup, wherein, scraping-resistant agent is the urethane acrylate class coating of suitable Chemical Co., Ltd.'s production in Danyang
BW1001；Ethyl acetate comes from Changzhou Asource Chemical Co., Ltd.；
3. the mixed material A~C for forming the heat-insulated glue-line 3 of intelligence is prepared
The mixed material for forming the heat-insulated glue-line of the intelligence is by nana intelligent 1~50wt% of heat-barrier material, solvent acetic acid second
Ester 20~35 wt%, 10~25wt% of solvent toluene, 50~65wt% of adhesive, the wt% of curing agent 0.5~2.0 composition are above-mentioned
Each component sum is 100 wt%, and Ju Ti Pei Fang is shown in Table 1.
Each component is weighed by the formula ratio of table 1, at being 18~28 DEG C in environment temperature, in container, first by nana intelligent
After heat-barrier material is mixed and stirred for 12~18 minutes with solvent toluene, then the mixture with solvent ethyl acetate and stirring 12~18
After minute, acrylic acid adhesive is added, after stirring 18~22 minutes, after adding curing agent to be stirred for 12~18 minutes, with rotation
Viscosimeter or Cai's grace cup measurement viscosity are 80~300 centipoises, you can the mixture for forming the heat-insulated glue-line of intelligence is obtained respectively
Material A~C, you can save backup.
Table 1
The raw material of nana intelligent heat-barrier material used by table 1 is the nano-silica of Shanghai Huzheng Nano-Tech Co., Ltd.'s production
Change vanadium dispersion liquid, the vanadium dioxide dispersion liquid of mixed nanometer tungsten, wherein, the nano vanadium dioxide of nano vanadium dioxide dispersion liquid contains
It is 10wt% to measure, and the vanadium dioxide content of the mixed nanometer tungsten of the vanadium dioxide dispersion liquid of mixed nanometer tungsten is 15wt%；
In table 1 consumption of nana intelligent heat-barrier material refer to actually contain in dispersion liquid used nano vanadium dioxide, receive
The quantity of the vanadium dioxide of rice Doped Tungsten；
Adhesive is that acrylic acid adhesive is that SAA1401 is produced by Xi'an Naviation Sanwo Chemical Co., Ltd., and its solid contains
It is 40wt%~45wt% to measure, or polyurethane adhesive is that SOL-760 is produced by Ai Jing KCCs of South Korea, its solid
Content is 33wt%~37wt%；
Curing agent is SAC12（Used cooperatively with acrylic acid adhesive SAA1401）By aluminium acetylacetonate 5wt%, toluene
65wt%, isopropanol 35wt% constitute, be Xi'an Naviation Sanwo Chemical Co., Ltd. production, its solids content be 4.5wt%~
5.5wt%, or curing agent is DN-980S, and it is HMDI, is that South Korea's love respects chemical strain
Formula commercial firm produces, its solids content 100wt%（Used cooperatively with polyurethane adhesive SOL-760）；
Ethyl acetate and toluene are the production of Changzhou Asource Chemical Co., Ltd.；
4. the mixed material for forming ultraviolet-resistant pressure-sensitive adhesive layer 4 is prepared
By adhesive：Solvent：Ultraviolet absorber：The mass ratio of curing agent is 20：20：0.3：0.3 prepares each component, in ring
Border temperature be 15~25 DEG C at, saved backup after stirring；
Wherein, adhesive is the SAA1401 of Xi'an Naviation Sanwo Chemical Co., Ltd.'s production, and its solids content is 40wt%
~45wt%；Ultraviolet absorber is Tinuvin 571, is German BASF joint-stock company production, and its solids content is
99.9wt%；Curing agent be Xi'an Naviation Sanwo Chemical Co., Ltd. production SAC12, its solids content be 4.5wt%~
5.5wt%；Solvent is ethyl acetate, from Changzhou Asource Chemical Co., Ltd.；
In nana intelligent thermal-insulation window film, form the mixed material of the anti-scratch layer 1, form the heat-insulated glue-line 3 of intelligence
Mixed material and the mixed material for forming ultraviolet-resistant pressure-sensitive adhesive layer 4 are coated with using slit, or scraper type coating method
It is coated to form coating.
（B）Prepare nana intelligent thermal-insulation window film
1. nana intelligent thermal-insulation window film A is prepared
On a surface of transparent polyester film 2-1, after coating forms the mixed material of anti-scratch layer 1, temperature 80~
150 DEG C, anti-scratch layer 1 is obtained after ultraviolet light polymerization, the heat-insulated glue-line of intelligence is coated on another surface of transparent polyester film 2-1
Mixed material A after, in 80~130 DEG C of temperature, place 10~120 seconds solidify afterwards and obtain the heat-insulated glue-line 3 of intelligence, with argent
The metal coating surface of the polyester film 2-2 of coating is compounded in the outer surface of the heat-insulated glue-line 3 of intelligence, poly- with plated metallic silver
After coating forms the mixed material of ultraviolet-resistant pressure-sensitive adhesive layer on another surface of ester film 2-2, in 80~130 DEG C of temperature, put
Put 10~120 seconds solidify afterwards and obtain ultraviolet-resistant pressure-sensitive adhesive layer 4, then mould release membrance 5 is compounded in the appearance of ultraviolet-resistant pressure-sensitive adhesive layer 4
Face, so as to obtain the thermal-insulation window film A of the nana intelligent that each layer is complex as a whole（As shown in Figure 1）.
2. nana intelligent thermal-insulation window film B is prepared
Nana intelligent thermal-insulation window film A methods are essentially identical with preparing, and difference is the mixed material B with the heat-insulated glue-line of intelligence
The mixed material A of the heat-insulated glue-line of intelligence is replaced, nana intelligent thermal-insulation window film B is obtained（As shown in Figure 1）.
3. nana intelligent thermal-insulation window film C is prepared
Nana intelligent thermal-insulation window film C methods are essentially identical with preparing, and difference is the mixed material C with the heat-insulated glue-line of intelligence
The mixed material A of the heat-insulated glue-line of intelligence is replaced, nana intelligent thermal-insulation window film B is obtained（As shown in Figure 1）.
（C）Detection nana intelligent thermal-insulation window film performance
Performance to the nana intelligent thermal-insulation window film A~C of above-mentioned preparation detects, the results are shown in Table 2.
Table 2
Note：In table 2, each item data is as follows to the utility model nana intelligent thermal-insulation window film obtained in embodiment
A~C carries out detecting acquisition：
1. light transmittance：The solar film transmission measurement instrument produced using Lin Shang Science and Technology Ltd.s of Shenzhen（Model
LS103）, carried out with reference to ASTM D1003 standard methods；
2. ultraviolet-resistant rate：Tested using Japanese Shimadzu UV-3600 types spectrophotometer, with reference to standard GB/T/T
2680 are detected；
3. peel strength：Detected with reference to standard GB/T/T 2792；
4. hardness：Detected with reference to standard GB/T/T 6739.
Nana intelligent thermal-insulation window film of the present utility model is can be seen that from the testing result of table 2, in temperature Gao Shineng effectively
Infrared ray is intercepted, a large amount of infrared rays are passed through when temperature is low, while do not influence user's sight line again, ultraviolet-resistant rate ＞ 99%.Its
Product translucency, hardness, peel strength meet user's requirement.
It is very simple using nana intelligent thermal-insulation window film of the present utility model, as long as after being cut according to specific size, will be from
The outermost layer of type film 5 is pasted onto glass surface after peeling off.The utility model nanometer is pasted on the glass such as building, automobile
After intelligent thermal-insulation window film, the effect of insulation and heat-insulating and energy-saving can be very well played.The utility model have relatively low radiance and
Visible light transmissivity higher, has good heat insulation effect in the case where daylighting is not influenceed；It can also be according to ring simultaneously
The height of border temperature, automatically optionally intercepts or passes through infrared ray rejection rate, applies on automobile and building glass, reaches
To the effect of heat-insulating and energy-saving.
Claims (5)
1. a kind of nana intelligent thermal-insulation window film, it is characterised in that it is by anti-scratch layer（1）, polyester film or polycarbonate membrane base
Material（2-1）, the heat-insulated glue-line of intelligence（3）, the polyester film with the coat of metal or the makrolon film base material with the coat of metal（2-
2）, ultraviolet-resistant pressure-sensitive adhesive layer（4）And mould release membrance（5）Constitute, and each layer is complex as a whole；
The anti-scratch layer（1）Ultraviolet light polymerization is combined in polyester film or makrolon film base material（2-1）A surface on, intelligence
Can heat-insulated glue-line（3）Heat cure is combined in polyester film or makrolon film base material（2-1）Another surface on, with metal-plated
The polyester film or the makrolon film base material with the coat of metal of layer（2-2）Metal coating surface be compounded in the heat-insulated glue-line of intelligence
（3）Outer surface, ultraviolet-resistant pressure-sensitive adhesive layer（4）Heat cure is combined in the polyester film with the coat of metal or with the coat of metal
Makrolon film base material（2-2）Another surface on, mould release membrance（5）It is compounded in ultraviolet-resistant pressure-sensitive adhesive layer（4）Appearance
Face.
2. nana intelligent thermal-insulation window film according to claim 1, it is characterised in that the polyester film or polycarbonate membrane base
Material（2-1）It is surface poly- by sided corona treatment or chemically treated transparent polyester film or makrolon film base material, or dyeing
Ester film or makrolon film base material or be primary colors polyester film or makrolon film base material, or ultraviolet-resistant polyester film or
Makrolon film base material, or aluminized polyester film or makrolon film base material, or magnetron sputtering polyester film or poly- carbonic acid
Ester film base material.
3. nana intelligent thermal-insulation window film according to claim 1, it is characterised in that the polyester film with the coat of metal
Or the makrolon film base material with the coat of metal（2-2）The coat of metal be that polyester film or poly- carbon are attached to by magnetron sputtering
On one surface of acid esters film base material.
4. nana intelligent thermal-insulation window film according to claim 1, it is characterised in that the nana intelligent thermal-insulation window film thickness
It is 50~444 μm, wherein, anti-scratch layer（1）Thickness be 1~5 μm；Polyester film or makrolon film base material（2-1）Thickness
It is 12~175 μm；The heat-insulated glue-line of nana intelligent（3）Thickness be 6~25 μm；Polyester film with the coat of metal or with metal
The makrolon film base material of coating（2-2）Thickness be 12~175 μm；Ultraviolet-resistant pressure-sensitive adhesive layer（4）Thickness be 6~25 μ
m；Mould release membrance（5）Thickness be 19~39 μm.
5. nana intelligent thermal-insulation window film according to claim 1, it is characterised in that the polyester film or polycarbonate membrane base
Material（2-1）With the polyester film with the coat of metal or the makrolon film base material with the coat of metal（2-2）Thickness it is identical or
Person is different.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107283975A (en) * | 2017-07-30 | 2017-10-24 | 合肥锦和信息技术有限公司 | A kind of radiation proof computer pad pasting |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107283975A (en) * | 2017-07-30 | 2017-10-24 | 合肥锦和信息技术有限公司 | A kind of radiation proof computer pad pasting |
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