CN106348249A - Manufacturing method for chlorine dioxide gas synthesis device - Google Patents
Manufacturing method for chlorine dioxide gas synthesis device Download PDFInfo
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- CN106348249A CN106348249A CN201610950960.3A CN201610950960A CN106348249A CN 106348249 A CN106348249 A CN 106348249A CN 201610950960 A CN201610950960 A CN 201610950960A CN 106348249 A CN106348249 A CN 106348249A
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- storehouse
- aerated reaction
- raw material
- group
- aeration
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/024—Preparation from chlorites or chlorates from chlorites
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- Oxygen, Ozone, And Oxides In General (AREA)
Abstract
The invention is suitable for the field of a chlorine dioxide synthesis technique and provides a manufacturing method for a chlorine dioxide gas synthesis device. The method comprises the following steps: manufacturing a raw material pre-mixing cabin for mixing raw materials used for synthesis chlorine dioxide gas, and forming a raw material inlet and a liquid outlet on the raw material pre-mixing cabin; manufacturing an aeration reaction cabin set which includes a plurality of aeration reaction cabins, and forming a feeding port, a discharging port, an aeration port and a chlorine dioxide gas overflow port on each aeration reaction cabin; manufacturing an aeration block for quantitatively aerating, and arranging the aeration block in each aeration reaction cabin; and completing the mounting and connection of the raw material pre-mixing cabin and the aeration reaction cabin set. According to the invention, the raw material pre-mixing cabin and the aeration reaction cabin set are manufactured, so that the purity of the generated chlorine dioxide gas is high, the chlorine dioxide can exert effects without side effects, and the environmental protection is benefited.
Description
Technical field
The invention belongs to the field of chlorine dioxide synthetic technology, particularly to a kind of system of chlorine dioxide synthesizer
Make method.
Background technology
Chlorine dioxide has functions that excellent disinfection eliminates the unusual smell, and is increasingly recognized by people in air sterillization application
Know and accept.Chlorine dioxide is a kind of Strong oxdiative gas, and this Strong oxdiative gas is by two or more chemical raw material (such as chlorine
Sour sodium, sodium chlorite adding citric acid or hydrochloric acid etc.) by obtaining in the reaction of gas reaction storehouse.
Although chlorine dioxide has functions that excellent disinfection eliminates the unusual smell, if purity of chlorine dioxide is not high,
Such as the residue of the chloroform thing such as chlorite or chlorate will be produced, these residues can lead to chlorine dioxide playing effect
While also bring stronger side effect.Specifically, purity of chlorine dioxide is whether completely chlorine dioxide chemical energy changes
Result embodies.Purity is high, does not have the by-product such as chlorate and chlorite and chloroform thing to produce, terminal is using with regard to safety and environmental protection.
Otherwise purity is not high, and the by-product that it produces will use with chlorine dioxide and bring secondary pollution, be unfavorable for environmental protection.
However, the methods that prior art is primarily directed to chlorine dioxide generation improve, such as acidization
Preparation method, electrochemical process preparation method, electrolysis preparation method etc.；These various preparation method researchs are how to produce
Chlorine dioxide, and lack research for how improving purity of chlorine dioxide aspect.The generation chlorine dioxide of such as prior art
Device, has more improvement in terms of how producing chlorine dioxide, and the China being " cn105849036a " referring to application publication number is special
Sharp application documents, solve the problems, such as how persistence produces chlorine dioxide.But, how conjunction is made for structure of reactor
How reason, improve the purity of chlorine dioxide, all do not refer to.
Content of the invention
Present invention is primarily targeted at providing a kind of manufacture method of chlorine dioxide synthesizer it is intended to solve to pass
The purity of chlorine dioxide that the chlorine dioxide synthesizer that the manufacture method of system chlorine dioxide synthesizer exists produces
Low problem.
The present invention is achieved in that a kind of manufacture method of chlorine dioxide synthesizer, comprises the steps:
Make and close storehouse for the raw material premix being mixed the raw material of synthesis chlorine dioxide, in described raw material premix
Close and open up material inlet and liquid outlet on storehouse；
Make aerated reaction storehouse group, aerated reaction storehouse group is set to multiple aerated reaction storehouses, anti-in the described aeration of each
Answer and charging aperture, discharging opening, aeration opening and chlorine dioxide overfall are all opened up on storehouse；
Make the aeration block for quantitative aeration, and described aeration block is set in the described aerated reaction storehouse of each；
Complete described raw material premix are closed with storehouse and the installation of described aerated reaction storehouse group connects.
As the preferred technical solution of the present invention:
Further, complete described raw material premix are closed with the step installing connection of storehouse and described aerated reaction storehouse group described
After rapid, described aerated reaction storehouse group is carried out with closing pouring.
Further, after the described step that described aerated reaction storehouse group is carried out with closing pouring, by described raw material premix
Close storehouse and described aerated reaction storehouse group is integrated in a housing and closes storehouse and described aerated reaction storehouse group to described raw material premix
Carry out integrally closed.
Further, in the described step making for the described aeration block of quantitative aeration, described aeration block is got
Multiple solarization air caps, and open up connecting hole on described aeration block.
Further, complete described raw material premix are closed with the installation Connection Step of storehouse and described aerated reaction storehouse group described
In, the height of the liquid outlet in described raw material premix conjunction storehouse is set higher than the height of the charging aperture in described aerated reaction storehouse.
Further, in the described step making described aerated reaction storehouse group, described aerated reaction storehouse group includes first
Aerated reaction storehouse, the second aerated reaction storehouse and the 3rd aerated reaction storehouse, will be anti-to described first aerated reaction storehouse, described second aeration
Described in Ying Canghe, the 3rd aerated reaction storehouse is sequentially connected；And described raw material premix are closed volume and the described aerated reaction storehouse group in storehouse
Total measurement (volume) ratio be set to 1:13.6；Described first aerated reaction storehouse, described second aerated reaction storehouse and the 3rd aerated reaction storehouse
Volume lapse rate is set to 0.5 times.
Further, close storehouse in described making for the raw material premix being mixed the raw material of synthesis chlorine dioxide
Step in, close to offer on storehouse to enter for air and described raw material premix are closed in storehouse in described raw material premix and form air
The pore of pressure.
Further, after the described step completing to the making of aerated reaction storehouse group, make for quantitative exposure described
Before the step of the aeration block of gas, described aerated reaction storehouse group is provided for controlling the ambient temperature of described aerated reaction storehouse group
Temperature control part；Or, after the described step completing to the making of aerated reaction storehouse group, complete to described raw material premix described
Before closing storehouse and the step of installation connection of described aerated reaction storehouse group, control is provided on the group of described aerated reaction storehouse described
The temperature control part of the ambient temperature of aerated reaction storehouse group.
Further, after the described step completing to the making of aerated reaction storehouse group, make for quantitative exposure described
Before the step of the aeration block of gas, described aerated reaction storehouse group is also associated with for controlling the air pressure stream in the group of described aerated reaction storehouse
The reaction controlling storehouse of amount；Described reaction controlling storehouse is included the oxygen supplement air pump for producing tolerance and is connected with described oxygen supplement air pump
Multiple pneumatic flow meters, the described pneumatic flow meter of each is correspondingly connected with the described aeration block of each；
Or, after the described step completing to the making of aerated reaction storehouse group, complete to described raw material premix described
Before closing storehouse and the step of installation connection of described aerated reaction storehouse group, described aerated reaction storehouse group is also associated with described for controlling
The reaction controlling storehouse of the pneumatic flow in the group of aerated reaction storehouse；Described reaction controlling storehouse includes the oxygen supplement air pump for producing tolerance
And the multiple pneumatic flow meters being connected with described oxygen supplement air pump, the described pneumatic flow meter of each correspondingly with described in each
Aeration block is connected.
Further, complete described raw material premix are closed with the step installing connection of storehouse and described aerated reaction storehouse group described
After rapid, described aerated reaction storehouse group is connected with the waste trap for separating treatment waste liquid.
The manufacture method of the chlorine dioxide synthesizer that the present invention provides, by making a generation chlorine dioxide
The synthesizer of body, in synthesis, raw material first closes in storehouse in raw material premix and mixes chlorine dioxide, and mixed raw material enters
Aerated reaction storehouse group carries out multi-stage aeration reaction so that overall generating process interlink function, and then the raw material of chlorine dioxide is entering
During row conversion, reaction is more abundant, so that the chlorine dioxide purity of generation is reached high, so that chlorine dioxide exists
It is free from side effects generation while playing effect, be conducive to environmental protection.
Brief description
Fig. 1 be chlorine dioxide synthesizer provided in an embodiment of the present invention structural representation；
Fig. 2 be chlorine dioxide synthesizer provided in an embodiment of the present invention perspective view.
In figure: 1- housing, 11- raw material premix conjunction storehouse, 111- material inlet, 112- liquid outlet, 12- aerated reaction storehouse group,
121- the first aerated reaction storehouse, 1211- downtake pipe, 1212- charging aperture, 122- the second aerated reaction storehouse, 1221- second row
Trachea, 123- the 3rd aerated reaction storehouse, 1231- the 3rd exhaustor, 1232- discharging opening, 1233- aeration opening, 1234- chlorine dioxide
Gas overflowing mouth, 124- aeration block, 125- chlorine dioxide exhaust main, 13- reaction controlling storehouse, 131- oxygen supplement air pump, 132- gas
Pressure type flowmeter, 14- pottery temperature control plate, 141- temperature control plate power port, 15- waste trap, 151- waste discharge liquid pipe.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, below in conjunction with drawings and Examples, right
The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only in order to explain the present invention, not
For limiting the present invention.
It should be noted that when element is referred to as " being fixed on " or " being arranged at " another element, it can be directly another
On one element or be connected on this another element.When an element is referred to as " being connected to " another element, it is permissible
It is directly to another element or be indirectly connected to this another element.
The present invention provides a kind of manufacture method of chlorine dioxide synthesizer, closes storehouse 11 by the raw material premix of setting
And aerated reaction storehouse group 12 is so that the chlorine dioxide purity producing is high, so that chlorine dioxide is playing the same of effect
When have no side effect generation, be conducive to environmental protection.
Refer to accompanying drawing 1 and Fig. 2, the manufacture method of this chlorine dioxide synthesizer comprises the steps:
Make and close storehouse 11 for the raw material premix being mixed the raw material of synthesis chlorine dioxide, close in raw material premix
Material inlet 111 and liquid outlet 112 are opened up on storehouse 11；
Make aerated reaction storehouse group 12, aerated reaction storehouse group 12 is set to multiple aerated reaction storehouses, anti-in the aeration of each
Answer and charging aperture 1212, discharging opening 1232, aeration opening 1233 and chlorine dioxide overfall 1234 are all opened up on storehouse；
Make the aeration block 124 for quantitative aeration, and be respectively provided with aeration block 124 in the aerated reaction storehouse of each；
Complete raw material premix are closed with storehouse 11 and the installation of aerated reaction storehouse group 12 connects.
The manufacture method of chlorine dioxide synthesizer provided in an embodiment of the present invention, by making a generation dioxy
Change the synthesizer of chlorine body, in synthesis, raw material first closes in storehouse 11 in raw material premix and mixes chlorine dioxide, mixed
Raw material enters 12 groups of aerated reaction storehouse and carries out multi-stage aeration reaction so that overall generating process interlink function, and then chlorine dioxide
Raw material during being converted, reaction is more abundant, so that the chlorine dioxide purity of generation is reached high so that
Chlorine dioxide is free from side effects generation while playing effect, is conducive to environmental protection.
Further, after completing the step of the installation connection that raw material premix are closed with storehouse 11 and aerated reaction storehouse group 12, right
Aerated reaction storehouse group 12 carries out closing pouring.In the present embodiment, it is preferred to use high polyester epoxide-resin glue is to aerated reaction storehouse group
12 carry out closing pouring, and to prevent, raw material premix from closing storehouse 11 and the connector of aerated reaction storehouse group 12 loosens leakage, thus improving
Raw material premix close the service life of storehouse 11 and aerated reaction storehouse group 12.
Further, after aerated reaction storehouse group 12 being carried out close the step watered, raw material premix are closed storehouse 11 and aeration
Reaction warehouse group 12 is integrated in a housing 1 and carries out integrally closed to raw material premix conjunction storehouse 11 and aerated reaction storehouse group 12.This
In embodiment, it is preferred to use pvc plate closes storehouse 11 to raw material premix and aerated reaction storehouse group 12 carries out integrally closed, protects further
Shield raw material premix close storehouse 11 and aerated reaction storehouse group 12, thus improving the use that raw material premix close storehouse 11 and aerated reaction storehouse group 12
Life-span.
Further, for the ease of the raw material after premixing from liquid outlet 112 overflow to the first aerated reaction storehouse 121 in,
Meanwhile, mixed raw material enters aerated reaction storehouse group 12 with carrying out ladder multi-stage aeration reaction, contributes to overall generating process
Interlink function, to improve the purity of chlorine dioxide, in the step making aerated reaction storehouse group 12, aerated reaction storehouse group 12
Including the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123, by the first aerated reaction storehouse
121st, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123 are sequentially connected；And raw material premix are closed volume and the exposure in storehouse 11
The total measurement (volume) ratio of solid/liquid/gas reactions storehouse group 12 is set to 1:13.6；First aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd exposure
The volume lapse rate in solid/liquid/gas reactions storehouse 123 is set to 0.5 times.Further, complete to close storehouse 11 and aerated reaction storehouse to raw material premix
In the installation Connection Step of group 12, height raw material premix being closed the liquid outlet 112 in storehouse 11 is set higher than the first aerated reaction storehouse
The height of 121 charging aperture 1212.
Additionally, the liquid outlet 112 that the charging aperture 1212 in the first aerated reaction storehouse 121 closes storehouse 11 with raw material premix is connected.The
The height of the charging aperture 1212 in one aerated reaction storehouse 121 is higher than the height of its discharging opening 1232, the entering of the second aerated reaction storehouse 122
The height of material mouth 1212 is higher than the height of its discharging opening 1232, and the height of the charging aperture 1212 in the 3rd aerated reaction storehouse 123 is higher than
The height of its discharging opening 1232 it is preferable that difference in height is located between 0.3～0.6cm, in order to form raw material from a upper aeration
Reaction warehouse is to the natural inflow in next aerated reaction storehouse.Specifically, aeration opening 1233 is separately positioned on the first aerated reaction storehouse
121st, the bottom in the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123.Charging aperture 1212, discharging opening 1232 are respectively provided with
In the middle and lower part in the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123, charging aperture 1212 He
Discharging opening 1232 is opened in the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123 respectively
The left and right sides.Chlorine dioxide overfall 1234 is separately positioned on the first aerated reaction storehouse 121, the second aerated reaction storehouse 122
Top with the 3rd aerated reaction storehouse 123.It should be noted that, to put it more simply, the first aerated reaction storehouse 121 of the present embodiment,
Two aerated reaction storehouses 122, the charging aperture 1212 in the 3rd aerated reaction storehouse 123, discharging opening 1232, aeration opening 1233 and titanium dioxide
Chlorine body overfall 1234 all can be indicated using same label, does not in addition distinguish.
Specifically, material inlet 111 could be arranged to two, in order to pass through not the raw material producing chlorine dioxide respectively
Same material inlet 111 imports to raw material premix and closes in storehouse 11.Refinement ground, one of which is led by the first material inlet 111
Enter and close in storehouse 11 to raw material premix, another by the raw material of generation chlorine dioxide is imported to by the second material inlet 111
Raw material premix are closed in storehouse 11.
Additionally, it should be noted that, the aerated reaction storehouse group 12 of the embodiment of the present invention is preferably arranged to three, i.e. sequentially phase
Even and volume the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123 successively decreased successively.Permissible
Understand ground, the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123 are mutually communicated for three
Ladder aerated reaction storehouse.Aerated reaction storehouse group 12 includes but is not limited to three aerated reaction storehouses, can be in three aerated reaction storehouses
The upper quantity increasing aerated reaction storehouse, in order to carry out the step aeration stripping of more than three-level by the raw material after premixing.Additionally,
Set in the parameter of relation that can also exist according to three aerated reaction storehouses, zoomed in or out parameter in proportion, with full
The different change to chlorine dioxide demand of foot.
Specifically, the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123 are both designed as
The cylindrical shape of high polyester pvc material, in order to carry out three-level step aeration stripping by the raw material after premixing.First aeration is anti-
Storehouse 121 is answered to connect downtake pipe 1211, the second aerated reaction storehouse 122 connects second exhaust pipe 1221, the 3rd aerated reaction storehouse
123 connection the 3rd exhaustors 1231, downtake pipe 1211, second exhaust pipe 1221 and the 3rd exhaustor 1231 are collected to one
On chlorine dioxide exhaust main 125, export working space in order to after collecting chlorine dioxide.
In the step making aerated reaction storehouse group 12, it is contemplated that raw material premix close the size of storehouse 11 volume, determine raw material
The time speed of the ratio, the amount entering and entrance that enter, meanwhile, the purity of the output of chlorine dioxide and raw material mixing ratio
Time of example and raw material reaction and have direct relation, therefore, so that raw material is in rear end step with aeration storage capacity etc.
The reaction of aerated reaction storehouse is more abundant, and then makes the output having chlorine dioxide with high purity, and raw material premix close volume and the exposure in storehouse 11
The total measurement (volume) ratio of solid/liquid/gas reactions storehouse group 12 is set to 1:13.6；First aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd exposure
The volume lapse rate in solid/liquid/gas reactions storehouse 123 is set to 0.5 times.Preferably, raw material premix close volume and the first aerated reaction storehouse in storehouse 11
121 volumetric ratio is set to 1:5, and the volumetric ratio of volume and the second aerated reaction storehouse 122 that raw material premix close storehouse 11 is set to 1:4.5,
The volumetric ratio of volume and the 3rd aerated reaction storehouse 123 that raw material premix close storehouse 11 is set to 1:4.0.
Hereinafter storehouse 11 is closed to raw material premix and the setting relation of aerated reaction storehouse group 12 volume is illustrated, referring to table 1.Tool
Body ground, premixing storage capacity is 1:13.6 times with aerated reaction storehouse group 12 total measurement (volume) ratio, and each step aeration storage capacity lapse rate is
0.5 times.The volumetric ratio of volume and the first aerated reaction storehouse 121 that raw material premix close storehouse 11 is set to 1:5, and raw material premix close storehouse 11
The volumetric ratio in volume and the second aerated reaction storehouse 122 is set to 1:4.5, and raw material premix close volume and the 3rd aerated reaction storehouse in storehouse 11
123 volumetric ratio is set to 1:4.0.
Table 1
Because we are when making chlorine dioxide cooperative devices, by abiding by this volume fraction relation, so that
It is high that chlorine dioxide produces purity.
Further, in the present embodiment, it is in raw material in sodium chlorate or sodium chlorite adding citric acid or hydrochloric acid, we select
Sodium chlorite and hydrochloric acid to obtain chlorine dioxide for raw material, and its reaction equation is:
2clo2+h2o-hclo2+hclo；
According to reaction equation, select to go out chlorine dioxide with the acid of sodium chlorite salt adding for raw material reaction, set sodium chlorite
Concentration is 7～10%, chooses a concentration point；Set concentration of hydrochloric acid as 6～9%, choose a concentration point, set sodium chlorite
Solution reaction amount is 75ml/h, sets hydrochloric acid solution quantitative response amount as 82.5ml/h, then draw after reaction chlorine dioxide in theory
Yield should be in more than 5000mg/h.During by setting material concentration and consumption, abiding by raw material premixing storehouse 11 in table 1 and having held
The setting relation of the long-pending step aeration storage capacity with insertion, then the yield of chlorine dioxide is 5100mg, has reached theoretical quantum of output.
Close in the step in storehouse 11 making for the raw material premix being mixed the raw material of synthesis chlorine dioxide, former
The upper end in material premixing storehouse 11 is provided with and enters for air and make raw material premix to close the pore of formation air pressure in storehouse 11.Pass through
The upper end closing storehouse 11 in raw material premix opens up a pore, enters for air, to form storehouse inner air pressure, facilitates raw material premix
After conjunction, can be flowed in the first aerated reaction storehouse 121 from liquid outlet 112 under gas pressure.
Further, raw material premix close storehouse 11 and aerated reaction storehouse group 12 is integrated in a housing 1, specifically, Ke Yiyou
The high polyester pvc plate of one fixed dimension is fabricated to a cubic box with closure cap, anti-in order to carry out aeration stripping
Should.
Further, after completing the step to the making of aerated reaction storehouse group 12, making the exposure for quantitative aeration
Before the step of air parcel 124, aerated reaction storehouse group 12 is provided with the temperature control part of the ambient temperature for controlling aerated reaction storehouse group 12.This
Outer it is also possible to after completing the step to the making of aerated reaction storehouse group 12, complete to close storehouse 11 to raw material premix and aeration is anti-
Before answering the step that the installation of storehouse group 12 connects, aerated reaction storehouse group 12 is provided with the ambient temperature for controlling aerated reaction storehouse group 12
Temperature control part.In this enforcement, temperature control part preferably employs ceramic temperature control plate 14.Preferably, the ceramic temperature control plate 14 in this enforcement sets
It is set to three, the ceramic temperature control plate 14 of three is contacted by electric power connection line, temperature control plate power port 141 is provided with housing 1, three
Individual ceramic temperature control plate 14 connects with the temperature control plate power port 141 of setting, ensures three aerated reaction storehouses by above-mentioned steps
Ambient temperature within the specific limits.Preferably, the temperature of pottery magnetic temperature control plate 14 is set in 20～30 degree.Further so that making pottery
Porcelain temperature control plate 14 controls ambient temperature at 10～20 degree.
Further, after completing the step to the making of aerated reaction storehouse group 12, making the exposure for quantitative aeration
Before the step of air parcel 124, aerated reaction storehouse group 12 is also associated with for controlling the anti-of pneumatic flow in aerated reaction storehouse group 12
Storehouse 13 should be controlled；Reaction controlling storehouse 13 includes oxygen supplement air pump 131 for producing tolerance and many with what oxygen supplement air pump 131 was connected
Individual pneumatic flow meter 132, the pneumatic flow meter 132 of each is correspondingly connected with the aeration block 124 of each.Additionally, should be noted
It is it is also possible to after completing the step to the making of aerated reaction storehouse group 12, complete to close storehouse 11 and aeration to raw material premix
Before the step that the installation of reaction warehouse group 12 connects, carry out the operation of the setting in above-mentioned reaction controlling storehouse 13.Reaction controlling storehouse 13
Concrete structure is identical with aforesaid structure, here, repeating no more.
It should be noted that, aeration block 124 can adopt existing conventional techniques.Specifically, making for quantitative aeration
In the step of aeration block 124, aeration block 124 gets multiple solarization air caps, and connecting hole is opened up on aeration block.The present embodiment
In, preferentially multiple solarization air caps are got using laser, and open up connection circular hole at the middle part of aeration block 124.Get through laser
Multiple solarization air caps are so that the intensive amount of solarization air cap disclosure satisfy that while aeration so that the first aerated reaction storehouse 121, second exposes
It is in aerosol aeration state in solid/liquid/gas reactions storehouse 122 and the 3rd aerated reaction storehouse 123；And it is provided with connection in the middle part of aeration block 124
Circular hole, communicates in order to same other elements, so that different aerated reaction storehouses reaches different tolerance.Connect in the present embodiment
Circular hole is communicated with multiple pneumatic flow meters 132, to realize different aerated reaction storehouses and to reach different tolerance.
Specifically, aeration block 124 adopts the dilute aeration block of polyester tetrafluoro 124, and the aeration block 124 of each is used for the gas of each
Pressure type flowmeter 132 is connected, so that the aeration block 124 of each carries out quantitative aeration in different aerated reaction storehouses.Additionally, gas
Pressure type flowmeter 132 can adopt existing conventional techniques, specifically, connecting circular tube and the exposure of each that pneumatic flow meter 132 is arranged
The connection circular hole of air parcel 124 communicates, and the aerated reaction storehouse in order to make different reaches different tolerance.In addition, solarization air cap is permissible
Get through laser, the intensive amount of the solarization air cap got by laser is while disclosure satisfy that aeration, so that the exposure of each
It is in aerosol aeration state in solid/liquid/gas reactions storehouse.Additionally, it should be noted that, during using, the air pressure of oxygen supplement air pump 131
Supply should be greater than the first aerated reaction storehouse 121, the second aerated reaction storehouse 122 and the 3rd aerated reaction storehouse 123 aeration institute simultaneously
The tolerance needing.
Further, after completing raw material premix are closed with storehouse 11 and the installation connection of aerated reaction storehouse group 12, aerated reaction
Storehouse group 12 is connected with the waste trap 15 for separating treatment waste liquid.Waste trap 15 passes through waste discharge liquid pipe 151 and the 3rd
The discharging opening 1232 in aerated reaction storehouse 123 is connected.Specifically, waste discharge liquid pipe 151 can be designed as u shape discharging tube, in order to logical
Cross and carry out, after separating treatment, being transported to waste liquid outlet by the waste liquid of reception, be conducive to environmental protection further.
It should be noted that, in the present embodiment, by aerated reaction storehouse group 12, raw material premix close storehouse 11 and reaction controlling storehouse 13 is equal
It is placed in same housing 1, specifically, housing 1 includes a device storehouse and No. two device storehouses, and aerated reaction storehouse group 12 is placed in
In a number device storehouse, raw material premix close storehouse 11 and reaction controlling storehouse 13 is placed in No. two device storehouses.
During use: the liquid charging stock of two kinds of generation chlorine dioxide is closed storehouse by being input into raw material premix two communicating pipes,
When raw material premix close the hole position reaching liquid outlet, raw material flows in the first aerated reaction storehouse, and raw material reaches the first aerated reaction storehouse
The hole position of discharging opening when, raw material flows into the second aerated reaction storehouse, and raw material reaches the hole position of the discharging opening in the second aerated reaction storehouse
When, raw material flows into the 3rd aerated reaction storehouse.
Reaction process flow process: when raw material enters in aerated reaction storehouse, start oxygen supplement air pump, restart pottery magnetic temperature control plate,
First aerated reaction storehouse, the second aerated reaction storehouse and the 3rd aerated reaction storehouse aeration simultaneously, the chlorine dioxide of aeration stripping
Overflow and collect to two from the upper end outlet hole in the first aerated reaction storehouse, the second aerated reaction storehouse and the 3rd aerated reaction storehouse respectively
Discharge after chlorine monoxid exhaust main.Further, it is also possible to by the built-in unidirectional fan effect of the port of export in chlorine dioxide exhaust main,
In order to by chlorine dioxide by irreversible export need Work places.It should be noted that, chlorine dioxide aerofluxuss
The built-in unidirectional fan of the port of export of house steward can not be anti-loaded.Start to volatilize in Work places after chlorine dioxide output, so that
Air sterilizing eliminates the unusual smell and works, and is gone out through removal waste fluid bank of tubes by the waste liquid after aeration stripping, and through waste trap
Environmental protection treatment.
These are only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and
Any modification, equivalent or improvement of being made within principle etc., should be included within the scope of the present invention.
Claims (10)
1. a kind of manufacture method of chlorine dioxide synthesizer is it is characterised in that comprise the steps:
Make and close storehouse for the raw material premix being mixed the raw material of synthesis chlorine dioxide, close storehouse in described raw material premix
On open up material inlet and liquid outlet；
Make aerated reaction storehouse group, aerated reaction storehouse group is set to multiple aerated reaction storehouses, in the described aerated reaction storehouse of each
On all open up charging aperture, discharging opening, aeration opening and chlorine dioxide overfall；
Make the aeration block for quantitative aeration, and described aeration block is set in the described aerated reaction storehouse of each；
Complete described raw material premix are closed with storehouse and the installation of described aerated reaction storehouse group connects.
2. chlorine dioxide synthesizer as claimed in claim 1 manufacture method it is characterised in that described complete right
After described raw material premix close storehouse and the step of installation connection of described aerated reaction storehouse group, described aerated reaction storehouse group is sealed
Close pouring.
3. the manufacture method of chlorine dioxide synthesizer as claimed in claim 2 is it is characterised in that described to described
After aerated reaction storehouse group carries out closing the step watered, described raw material premix are closed storehouse and described aerated reaction storehouse group is integrated in one
Close storehouse in housing and to described raw material premix and described aerated reaction storehouse group carries out integrally closed.
4. the manufacture method of chlorine dioxide synthesizer as claimed in claim 1 is it is characterised in that use in described making
In the step of the described aeration block of quantitative aeration, described aeration block gets multiple solarization air caps, and open on described aeration block
If connecting hole.
5. the chlorine dioxide synthesizer as described in any one of Claims 1 to 4 manufacture method it is characterised in that
In the described installation Connection Step completing to described raw material premix conjunction storehouse and described aerated reaction storehouse group, described raw material premix are closed
The height of the liquid outlet in storehouse is set higher than the height of the charging aperture in described aerated reaction storehouse.
6. the chlorine dioxide synthesizer as described in any one of Claims 1 to 4 manufacture method it is characterised in that
In the step of described making described aerated reaction storehouse group, described aerated reaction storehouse group includes the first aerated reaction storehouse, the second aeration
Reaction warehouse and the 3rd aerated reaction storehouse, by described first aerated reaction storehouse, described second aerated reaction storehouse and described 3rd aeration
Reaction warehouse is sequentially connected；And the total measurement (volume) ratio that described raw material premix are closed the volume in storehouse and described aerated reaction storehouse group is set to 1:
13.6；The volume lapse rate in described first aerated reaction storehouse, described second aerated reaction storehouse and the 3rd aerated reaction storehouse is set to 0.5
Times.
7. the chlorine dioxide synthesizer as described in any one of Claims 1 to 4 manufacture method it is characterised in that
Described making is closed in the step in storehouse for the raw material premix being mixed the raw material of synthesis chlorine dioxide, in described raw material
Offer on premixing storehouse and enter for air and make described raw material premix to close the pore of formation air pressure in storehouse.
8. the chlorine dioxide synthesizer as described in any one of Claims 1 to 4 manufacture method it is characterised in that
After the described step completing to the making of aerated reaction storehouse group, before the described step making for the aeration block of quantitative aeration,
Described aerated reaction storehouse group is provided for control the temperature control part of the ambient temperature of described aerated reaction storehouse group；
Or, after the described step completing to the making of aerated reaction storehouse group, complete to close storehouse to described raw material premix described
With installing before the step connecting of described aerated reaction storehouse group, described aerated reaction storehouse group is provided for controlling described aeration
The temperature control part of the ambient temperature of reaction warehouse group.
9. the chlorine dioxide synthesizer as described in any one of Claims 1 to 4 manufacture method it is characterised in that
After the described step completing to the making of aerated reaction storehouse group, before the described step making for the aeration block of quantitative aeration,
Described aerated reaction storehouse group is also associated with the reaction controlling storehouse for controlling the pneumatic flow in the group of described aerated reaction storehouse；Described
Reaction controlling storehouse includes based on the oxygen supplement air pump by producing tolerance and multiple pneumatic flow of being connected with described oxygen supplement air pump, often
Individual described pneumatic flow meter is correspondingly connected with the described aeration block of each.
Or, after the described step completing to the making of aerated reaction storehouse group, complete to close storehouse to described raw material premix described
With installing before the step connecting of described aerated reaction storehouse group, described aerated reaction storehouse group is also associated with for controlling described aeration
The reaction controlling storehouse of the pneumatic flow in reaction warehouse group；Described reaction controlling storehouse include oxygen supplement air pump for producing tolerance and
The multiple pneumatic flow meters being connected with described oxygen supplement air pump, the described pneumatic flow meter of each the correspondingly described aeration with each
Block is connected.
10. the chlorine dioxide synthesizer as described in any one of Claims 1 to 4 manufacture method it is characterised in that
After the described step completing the installation in described raw material premix conjunction storehouse and described aerated reaction storehouse group is connected, described aerated reaction storehouse
Group is connected with the waste trap for separating treatment waste liquid.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610950960.3A CN106348249A (en) | 2016-10-26 | 2016-10-26 | Manufacturing method for chlorine dioxide gas synthesis device |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610950960.3A CN106348249A (en) | 2016-10-26 | 2016-10-26 | Manufacturing method for chlorine dioxide gas synthesis device |
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| Publication Number | Publication Date |
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| CN106348249A true CN106348249A (en) | 2017-01-25 |
Family
ID=57865098
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610950960.3A Pending CN106348249A (en) | 2016-10-26 | 2016-10-26 | Manufacturing method for chlorine dioxide gas synthesis device |
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| CN108975277A (en) * | 2018-08-23 | 2018-12-11 | 四川齐力绿源水处理科技有限公司 | A kind of preparation method of high-pure chlorinedioxide |
| CN116656466A (en) * | 2023-06-06 | 2023-08-29 | 上海勘测设计研究院有限公司 | Split photosynthetic organism hydrogen production reactor |
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| US20080023668A1 (en) * | 2004-07-08 | 2008-01-31 | Joseph Callerame | Clathrate of chlorine dioxide |
| JP2014033955A (en) * | 2012-08-08 | 2014-02-24 | Cleancare Inc | Chlorine dioxide gas sterilizer/pure chlorine dioxide solution generator |
| CN203807156U (en) * | 2014-04-02 | 2014-09-03 | 山东山大华特科技股份有限公司 | Integrated chlorine dioxide preparation device |
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| CN101003362A (en) * | 2007-01-11 | 2007-07-25 | 樊德强 | Safe, environmental protecting chlorine dioxide generator |
| CN101024492A (en) * | 2007-02-09 | 2007-08-29 | 中北大学 | High-purity chlorine dioxide gas generating method and apparatus |
| JP2014033955A (en) * | 2012-08-08 | 2014-02-24 | Cleancare Inc | Chlorine dioxide gas sterilizer/pure chlorine dioxide solution generator |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108975277A (en) * | 2018-08-23 | 2018-12-11 | 四川齐力绿源水处理科技有限公司 | A kind of preparation method of high-pure chlorinedioxide |
| CN116656466A (en) * | 2023-06-06 | 2023-08-29 | 上海勘测设计研究院有限公司 | Split photosynthetic organism hydrogen production reactor |
| CN116656466B (en) * | 2023-06-06 | 2024-05-31 | 上海勘测设计研究院有限公司 | Split photosynthetic organism hydrogen production reactor |
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