CN206138958U - Attaches wall vibration pulsation adsorption equipment - Google Patents

Abstract

The utility model belongs to the technical field of fluid flow control and heat and mass transfer, and relates to a wall-attached oscillating pulsation adsorption device and method. The utility model obtains a brand-new wall-attached oscillating pulsation adsorption device and method, which can overcome the uneven flow velocity of the adsorbent bed section, the uneven adsorption saturation of the adsorbent, and the fact that the gas is separated from the adsorbent in the usual adsorption device and method. Inefficiencies such as inconsistent separation or purification levels at various points along the cross-section. Compared with the traditional adsorption device, the capacity and volume can be reduced, and the loading amount of the adsorbent can be saved. The high-efficiency pulsating flow is still used in the desorption stage, which can shorten the desorption regeneration time and save high-temperature inert gas or clean process gas consumed by desorption.

Description

Wall-attached oscillating pulsation adsorption device

technical field

The invention belongs to the technical field of fluid flow control and heat and mass transfer, and relates to a jet oscillation pressure swing adsorption device.

Background technique

The use of solid adsorbents to adsorb specific components in process gases, such as CO2, moisture, etc., to achieve the purpose of separation and purification, is a commonly used process technology in many industrial productions such as petrochemical and natural gas. With the development of social productive forces, industrial production is gradually developing from extensive to refined, and the efficiency of production equipment has attracted more and more attention.

Most of the existing adsorption technologies and processes use a fixed bed loaded with adsorbent filler particles to introduce the process gas to be treated into the absorption tank, pass through the packing layer from bottom to top, and adsorb unnecessary components or impurities to the adsorbent. In packing, the gas leaving the adsorbent is separated or purified.

In order to achieve a certain amount of adsorption, reduce the number of desorption and regeneration of the adsorbent, and prolong the switching cycle of intermittent production, the diameter and thickness of the fixed bed of the adsorption tank are generally large. It will cause the gas velocity of the process gas passing through the packing to be uneven in the cross-section of the adsorption tank, and there will be loose and smooth flow areas and flow dead ends, and the adsorbed amount or concentration of the gas when it leaves the packing layer will be uneven. Remix. This uneven flow will lead to early adsorption saturation of the adsorbent in the free flow area, and before the adsorbent in other areas fails, the effect of gas separation or purification has deteriorated, and the desorption operation has to be switched in advance.

Although thickening the adsorbent bed can prolong the adsorption cycle, the flow resistance will increase, which will increase energy consumption and make it difficult to unload the adsorbent. However, the above-mentioned imagination of uneven gas velocity in the same cross-section and uneven adsorption saturation concentration of adsorbents still exists. In addition to wasting equipment volume, adsorbents with low saturation are always desorbed and regenerated with heating every time, which not only wastes materials, but also Unnecessary consumption of energy.

For the desorption regeneration of the adsorbent, it is generally necessary to heat the inert gas (and accompanied by depressurization) to flow through the adsorbent bed to take away the adsorbed components or impurities. In this process, in addition to the uneven gas velocity and the different desorption rates of the adsorbents, local overheating may also occur, exceeding the tolerance temperature of the adsorbent and causing it to fail prematurely. The desorption regeneration efficiency is low, and more precious desorption regeneration gas will be consumed.

Contents of the invention

The invention provides an adsorption device that adopts wall-attached oscillating and pulsating flow to improve the uniformity of air flow. The innovation point is to use N high-efficiency externally excited wall-attached oscillators to convert process gas into 2N shares with a duty ratio of 1. /2, the frequency is equal, and the pulse flow with different starting phases, each pulse flow is separately from 2N or 2N pairs (4N) on the adsorption tank, and the circumferentially opposite nozzles are connected in parallel to form 2N Yes, flow symmetry to avoid partial impact) One of the nozzles enters the adsorption tank. In this way, for the part of the adsorbent bed that is opposite to any nozzle, what is subjected to and flows through is a pulse flow that is rushed and interrupted, which continuously starts to accelerate the boosting shock and quickly terminates the energy storage And the oscillation effect of instantaneous release can break through the flow dead zone and greatly overcome the problem of uneven flow velocity in the adsorbent bed. Pulse flow can also increase the degree of turbulence, strengthen diffusion, stimulate thinning and break the gas boundary layer on the surface of adsorbent particles, increase the gradient of surface concentration difference, and enable mass transfer and adsorption to proceed faster. When entering from 2N or 2N pairs of inlets, the azimuth and phase time difference of each pulse flow entering the adsorption tank are staggered, which can make the force on the bed symmetrical and even, and avoid deflection impact and vibration.

For the desorption and regeneration operation, the same method is also adopted, except that 2N or 2N pairs of nozzles under the adsorption tank are changed to introduce 2N pulsating desorption and regeneration airflows one by one. out of the mouth.

Technical scheme of the present invention:

A wall-attached oscillating pulsation adsorption device, which connects the process gas in parallel to the inlets of N high-efficiency externally excited wall-attached oscillators, and the 2N pulse outlets of the oscillators are respectively connected to the upper space of the adsorption tank, consisting of 2N blocks Or in the 2N or 2N pairs of independent space chambers divided by 4N upper space partition plates that are separated from each other but not necessarily sealed, the lower end of the chamber is the upper sieve plate and filter screen of the adsorbent bed, and under the sieve plate, also set 4N/n (n = 1 ~ 4) blocks are aligned with the upper space partition plate, and the packing upper partition plate with a certain height separates the upper part of the adsorbent bed from the section to prevent the pulsating airflow from searching. The path of least resistance flows and mixes prematurely.

For the regeneration operation, however, the same solution as for the adsorption operation described above is adopted.

The key technology of the wall-attached oscillating and pulsating adsorption device of the present invention is to use a high-efficiency externally excited airflow oscillator, which makes the airflow entering the oscillator alternately switch the attached wall, and can form a 1/2 occupancy in the two downstream branch channels. The empty-ratio pulse flow guides the pulse flow into each separated and independent space chamber, and alternately flows into the adsorbent bed from different areas of the cross section, which can achieve the effect of uniform flow everywhere and eliminate dead zones. The N airflow oscillators used in the present invention are introduced into the oscillation cavity to excite the main airflow to oscillate. The excitation flow is all taken from the process gas of the same pressure. The duty ratio is close to 1/2, and the alternating pulse flow with a phase difference of T/2 (T is the oscillation period) is respectively introduced into the two excitation flow inlets on both sides of the oscillator, and alternately impacts and compresses from both sides of the main airflow. Primary airflow bends and switches Coanda. Due to the high pressure of the excitation flow, it can self-expand and accelerate longitudinally, so it will basically not cause the energy loss of the main flow, that is, a small pressure drop, instead of consuming a large amount of kinetic energy of the main fluid to reduce the pressure like a traditional self-excited oscillator, like an ejector. The self-excited flow accelerates the momentum transmission and produces a large pressure loss, which is the key to the practical significance of the present invention. In addition, the external excitation oscillation is reliable and stable, and the oscillation frequency can be adjusted arbitrarily, which can be lower than 0.1Hz. The oscillation efficiency will become higher as the frequency decreases, instead of just producing no effect on the process like a self-excited oscillator. Oscillation of hundreds of Hz frequency. This is also the guarantee that the method can be applied to the adsorption process.

The high-efficiency externally excited airflow oscillator adopted in the present invention can be used under high-pressure low-temperature adsorption conditions and low-pressure high-temperature desorption conditions, and has wide adaptability to flow rate, flow rate, pressure, temperature and expansion ratio.

The present invention adopts the airflow oscillator instead of using other switching methods to generate pulsating flow. The reason is that the reversing modulating valve only needs to process a small airflow of 5-20% of the total flow of process gas as the excitation flow, and this can be achieved. The small stream controls the oscillating flow of the large stream, thereby greatly reducing the impact of the airflow on the action switching unit. As long as the pressure remains equal, the temperature of the small flow for excitation does not have to be equal to that of the main flow, thus avoiding the possibility of malfunctions caused by the adsorption of low-temperature and desorption of high-temperature process gases to the excitation flow modulation reversing action device.

The wall-attached oscillating pulsation adsorption device of the present invention can also be operated in series or in parallel with multiple tanks like the common adsorption device and method.

Beneficial effects of the present invention: the present invention obtains a brand-new wall-attached oscillating pulsation adsorption device, which can overcome the uneven cross-sectional flow velocity of the adsorbent bed, uneven adsorption saturation of the adsorbent, and gas Inefficiencies such as inconsistent separation or purification levels at various points along the cross-section after detaching from the adsorbent.

Under the condition of the same processing capacity, the wall-attached oscillating pulsation adsorption device of the present invention can reduce the capacity and volume compared with the traditional adsorption device, and save the loading amount of the adsorbent.

Since the high-efficiency pulsating flow is still used in the desorption stage, the wall-attached oscillating pulsation adsorption device of the present invention can shorten the desorption regeneration time and save high-temperature inert gas or clean process gas consumed by desorption.

Description of drawings

Fig. 1 is a connection flowchart of various components of the Coanda oscillating and pulsating adsorption device of the present invention.

Fig. 2 is a schematic diagram of the upper and lower space partition plates and nozzle orientations of the upper cover and the bottom of the adsorption tank in the wall-attached oscillating pulsation adsorption device of the present invention.

Fig. 3 is a schematic diagram of an implementation structure of the excitation flow modulator in the wall-attached oscillating pulsation adsorption device of the present invention.

In the figure: 1 raw material gas inlet; 2 raw material gas opening and closing valve; 3 raw material gas oscillator inlet;

4 Raw material gas oscillator; 5 Raw gas excitation flow modulation unit; 6 Branch outlet of raw gas oscillator;

7 the upper nozzle of the adsorption tank; 8 the upper space partition plate; 9 the upper sieve plate and filter screen; 10 the upper partition plate of the filler;

11 The lower partition plate of packing; 12 The lower sieve plate and filter screen; 13 The lower space partition plate; 14 The lower nozzle of the adsorption tank;

15 Regenerated gas oscillator branch outlet; 16 Regenerated gas excitation flow modulation unit; 17 Regenerated gas oscillator;

18 Regeneration gas oscillator inlet; 19 Regeneration gas opening and closing valve; 20 Regeneration gas inlet;

21 Regeneration gas oscillator excitation inlet; 22 Purified gas outlet opening and closing valve; 23 Purified gas outlet;

24 adsorption tank; 25 adsorbent filler; 26 adsorption tank cover; 27 regeneration gas outlet;

28 regeneration gas outlet opening and closing valve; 29 feed gas oscillator excitation inlet; 30 excitation outlet;

31 body; 32 semi-hollow rotating shaft; 33 fixed cylinder liners; 34 cylinder liner side wall openings; 35 shaft side wall openings.

detailed description

A typical implementation of the wall-attached oscillating pulsation adsorption device of the present invention is described as follows, but not limited to this implementation:

The wall-attached oscillating pulsation adsorption device of the present invention comprises a raw material gas on-off valve 2, a raw material gas oscillator 4, a raw material gas excitation flow modulation unit 5; an upper space partition plate 8, an upper sieve plate and a filter screen 9, and packing Upper partition plate 10, packing lower partition plate 11, lower sieve plate and filter screen 12, lower space partition plate 13; regeneration gas excitation flow modulation unit 16, regeneration gas oscillator 17, regeneration gas opening and closing valve 19, purification Gas outlet opening and closing valve 22; adsorption tank 24, adsorbent filler 25, adsorption tank cover 26; regeneration gas outlet opening and closing valve 28;

The notable feature of the present invention is: N (N = 1 ~ 10) raw material gas oscillators 3 are used to convert the raw material gas containing impurity gas coming in from the raw material gas inlet 1 of the device into 2N shares by vibrating with the wall The gas with a ratio of 1/2 intermittent pulse flow flows into the adsorption tank 24 from the 2N pairs of adsorption tank upper cover 26 or the 2N pairs of nozzles 7 on the adsorption tank that are opposite to each other in parallel. The upper space partition plate 8 of the adsorption tank 24 divides the upper flow space into 2N, or 2N pairs of independent upper space partitions that are used in twos on the circumference. The upper initial section is divided into 4N/n cross-sectional partitions, and is aligned with each upper space partition, so that the raw material gas with 2N strands or 2N pairs of intermittent pulse flows can only be along the upper flow space and the packing. Flow and cut-off of the flow channels in the separate spaces defined separately, thereby avoiding the flow dead zone; at each moment, there are N streams or N pairs of feed gas flowing through the adsorbent filler 25 according to their respective intermittently arranged flow areas, and after being purified , pass through the lower sieve plate and filter screen 12, and flow out from 2N, or 2N pairs of adsorption tank lower nozzles 14 that are circumferentially opposite to each other in parallel, and then pass through 2N opened purification gas outlet opening and closing valves 22, from the purification Gas outlet 23 flows out of the device.

Similarly, the regeneration operation also uses N (N = 1 ~ 10) regeneration gas oscillators 17, and the regeneration gas coming in from the regeneration gas inlet 20 of the device is oscillated by the attached wall to become 2N shares with a duty ratio of 1/2 intermittent The pulsed gas flows into the adsorption tank 24 one by one from the 2N bottom openings of the adsorption tank 25, or the 2N pairs of the lower nozzles 14 of the adsorption tanks connected in parallel to each other on the circumference, and the lower space of the adsorption tank 24 is separated. The plate 13 divides the lower through-flow space into 2N, or 2N pairs of independent lower space partitions that are used in pairs opposite to each other on the circumference. n cross-sectional partitions, which are aligned with each lower space partition, so that the regeneration gas with intermittent pulse flow of 2N strands or 2N pairs of strands can only flow along the flow channels of the separate spaces defined for each in the lower flow space and the initial section of the filler. and cut-off, so as to avoid the flow dead zone; every moment, there are N strands or N pairs of regenerative gas flows through the adsorbent packing 25 according to their respective intermittently arranged flow areas, and after absorbing impurities, they pass through the upper sieve plate and filter The net 9 flows out from the upper nozzles 7 of 2N or 2N pairs of adsorption tanks that are circumferentially opposite in parallel, and then flows out of the device from the regeneration gas outlet 27 through the 2N regeneration gas outlet on-off valves 28 that are opened.

Referring to Fig. 3, the raw material gas excitation flow modulation unit 5 and the regeneration gas excitation flow modulation unit 16 are mainly composed of a body 31, a semi-hollow rotating shaft 32, a fixed cylinder liner 33, an excitation outlet 30, a gas inlet, two end covers, and bearings. And seals and other components.

The wall-attached oscillating pulsation adsorption device of the present invention separates a small stream of raw material gas into the raw material gas excitation flow modulation unit 5, which is switched to 2 to 2N (the more N, the finer the phase difference between each intermittent pulse flow can be) Bifurcated) The pulse excitation flow of the intermittent flow of small streams with a period of T is paired into 1 to N pairs with a phase difference of T/2, and is connected to the left and right of N feed gas oscillators 4, a total of 2N Raw material gas oscillator excitation inflow port 29; If the quantity of raw material gas oscillator excitation inflow port 29 is more than the number of excitation streams, then each raw gas oscillator 4 groups are equal to the number of excitation streams, and the raw material gas in the group oscillates The device excitation inflow port 29 left and left, right and right are connected in parallel. The pulse excitation flow excites each feed gas oscillator 4 to generate wall switching oscillation, and each feed gas oscillator 4 generates two intermittent pulse flows with a phase difference of T/2 and a duty ratio of 1/2. For the intermittent pulse flow from the branch outlet 6 of all feed gas oscillators, the minimum phase difference is T/2-T/2N according to the number of pulse-excited streams 2-2N.

The wall-attached oscillating pulsation adsorption device of the present invention separates a small stream of regeneration gas into the regeneration gas excitation flow modulation unit 16, and is switched to a pulse excitation flow of 2 to 2N small strands whose period is T and is intermittently flowed according to two phases The pairs with a difference of T/2 form 1 to N pairs, which are connected to the left and right of N regenerative gas oscillators 17, and there are altogether 2N regenerative gas oscillator excitation inflow ports 21; if the number of regenerative gas oscillator excitation inflow ports 21 is large In terms of the number of excitation streams, the regeneration gas oscillators 17 are grouped to be equal to the number of excitation streams, and the regeneration gas oscillator excitation flow ports 21 in the group are connected in parallel between left and left, right and right. The pulse excitation flow excites each regeneration gas oscillator 17 to generate Coanda switching oscillation, and each regeneration gas oscillator 17 generates two intermittent pulse flows with a phase difference of T/2 and a duty ratio of 1/2. The minimum phase difference of the intermittent pulse flows coming out of the branch outlet 15 of all regeneration gas oscillators is T/2~T/2N according to the number of pulse excitation streams 2~2N;

Referring to Fig. 2, the wall-attached oscillating pulsation adsorption device of the present invention, the upper space partition plate 8 in its adsorption tank 24, and the upper partition plate 10 on the filler, wherein a kind of implementation structure is to press the space cross section according to the center of the adsorption tank 24 The radiating melons are divided into equal-sized melon petal shapes. The number of the upper space partition plate 8 is 4N petals or 2N petals, and the shape of each petal is three vertical sides, a semi-elliptical or semi-disc shape, a single curved side right angle that completely coincides with the curvature of the inner wall of the adsorption tank cover 26 quadrilateral. After the space dividing plate 8 on each petal is radially assembled or welded, it is fixed or welded to the inner wall of the adsorption tank loam cake 26; Be close to the upper surface of upper sieve plate and filter screen 9. The number of partitions 10 on the filler is 4N or 2N or N, each of which is rectangular in shape, with a width equal to the inner radius of the adsorption tank 24 and a height of 0 to 50% of the height of the adsorbent filler 25; After the upper separation plate 10 of the petal filler is radially assembled or welded, it is aligned with the upper space separation plate 8 and embedded in the adsorbent filler 25, and its upper side is attached to the lower surface of the upper sieve plate and the filter screen 9.

In the wall-attached oscillating pulsation adsorption device of the present invention, the lower space partition plate 13 in the adsorption tank 24 and the lower partition plate 11 of the filler, one of the implementation structures is to divide the space cross-section according to the center of the adsorption tank 24 and radiate outwards. Become the shape of melon petals of equal size; the quantity of the lower space dividing plate 13 is 4N petals or 2N petals, and the shape of every petal is all three vertical sides, a semi-ellipse or semi-disc shape, and the curvature of the inner wall at the bottom of the adsorption tank 24 Perfectly coincident right-angled quadrilaterals. After the space dividers 13 under each petal are radially assembled or welded, they are fixed or welded to the inner wall of the bottom of the adsorption tank 24; Surface; the quantity of the partition plate 11 under the packing is 4N petals or 2N petals or N petals. ; After each flap packing lower partition plate 11 is radially assembled or welded, it is placed in alignment with the lower space partition plate 13 or installed on the upper surface of the lower sieve plate and filter screen 12 .

Referring to Fig. 3, the Coanda oscillating and pulsating adsorption device of the present invention, its feed gas excitation flow modulation unit 5, and regeneration gas excitation flow modulation unit 16, one embodiment is to pass the solid end of the semi-hollow shaft 32 out of the body 31 One end cover is used to be driven by the outside; the raw material gas or regeneration gas is introduced from the other end cover of the body 31, and is received by the hollow end opening of the semi-hollow rotating shaft 32, and the shaft sides of the semi-hollow rotating shaft 32 with different circumferential azimuth angles The wall opening 35, with the rotation of the semi-hollow rotating shaft 32, will be opened and closed periodically with the cylinder liner side wall openings 34 with different circumferential azimuth angles of the fixed cylinder liner 33 according to different time differences (phase differences) respectively, from each excitation flow Outlet 30 flows out 2-2N pulsating excitation streams with required time difference. Adjusting the rotational speed of the semi-hollow shaft 32 can control the Coanda oscillation frequency of the feed gas oscillator 4 or the regeneration gas oscillator 17 .

The operating principle of the wall-attached oscillating pulsation adsorption device is described as follows:

Adsorption stage: the regeneration gas on-off valve 19 and the regeneration gas outlet on-off valve 28 are closed, the raw gas on-off valve 2 and the purified gas outlet on-off valve 22 are opened. The raw gas to be separated and purified enters from the raw gas inlet 1 of the device, passes through the opened raw gas on-off valve 2, and enters the N raw gas oscillator inlets 3 at the same time. Another small stream enters the raw material gas excitation flow modulation unit 5, and is switched and modulated into 2N or N or N/2 excitation flows with different time differences; the excitation flow with a time difference of T/2 is paired, and each pair Both are connected to one or two, or the left and right raw gas oscillators of 4 parallel raw gas oscillators 4 excite the inflow port 29, and the raw material gas entering the raw gas oscillator inlet 3 is excited to generate Coanda oscillation, alternately from The left and right raw material gas oscillator branch outlets 6 of the raw material gas oscillator 4 discharge the raw material gas oscillator 4, and then enter the upper space through the upper nozzles 7 of the adsorption tanks connected to the respective corresponding connection of the raw material gas oscillator branch outlets 6 The separate upper space partitions separated by the partition plate 8 then pass through the limited area of the upper sieve plate and the filter screen 9 corresponding to the partition range, and enter the adsorbent packing 25, and the partition plate 10 on the packing Constrained, it continues to flow down through the adsorbent packing 25 in the partition until it exceeds the height of the separation plate 10 on the packing before diffusing to other regions. The impurity components of the pulse-flowing raw gas are separated and purified in the adsorbent filler 25, and the purified gas passes through the lower sieve plate and filter screen 12, and the lower flow space at the bottom of the adsorption tank 24, and flows out from the lower nozzle 14 of the adsorption tank. Tank 24; then through the opened purification gas outlet on-off valve 22, the device flows out from the purification gas outlet 23.

Regeneration stage: raw gas on-off valve 2 and purified gas outlet on-off valve 22 are closed, regeneration gas on-off valve 19 and regeneration gas outlet on-off valve 28 are opened. The pure regeneration gas enters from the regeneration gas inlet 20 of the device, passes through the opened regeneration gas on-off valve 19, and enters the N regeneration gas oscillator inlets 18 at the same time. Another small stream enters the regeneration gas excitation flow modulation unit 16, and is switched and modulated into 2N or N or N/2 excitation flows with different time differences; the excitation flow with a time difference of T/2 is paired, and each pair Both are connected to one or two, or the left and right regeneration gas oscillators of 4 parallel regeneration gas oscillators 17 excite the inflow port 21, and stimulate the regeneration gas entering the regeneration gas oscillator inlet 18 to generate Coanda oscillation, alternately from The left and right two regeneration gas oscillator branch outlets 15 of the regeneration gas oscillator 17 are discharged from the regeneration gas oscillator 17, and then enter the lower space through the lower nozzles 14 of the adsorption tanks respectively connected to the regeneration gas oscillator branch outlets 15. The separate lower space partitions separated by the partition plate 13 then pass through the limited area of the lower sieve plate and the filter screen 12 corresponding to the partition range, and enter the adsorbent packing 25, and the partition plate 11 under the packing Constrained, it continues to flow upwards through the adsorbent packing 25 in the partition until it exceeds the height of the partition plate 11 under the packing before diffusing to other regions. The pulse-flowing regeneration gas desorbs and carries away the impurities adsorbed in the adsorbent packing 25, passes through the upper sieve plate and filter screen 9, and the upper flow space on the upper part of the adsorption tank 24, and flows out from the upper nozzle 7 of the adsorption tank Adsorption tank 24; then through the opened regeneration gas outlet on-off valve 28, the device flows out from the regeneration gas outlet 27.

The scope of operating parameters of the wall-attached oscillating pulsation adsorption device and method of the present invention is as follows:

Operating air pressure range: 0.01～40MPa;

Process gas flow rate: 0.1～10000Nm ³ /hr

Pulse flow oscillation frequency: 0.1 ~ 100Hz.

Claims (10)

1. a kind of wall-attached vibrating is pulsed adsorbent equipment, it is characterised in that wall-attached vibrating pulsation adsorbent equipment is opened including unstripped gas Valve closing (2), unstripped gas agitator (4), unstripped gas stimulus stream modulating unit (5), upper space demarcation strip (8), upper sieve plate and filter screen (9), demarcation strip (11), lower sieve plate and filter screen (12), lower space demarcation strip (13), regeneration under demarcation strip (10), filler on filler Gas stimulus stream modulating unit (16), regeneration gas agitator (17), regeneration gas open and close valve (19), clean gas outlet open and close valve (22), (26) and regeneration gas outlet open and close valve (28) are covered on adsorption tanks (24), adsorbent filler (25), adsorption tanks；From unstripped gas entrance (1) unstripped gas of the impure gas come in through unstripped gas open and close valve (2), using N=1～10 unstripped gas agitator (4), The gas that 2N stock dutycycles are the flowing of 1/2 intermittent pulse is become by wall-attached vibrating, one-to-one cover from adsorption tanks (26) open up 2N adsorption tanks upper orifice (7) or circumference to entering in adsorption tanks (24) to adsorption tanks upper orifice (7) stream to 2N in parallel two-by-two； Through-flow space on adsorption tanks (24) is separated into 2N or circumference to two-by-two simultaneously by the upper space demarcation strip (8) in adsorption tanks (24) 2N is to independent upper space partition zone；The upper initial segment of adsorbent filler (25) is separated into 4N/n by demarcation strip (10) on filler Individual section subregion, itself and with each on space partition zone para-position, make the unstripped gas that 2N stocks or 2N flow to stock intermittent pulse upper logical On fluid space and adsorbent filler (25) initial segment can only along to the respective compartment flow passage for limiting and cut-off, wherein N=1～4；It is each instantaneous, there are N stocks or N to pass through adsorbent filler by the flow region that arrangement is jumped between each to stock unstripped gas (25) lower sieve plate and filter screen (12), are then passed through, from 2N or circumference to flowing to adsorption tanks lower nozzle (14) to 2N in parallel two-by-two Go out, then by the clean gas outlet open and close valve (22) of 2N opening, from clean gas outlet (23) bleeder；

Equally, N=1～10 regeneration gas agitator (17) are also adopted by, from regeneration gas entrance (20) through regeneration gas open and close valve (19) regeneration gas come in, by wall-attached vibrating the gas that 2N stock dutycycles are the flowing of 1/2 intermittent pulse is become, one-to-one from suction 2N that attached tank (24) bottom opens up or circumference to adsorption tanks lower nozzle (14) stream to 2N in parallel two-by-two to entering adsorption tanks (24) In；Lower space demarcation strip (13) through-flow space by under of adsorption tanks (24) is separated into 2N or circumference to 2N pair two-by-two Independent lower space partition zone, the lower initial segment of adsorbent filler (25) is separated into 4N/n section point by demarcation strip (11) under filler Area, its simultaneously with each lower space partition zone para-position, make regeneration gas that 2N stocks or 2N flow to the stock intermittent pulse through-flow space under Can only be along to the respective compartment flow passage for limiting and cut-off with initial segment under filler；It is each instantaneous, there are N stocks or N pair Stock regeneration gas is then passed through upper sieve plate and filter screen (9), from 2N by the flow region of arrangement is jumped through adsorbent filler (25) between each Individual or circumference flows out to the 2N to parallel connection two-by-two to adsorption tanks upper orifice (7), then by the regeneration gas outlet opening and closing of 2N opening Valve (28), from regeneration gas (27) bleeder is exported.

2. wall-attached vibrating according to claim 1 is pulsed adsorbent equipment, it is characterised in that unstripped gas is separated into one entrance Unstripped gas stimulus stream modulating unit (5), is switched to the pulse excitation stream that 2～2N stock cycles are all the intermittent flow of T, by two-by-two Phase contrast is paired into 1～N pair for T/2's, and the left and right common 2N unstripped gas agitator for being communicated to N number of unstripped gas agitator (4) swashs Encourage inflow entrance (29)；If the quantity of unstripped gas oscillator drive inflow entrance (29) is more than stimulus stream number of share of stock, by the vibration of each unstripped gas Device (4) packet it is equal with pulse excitation stream number of share of stock, unstripped gas oscillator drive inflow entrance (29) in group require it is left and it is left and right with Right parallel connection；It is T/2, the intermittent pulse swash of wave that dutycycle is 1/2 that each unstripped gas agitator (4) produces two strands of phase contrasts；It is all Unstripped gas agitator branch outlet (6) the intermittent pulse swash of wave out, according to the difference of pulse excitation stream 2～2N of number of share of stock, it is minimum Phase contrast is T/2～T/2N；Described unstripped gas stimulus stream modulating unit (5) includes body (31), semi-hollow rotating shaft (32), solid Determine cylinder sleeve (33), excitation flow export (30) and gas access, two end cap, bearing and sealing member.

3. wall-attached vibrating according to claim 1 and 2 is pulsed adsorbent equipment, it is characterised in that regeneration gas is separated into one Into regeneration gas stimulus stream modulating unit (16), the pulse excitation that 2～2N shallow bid cycles are all the intermittent flow of T is switched to Stream, 1～N pair is paired into by phase contrast two-by-two for T/2, is communicated to the left and right common 2N regeneration of N number of regeneration gas agitator (17) Gas oscillator drive inflow entrance (21)；If the quantity of regeneration gas oscillator drive inflow entrance (21) is more than stimulus stream number of share of stock, will again The packet of angry agitator (17) is equal with stimulus stream number of share of stock, regeneration gas oscillator drive inflow entrance (21) in group require it is left with Left and right and right parallel connection；It is T/2, the intermittent pulse that dutycycle is 1/2 that each regeneration gas agitator (17) produces two strands of phase contrasts Stream；All regeneration gas agitator branch outlets (15) intermittent pulse swash of wave out, according to 2～2N of pulse excitation stream number of share of stock not Together, its minimum phase difference is T/2～T/2N；Described regeneration gas stimulus stream modulating unit (16) is including body (31), semi-hollow Rotating shaft (32), fixed cylinder sleeve (33), excitation flow export (30) and gas access, two end cap, bearing and sealing member.

4. wall-attached vibrating according to claim 1 and 2 is pulsed adsorbent equipment, it is characterised in that upper in adsorption tanks (24) Space Cross Section is carved up into phase by demarcation strip (10) by the center of adsorption tanks (24) to external radiation on space demarcation strip (8) and filler Etc. the melon lobed shape of size；The quantity of upper space demarcation strip (8) is 4N lobes or 2N lobes, the shape per lobe be all three vertical edges and One semiellipse or partly dish composition, the single being completely superposed with lid (26) inwall curvature on adsorption tanks per lobe is at right angle four Shape；The radial assembling or after welding per space demarcation strip (8) on lobe, is fixedly mounted with or is welded on adsorption tanks and cover the inwall of (26)；On The height of space demarcation strip (8) be on adsorption tanks cover (26) lid dress after, upper space demarcation strip (8) be close to below upper sieve plate and The upper surface of filter screen (9)；The quantity of demarcation strip (10) is 4N lobes or 2N lobes or N lobes on filler, and each lobed shape is all rectangle, width It is highly the 0～50% of adsorbent filler (25) height equal to the inside radius of adsorption tanks (24)；Demarcation strip (10) on each lobe filler After radial assembling or welding, with upper space demarcation strip (8) para-position and adsorbent filler (25) of nuzzling, its top fits in sieve The lower surface of plate and filter screen (9).

5. wall-attached vibrating according to claim 3 is pulsed adsorbent equipment, it is characterised in that the upper space in adsorption tanks (24) Demarcation strip (10) carves up into Space Cross Section to external radiation equal big by the center of adsorption tanks (24) on demarcation strip (8) and filler Little melon lobed shape；The quantity of upper space demarcation strip (8) is 4N lobes or 2N lobes, and the shape per lobe is all three vertical edges and one Semiellipse or half dish composition, the single side right angle tetragon that (26) inwall curvature is completely superposed is covered per lobe with adsorption tanks；Often On lobe space demarcation strip (8) it is radial assembling or weld after, be fixedly mounted with or be welded on adsorption tanks cover (26) inwall；Upper space point The height of dividing plate (8) is to cover on adsorption tanks after (26) lid dress, and upper space demarcation strip (8) is close to below upper sieve plate and filter screen (9) upper surface；The quantity of demarcation strip (10) is 4N lobes or 2N lobes or N lobes on filler, and each lobed shape is all rectangle, and width is equal to The inside radius of adsorption tanks (24), is highly the 0～50% of adsorbent filler (25) height；Demarcation strip (10) radiation on each lobe filler After shape is assembled or welded, and upper space demarcation strip (8) para-position and adsorbent filler (25) of nuzzling, its top fit in upper sieve plate with The lower surface of filter screen (9).

6. according to claim 1,2 or 5 wall-attached vibrating pulsation adsorbent equipment, it is characterised in that in adsorption tanks (24) Demarcation strip (11) carves up Space Cross Section to external radiation by the center of adsorption tanks (24) under lower space demarcation strip (13) and filler Into the melon lobed shape of equal sizes；The quantity in lower space demarcation strip (13) is 4N lobes or 2N lobes, and the shape per lobe is all three and hangs down Straight flange and a semiellipse or half dish composition, the single side right angle that (26) inwall curvature is completely superposed is covered per lobe with adsorption tanks Tetragon；Under each lobe space demarcation strip (13) it is radial assembling or weld after, be fixedly mounted with or be welded to adsorption tanks (24) bottom interior wall； The height in lower space demarcation strip (13) is the lower surface that lower sieve plate and filter screen (12) are close in lower space demarcation strip (13) top；Fill out The quantity of the lower demarcation strip (11) of material is 4N lobes or 2N lobes or N lobes, and each lobed shape is all rectangle, and width is equal to the interior of adsorption tanks (24) Radius, is highly the 0～50% of adsorbent filler (25) height；The radial assembling of demarcation strip (11) or welding under each lobe filler Afterwards, the upper surface of lower sieve plate and filter screen (12) is laid or is installed on demarcation strip (13) para-position of lower space.

7. wall-attached vibrating according to claim 3 is pulsed adsorbent equipment, it is characterised in that the lower space in adsorption tanks (24) Demarcation strip (11) carves up into Space Cross Section to external radiation equal by the center of adsorption tanks (24) under demarcation strip (13) and filler The melon lobed shape of size；The quantity in lower space demarcation strip (13) is 4N lobes or 2N lobes, the shape per lobe be all three vertical edges and One semiellipse or partly dish composition, the single being completely superposed with lid (26) inwall curvature on adsorption tanks per lobe is at right angle four Shape；Under each lobe space demarcation strip (13) it is radial assembling or weld after, be fixedly mounted with or be welded to adsorption tanks (24) bottom interior wall；Lower sky Between the height of demarcation strip (13) be that the lower surface of lower sieve plate and filter screen (12) is close in lower space demarcation strip (13) top；Under filler The quantity of demarcation strip (11) is 4N lobes or 2N lobes or N lobes, and each lobed shape is all rectangle, and width is equal to interior the half of adsorption tanks (24) Footpath, is highly the 0～50% of adsorbent filler (25) height；Under each lobe filler demarcation strip (11) it is radial assembling or weld after, The upper surface of lower sieve plate and filter screen (12) is laid or is installed on demarcation strip (13) para-position of lower space.

8. wall-attached vibrating according to claim 4 is pulsed adsorbent equipment, it is characterised in that the lower space in adsorption tanks (24) Demarcation strip (11) carves up into Space Cross Section to external radiation equal by the center of adsorption tanks (24) under demarcation strip (13) and filler The melon lobed shape of size；The quantity in lower space demarcation strip (13) is 4N lobes or 2N lobes, the shape per lobe be all three vertical edges and One semiellipse or partly dish composition, the single being completely superposed with lid (26) inwall curvature on adsorption tanks per lobe is at right angle four Shape；Under each lobe space demarcation strip (13) it is radial assembling or weld after, be fixedly mounted with or be welded to adsorption tanks (24) bottom interior wall；Lower sky Between the height of demarcation strip (13) be that the lower surface of lower sieve plate and filter screen (12) is close in lower space demarcation strip (13) top；Under filler The quantity of demarcation strip (11) is 4N lobes or 2N lobes or N lobes, and each lobed shape is all rectangle, and width is equal to interior the half of adsorption tanks (24) Footpath, is highly the 0～50% of adsorbent filler (25) height；Under each lobe filler demarcation strip (11) it is radial assembling or weld after, The upper surface of lower sieve plate and filter screen (12) is laid or is installed on demarcation strip (13) para-position of lower space.

9. according to claim 2,5,7 or 8 wall-attached vibrating pulsation adsorbent equipment, it is characterised in that unstripped gas stimulus stream Modulating unit (5) and regeneration gas stimulus stream modulating unit (16), are that the solid-end of semi-hollow rotating shaft (32) is passed into body (31) One end end cap be used for turned by the external world；Unstripped gas or regeneration gas are introduced from body (31) the other end end cap, are turned by semi-hollow The hollow end opening of axle (32) receives, the axle sidewall opening (35) at each different circumferential orientation angle of semi-hollow rotating shaft (32), will With the rotation of semi-hollow rotating shaft (32), press from the cylinder sleeve sidewall opening (34) at fixed cylinder sleeve (33) each different circumferential orientation angle Each different phase contrasts is opened periodically and closing, and from each excitation flow export (30) 2～2N stock arteries and veins of the required time difference is flowed out Dynamic stimulus stream；Adjust semi-hollow rotating shaft (32) rotating speed, that is, control unstripped gas agitator (4) or regeneration gas agitator (17) it is attached Wall frequency of oscillation.

10. wall-attached vibrating according to claim 6 is pulsed adsorbent equipment, it is characterised in that the modulation of unstripped gas stimulus stream is single First (5) and regeneration gas stimulus stream modulating unit (16), are one end that the solid-end of semi-hollow rotating shaft (32) is passed body (31) End cap is used to be turned by the external world；Unstripped gas or regeneration gas are introduced from body (31) the other end end cap, by semi-hollow rotating shaft (32) Hollow end opening receive, the axle sidewall opening (35) at each different circumferential orientation angle of semi-hollow rotating shaft (32) will be with half The rotation of hollow rotating shaft (32), from the cylinder sleeve sidewall opening (34) at fixed cylinder sleeve (33) each different circumferential orientation angle by each not Same phase contrast is opened periodically and closing, and from each excitation flow export (30) 2～2N stock impulse excitations of the required time difference are flowed out Stream；The rotating speed of semi-hollow rotating shaft (32) is adjusted, that is, controls the wall-attached vibrating of unstripped gas agitator (4) or regeneration gas agitator (17) Frequency.