CN206132587U - Detect atmospheric environment to corrosive sensor of metal material - Google Patents
Detect atmospheric environment to corrosive sensor of metal material Download PDFInfo
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- CN206132587U CN206132587U CN201621141493.1U CN201621141493U CN206132587U CN 206132587 U CN206132587 U CN 206132587U CN 201621141493 U CN201621141493 U CN 201621141493U CN 206132587 U CN206132587 U CN 206132587U
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- metal film
- atmospheric environment
- sensor
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- 239000007769 metal material Substances 0.000 title claims abstract description 35
- 238000001514 detection method Methods 0.000 claims abstract description 72
- 229910052751 metal Inorganic materials 0.000 claims abstract description 54
- 239000002184 metal Substances 0.000 claims abstract description 54
- 239000000463 material Substances 0.000 claims abstract description 13
- 238000005260 corrosion Methods 0.000 claims description 26
- 230000007797 corrosion Effects 0.000 claims description 26
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 239000010949 copper Substances 0.000 claims description 10
- 238000009413 insulation Methods 0.000 claims description 10
- 229910052725 zinc Inorganic materials 0.000 claims description 10
- 239000011701 zinc Substances 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 239000004411 aluminium Substances 0.000 claims description 6
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 3
- 229910052571 earthenware Inorganic materials 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims description 2
- 238000012360 testing method Methods 0.000 abstract description 6
- 239000003990 capacitor Substances 0.000 abstract 3
- 238000000034 method Methods 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 7
- 238000000151 deposition Methods 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004070 electrodeposition Methods 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
Landscapes
- Testing Resistance To Weather, Investigating Materials By Mechanical Methods (AREA)
Abstract
The utility model discloses a detect atmospheric environment to corrosive sensor of metal material, including first lead -out wire, second lead -out wire, detecting element and fixed plate, first lead -out wire and second lead -out wire parallel arrangement, its tip do not are equipped with the first terminal and second terminal, be equipped with multiunit detecting element between first lead -out wire and the second lead -out wire, the detecting element load is at the fixed plate surface, detecting element includes multiunit detection device, detection device includes test capacitor and metal film, the metal film is established ties with the test capacitor, with a set of the test capacitor model of the detection device use among the detecting element is the same, and the metal film material of use is different. The utility model discloses the branch number of direct total capacitance value that obtains according to the detection and the metal film that consumes is quick accurate provides grading result, rate of accuracy height.
Description
Technical field
The utility model is specifically related to a kind of sensor of detection atmospheric environment to metallic material corrosion.Espespecially by inspection
Survey the break-make of different-thickness film prepared by dissimilar metals materials to divide the corrosivity rank of atmospheric environment
Device, belongs to sensor technical field.
Background technology
The erosion analysis universal standard of atmospheric environment is ISO9223-2012 (corrosion of metal and alloy, atmospheric corrosion
Property classification).In the standard according to iron, copper, four kinds of standard metal materials of zinc and aluminium in atmospheric environment the etching extent of the 1st year to big
Gas corrosion is evaluated.But the evaluation procedure complex operation involved by the standard, artificial disturbance factor is numerous, evaluation result
Accuracy and repeatability are poor.For this, numerous new methods are suggested in the standard base, patent CN201220196861.8
A kind of air environmental pollution thing corrosion monitoring sensor is disclosed, the same metal different cross-sectional metal film of detection is employed
Break-make is evaluated atmospheric environment, although the method conveniently can be judged the corrosivity of atmospheric environment, but
It is because the in uneven thickness of single kind metallic material film, severe local corrosion, atmospheric environment cause the spy of metal material
The reasons such as anisotropic etch difference, easily cause the erroneous judgement of evaluation result, inaccurate.
Utility model content
The utility model is in order to solve the above problems, it is proposed that a kind of biography of detection atmospheric environment to metallic material corrosion
Sensor, the total capacitance value and the bar number of the metal film for consuming that the utility model is directly obtained according to detection is fast and accurately given and commented
Level result, accuracy rate is high, solves due to the uneven of single kind metallic material film, severe local corrosion, atmospheric environment
Cause metal material the specificity corrosion reason such as difference cause the erroneous judgement of evaluation result, it is inaccurate the problems such as.
To achieve these goals, the utility model is adopted the following technical scheme that：
A kind of sensor of detection atmospheric environment to metallic material corrosion, including the first lead-out wire, the second lead-out wire, inspection
Unit and fixed plate are surveyed, first lead-out wire and the second lead-out wire be arranged in parallel, its end is respectively equipped with the first terminal and the
Two-terminal, is provided with multigroup detector unit between first lead-out wire and the second lead-out wire, the detector unit is sequentially fixed at
In fixed plate；
The detector unit includes many set detecting devices；
The detection means includes detection electric capacity and metal film, the metal film be supported on the outer surface of insulation tube then with
Detection capacitances in series；
The detection electric capacity model that detection means in detector unit described in same group is used is identical, the metal membrane material for using
It is different.
The detector unit is provided with five groups.
The detector unit is provided with four detection means per group.
Detector unit metal film in the same set is respectively using material in iron, copper, zinc and aluminium four.
Ferrous metal film thickness of the detector unit in different groups is respectively 1.3 μm, 25 μm, 50 μm, 80 μm and 200
μm。
Copper thickness of metal film of the detector unit in different groups be respectively 0.1 μm, 0.6 μm, 1.3 μm, 2.8 μm and
5.6μm。
Zinc matter thickness of metal film of the detector unit in different groups be respectively 0.1 μm, 0.7 μm, 2.1 μm, 4.2 μm and
8.4μm。
Aluminum metal film thickness of the detector unit in different groups is respectively 0.1 μm, 0.22 μm, 0.74 μm, 1.9 μm
With 3.7 μm.
The detection electric capacity is respectively 100pF, 200pF, 400pF, 800pF, 1600pF in different group detector units.
The fixed plate is glass tube, earthenware or pitch tube.
The beneficial effects of the utility model are：
(1) the utility model directly according to the bar number of the total capacitance value that obtains of detection and the metal film for consuming fast and accurately
Provide rating result, accuracy rate is high, solve due to the uneven of single kind metallic material film, severe local corrosion, big
Compression ring border cause the specificity corrosion reason such as difference of metal material cause the erroneous judgement of evaluation result, it is inaccurate the problems such as；
(2) metal film is supported on the utility model the outer surface of the outer surface of insulation tube, particularly double glazing pipe, gold
The uniformity of category film is good.The thickness distribution of metal film selected by inventive sensor, metal film uniformity is good, the knot with insulation tube
Close performance high, be less prone to the phenomenons such as crackle；
(3) sensor of the present utility model can simply, fast and accurately detect different metal material in same big compression ring
Corrosion-susceptible degree in border, to use for the selection of metal foundation is provided.
Description of the drawings
Fig. 1 is the utility model overall structure diagram；
Fig. 2 is the utility model detector unit structural representation；
Fig. 3 is the structural representation of the utility model embodiment 2；
Fig. 4 is the utility model metal film and insulation tube support structures schematic diagram；
Wherein, 1, fixed plate, 2, detector unit, 3, metal film, 4, detection electric capacity, the 5, second lead-out wire, 6, first draws
Line, 7, the first terminal, 8, Second terminal, 9, insulation tube.
Specific embodiment：
Below in conjunction with the accompanying drawings the utility model is described in further detail with embodiment.
Embodiment 1：
As shown in figure 1, a kind of detection sensor of the atmospheric environment to metallic material corrosion, including the first lead-out wire 6, the
Two lead-out wires 5, detector unit 2 and fixed plate 1, the lead-out wire 5 of first lead-out wire 6 and second be arranged in parallel, its end difference
The first terminal 7 and Second terminal 8 are provided with, multigroup detector unit 2 is provided between the lead-out wire 5 of first lead-out wire 6 and second, such as
Shown in Fig. 4, the detector unit 2 is sequentially fixed in fixed plate 1, and the detector unit 2 includes many set detecting devices；Same group
Detection means in detector unit 2 is arranged in parallel；The detection means includes detection electric capacity 4 and metal film 3, the metal film 3
It is supported on the outer surface of insulation tube 9 and then connects with detection electric capacity 4；Specifically, the metal film 3 adopts physical vapour deposition (PVD)
Method, chemical vapour deposition technique, solution electrodeposition process or solution-deposition method are deposited on metal film 3 on the outer surface of insulation tube 9；Together
The model of detection electric capacity 4 that detection means in detector unit 2 described in a group is used is identical, and the material of metal film 3 for using is different.
Set five groups of detector units 2 in the present embodiment altogether, four detection means are included in each detector unit 2, each detection
Four detection means in unit 2 adopt different types of metal material, the metal film 3 in the same set of the detector unit 2
Respectively using material in iron, copper, zinc and aluminium four.So every group detector unit 2 has four detection means, has five groups of detector units
2,20 detection means altogether, the detection means of every kind of material has five, totally four kinds of materials.According to foregoing description, to 20
Detection means is numbered as follows：Iron is represented with C1, represented with C11 in the irony detection means of first group of detector unit 2,
The irony detection means of two groups of detector units 2 is represented with C12, in the irony detection means C13 tables of the 3rd group of detector unit 2
Show, represented with C14 in the irony detection means of the 4th group of detector unit 2, use in the irony detection means of the 5th group of detector unit 2
C15 represents, illustrates by C12 that first digit 1 represents iron, and second digit 2 is represented in second group of detector unit 2, together
Reason, copper represents that zinc is represented with C3 with C2, and aluminium is represented with C4.Such 20 detection means are numbered as shown in figure 1, the detection
Ferrous metal film 3 thickness of the unit 2 in different groups is respectively 1.3 μm, 25 μm, 50 μm, 80 μm and 200 μm, that is to say, that iron
1.3 μm of matter metal film 3C11 thickness, 25 μm of C12 thickness, 50 μm of C13 thickness, 80 μm of C14 thickness, 200 μm of C15 thickness.The inspection
Survey copper metal film 3 thickness of the unit 2 in different groups and be respectively 0.1 μm, 0.6 μm, 1.3 μm, 2.8 μm and 5.6 μm, that is,
Say copper 0.1 μm of metal film 3C21 thickness, 0.6 μm of C22 thickness, 1.3 μm of C23 thickness, 2.8 μm of C24 thickness, the μ of C25 thickness 5.6
m.Zinc matter metal film 3 thickness of the detector unit 2 in different groups is respectively 0.1 μm, 0.7 μm, 2.1 μm, 4.2 μm and 8.4 μ
M, same 0.1 μm of zinc matter film C31 thickness, 0.7 μm of C32 thickness, 2.1 μm of C33 thickness, 4.2 μm of C34 thickness, C35 thickness
8.4μm.Aluminum metal film 3 thickness of the detector unit 2 in different groups is respectively 0.1 μm, 0.22 μm, 0.74 μm, 1.9 μm
With 3.7 μm, 0.1 μm of aluminum film C41 thickness, 0.22 μm of C42 thickness, 0.74 μm of C43 thickness, 1.9 μm of C44 thickness, C45 thickness
3.7μm.The detection electric capacity 4 is respectively 100pF, 200pF, 400pF, 800pF, 1600pF in different group detector units 2,
Detection electric capacity 4 used in first group of detector unit 2 is 100pF, with the increase of the thickness of metal film 3, detects the numerical value of electric capacity 4
It is bigger, it is followed successively by 200pF, 400pF, 800pF, 1600pF.The insulation tube 9 is glass tube, earthenware or pitch tube, at this
Preferred double glazing pipe in embodiment.Metal film 3 adopts physical vaporous deposition, chemical vapour deposition technique, solution electrodeposition process
Or solution-deposition method is deposited on metallic diaphragm on the outer surface of insulation tube 9.
Based on a kind of atmosphere environment corrosion evaluation method of the sensor, the bar number and institute according to the film for being consumed
The capacitance of detection judges the corrosive grade of environment.The bar number of the film for being consumed and the capacitance for being detected judge environment
Corrosive grade relation is as shown in table 1：
Table 1：The bar number of the film of consumption and the capacitance for being detected judge the corrosive grade relation of environment
Generally, sensor is in consumption process, and the time that thin metal film 3 is exhausted is shorter, thick metal
The time that film 3 is exhausted is longer.Also, in same atmospheric environment, the film consumption of the same specification of four kinds of metal materials
Finish time phase difference less, but be not precluded within certain atmospheric environment, the wear rate of one of which metal film 3 is fast compared with other.
Corrosiveness of the environment classification testing result reference table is set up for this.
In table 1, when all films are not all consumed, the detection value of electric capacity 4 should be 12400pF, corresponding atmospheric environment
Corrosion class is 1 grade.Certainly it is that a certain minimum gauge metal film 3 runs out of when consuming any 1 in material in four
Finish, now capacitance is 12300pF, and the corrosive grade of environment can not be judged accordingly for 2 grades, should be still 1 grade, use formula：3C1+4
(C2+C3+C4+C5) represent, therein 1,2,3,4,5 represent respectively first group of detector unit, 2, second group of detector unit 2 ...,
It is identical with first digit meaning in detection means, all it is to represent some detector unit 2.Wherein 3C1 represents first group of detection
Have in unit 2 metal film 3 be consumed cause fracture, 4 (C2+C3+C4+C5) represent second and third, four, five groups of detector units 2
In 4 metal films 3 be not consumed cause fracture, when consuming 2, it may be possible to which the metal film 3 of two minimum gauges disappears
Consumption, now detects that the value of electric capacity 4 is 12200pF, still not can determine that corrosiveness of the environment grade for 2 grades, should be still 1 grade, uses formula：
2C1+4 (C2+C3+C4+C5) represents have two metal films 3 to be consumed fracture in that is, first group detector unit 2, and other four groups
Metal film 3 in detector unit 2 does not rupture, and when consuming, the minimum that two metal films 3 are certain metal material is little by two with secondary
Gauge metal film 3 is planted, this reflects that the metal material is more sensitive in this kind of atmospheric environment, the detection value of electric capacity 4 is
12100pF, now the atmospheric environment is stronger to the corrosivity of the material, and the corrosive grade that environment can be evaluated is 2 grades.Use formula：3
(C1+C2)+4 (C3+C4+C5) represent, by that analogy, according to detection electric capacity 4 value can Fast Evaluation atmospheric environment corrosivity etc.
Level, table 2 below is corrosiveness of the environment classification testing result reference table.
Table 2 is corrosiveness of the environment classification testing result reference table
Embodiment 2：
As shown in figure 3, as another embodiment, the detection means of same metal material can be put together,
Four detector units 2 are material is thus formed, has five detection means, five in every group of detector unit 2 in each detector unit 2
Detection means is same metal material, and the metal material for so assuming first group of detector unit 2 is iron, and five detection means are divided
Bian Hao not be C11, C12, C13, C14 and C15, the metal material of second group of detector unit 2 is copper, and five detection means are compiled respectively
Number it is C21, C22, C23, C24 and C25, the metal material of the 3rd group of detector unit 2 is zinc, and five detection means are numbered respectively and are
C31, C32, C33, C34 and C35, the metal material of the 4th group of detector unit 2 is aluminium, five detection means number respectively be C41,
C42, C43, C44 and C45, its result of calculation is identical with the result of calculation in embodiment.
It is not new to this practicality although the above-mentioned accompanying drawing that combines is described to specific embodiment of the present utility model
The restriction of type protection domain, one of ordinary skill in the art should be understood that on the basis of the technical solution of the utility model, ability
Various modifications or deform still in protection model of the present utility model that field technique personnel make by need not paying creative work
Within enclosing.
Claims (10)
1. a kind of sensor of detection atmospheric environment to metallic material corrosion, is characterized in that：Draw including the first lead-out wire, second
Outlet, detector unit and fixed plate, first lead-out wire and the second lead-out wire be arranged in parallel, and its end is respectively equipped with first end
Son and Second terminal, are provided with multigroup detector unit between first lead-out wire and the second lead-out wire, the detector unit is successively
It is fixed in fixed plate；
The detector unit includes many set detecting devices；
The detection means includes detection electric capacity and metal film, the metal film be supported on the outer surface of insulation tube then with detection
Capacitances in series；
The detection electric capacity model that detection means in detector unit described in same group is used is identical, and the metal membrane material for using is not
Together.
2. a kind of sensor of the detection atmospheric environment as claimed in claim 1 to metallic material corrosion, is characterized in that：It is described
Detector unit is provided with five groups.
3. a kind of sensor of the detection atmospheric environment as claimed in claim 2 to metallic material corrosion, is characterized in that：It is described
Detector unit is provided with four detection means per group.
4. a kind of sensor of the detection atmospheric environment as claimed in claim 3 to metallic material corrosion, is characterized in that：It is described
Detector unit metal film in the same set is respectively using material in iron, copper, zinc and aluminium four.
5. a kind of sensor of the detection atmospheric environment as claimed in claim 4 to metallic material corrosion, is characterized in that：It is described
Ferrous metal film thickness of the detector unit in different groups is respectively 1.3 μm, 25 μm, 50 μm, 80 μm and 200 μm.
6. a kind of sensor of the detection atmospheric environment as claimed in claim 4 to metallic material corrosion, is characterized in that：It is described
Copper thickness of metal film of the detector unit in different groups is respectively 0.1 μm, 0.6 μm, 1.3 μm, 2.8 μm and 5.6 μm.
7. a kind of sensor of the detection atmospheric environment as claimed in claim 4 to metallic material corrosion, is characterized in that：It is described
Zinc matter thickness of metal film of the detector unit in different groups is respectively 0.1 μm, 0.7 μm, 2.1 μm, 4.2 μm and 8.4 μm.
8. a kind of sensor of the detection atmospheric environment as claimed in claim 4 to metallic material corrosion, is characterized in that：It is described
Aluminum metal film thickness of the detector unit in different groups is respectively 0.1 μm, 0.22 μm, 0.74 μm, 1.9 μm and 3.7 μm.
9. a kind of sensor of the detection atmospheric environment as claimed in claim 1 to metallic material corrosion, is characterized in that：It is described
Detection electric capacity is respectively 100pF, 200pF, 400pF, 800pF, 1600pF in different group detector units.
10. a kind of sensor of the detection atmospheric environment as claimed in claim 1 to metallic material corrosion, is characterized in that：Institute
Fixed plate is stated for glass tube, earthenware or pitch tube.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621141493.1U CN206132587U (en) | 2016-10-20 | 2016-10-20 | Detect atmospheric environment to corrosive sensor of metal material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621141493.1U CN206132587U (en) | 2016-10-20 | 2016-10-20 | Detect atmospheric environment to corrosive sensor of metal material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN206132587U true CN206132587U (en) | 2017-04-26 |
Family
ID=58574824
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201621141493.1U Active CN206132587U (en) | 2016-10-20 | 2016-10-20 | Detect atmospheric environment to corrosive sensor of metal material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN206132587U (en) |
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2016
- 2016-10-20 CN CN201621141493.1U patent/CN206132587U/en active Active
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