CN206232401U - A kind of system of Crouse's direct current method Recovered sulphur - Google Patents
A kind of system of Crouse's direct current method Recovered sulphur Download PDFInfo
- Publication number
- CN206232401U CN206232401U CN201621299546.2U CN201621299546U CN206232401U CN 206232401 U CN206232401 U CN 206232401U CN 201621299546 U CN201621299546 U CN 201621299546U CN 206232401 U CN206232401 U CN 206232401U
- Authority
- CN
- China
- Prior art keywords
- gas
- sulphur
- heat exchanger
- reactor
- acid gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Treating Waste Gases (AREA)
Abstract
The utility model is related to a kind of system of Crouse's direct current method Recovered sulphur, belongs to Clausius equlity sulphur technical field.The utility model is by setting third-stage reactor and three-level gas-gas heat exchanger, binding reactor temperature control valve (TCV) and temperature of reactor transmitter, along with the specific type of attachment of equipment, intensification of the acid gas from sulphur cooler to reactor region is solved the problems, such as, high concentration acid gas is reduced and is entered reactor, improve sulfur recovery rate, reduce energy consumption, cost-effective, sulfur recovery rate is improved to 96 99%, higher than the 94 97% of conventional Claus direct current method sulfur recovery rate.
Description
Technical field
The utility model is related to a kind of system of Recovered sulphur, and more specifically, the utility model is related to a kind of Crouse
The system of direct current method Recovered sulphur, belongs to Clausius equlity sulphur technical field.
Background technology
Simultaneously Recovered sulphur is that current utilization rate is most wide to Claus method treatment hydrogen sulfide acid gas, efficiency highest technique, H2S acid
Gas in combustion furnace, by supplementing appropriate air, makes H by after buffering2S burn incompletelys in combustion furnace, H2S portion burns
It is converted into SO2, adjust air inlet amount.H in combustion furnace2S and SO2Ratio is 2:1, H2S and SO2Reaction occurs under ignition temperature
Redox reaction, can obtain gaseous elemental sulphur（Sulphur）.Mix waste gas make gaseous elemental sulphur be cooled to liquid through over cure cooler
State sulphur, now acid gas include H2S、SO2、COS、CS2、H2After O and sulphur steam etc., reheated device or high temperature blending valve, acid gas temperature
Temperature needed for claus reaction device is brought up to, then by LT claus reaction device, in the presence of catalyst, COS, CS2Then
With H2There is hydrolysis in O, obtain H2S, H2S and SO2Reaction is further continued for, acid gas further reclaims sulphur through over cure cooler after reaction
Sulphur.Acid gas is by three-level（Two-stage）After reactor, still there is very small amount H in tail gas2S、SO2、COS、CS2、H2O and sulphur steam
Deng reclaiming certain sulphur by catching sulphur device, then by incinerator, fully burn into SO2After discharge.
--- the sulfur recovery rate of conventional Claus technique is typically only capable to reach 94-97%, and its rate of recovery is limited following original
Cause：
1st, because thermodynamics is limited, the conversion reaction of sulphur can not possibly be complete, and Process Gas still have H2S、SO2, limit sulphur
Conversion ratio.
2nd, claus reaction will produce a certain amount of steam, with the increase of steam, relative reduction H2S and SO2It is dense
Degree, have impact on the balance of claus reaction, hinder the generation of sulphur.
3rd, due to CO in acid gas2And the presence of hydro carbons, Process Gas can form COS and CS2, it is necessary to it is allowed to hydrolysis,
Therefore, the temperature of reactor must be controlled at 300-340 DEG C, though high temperature is conducive to hydrolysis, it is unfavorable for the flat of claus reaction
Weighing apparatus, limits the conversion ratio of sulphur.
4th, the conversion ratio of conventional Claus technique sulphur is not normal very sensitive to the proportioning of air and acid gas, if can not keep
H2S：SO2=2:1 optimal proportion, will cause the conversion ratio of sulphur reduces.
There are problems that intensification of the acid gas from sulphur cooler to reactor region in the prior art, conventional method has reheater, electricity
Heating, high temperature blending valve, sulphur cooler outlet acid gas temperature can be raised reach the requirement of reactor intake air temperature.But three is
There is its shortcoming, reheater and high temperature blending valve can introduce high-temperature and high concentration acid gas, so as to cause reactor load, cause sulfur recovery rate
Decline, and electrically heated power consumption cost is higher.
Utility model content
The utility model aims to solve the problem that prior art Clausius equlity sulphur method acid gas from sulphur cooler to reactor region
Intensification problem, there is provided a kind of system of Crouse's direct current method Recovered sulphur, acid gas can be solved from sulphur cooler to reactor region
Intensification problem, additionally it is possible to ensure sulfur recovery rate higher.
To achieve these goals, its specific technical scheme is as follows：
A kind of system of Crouse's direct current method Recovered sulphur, it is characterised in that：Including combustion furnace and waste heat boiler；The combustion
Burn stove to be connected with the waste heat boiler, the combustion furnace passes through high-temperature acid flow control valves and the first gas-gas heat exchanger, second
The high temperature acid gas import connection of gas-gas heat exchanger and the 3rd gas-gas heat exchanger；The waste heat boiler is by pre- sulphur cooler and described the
The low temperature acid gas import connection of one gas-gas heat exchanger；The outlet of low temperature acid gas and the first-stage reactor of first gas-gas heat exchanger connect
Connect, the high temperature acid gas outlet of first gas-gas heat exchanger and the waste heat boiler are connected with the pipeline of pre- sulphur cooler junction,
The high-temperature acid gas outlet of first gas-gas heat exchanger is provided with first-stage reactor temperature control valve (TCV), and its aperture is by being arranged on
State the first-stage reactor temperature transmitter control on first-stage reactor；The first-stage reactor is by one-level sulphur cooler and described the
The low temperature acid gas import connection of two gas-gas heat exchangers, the outlet of low temperature acid gas and the second reactor of second gas-gas heat exchanger connect
Connect, the high temperature acid gas outlet of second gas-gas heat exchanger and the waste heat boiler connect with the pipeline of the pre- sulphur cooler junction
Connect, the high-temperature acid gas outlet of second gas-gas heat exchanger is provided with second reactor temperature control valve (TCV), and its aperture is by setting
Second reactor temperature transmitter control on the second reactor；The second reactor passes through two grades of sulphur coolers and institute
State the low temperature acid gas import connection of the 3rd gas-gas heat exchanger, the low temperature acid gas outlet of the 3rd gas-gas heat exchanger and third-order reaction
Device is connected, the pipe of the outlet of the high temperature acid gas of the 3rd gas-gas heat exchanger and the waste heat boiler and the pre- sulphur cooler junction
Road is connected, and the high-temperature acid gas outlet of the 3rd gas-gas heat exchanger is provided with third-stage reactor temperature control valve (TCV), its aperture by
It is arranged on the third-stage reactor temperature transmitter control on the third-stage reactor；The third-stage reactor connects with three-level sulphur cooler
Connect.
The utility model is preferred, and the low temperature acid gas outlet of the three-level sulphur cooler is connected with catches sulphur device.
The utility model is preferred, the pre- sulphur cooler, one-level sulphur cooler, two grades of sulphur coolers, three-level sulphur coolers and catches
Sulphur device is connected by pipeline with sulphur liquid collecting tank, and the sulphur of recovery is stored into the sulphur liquid collecting tank.
The utility model is preferred, and described sulphur device of catching also is connected with incinerator and chimney in turn.
All devices, device and part in the utility model system can be using the conventional products of this area.
The Advantageous Effects that the utility model brings：
1st, reheater is to draw hydrogen sulfide acid gas to be ignited in natural gas in the prior art, and oxygen combustion in air, releasing
Heat, mixes acid gas and mixes with sulphur cooler acid gas, to realize the lifting of acid gas temperature after burning.Because introducing high concentration in this place
Acid gas, increase reactor load, sulfur recovery rate reduction.The utility model is reduced highly concentrated compared with reheater in direct current method
Degree acid gas enters reactor, improves sulfur recovery rate.
2nd, electrical heating process is to use electrical heating sulphur cooler acid gas in the prior art, to reach temperature of reactor requirement.This
Utility model reduces energy consumption compared with electrical heating, has saved cost.
3rd, after prior art high temperature blending valve mixes sulphur cooler acid gas and high-temperature and high concentration acid gas, temperature of reactor is reached
After demand, reaction in reactor is delivered to.The utility model reduces high concentration acid gas and enters reaction compared with high temperature blending valve
Device, improves sulfur recovery rate.
4th, the utility model sulfur recovery rate is improved to 96-99%, higher than the 94- of conventional Claus direct current method sulfur recovery rate
97%。
Brief description of the drawings
Fig. 1 is the utility model system connection diagram.
Reference：1 is combustion furnace, 2 is waste heat boiler, 3 is high-temperature acid flow control valves, 4 is the first gas-gas heat exchange
Device, 5 be the second gas-gas heat exchanger, 6 be the 3rd gas-gas heat exchanger, 7 be pre- sulphur cooler, 8 be first-stage reactor, 9 be first order reaction
Device temperature control valve (TCV), 10 be first-stage reactor temperature transmitter, 11 be one-level sulphur cooler, 12 be second reactor, 13 be two grades
Temperature of reactor regulating valve, 14 be second reactor temperature transmitter, 15 be two grades of sulphur coolers, 16 be third-stage reactor, 17 be
Third-stage reactor temperature control valve (TCV), 18 be third-stage reactor temperature transmitter, 19 be three-level sulphur cooler, 20 to catch sulphur device, 21 being
Sulphur liquid collecting tank, 22 be incinerator, 23 be chimney.
Specific embodiment
Embodiment 1
A kind of system of Crouse's direct current method Recovered sulphur, including combustion furnace 1 and waste heat boiler 2；The combustion furnace 1 and institute
State waste heat boiler 2 to connect, the combustion furnace 1 passes through the gas-gas heat exchanger 4 of high-temperature acid flow control valves 3 and first, the second gas gas
The high temperature acid gas import connection of the gas-gas heat exchanger 6 of heat exchanger 5 and the 3rd；The waste heat boiler 2 is by pre- sulphur cooler 7 and described the
The low temperature acid gas import connection of one gas-gas heat exchanger 4；The low temperature acid gas outlet of first gas-gas heat exchanger 4 and first-stage reactor
8 connections, the high temperature acid gas outlet of first gas-gas heat exchanger 4 and the pipeline of the waste heat boiler 2 and the pre- junction of sulphur cooler 7
Connection, the high-temperature acid gas outlet of first gas-gas heat exchanger 4 is provided with first-stage reactor temperature control valve (TCV) 9, its aperture by
The first-stage reactor temperature transmitter 10 being arranged on the first-stage reactor 8 is controlled；The first-stage reactor 8 passes through one-level sulphur
Cooler 11 is connected with the low temperature acid gas import of second gas-gas heat exchanger 5, and the low temperature acid gas of second gas-gas heat exchanger 5 goes out
Mouth is connected with second reactor 12, and the high temperature acid gas outlet of second gas-gas heat exchanger 5 and the waste heat boiler 2 are pre- with described
The pipeline connection of the junction of sulphur cooler 7, the high-temperature acid gas outlet of second gas-gas heat exchanger 5 is provided with second reactor temperature
Degree regulating valve 13, its aperture is controlled by the second reactor temperature transmitter 14 being arranged on the second reactor 12；It is described
Second reactor 12 is connected by two grades of sulphur coolers 15 with the low temperature acid gas import of the 3rd gas-gas heat exchanger 6, and the described 3rd
The low temperature acid gas outlet of gas-gas heat exchanger 6 is connected with third-stage reactor 16, the high temperature acid gas outlet of the 3rd gas-gas heat exchanger 6
It is connected with the pipeline of the pre- junction of sulphur cooler 7 with the waste heat boiler 2, the high temperature acid gas of the 3rd gas-gas heat exchanger 6
Exit is provided with third-stage reactor temperature control valve (TCV) 17, and its aperture is by the third-order reaction that is arranged on the third-stage reactor 16
Device temperature transmitter 18 is controlled；The third-stage reactor 16 is connected with three-level sulphur cooler 19.
Embodiment 2
Using the method for Crouse's direct current method Recovered sulphur of the utility model system, including following methods step：
A, combustion furnace 1 are connected with waste heat boiler 2, and the combustion furnace 1 passes through the gas gas of high-temperature acid flow control valves 3 and first
The high temperature acid gas import connection of heat exchanger 4, the second gas-gas heat exchanger 5 and the 3rd gas-gas heat exchanger 6；Waste heat boiler 2 is cold with pre- sulphur
Device 7 is connected；High temperature acid gas in the combustion furnace 1 enters first gas-gas heat exchanger 4, the low temperature in the waste heat boiler 2
Acid gas enters first gas-gas heat exchanger 4 by the pre- sulphur cooler 7, and two kinds of acid gas enter in first gas-gas heat exchanger 4
Row gas-gas heat exchange；
B, the low temperature acid gas outlet of first gas-gas heat exchanger 4 are connected with first-stage reactor 8, first gas-gas heat exchange
The high temperature acid gas outlet of device 4 and the waste heat boiler 2 are connected with the pipeline of the pre- junction of sulphur cooler 7, first gas-gas heat exchange
The high-temperature acid gas outlet of device 4 is provided with first-stage reactor temperature control valve (TCV) 9, and its aperture is by being arranged on the first-stage reactor 8
On first-stage reactor temperature transmitter 10 control；Low temperature acid gas after heat exchange enters the first-stage reactor 8, the height after heat exchange
Warm acid gas returns to the pre- sulphur cooler 7；
First-stage reactor temperature transmitter 10 on C, the first-stage reactor 8 controls the first-stage reactor temperature adjustment
The aperture of valve 9, so as to control to enter the low temperature acid gas temperature of first-stage reactor 8；The first-stage reactor 8 is cold with the one-level sulphur
Device 11 is connected, and reacted low temperature acid gas enters the Recovered sulphur of one-level sulphur cooler 11, and the low temperature acid gas after Recovered sulphur enters
Enter the second gas-gas heat exchanger 5, second reactor 12, the high temperature of second gas-gas heat exchanger 5 are entered after being exchanged heat with high temperature acid gas
Acid gas exit is provided with second reactor temperature control valve (TCV) 13, and its aperture is by be arranged on the second reactor 12 two grades
Temperature of reactor transmitter 14 is controlled；The pre- sulphur cooler 7 is returned to by the high temperature acid gas for exchanging heat；
Second reactor temperature transmitter 14 on D, the second reactor 12 controls the second reactor temperature to adjust
The aperture of valve 13 is saved, so as to control to enter the low temperature acid gas temperature of second reactor 12；The second reactor 12 and described two
Level sulphur cooler 15 is connected, and reacted low temperature acid gas enters two grades of sulphur coolers 15 Recovered sulphur, the low temperature after Recovered sulphur
Acid gas enters the 3rd gas-gas heat exchanger 6, and third-stage reactor 16, the 3rd gas-gas heat exchanger 6 are entered after being exchanged heat with high temperature acid gas
High-temperature acid gas outlet be provided with third-stage reactor temperature control valve (TCV) 17, its aperture is by being arranged on the third-stage reactor 16
Third-stage reactor temperature transmitter 18 control；The pre- sulphur cooler 7 is returned to by the high temperature acid gas for exchanging heat；
Third-stage reactor temperature transmitter 18 on E, the third-stage reactor 16 controls the third-stage reactor temperature to adjust
The aperture of valve 17 is saved, so as to control to enter the low temperature acid gas temperature of third-stage reactor 16；The third-stage reactor 16 and three-level sulphur
Cooler 19 is connected, and reacted low temperature acid gas enters the Recovered sulphur of three-level sulphur cooler 19.
In step, the temperature of the high temperature acid gas in the combustion furnace 1 is 1000-1200 DEG C.
In stepb, the temperature of the low temperature acid gas in the waste heat boiler 2 is 340-350 DEG C, by after pre- sulphur cooler 7
The temperature of low temperature acid gas is 140-160 DEG C.
Embodiment 3
On the basis of embodiment 1：
Preferably, the low temperature acid gas outlet of the three-level sulphur cooler 19 is connected with and catches sulphur device 20.
Further, the pre- sulphur cooler 7,11, two grades of sulphur coolers 15 of one-level sulphur cooler, three-level sulphur cooler 19 and sulphur is caught
Device 20 is connected by pipeline with sulphur liquid collecting tank 21.
Further, described sulphur device 20 of catching also is connected with incinerator 22 and chimney 23 in turn.
Embodiment 4
The temperature of the high temperature acid gas in combustion furnace is 1000-1200 DEG C, after combustion furnace 1, waste heat boiler 2 in waste heat boiler
Low temperature acid gas be 340-350 DEG C, into after pre- sulphur cooler 7 condensation Recovered sulphur, the temperature of low temperature acid gas is 140-160 DEG C,
After being heated through the first gas-gas heat exchanger 4, temperature rises to 280-310 DEG C, into first-stage reactor 8, it is reacted after, acid gas temperature
340-350 DEG C is increased to, temperature is reduced to 140-160 DEG C after one-level sulphur cooler 11, after the second gas-gas heat exchanger 5, temperature
Rise to 250-280 DEG C, into second reactor 12, it is reacted after, acid gas temperature is 290-310 DEG C, through two grades of sulphur coolers 15
After condensation Recovered sulphur, temperature is reduced to 140-160 DEG C, then through the 3rd gas-gas heat exchanger 6 after, temperature rises to 180-200 DEG C,
Into third-stage reactor 16, it is reacted after, acid gas temperature is 190-220 DEG C, then through the condensation Recovered sulphur of three-level sulphur cooler 19 after,
Temperature is reduced to 140-160 DEG C.The outlet acid gas of three-level sulphur cooler 19 enters catches sulphur device 20, sulphur Steam Recovery part in trapping acid gas
Sulphur.
Claims (4)
1. a kind of system of Crouse's direct current method Recovered sulphur, it is characterised in that：Including combustion furnace（1）And waste heat boiler（2）；Institute
State combustion furnace（1）With the waste heat boiler（2）Connection, the combustion furnace（1）By high-temperature acid flow control valves（3）With first
Gas-gas heat exchanger（4）, the second gas-gas heat exchanger（5）With the 3rd gas-gas heat exchanger（6）The import of high temperature acid gas connection；The waste heat
Boiler（2）By pre- sulphur cooler（7）With first gas-gas heat exchanger（4）The import of low temperature acid gas connection；The first gas gas
Heat exchanger（4）Low temperature acid gas outlet and first-stage reactor（8）Connection, first gas-gas heat exchanger（4）High temperature acid gas go out
Mouth and the waste heat boiler（2）With pre- sulphur cooler（7）The pipeline connection of junction, first gas-gas heat exchanger（4）High temperature
Acid gas exit is provided with first-stage reactor temperature control valve (TCV)（9）, its aperture is by being arranged on the first-stage reactor（8）On one
Stage reactor temperature transmitter（10）Control；The first-stage reactor（8）By one-level sulphur cooler（11）With the second gas gas
Heat exchanger（5）The import of low temperature acid gas connection, second gas-gas heat exchanger（5）Low temperature acid gas outlet and second reactor
（12）Connection, second gas-gas heat exchanger（5）High temperature acid gas outlet and the waste heat boiler（2）With the pre- sulphur cooler
（7）The pipeline connection of junction, second gas-gas heat exchanger（5）High-temperature acid gas outlet be provided with second reactor temperature
Regulating valve（13）, its aperture is by being arranged on the second reactor（12）On second reactor temperature transmitter（14）Control；
The second reactor（12）By two grades of sulphur coolers（15）With the 3rd gas-gas heat exchanger（6）The import of low temperature acid gas connect
Connect, the 3rd gas-gas heat exchanger（6）Low temperature acid gas outlet and third-stage reactor（16）Connection, the 3rd gas-gas heat exchanger
（6）High temperature acid gas outlet and the waste heat boiler（2）With the pre- sulphur cooler（7）The pipeline connection of junction, the described 3rd
Gas-gas heat exchanger（6）High-temperature acid gas outlet be provided with third-stage reactor temperature control valve (TCV)（17）, its aperture is by being arranged on
State third-stage reactor（16）On third-stage reactor temperature transmitter（18）Control；The third-stage reactor（16）It is cold with three-level sulphur
Device（19）Connection.
2. the system of a kind of Crouse's direct current method Recovered sulphur according to claim 1, it is characterised in that：The three-level sulphur
Cooler（19）The outlet of low temperature acid gas be connected with and catch sulphur device（20）.
3. the system of a kind of Crouse's direct current method Recovered sulphur according to claim 2, it is characterised in that：The pre- sulphur is cold
Device（7）, one-level sulphur cooler（11）, two grades of sulphur coolers（15）, three-level sulphur cooler（19）And catch sulphur device（20）By pipeline and sulphur
Liquid collecting tank（21）Connection.
4. the system of a kind of Crouse's direct current method Recovered sulphur according to Claims 2 or 3, it is characterised in that：Described
Catch sulphur device（20）Also it is connected with incinerator in turn（22）And chimney（23）.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621299546.2U CN206232401U (en) | 2016-11-30 | 2016-11-30 | A kind of system of Crouse's direct current method Recovered sulphur |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621299546.2U CN206232401U (en) | 2016-11-30 | 2016-11-30 | A kind of system of Crouse's direct current method Recovered sulphur |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN206232401U true CN206232401U (en) | 2017-06-09 |
Family
ID=58980309
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201621299546.2U Expired - Fee Related CN206232401U (en) | 2016-11-30 | 2016-11-30 | A kind of system of Crouse's direct current method Recovered sulphur |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN206232401U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110713175A (en) * | 2019-10-17 | 2020-01-21 | 山西潞安煤基清洁能源有限责任公司 | Method and device for improving sulfur recovery efficiency |
-
2016
- 2016-11-30 CN CN201621299546.2U patent/CN206232401U/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110713175A (en) * | 2019-10-17 | 2020-01-21 | 山西潞安煤基清洁能源有限责任公司 | Method and device for improving sulfur recovery efficiency |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN202177093U (en) | Multi-level efficient displacement type fume waste-heat utilization system | |
| CN101927982B (en) | Isothermal direct oxidization recovery technology of sulfur | |
| CN107055486B (en) | A kind of flue gas acid preparing process waste heat utilizes method | |
| CN106698362B (en) | A kind of energy-efficient sulfur recovery unit and method | |
| CN205717146U (en) | A kind of ultrahigh pressure coal gas boiler | |
| CN109585878A (en) | A kind of combined power generation device heat energy recycling device | |
| CN209726226U (en) | A kind of high-sulfur exhaust treatment system | |
| CN206232401U (en) | A kind of system of Crouse's direct current method Recovered sulphur | |
| CN213060208U (en) | Preheating system for uniformly heating sulfuric acid converter by using preheater | |
| CN105841177B (en) | The desulphurization denitration clean exhaust system of low temperature waste gas | |
| CN209922896U (en) | System for heating sulfuric acid converter by using preheater | |
| CN1151574C (en) | Combined electric generator system integrating fuel battery of carbonate with turbine | |
| CN206232400U (en) | A kind of system for Crouse's direct current method Recovered sulphur | |
| CN106744704B (en) | A kind of method of Crouse's direct current method Recovered sulphur | |
| CN106586973B (en) | A method of being used for Crouse's direct current method Recovered sulphur | |
| CN215864054U (en) | Air waste heat utilization system | |
| CN106629631B (en) | A kind of the sulfur waste cleavage systems and technique of oxygen-enriched combustion-supporting | |
| CN206247373U (en) | A kind of pipe heat exchanger residual neat recovering system | |
| CN202470782U (en) | Secondary smoke residual heat utilization system for hot blast stove | |
| CN108744918A (en) | System and process for realizing efficient denitration of coke oven flue gas by using waste heat of raw gas | |
| CN212361988U (en) | Flue gas waste heat utilization system | |
| CN208716846U (en) | A kind of lighter hydrocarbons producing synthesis gas reforming unit converting the conversion of gas pre-heating heat-exchanging formula using one section of high temperature | |
| CN211232943U (en) | System for recycling waste gas of radioactive organic waste steam reforming device | |
| CN115143455A (en) | Novel chemical looping combustion method comprising hydrogen production process | |
| CN201531870U (en) | Device for carbon dioxide emission reduction through oxygen combustion in circulating fluidized bed based on warm flue gas recirculation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170609 Termination date: 20201130 |