CN206156750U - Chlorine dioxide gas synthesizer - Google Patents
Chlorine dioxide gas synthesizer Download PDFInfo
- Publication number
- CN206156750U CN206156750U CN201621193251.7U CN201621193251U CN206156750U CN 206156750 U CN206156750 U CN 206156750U CN 201621193251 U CN201621193251 U CN 201621193251U CN 206156750 U CN206156750 U CN 206156750U
- Authority
- CN
- China
- Prior art keywords
- storehouse
- aerated reaction
- chlorine dioxide
- raw material
- aeration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 160
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 81
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 81
- 239000002994 raw material Substances 0.000 claims abstract description 91
- 238000005273 aeration Methods 0.000 claims abstract description 67
- 239000007788 liquid Substances 0.000 claims abstract description 31
- 238000006243 chemical reaction Methods 0.000 claims description 168
- 239000000463 material Substances 0.000 claims description 13
- 239000002699 waste material Substances 0.000 claims description 13
- 238000007599 discharging Methods 0.000 claims description 12
- 238000006213 oxygenation reaction Methods 0.000 claims description 7
- 239000000376 reactant Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 5
- 230000007423 decrease Effects 0.000 claims description 4
- 238000005259 measurement Methods 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 4
- 230000007613 environmental effect Effects 0.000 abstract description 7
- 230000015572 biosynthetic process Effects 0.000 abstract description 6
- 238000003786 synthesis reaction Methods 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- 230000008676 import Effects 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 231100000957 no side effect Toxicity 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 16
- 230000001276 controlling effect Effects 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 7
- 229960002218 sodium chlorite Drugs 0.000 description 7
- 239000000919 ceramic Substances 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229910001919 chlorite Inorganic materials 0.000 description 2
- 229910052619 chlorite group Inorganic materials 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- DFGWJCZWKBGVOX-UHFFFAOYSA-N [Cl+].[O-2].[O-2].[Ti+4] Chemical compound [Cl+].[O-2].[O-2].[Ti+4] DFGWJCZWKBGVOX-UHFFFAOYSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013064 chemical raw material Substances 0.000 description 1
- -1 chlorate chloroform Chemical compound 0.000 description 1
- 229940077239 chlorous acid Drugs 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The utility model is suitable for a chlorine dioxide synthesis technology's field provides a chlorine dioxide gas synthesizer, preblend the storehouse and preblend the aerated reactor storehouse group that the storehouse links to each other and is used for carrying out the raw materials after the mixture multistage aeration with the raw materials including the raw materials, the raw materials preblends the storehouse and is equipped with raw materials import and liquid outlet, aerated reactor storehouse group includes a plurality of aerated reactor storehouses that link to each other in order according to the raw material handling route, all is equipped with feed inlet, discharge gate, aeration mouth and chlorine dioxide gas overfall on the aerated reactor storehouse of every, is equipped with the aeration piece that is used for quantitative aeration in the aerated reactor storehouse of every. The utility model discloses a raw materials that sets up preblends storehouse and aerated reactor storehouse group for the chlorine dioxide gas purity that produces is high, thereby makes chlorine dioxide no side effect in the performance efficiency produce, is favorable to the environmental protection.
Description
Technical field
The utility model belongs to the field of chlorine dioxide synthetic technology, more particularly to a kind of chlorine dioxide synthesis dress
Put.
Background technology
Chlorine dioxide has functions that excellent disinfection eliminates the unusual smell, and is increasingly recognized by people in air sterillization application
Know and receive.Chlorine dioxide is a kind of Strong oxdiative gas, and this Strong oxdiative gas is by two or more chemical raw material (such as chlorine
Sour sodium, sodium chlorite adding citric acid or hydrochloric acid etc.) obtained by reacting in gas reaction storehouse Inner.
Although chlorine dioxide has functions that excellent disinfection eliminates the unusual smell, if purity of chlorine dioxide is not high,
The residue of such as chlorite or chlorate chloroform thing will be produced, these residues can cause chlorine dioxide playing effect
While also bring stronger side effect.Specifically, purity of chlorine dioxide is whether completely chlorine dioxide chemical energy changes
As a result embody.Purity is high, produces without chlorate and the accessory substance such as chlorite and chloroform thing, and terminal is used with regard to safety and environmental protection.
Otherwise purity is not high, and the accessory substance that it is produced will bring secondary pollution as chlorine dioxide is used, and be unfavorable for environmental protection.
However, the methods that prior art is primarily directed to chlorine dioxide generation are improved, such as acidization
Preparation method, electrochemical process preparation method, electrolysis preparation method etc.；These various preparation method researchs are how to produce
Chlorine dioxide, and lack research for how to improve purity of chlorine dioxide aspect.The generation chlorine dioxide of such as prior art
Device, there is more improvement in terms of how producing chlorine dioxide, special for the China of " CN105849036A " referring to application publication number
Sharp application documents, solve the problems, such as how continuation produces chlorine dioxide.But, for how structure of reactor makes conjunction
How reason, improve the purity of chlorine dioxide, does not refer to.
Utility model content
Main purpose of the present utility model is to provide a kind of chlorine dioxide synthesizer, it is intended to solve traditional dioxy
Change the low problem of the purity of chlorine dioxide of the generation that chlorine body synthesizer is present.
The utility model is achieved in that a kind of chlorine dioxide synthesizer, including：Raw material premix close storehouse and
Storehouse is closed with the raw material premix to be connected and for mixed raw material to be carried out the aerated reaction storehouse group of multi-stage aeration；The raw material
Premixing storehouse is provided with material inlet and liquid outlet；Aerated reaction storehouse group include according to Feedstock treating path be sequentially connected it is many
Individual aerated reaction storehouse, on the aerated reaction storehouse of each charging aperture, discharging opening, aeration opening and chlorine dioxide are equipped with
Overfall, is provided with for the aeration block of quantitative aeration in the aerated reaction storehouse of each.
As optimal technical scheme of the present utility model：
Further, aerated reaction storehouse group include being sequentially connected and the first aerated reaction storehouse that volume successively decreases successively,
Second aerated reaction storehouse and the 3rd aerated reaction storehouse；The charging aperture in the first aerated reaction storehouse closes storehouse with the raw material premix
Liquid outlet is connected, and the raw material premix close the height of the height higher than the charging aperture in the first aerated reaction storehouse of the liquid outlet in storehouse
Degree.
Further, the volume in the raw material premix conjunction storehouse is set to 1 with the total measurement (volume) ratio of aerated reaction storehouse group：
13.6；The volume lapse rate in the first aerated reaction storehouse, the second aerated reaction storehouse and the 3rd aerated reaction storehouse is set to 0.5
Times.
Further, the volume in the raw material premix conjunction storehouse is set to 1 with the volumetric ratio in the first aerated reaction storehouse：5, institute
The volume for stating raw material premix conjunction storehouse is set to 1 with the volumetric ratio in the second aerated reaction storehouse：4.5, the raw material premix close storehouse
Volume is set to 1 with the volumetric ratio in the 3rd aerated reaction storehouse：4.0.
Further, the total amount of reactant liquor in the group of the aerated reaction storehouse is set to 169 with the ratio of aeration total amount：1.
Further, the raw material premix are closed storehouse and are provided with for air entrance and cause the raw material premix to close formation in storehouse
The pore of air pressure.
Further, the raw material premix close storehouse and aerated reaction storehouse group is integrated in a housing.
Further, aerated reaction storehouse group is provided with the temperature control for controlling the environment temperature of aerated reaction storehouse group
Part.
Further, aerated reaction storehouse group is also associated with the pneumatic flow for controlling in the group of the aerated reaction storehouse
Reaction controlling storehouse；The reaction controlling storehouse includes the oxygenation air pump for producing tolerance and is connected with the oxygenation air pump
Multiple pneumatic flow meters, the pneumatic flow meter of each is correspondingly connected with the aeration block of each.
Further, aerated reaction storehouse group is connected with for the waste trap of separating treatment waste liquid.
The chlorine dioxide synthesizer that the utility model is provided, by the conjunction for making a generation chlorine dioxide
Into device, in synthesis, raw material is first closed in storehouse and mixed chlorine dioxide in raw material premix, and it is anti-that mixed raw material enters aeration
Storehouse group is answered to carry out multi-stage aeration reaction so that overall generating process interlink function, and then the raw material of chlorine dioxide is being converted
During, reaction more fully, make generation chlorine dioxide purity reach it is high so that chlorine dioxide is playing work(
It is free from side effects while effect generation, is conducive to environmental protection.
Description of the drawings
Fig. 1 is the structural representation of the chlorine dioxide synthesizer that the utility model embodiment is provided；
Fig. 2 is the dimensional structure diagram of the chlorine dioxide synthesizer that the utility model embodiment is provided.
In figure：1- housings, 11- raw material premix conjunction storehouse, 111- material inlets, 112- liquid outlets, 12- aerated reactions storehouse group,
The first aerated reactions of 121- storehouse, 1211- downtake pipes, 1212- charging apertures, the second aerated reactions of 122- storehouse, 1221- second rows
Tracheae, the aerated reaction storehouses of 123- the 3rd, the blast pipes of 1231- the 3rd, 1232- discharging openings, 1233- aeration openings, 1234- chlorine dioxide
Gas overflowing mouth, 124- aeration blocks, 125- chlorine dioxide exhaust mains, 13- reaction controllings storehouse, 131- oxygenation air pumps, 132- gas
Pressure type flowmeter, 14- ceramics temperature control plates, 141- temperature control plate power ports, 15- waste traps, 151- waste discharge liquid pipes.
Specific embodiment
In order that the purpose of this utility model, technical scheme and advantage become more apparent, below in conjunction with accompanying drawing and enforcement
Example, is further elaborated to the utility model.It should be appreciated that specific embodiment described herein is only to explain this
Utility model, is not used to limit the utility model.
It should be noted that when element is referred to as " being fixed on " or " being arranged at " another element, it can be directly another
On one element or it is connected on another element.When an element is referred to as " being connected to " another element, it can be with
It is directly to another element or is indirectly connected to another element.
The utility model provides a kind of chlorine dioxide synthesizer, closes storehouse 11 by the raw material premix for arranging and exposes
Solid/liquid/gas reactions storehouse group 12 so that the chlorine dioxide purity of generation is high so that chlorine dioxide while effect is played without pair
Effect is produced, and is conducive to environmental protection.
Accompanying drawing 1 and Fig. 2 are referred to, the chlorine dioxide synthesizer includes：Raw material premix close storehouse 11 and and raw material
Premixing storehouse 11 is connected and for mixed raw material to be carried out the aerated reaction storehouse group 12 of multi-stage aeration；Raw material premix close storehouse 11
It is provided with material inlet 111 and liquid outlet 112；Aerated reaction storehouse group 12 includes the multiple exposures being sequentially connected according to Feedstock treating path
Solid/liquid/gas reactions storehouse, is equipped with charging aperture 1212, discharging opening 1232, aeration opening 1233 and chlorine dioxide on the aerated reaction storehouse of each
Gas overflowing mouth 1234, is provided with the aeration block 124 for quantitative aeration in the aerated reaction storehouse of each.
The chlorine dioxide synthesizer that the utility model embodiment is provided, by making a generation chlorine dioxide
The synthesizer of body, in synthesis, raw material first closes mixing in storehouse 11 to chlorine dioxide in raw material premix, and mixed raw material enters
Entering aerated reaction storehouse group 12 carries out multi-stage aeration reaction so that overall generating process interlink function, and then the raw material of chlorine dioxide
During being converted, reaction more fully, make generation chlorine dioxide purity reach it is high so that titanium dioxide
Chlorine is free from side effects generation while effect is played, and is conducive to environmental protection.
Further, for the ease of the raw material after premixing from the overflow of liquid outlet 112 to the first aerated reaction storehouse 121 in,
Meanwhile, mixed raw material carries out the multi-stage aeration reaction of ladder ground into aerated reaction storehouse group 12, contributes to overall generating process
Interlink function, to improve the purity of chlorine dioxide, aerated reaction storehouse group 12 includes being sequentially connected and volume successively decreases successively
First aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123；The first aerated reaction storehouse 121 is entered
Material mouth 1212 and raw material premix are closed the liquid outlet 112 in storehouse 11 and are connected, and it is higher than that raw material premix close the height of the liquid outlet 112 in storehouse 11
The height of the charging aperture 1212 in one aerated reaction storehouse 121.
Additionally, height of the height of the charging aperture 1212 in the first aerated reaction storehouse 121 higher than its discharging opening 1232, second exposes
The height of the charging aperture 1212 in solid/liquid/gas reactions storehouse 122 higher than its discharging opening 1232 height, the charging aperture in the 3rd aerated reaction storehouse 123
Height of 1212 height higher than its discharging opening 1232, it is preferable that difference in height is located between 0.3～0.6cm, in order to form original
Natural inflow of the material from a upper aerated reaction storehouse to next aerated reaction storehouse.Specifically, aeration opening 1233 is separately positioned on
The bottom in the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123.Charging aperture 1212, discharging
Under mouth 1232 is separately positioned in the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123
Portion, charging aperture 1212 and discharging opening 1232 are opened in respectively the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd
The left and right sides in aerated reaction storehouse 123.Chlorine dioxide overfall 1234 be separately positioned on the first aerated reaction storehouse 121,
Two aerated reaction storehouses 122 and the top in the 3rd aerated reaction storehouse 123.It should be noted that, to put it more simply, first exposure of the present embodiment
Solid/liquid/gas reactions storehouse 121, the second aerated reaction storehouse 122, the charging aperture 1212 in the 3rd aerated reaction storehouse 123, discharging opening 1232, aeration opening
1233 and chlorine dioxide overfall 1234 can be indicated using same label, do not make in addition differentiation.
Specifically, material inlet 111 could be arranged to two, in order to the raw material by chlorine dioxide is produced respectively by not
Same material inlet 111 imports to raw material premix and closes in storehouse 11.Refinement ground, one of which is led by the first material inlet 111
Enter to raw material premix and close in storehouse 11, another by the raw material of generation chlorine dioxide is imported to by the second material inlet 111
Raw material premix are closed in storehouse 11.
Additionally, it should be noted that, the aerated reaction storehouse group 12 of the utility model embodiment is preferably arranged to three, i.e., suitable
The first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123 that secondary connected and volume successively decreases successively.
It is to be appreciated that the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123 are mutually passed through for three
Logical ladder aerated reaction storehouse.Aerated reaction storehouse group 12 includes but is not limited to three aerated reaction storehouses, can be anti-in three aerations
Answering increases the quantity in aerated reaction storehouse on storehouse, in order to the raw material after premixing to be carried out step aeration stripping more than three-level.
In addition it is also possible to be set in the parameter of the relation existed according to three aerated reaction storehouses, parameter is zoomed in or out in proportion,
To meet the different changes to chlorine dioxide demand.
Specifically, the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123 are both designed as
The cylindrical shape of high polyester PVC materials, in order to the raw material after premixing is carried out into three-level step aeration stripping.First aeration is anti-
Storehouse 121 is answered to connect downtake pipe 1211, the connection of the second aerated reaction storehouse 122 second exhaust pipe 1221, the 3rd aerated reaction storehouse
123 the 3rd blast pipes 1231 of connection, downtake pipe 1211, the blast pipe 1231 of second exhaust pipe 1221 and the 3rd are collected to one
To working space on chlorine dioxide exhaust main 125, in order to output after chlorine dioxide is collected.
Further, it is contemplated that raw material premix close the volume of storehouse 11 size, determine raw material enter ratio, enter amount with
And the time speed for entering, meanwhile, the time of the purity of the output of chlorine dioxide and Raw Material Blending Ratio and raw material reaction and
There is direct relation with aeration storage capacity etc., therefore, in order that raw material reacts more fully in rear end step aerated reaction storehouse, enter
And the output for having chlorine dioxide with high purity is caused, raw material premix are closed the volume in storehouse 11 and are set with the total measurement (volume) ratio of aerated reaction storehouse group 12
For 1：13.6；The volume lapse rate in the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123 sets
For 0.5 times.Preferably, the volumetric ratio of volume and the first aerated reaction storehouse 121 that raw material premix close storehouse 11 is set to 1：5, raw material is pre-
The volumetric ratio in the volume of mixing bunker 11 and the second aerated reaction storehouse 122 is set to 1：4.5, raw material premix close the volume and the 3rd in storehouse 11
The volumetric ratio in aerated reaction storehouse 123 is set to 1：4.0.
The setting relation that raw material premix close storehouse 11 and the volume of aerated reaction storehouse group 12 is illustrated below, referring to table 1.Tool
Body ground, premixing storage capacity and the total measurement (volume) ratio of aerated reaction storehouse group 12 are 1：13.6 times, each step aeration storage capacity lapse rate is
0.5 times.The volumetric ratio of volume and the first aerated reaction storehouse 121 that raw material premix close storehouse 11 is set to 1：5, raw material premix close storehouse 11
The volumetric ratio in volume and the second aerated reaction storehouse 122 is set to 1：4.5, raw material premix close the volume in storehouse 11 and the 3rd aerated reaction storehouse
123 volumetric ratio is set to 1：4.0.
Table 1
Because we abide by this volume fraction relation of Xun, so that chlorine dioxide produces purity height.
Further, in the present embodiment, in being raw material in sodium chlorate or sodium chlorite adding citric acid or hydrochloric acid, we select
Sodium chlorite and hydrochloric acid obtain chlorine dioxide for raw material, and its reaction equation is：
2ClO2+H2O-HClO2+HClO3
According to reaction equation, select to add hydrochloric acid to go out chlorine dioxide as raw material reaction with sodium chlorite, set sodium chlorite
Concentration is 7～10%, chooses a concentration point；Concentration of hydrochloric acid is set as 6～9%, a concentration point is chosen, sodium chlorite is set
Solution reaction amount is 75ml/H, set hydrochloric acid solution quantitative response amount draw as 82.5ml/H, then react after chlorine dioxide in theory
Yield should be in more than 5000mg/H.By setting when material concentration and consumption, abide by raw material premixing storehouse 11 in Xun tables 1 and hold
The setting relation of product and the step aeration storage capacity of insertion, then the yield of chlorine dioxide is 5100mg, has reached theoretical quantum of output.
Additionally, in order to further be set by the total amount and the relation of aeration total amount of the reactant liquor in aerated reaction storehouse group 12
It is fixed so that raw material reacts more fully in the group of aeration storehouse, and then cause the output for having chlorine dioxide with high purity, aerated reaction storehouse group
The total amount of the reactant liquor in 12 is set to 169 with the ratio of aeration total amount：1.
Hereinafter citing is set for the total amount of the reactant liquor in aerated reaction storehouse group 12 and the relation of aeration total amount, referring to
Table 2.
Table 2
Take in table 21 citing and further illustrate the total amount of reactant liquor and the setting relation of aeration total amount：Still chlorous acid is taken
Sodium and hydrochloric acid are described as follows as chlorine dioxide reaction raw material：
Its reaction equation is：
2ClO2+H2O-HClO2+HClO3
Sodium chlorite and hydrochloric acid as liquid charging stock premixing after → overflow into and carry out aeration in the first aerated reaction storehouse 121
The volume of liquid storage is that the aeration tolerance of 169.60ml → needs should be maintained in the first aerated reaction storehouse 121 of stripping → now
1.0L/min。
When the raw material of aeration storehouse 1 is overflowed to 169.60ml → raw material overflows into and continues in the second aerated reaction storehouse 122 automatically
The volume of liquid storage is that the aeration tolerance of 141.30ml → needs should be maintained in the second aerated reaction storehouse 122 of aeration stripping → now
0.83L/min。
When the raw material of aeration storehouse 2 is overflowed to 141.30ml → raw material overflows into and continues in the 3rd aerated reaction storehouse 123 automatically
The volume of the liquid storage of the 3rd aerated reaction storehouse 123 of aeration stripping → now is that the aeration tolerance of 113.1ml → needs should be maintained at
0.67L/min。
In above three-level step aeration, each aerated reaction storehouse upper end is designed with chlorine dioxide overfall 1234,
The chlorine dioxide that aeration stripping goes out is facilitated to overflow.Amount further by the reactant liquor in each of the above aerated reaction storehouse is total with aeration
The relation setting of amount, is set for step aeration stripping, in order in this chlorine dioxide synthesizer according to this relation
Middle acquisition chlorine dioxide with high purity gas.
Additionally, referring to table 3, the speed that control material rate is entered in aerated reaction storehouse group 12 with raw material can also be passed through,
Further improve the purity of chlorine dioxide.Specifically, the speed speed that raw material is entered in aerated reaction storehouse group 12, has referred to
How many raw materials how long, in aerated reaction storehouse group 12 reacted and by complete aeration stripping by interior resting on.
Table 3
Further, the upper end in raw material premix conjunction storehouse 11 is provided with and enter for air and cause raw material premix to close formation in storehouse 11
The pore of air pressure.A pore is opened up by closing the upper end in storehouse 11 in raw material premix, is entered for air, it is empty in storehouse to be formed
Atmospheric pressure, after facilitating raw material premix to close, can be flowed into the first aerated reaction storehouse 121 under gas pressure from liquid outlet 112
It is interior.
Further, raw material premix close storehouse 11 and aerated reaction storehouse group 12 is integrated in a housing 1, specifically, Ke Yiyou
The high polyester PVC board of one fixed dimension is fabricated to a cubic box with closure cap, anti-in order to carry out aeration stripping
Should.Further, aerated reaction storehouse group 12 is provided with the temperature control part for controlling the environment temperature of aerated reaction storehouse group 12, preferably
Ground, temperature control part is set to ceramic temperature control plate 14.Preferably, the ceramic temperature control plate 14 in this enforcement is set to three, the ceramics of three
Temperature control plate 14 is contacted by electric power connection line, and temperature control plate power port 141 is provided with housing 1, and the ceramic temperature control plate 14 of three is same
The temperature control plate power port 141 of setting is connected, with ensure three aerated reaction storehouses environment temperature within the specific limits.Preferably,
Ceramic temperature control plate 14 controls environment temperature at 10～20 degree.
Further, aerated reaction storehouse group 12 is also associated with for controlling the anti-of the pneumatic flow in aerated reaction storehouse group 12
Storehouse 13 should be controlled；Reaction controlling storehouse 13 includes the oxygenation air pump 131 for producing tolerance and many with what oxygenation air pump 131 was connected
Individual pneumatic flow meter 132, the pneumatic flow meter 132 of each is correspondingly connected with the aeration block 124 of each.It should be noted that, expose
Air parcel 124 can adopt existing conventional techniques.Preferably, aeration block 124 is provided with connecting hole and multiple solarization air caps, multiple
Solarization air cap and connecting hole insertion.Specifically, aeration block 124 adopts the dilute aeration block 124 of polyester tetrafluoro, on the aeration block 124 before
Afterwards the intensive solarization air cap in left and right, at the middle part of aeration block 124 connection circular hole is provided with, and the aeration block 124 of each is used for the air pressure of each
Flowmeter 132 is connected, so that the aeration block 124 of each carries out quantitative aeration in different aerated reaction storehouses.Additionally, air pressure
Flowmeter 132 can adopt existing conventional techniques, specifically, connecting circular tube and the aeration of each that pneumatic flow meter 132 is arranged
The connection circular hole of block 124 is communicated, in order to make different aerated reaction storehouses reach different tolerance.In addition, solarization air cap can be with Jing
Cross laser to get, the intensive amount of the solarization air cap got by laser is while disclosure satisfy that aeration, so that the aeration of each
Aerosol aeration state is in reaction warehouse.
Further, aerated reaction storehouse group 12 is connected with the waste trap 15 for separating treatment waste liquid.Waste liquid is separated
Device 15 is connected by waste discharge liquid pipe 151 with the discharging opening 1232 in the 3rd aerated reaction storehouse 123.Specifically, waste discharge liquid pipe 151 can be with
U-shaped discharging tube is designed as, in order to by carrying out the waste liquid of reception after separating treatment, to be transported to waste liquid outlet, further have
Beneficial to environmental protection.
It should be noted that, in the present embodiment, aerated reaction storehouse group 12, raw material premix is closed into storehouse 11 and reaction controlling storehouse 13 is equal
In being placed in same housing 1, specifically, housing 1 includes a device storehouse and No. two device storehouses, and aerated reaction storehouse group 12 is placed in
In a number device storehouse, raw material premix close storehouse 11 and reaction controlling storehouse 13 is placed in No. two device storehouses.
Preferred embodiment of the present utility model is these are only, it is all in this practicality not to limit the utility model
Any modification, equivalent or improvement made within new spirit and principle etc., should be included in guarantor of the present utility model
Within the scope of shield.
Claims (10)
1. a kind of chlorine dioxide synthesizer, it is characterised in that include：
Raw material premix are closed storehouse and close storehouse with the raw material premix and are connected and for mixed raw material to be carried out into multi-stage aeration
Aerated reaction storehouse group；
The raw material premix are closed storehouse and are provided with material inlet and liquid outlet；
Aerated reaction storehouse group includes the multiple aerated reaction storehouses being sequentially connected according to Feedstock treating path, the exposure of each
Charging aperture, discharging opening, aeration opening and chlorine dioxide overfall are equipped with solid/liquid/gas reactions storehouse, the aerated reaction of each
It is provided with storehouse for the aeration block of quantitative aeration.
2. chlorine dioxide synthesizer as claimed in claim 1, it is characterised in that aerated reaction storehouse group includes suitable
The first aerated reaction storehouse, the second aerated reaction storehouse and the 3rd aerated reaction storehouse that secondary connected and volume successively decreases successively；Described first
The liquid outlet that the charging aperture in aerated reaction storehouse closes storehouse with the raw material premix is connected, and the raw material premix close the height of the liquid outlet in storehouse
Height of the degree higher than the charging aperture in the first aerated reaction storehouse.
3. chlorine dioxide synthesizer as claimed in claim 2, it is characterised in that the raw material premix close the volume in storehouse
1 is set to the total measurement (volume) ratio of aerated reaction storehouse group：13.6；The first aerated reaction storehouse, the second aerated reaction storehouse
0.5 times is set to the volume lapse rate in the 3rd aerated reaction storehouse.
4. chlorine dioxide synthesizer as claimed in claim 3, it is characterised in that the raw material premix close the volume in storehouse
1 is set to the volumetric ratio in the first aerated reaction storehouse：5, the raw material premix close the volume and second aerated reaction in storehouse
The volumetric ratio in storehouse is set to 1：4.5, the raw material premix are closed the volume in storehouse and are set to 1 with the volumetric ratio in the 3rd aerated reaction storehouse：
4.0。
5. the chlorine dioxide synthesizer as described in any one of Claims 1 to 4, it is characterised in that the aerated reaction
The total amount of the reactant liquor in the group of storehouse is set to 169 with the ratio of aeration total amount：1.
6. the chlorine dioxide synthesizer as described in any one of Claims 1 to 4, it is characterised in that the raw material premix
Close storehouse to be provided with for air entrance and cause the raw material premix to close the pore that air pressure is formed in storehouse.
7. the chlorine dioxide synthesizer as described in any one of Claims 1 to 4, it is characterised in that the raw material premix
Close storehouse and aerated reaction storehouse group is integrated in a housing.
8. the chlorine dioxide synthesizer as described in any one of Claims 1 to 4, it is characterised in that the aerated reaction
Storehouse group is provided with the temperature control part for controlling the environment temperature of aerated reaction storehouse group.
9. the chlorine dioxide synthesizer as described in any one of Claims 1 to 4, it is characterised in that the aerated reaction
Storehouse group is also associated with the reaction controlling storehouse for controlling the pneumatic flow in the group of the aerated reaction storehouse；The reaction controlling Cang Bao
Include the oxygenation air pump by producing tolerance and multiple pneumatic flows for being connected with the oxygenation air pump based on, the air pressure of each
Flowmeter is correspondingly connected with the aeration block of each.
10. the chlorine dioxide synthesizer as described in any one of Claims 1 to 4, it is characterised in that the aerated reaction
Storehouse group is connected with for the waste trap of separating treatment waste liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621193251.7U CN206156750U (en) | 2016-10-26 | 2016-10-26 | Chlorine dioxide gas synthesizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621193251.7U CN206156750U (en) | 2016-10-26 | 2016-10-26 | Chlorine dioxide gas synthesizer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN206156750U true CN206156750U (en) | 2017-05-10 |
Family
ID=58656778
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201621193251.7U Active CN206156750U (en) | 2016-10-26 | 2016-10-26 | Chlorine dioxide gas synthesizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN206156750U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106315513A (en) * | 2016-10-26 | 2017-01-11 | 吴予奇 | Chlorine dioxide gas synthesizer |
-
2016
- 2016-10-26 CN CN201621193251.7U patent/CN206156750U/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106315513A (en) * | 2016-10-26 | 2017-01-11 | 吴予奇 | Chlorine dioxide gas synthesizer |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN206156750U (en) | Chlorine dioxide gas synthesizer | |
| CN206156748U (en) | Chlorine dioxide gas's aerated reactor device | |
| CN109970199A (en) | Biological denitrificaion couples N2O recycles integrated reactor and its method | |
| CN101880029B (en) | Continuous production device of composite chlorine dioxide and technology | |
| CN106348249A (en) | Manufacturing method for chlorine dioxide gas synthesis device | |
| CN205517697U (en) | Horizontal reactor | |
| CN106365121A (en) | Aeration reaction device of chlorine dioxide gas | |
| CN211412033U (en) | Pure chlorine dioxide gas tube type preparation device | |
| CN106315513A (en) | Chlorine dioxide gas synthesizer | |
| CN207983680U (en) | A kind of non-burning brick production device for automatically molding | |
| CN103623754A (en) | Light reaction device and applications in preparation of hydroxycobalamin or salts thereof | |
| CN208943870U (en) | A kind of feed nozzle mixing tube | |
| CN115285959A (en) | Low-cost continuous production method of iron phosphate | |
| CN114671766A (en) | Method for preparing nitrobenzoic acid by intersection type continuous oxidation | |
| CN205741223U (en) | A kind of can produce oxygen, ultrapure activated water and the multi-function device of hydrogen rich water simultaneously | |
| CN103936009B (en) | A kind of thermal decomposition of silane produces the device and method of nano level high-purity silicon powder | |
| CN207121443U (en) | Ozone water apparatus removes ozone mechanism and ozone water apparatus | |
| CN102583251B (en) | Chlorine dioxide reaction device | |
| CN110255774A (en) | The processing system and treatment process of cupric high ammonia-nitrogen wastewater | |
| CN204999911U (en) | Split type swirl marsh gas breathing machine | |
| CN105664820A (en) | Horizontal reactor | |
| CN216063251U (en) | Reaction device for preparing cobalt oxyhydroxide | |
| CN212713767U (en) | Gas-water separation and water storage device | |
| CN220443842U (en) | Continuous acidification apparatus for producing | |
| CN217459083U (en) | Byproduct ammonia water recovery unit in aluminium ash sponge brick production process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220329 Address after: 518000 1815, building a, No. 9, Furong Road, Tantou community, Songgang street, Bao'an District, Shenzhen, Guangdong Province Patentee after: Shenzhen Daqi disinfection New Technology Co.,Ltd. Address before: 518000 No. 3039 Baoan North Road, Luohu District, Shenzhen, Guangdong. Patentee before: Wu Yuqi Patentee before: Duan Ju Patentee before: Wu Yuxin |
|
| TR01 | Transfer of patent right |