CN206188537U - Preliminary treatment adds multistage dull and stereotyped ceramic membrane oiliness effluent disposal system - Google Patents
Preliminary treatment adds multistage dull and stereotyped ceramic membrane oiliness effluent disposal system Download PDFInfo
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Abstract
本实用新型公开了预处理加多级平板陶瓷膜含油废水处理系统,它包括预处理池、一级膜过滤池、二级膜过滤池、产水装置、曝气清洗装置、高压反冲洗装置、药剂反应装置、在线药剂清洗装置、滤液回收装置、污泥脱水装置、进水装置、离线清洗装置和自动控制装置,预处理池与一级膜过滤池之间设置有带导流孔的隔板,高压反冲洗装置和在线药剂清洗装置并联设置在产水装置两端之间,药剂反应装置与进水装置相连,曝气清洗装置包括设置在一级平板陶瓷膜组件和二级平板陶瓷膜组件下端的曝气管,它具有膜通量大、跨膜压差小、亲水疏油性、耐压强度高、耐酸碱性、使用寿命长等特点,含油废水处量效率高,处量效果好,处理废水可直接对外排放或回用。
The utility model discloses a pretreatment plus multi-stage flat ceramic membrane oily wastewater treatment system, which includes a pretreatment tank, a first-level membrane filtration tank, a second-level membrane filtration tank, a water production device, an aeration cleaning device, a high-pressure backwashing device, Chemical reaction device, online chemical cleaning device, filtrate recovery device, sludge dehydration device, water inlet device, off-line cleaning device and automatic control device, a partition with diversion holes is set between the pretreatment tank and the primary membrane filter tank, The high-pressure backwashing device and the online chemical cleaning device are installed in parallel between the two ends of the water production device, the chemical reaction device is connected to the water inlet device, and the aeration cleaning device is installed at the lower end of the first-level flat ceramic membrane module and the second-level flat ceramic membrane module. The aeration tube has the characteristics of large membrane flux, small transmembrane pressure difference, hydrophilic and oleophobic properties, high compressive strength, acid and alkali resistance, long service life, etc., and has high treatment efficiency and good treatment effect for oily wastewater. , The treated wastewater can be directly discharged or reused.
Description
技术领域technical field
本实用新型涉及含油废水处理领域,具体涉及使用多级平板陶瓷膜含油废水处理设备。The utility model relates to the field of oily wastewater treatment, in particular to equipment for treating oily wastewater using multi-stage flat ceramic membranes.
背景技术Background technique
含油废水是指废水中含有较多的油类污染物以及无机盐份等其他污染因子的废水,其主要油类污染物是一定量的石油类或动植物油类,其主要来源于石油、石油化工、钢铁、焦化、煤气发生站、机械加工等工业部门。其中油类物质在废水中通常以四种状态存在。(1) 上浮油,油滴粒径大于100μm,易于从废水中分离出来。在石油污水中,这种油占水中总含油量60~80%。(2)分散油.油滴粒径介于10~100μm之间,悬浮于水中。(3)乳化油,油滴粒径小于10μm,油品在废水中分散的粒径很小,呈乳化状态,不易从废水中分离出来。(4)溶解油,油类溶解于水中的状态。目前含油废水的处理大多采用气浮、重力分离、离心分离等传统的方式进行,因为油类物质在水中有多种状态的形式存在使得传统方式对含有废水的处理效率非常有限,而且很难达到各种排放或回用水要求的标准。如果这些含油废水不加以回收处理直接排入河流、湖泊或海湾,会污染水体,影响水生生物生存;如果用于农业灌溉,则会堵塞土壤空隙,妨碍农作物生长。平板陶瓷膜含油废水处理系统作为新型高效含油废水处理技术已经得到各界使用者的认可和赞许,为含油废水的高效处理提供了经济实用的选择。Oily wastewater refers to wastewater containing more oil pollutants and other pollution factors such as inorganic salts. The main oil pollutants are a certain amount of petroleum or animal and vegetable oils, which mainly come from petroleum, petrochemical , Iron and steel, coking, gas generation stations, mechanical processing and other industrial sectors. Among them, oil substances usually exist in four states in wastewater. (1) Floating oil, the particle size of oil droplets is greater than 100μm, which is easy to separate from wastewater. In petroleum sewage, this oil accounts for 60-80% of the total oil content in water. (2) Dispersed oil. The particle size of oil droplets is between 10 and 100 μm, suspended in water. (3) Emulsified oil, the particle size of oil droplets is less than 10 μm, the particle size of oil dispersed in wastewater is very small, it is in an emulsified state, and it is not easy to separate from wastewater. (4) Dissolved oil, the state in which oil is dissolved in water. At present, the treatment of oily wastewater is mostly carried out by traditional methods such as air flotation, gravity separation, and centrifugal separation. Because oily substances exist in various forms in water, the efficiency of traditional methods for treating wastewater containing wastewater is very limited, and it is difficult to achieve Standards for various discharge or water reuse requirements. If the oily wastewater is discharged directly into rivers, lakes or bays without recycling, it will pollute the water body and affect the survival of aquatic organisms; if it is used for agricultural irrigation, it will block the soil voids and hinder the growth of crops. As a new high-efficiency oily wastewater treatment technology, the flat ceramic membrane oily wastewater treatment system has been recognized and praised by users from all walks of life, providing an economical and practical choice for the efficient treatment of oily wastewater.
实用新型内容Utility model content
针对上述现有技术中含油废水处理中所存在的问题,本实用新型提供了一种采用预处理加多级平板陶瓷膜处理含油废水的系统。Aiming at the problems existing in the treatment of oily wastewater in the prior art, the utility model provides a system for treating oily wastewater with pretreatment and multi-stage flat ceramic membranes.
本实用新型要解决的技术问题所采的技术方案是:所述预处理加多级平板陶瓷膜含油废水处理系统包括预处理池、一级过滤池、二级过滤池、产水装置、曝气清洗装置、高压反冲洗装置、药剂反应装置、在线药剂清洗装置、滤液回收装置、污泥脱水装置、进水装置、离线清洗装置和自动控制装置,所述预处理池与一级膜过滤池之间设置有带导流孔的隔板,一级膜过滤池和二级膜过滤池之间设置有隔板,高压反冲洗装置和在线药剂清洗装置并联设置在产水装置两端之间,药剂反应装置与进水装置相连,所述曝气清洗装置包括设置在一级平板陶瓷膜组件和二级平板陶瓷膜组件下端的曝气管,滤液回收装置与一级膜过滤池和二级膜过滤池相连,所述一级膜过滤池中设置有膜孔径为100nm-10um的亲水疏油性一级平板陶瓷膜组件,所述二级膜过滤池中设置有膜孔径为5nm-100nm的亲水疏油性二级平板陶瓷膜组件, 污泥脱水装置与预处理池相连,所述产水装置一端与一级平板陶瓷膜组件和二级平板陶瓷膜组件的出水端相连,产水装置另一端伸入二级膜过滤池内或设置在二级膜过滤池外。The technical solution adopted for the technical problem to be solved by the utility model is: the pretreatment plus multi-stage flat ceramic membrane oily wastewater treatment system includes a pretreatment pool, a primary filter pool, a secondary filter pool, a water production device, an aeration Cleaning device, high-pressure backwashing device, chemical reaction device, online chemical cleaning device, filtrate recovery device, sludge dehydration device, water inlet device, off-line cleaning device and automatic control device, between the pretreatment tank and the primary membrane filter tank A partition with diversion holes is provided, a partition is provided between the primary membrane filter tank and the secondary membrane filter tank, the high-pressure backwash device and the online chemical cleaning device are installed in parallel between the two ends of the water production device, and the chemical reaction device Connected with the water inlet device, the aeration cleaning device includes an aeration pipe arranged at the lower end of the first-level flat ceramic membrane module and the second-level flat ceramic membrane module, and the filtrate recovery device is connected with the first-level membrane filter tank and the second-level membrane filter tank , the first-stage membrane filtration tank is provided with a hydrophilic-oleophobic first-level flat ceramic membrane module with a membrane aperture of 100nm-10um, and the second-stage membrane filtration tank is provided with a hydrophilic-oleophobic membrane module with a membrane aperture of 5nm-100nm The second-stage flat ceramic membrane module, the sludge dewatering device is connected to the pretreatment tank, one end of the water production device is connected to the water outlet of the first-level flat ceramic membrane module and the second-level flat ceramic membrane module, and the other end of the water production device extends into the second In the primary membrane filter tank or outside the secondary membrane filter tank.
本实用新型与现有技术相比:Compared with the prior art, the utility model:
1、具有膜通量大、跨膜压差小、亲水疏油性、耐压强度高、耐酸碱性、使用寿命长特点,1. It has the characteristics of large membrane flux, small transmembrane pressure difference, hydrophilic and oleophobic, high compressive strength, acid and alkali resistance, and long service life.
2、含油废水处量效率高,处量效果好,处理废水可直接对外排放或回用。2. The treatment efficiency of oily wastewater is high, and the treatment effect is good. The treated wastewater can be directly discharged or reused.
附图说明Description of drawings
图1是本实用新型的连接关系结构示意图。Fig. 1 is a schematic diagram of the connection relationship structure of the present invention.
在图中,1、进水装置 2、进水口 3、药剂反应装置 4、池体 5、液面 6、隔板7、曝气清洗装置 8、一级膜过滤池 9、产水装置 10、高压反冲洗装置 11、在线药剂清洗装置 12、预处理池 13、曝气管 14、二级平板陶瓷膜组件 15、滤液回收装置 16、污泥脱水装置 17、酸洗池 18、次氯酸钠池 19、碱洗池 20、清水池 21、二级膜过滤池22、一级平板陶瓷膜组件 23、导流孔。In the figure, 1, water inlet device 2, water inlet 3, drug reaction device 4, pool body 5, liquid surface 6, partition plate 7, aeration cleaning device 8, primary membrane filter tank 9, water production device 10, High-pressure backwashing device 11, online chemical cleaning device 12, pretreatment tank 13, aeration pipe 14, secondary flat ceramic membrane module 15, filtrate recovery device 16, sludge dehydration device 17, pickling tank 18, sodium hypochlorite tank 19, Alkali cleaning pool 20, clean water pool 21, secondary membrane filter pool 22, primary flat ceramic membrane module 23, diversion hole.
具体实施方式detailed description
在图1中,所述预处理加多级平板陶瓷膜含油废水处理系统包括池体4、产水装置9、曝气清洗装置7、高压反冲洗装置10、药剂反应装置3、在线药剂清洗装置11、滤液回收装置15、污泥脱水装置16、进水装置1、离线清洗装置和自动控制装置,所述池体包括预处理池12、一级膜过滤池8和二级膜过滤池21,池体内含油废水的液面5,所述预处理池与一级膜过滤池之间设置有下端带导流孔23的隔板6,一级膜过滤池和二级膜过滤池之间设置有隔板,所述一只产水装置一端与一级平板陶瓷膜组件22出水端相连、另一端伸入二级膜过滤池内,另一只产水装置一端与二级平板陶瓷膜组件14出水端相连、另一端设置在二级膜过滤池外,高压反冲洗装置和在线药剂清洗装置并联后设置在产水装置之间的两端相连,药剂反应装置3与进水装置1相连,出水装置上的进水口2伸入预处理池内,所述曝气清洗装置包括设置在一级平板陶瓷膜组件和二级平板陶瓷膜组件下端的曝气管13,滤液回收装置与一级膜过滤池和二级膜过滤池的底部相连,污泥脱水装置与预处理池底部相连,所述离线清洗装置包括依次相连的酸洗池17、次氯酸钠池18、碱洗池19和清水池20,所述一级膜过滤池中设置有膜孔径为100nm-10um(不包括100nm,包括10um,即大于100nm至≤10um)的亲水疏油性一级平板陶瓷膜组件,所述二级膜过滤池中设置有膜孔径为5nm-100nm(包括5 nm 和100 nm)的亲水疏油性二级平板陶瓷膜组件。In Fig. 1, the pretreatment plus multi-stage flat ceramic membrane oily wastewater treatment system includes a pool body 4, a water production device 9, an aeration cleaning device 7, a high-pressure backwashing device 10, a chemical reaction device 3, and an online chemical cleaning device 11. Filtrate recovery device 15, sludge dewatering device 16, water inlet device 1, off-line cleaning device and automatic control device, the tank body includes a pretreatment tank 12, a primary membrane filtration tank 8 and a secondary membrane filtration tank 21, The liquid level 5 of the oily waste water in the tank body, a separator 6 with a diversion hole 23 at the lower end is arranged between the pretreatment tank and the first-stage membrane filter tank, and a separator is arranged between the first-stage membrane filter tank and the second-stage membrane filter tank One end of the one water production device is connected to the water outlet of the first-level flat ceramic membrane module 22, the other end extends into the second-level membrane filter tank, and one end of the other water production device is connected to the water outlet of the second-level flat ceramic membrane module 14, The other end is set outside the secondary membrane filter tank. The high-pressure backwashing device and the on-line chemical cleaning device are connected in parallel and connected at both ends between the water production devices. The chemical reaction device 3 is connected to the water inlet device 1, and the water inlet on the water outlet The water outlet 2 extends into the pretreatment tank, and the aeration cleaning device includes an aeration pipe 13 arranged at the lower end of the first-level flat ceramic membrane module and the second-level flat ceramic membrane module, and the filtrate recovery device is connected with the first-level membrane filter tank and the second-level membrane The bottom of the filter tank is connected, and the sludge dewatering device is connected with the bottom of the pretreatment tank. The off-line cleaning device includes a pickling tank 17, a sodium hypochlorite tank 18, an alkali cleaning tank 19 and a clear water tank 20 connected in sequence. The primary membrane filtration The pool is equipped with a hydrophilic and oleophobic primary flat ceramic membrane module with a membrane pore size of 100nm-10um (excluding 100nm, including 10um, that is, greater than 100nm to ≤10um), and the secondary membrane filtration pool is equipped with a membrane pore size of 5nm-100nm (including 5 nm and 100 nm) hydrophilic and oleophobic secondary flat ceramic membrane components.
所述预处理系统主要去除含油废水中的上浮油,使得经过预处理的各中油类指标降低到1000mg/l以下,并且在前段加入针对性的药剂去除污水中无机盐份和其他污染物质,为后续的膜处理系统创造更好的条件,也能减少膜污染和清洗的频率。The pretreatment system mainly removes the slick oil in the oily wastewater, so that the indicators of the pretreated oils are reduced to below 1000mg/l, and targeted agents are added in the front section to remove inorganic salts and other pollutants in the sewage, for Subsequent membrane treatment systems create better conditions and reduce the frequency of membrane fouling and cleaning.
所述一级过滤池中主要放置膜孔径比较大的一级平板陶瓷膜组件,经过预处理后的废水再经过一级膜过滤池,利用一级平板陶瓷膜的较大孔径把大颗粒状态下的有机物及分散油进行拦截,与产水装置配合工作实现油水分离,从而达到降低含油废水中的油含量。所述二级膜过滤池中主要放置孔径比较小的二级平板陶瓷膜组件,经过一级平板陶瓷膜组件处理后的污水再经过二级平板陶瓷膜组件处理进行高精度的过滤,把含有废水中的乳化油进行拦截,由产水装置把过滤后的清水从膜片中抽出,从而达到排放和回用的要求。The first-level flat ceramic membrane module with a relatively large membrane pore size is mainly placed in the first-level filter tank, and the pretreated wastewater passes through the first-level membrane filter tank, and the larger pore size of the first-level flat ceramic membrane is used to filter the large particles. The organic matter and dispersed oil are intercepted, and the oil-water separation is achieved by working with the water production device, so as to reduce the oil content in the oily wastewater. The second-level flat ceramic membrane module with a relatively small pore size is mainly placed in the second-level membrane filtration tank, and the sewage treated by the first-level flat ceramic membrane module is then processed by the second-level flat ceramic membrane module for high-precision filtration, and the waste water containing The emulsified oil in the filter is intercepted, and the filtered water is pumped out from the membrane by the water production device, so as to meet the requirements of discharge and reuse.
所述曝气清洗装置由安装在膜片底部的曝气管、空压机或风机等设备组成,与自动控制装置共同控制曝气量,利用设备产生的气泡对平板陶瓷膜组件中的膜片进行冲洗,把附着在膜表面的油污清洗下来。The aeration and cleaning device is composed of an aeration tube installed at the bottom of the diaphragm, an air compressor or a fan, etc., and controls the aeration rate together with the automatic control device, and uses the air bubbles generated by the equipment to cool the diaphragm in the flat ceramic membrane module. Rinse to clean off the oil stain attached to the surface of the membrane.
所述高压反冲洗装置利用其平板陶瓷膜耐高压的特点,由内向外压入高压水或高压空气,从内向外反冲洗堵在膜片面上的油污,保证膜通量的恢复。The high-pressure backwashing device utilizes the characteristics of high-pressure resistance of its flat ceramic membrane, presses high-pressure water or high-pressure air from the inside to the outside, and backwashes the oil stains blocked on the membrane surface from the inside to the outside to ensure the recovery of the membrane flux.
所述药剂反应装置主要用于前期预处理中加入药剂搅拌通过混凝、氧化还原等反应去除其他的一些无机盐份和其他杂质以达到净化污水水质的作用。The chemical reaction device is mainly used in the early pretreatment to add chemical and stir to remove some other inorganic salts and other impurities through coagulation, redox and other reactions to purify the water quality of sewage.
所述在线药剂清洗系统主要利用药剂溶液对附着在一级平板陶瓷膜和二级平板陶瓷膜膜面上的顽固油污进行化学清洗,以保证两级平板陶瓷膜的膜通量。The online chemical cleaning system mainly uses the chemical solution to chemically clean the stubborn oil stains attached to the surface of the first-level flat ceramic membrane and the second-level flat ceramic membrane, so as to ensure the membrane flux of the two-level flat ceramic membrane.
所述离线清洗系统包括依次相连的酸洗池、次氯酸钠池、碱洗池和清水池以及自动吊装设备,当各级平板陶瓷膜组件运行一定时间后在线药剂清洗装置的效率降低、膜片通量恢复有限后,充分利用膜片耐酸碱和耐腐蚀的特性,由自动吊装设备将膜片依次吊入酸洗池、次氯酸钠池、碱洗池、清水池中清洗后安装回各级平板陶瓷膜装置中使用,确保各级平板陶瓷膜组件的过滤通量恢复。The offline cleaning system includes sequentially connected pickling pools, sodium hypochlorite pools, alkali washing pools, clear water pools, and automatic hoisting equipment. When the flat ceramic membrane modules at all levels run for a certain period of time, the efficiency of the online chemical cleaning device decreases and the membrane flux After the recovery is limited, make full use of the acid and alkali resistance and corrosion resistance of the diaphragm, and the automatic hoisting equipment will lift the diaphragm into the pickling pool, sodium hypochlorite pool, alkali washing pool, and clean water pool in sequence, and then install it back to the flat ceramic membrane at all levels. It is used in the device to ensure the recovery of the filtration flux of the flat ceramic membrane modules at all levels.
所述滤液回收系统主要是用于回收一级平板陶瓷膜组件和二级平板陶瓷膜组件中的浓液,通过离心、萃取等方式把有价值的成份进行选择性回收,做到经济利益最大化。The filtrate recovery system is mainly used to recover the dope in the first-level flat ceramic membrane module and the second-level flat ceramic membrane module, and selectively recover valuable components through centrifugation and extraction to maximize economic benefits .
所述污泥脱水系统主要是通过压滤、离心等处理方式把预处理中加药反应产生的污泥和滤液回收后产生的废料进行脱水干化处理,防止产生二次污染。The sludge dewatering system is mainly to dehydrate and dry the sludge produced by the dosing reaction in the pretreatment and the waste produced after the filtrate recovery by pressure filtration, centrifugation and other treatment methods to prevent secondary pollution.
所述离线清洗系统主要特征是由酸洗池、次氯酸钠池、碱洗池、清水池及自动吊装设备组成,各级平板陶瓷膜组件运行一定时间后利用其耐酸碱和耐腐蚀的特性,膜组件由自动吊装设备先起吊到酸洗池中浸泡0.5-10小时,利用一定浓度的酸(如盐酸、硝酸、硫酸或醋酸等)把堵塞在膜孔中的有机物和无机物(如Fe、Fe(OH)3、CaCO3、MgCO3、CaSO4、Mu、Cr类化合物、无机颗粒及其溶胶粒等)溶化或分解掉,再进入次氯酸钠池中进行氧化还原在酸洗池中未能处理的污垢,之后再进入碱洗池中进行碱洗除油过程,最后再到清水池中清洗后重新由自动吊装设备安装回各级亲水疏油性平板陶瓷膜系统中重新使用。The main features of the off-line cleaning system are composed of pickling pools, sodium hypochlorite pools, alkali washing pools, clear water pools and automatic hoisting equipment. The components are first hoisted by the automatic hoisting equipment into the pickling pool for 0.5-10 hours, and the organic and inorganic substances (such as Fe, Fe, etc.) (OH) 3 , CaCO 3 , MgCO 3 , CaSO 4 , Mu, Cr compounds, inorganic particles and their sol particles, etc.) are melted or decomposed, and then enter the sodium hypochlorite pool for redox. Dirt, then enter the alkali washing tank for alkali washing and degreasing process, and finally wash in the clear water tank and then install it back to the hydrophilic and oleophobic flat ceramic membrane system at all levels by automatic lifting equipment for reuse.
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| CN107321189A (en) * | 2017-08-30 | 2017-11-07 | 安徽马钢工程技术集团有限公司 | A kind of outer cleaning device of MBR films line and cleaning method |
| CN108821481A (en) * | 2018-09-11 | 2018-11-16 | 重庆亚领环保科技有限公司 | A kind of system for processing chrome-containing wastewater and processing method |
| CN111195484A (en) * | 2020-01-17 | 2020-05-26 | 中国石油天然气股份有限公司 | Surfactant for cleaning plate-type ceramic membrane for oilfield wastewater treatment and cleaning method |
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| CN113788531A (en) * | 2021-10-19 | 2021-12-14 | 成都工业学院 | Based on NO2Automatic back flush system of dull and stereotyped membrane of MBR |
| CN114011244A (en) * | 2021-11-24 | 2022-02-08 | 江西五菱机电设备有限公司 | A thick liquids dewatering system for ceramic manufacture |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107321189A (en) * | 2017-08-30 | 2017-11-07 | 安徽马钢工程技术集团有限公司 | A kind of outer cleaning device of MBR films line and cleaning method |
| CN108821481A (en) * | 2018-09-11 | 2018-11-16 | 重庆亚领环保科技有限公司 | A kind of system for processing chrome-containing wastewater and processing method |
| CN108821481B (en) * | 2018-09-11 | 2024-12-10 | 重庆亚领环保科技有限公司 | Chromium-containing wastewater treatment system and treatment method |
| CN111195484A (en) * | 2020-01-17 | 2020-05-26 | 中国石油天然气股份有限公司 | Surfactant for cleaning plate-type ceramic membrane for oilfield wastewater treatment and cleaning method |
| CN111195484B (en) * | 2020-01-17 | 2022-05-06 | 中国石油天然气股份有限公司 | Surfactant and cleaning method for plate ceramic membrane used for cleaning oil field wastewater treatment |
| CN111841332A (en) * | 2020-07-21 | 2020-10-30 | 暨南大学 | Cleaning device and cleaning method suitable for hollow fiber membrane module |
| CN113562888A (en) * | 2021-08-30 | 2021-10-29 | 海南立昇净水科技实业有限公司 | water treatment system |
| CN113788531A (en) * | 2021-10-19 | 2021-12-14 | 成都工业学院 | Based on NO2Automatic back flush system of dull and stereotyped membrane of MBR |
| CN114011244A (en) * | 2021-11-24 | 2022-02-08 | 江西五菱机电设备有限公司 | A thick liquids dewatering system for ceramic manufacture |
| CN119118431A (en) * | 2024-10-18 | 2024-12-13 | 航天凯天环保科技股份有限公司 | A kitchen wastewater treatment system based on ceramic flat membrane |
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