CN206127029U - Coal chemical wastewater electricity chemical oxidation processing apparatus - Google Patents

Coal chemical wastewater electricity chemical oxidation processing apparatus Download PDF

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Publication number
CN206127029U
CN206127029U CN201621169588.4U CN201621169588U CN206127029U CN 206127029 U CN206127029 U CN 206127029U CN 201621169588 U CN201621169588 U CN 201621169588U CN 206127029 U CN206127029 U CN 206127029U
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coal chemical
waste water
electrochemical reactor
water tank
electrode
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CN201621169588.4U
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不公告发明人
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Beijing Zlxd Environmental Protection Engineering Co Ltd
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Beijing Zlxd Environmental Protection Engineering Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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Abstract

The utility model relates to a coal chemical wastewater electricity chemical oxidation processing apparatus belongs to energy -conserving environmental protection field. The utility model discloses the device is including electrochemical reactor, bag filter, activated carbon filter, centrifugal pump, middle water tank. Coal chemical wastewater gets into electrochemical reactor, bag filter, middle water tank in proper order after physics filters, waste water constantly circulates between electrochemical reactor, bag filter, middle water tank, reaches the setting value, entering activated carbon filter, messenger's waste water discharge to reach standard until the water quality index. The device has that treatment effeciency height, operating power consumption are low, long service life, plate electrode are difficult for advantages such as scale deposit.

Description

Coal chemical industrial waste water electrochemicial oxidation device
Technical field
This utility model is related to a kind of coal chemical industrial waste water electrochemicial oxidation device, belongs to field of waste water treatment, specifically It is related to Applied Electrochemistry oxidation technology and processes waste plant.
Background technology
China is the country of a rich coal resources, and coal chemical industry enterprises are more, is produced in coal coking, gas purification and chemical industry Product reclaim the process such as refined and generate substantial amounts of industrial wastewater, it is necessary to process in time, be recycled, and alleviate current water resource tight Lack the pressure brought with environmental pollution.Therefore, how to realize that coal chemical industry enterprises are up to standard, reduce discharge and concern national economy.
Coal chemical industry enterprises waste discharge has based on high concentration gas washing wastewater containing a large amount of phenol, cyanogen, oil, ammonia nitrogen etc. Poison, harmful substance.In comprehensive wastewater CODcr typically in 5000mg/l or so, ammonia nitrogen in 200 ~ 500mg/l, it is organic contained by waste water Pollutant include phenols, polycyclc aromatic compound and nitrogenous, oxygen, heterocyclic compound of sulfur etc., are a kind of typically containing in distress The industrial wastewater of the organic compound of degraded.
At present the domestic technology for processing coal chemical industrial waste water mainly adopts biochemical process, and biochemical process is to the phenol and benzene in waste water Class material has preferable removal to act on, but some hardly degraded organic substances are processed to quinolines, indoles, pyridines, carbazoles etc. Effect is poor so that the outer draining CODcr of coal chemical industry is difficult to reach primary standard;Simultaneously coal chemical industrial waste water is Jing after biochemical treatment The characteristics of there is colourity and very high turbidity again.
The hydroxyl produced under the effect such as light, electricity, high temperature, high pressure or catalyst can be utilized using high-level oxidation technology certainly By oxidants such as bases, by refractory organic oxidation Decomposition in waste water into easily biological-degradable material or mineralising.Coal Chemical Industry is given up The high-level oxidation technology adopted in water process research mainly includes ozone(O3)Oxidation, Fenton(Fenton)Oxidation, photocatalytic-oxidation The methods such as change, catalytic wet oxidation, electrochemical oxidation and ultrasound oxidation technology.Wherein ozone(O3)Oxidation, Fenton(Fenton)Oxygen Change, photochemical catalytic oxidation, catalytic wet oxidation, Conventional electrochemical oxidation and ultrasound oxidation technology have that oxidability is limited, are processed into This high problem.Boron-doped diamond application of electrode in electrochemical oxidation technique, with stable performance, energy consumption be low, oxidability Strong the characteristics of.
The content of the invention
The purpose of this utility model is the problem existed for above-mentioned prior art, there is provided a kind of coal chemical industrial waste water electrochemistry Oxidation treatment device, this device can process refractory organic with high efficiency, with stable performance, energy consumption be low, energy of oxidation The characteristics of power is strong.
What this utility model was achieved through the following technical solutions.
Coal chemical industrial waste water electrochemicial oxidation device include electrochemical reactor, bag filter, active carbon filter, Centrifugal pump, intermediate water tank;Electrochemical reactor, bag filter, intermediate water tank, active carbon filter are sequentially connected;Electrochemistry Electrode assemblie is set in reactor, and with boron-doped diamond electrode as anode, stainless steel electrode is negative electrode to electrode assemblie.
Electrode assemblie is by the electrode plate groups of 12 pieces of parallel distributions into electrode board size is 250mm × 500mm.
The filtering accuracy of bag filter is 0.08mm.
Filtrate adopts cocoanut active charcoal in active carbon filter, and granularity is 6-12 mesh.
Electrochemical reactor can produce great amount of hydroxy group free radical after being powered(·OH), hydroxyl radical free radical is a kind of important work Property oxidant, with extremely strong oxidability, can by hardly degraded organic substance, ammonium oxidation in coal chemical industrial waste water into innocuous substance, The precipitate such as the solid particle produced in course of reaction are collected through bag filter.
The beneficial effects of the utility model:This utility model adopts boron-doped diamond electrode, compares traditional electrode, can be formed Higher oxygen current potential so that the Organic substance that traditional high-level oxidation technology cannot degrade is degraded;The electrode has extremely low background Current value, battery lead plate not power consumption substantially, electric energy itself is mainly used in the degradation process of Organic substance, compared with traditional electrode plate, Reduce operating cost;The battery lead plate is less scaling, long service life;The plant automation degree is high, can be according to influent quality The power-on voltage of difference adjustment electrochemical reactor and conduction time, reach the purpose of energy efficient.
Description of the drawings
Fig. 1 is this utility model setting plane.
In figure, 1, electrochemical reactor, 2, bag filter, 3, intermediate water tank, 4, active carbon filter, 5, centrifugal pump.
Specific embodiment
This utility model is done below in conjunction with the accompanying drawings further is explained.
Coal chemical industrial waste water Jing inlet pipelines are entered(1)Electrochemical reactor, Jing electrochemical reactions produce substantial amounts of hydroxyl certainly By base, most ammonia-nitrogen, COD are can remove, entered afterwards(2)Bag filter, the bulky grain that can filter electrochemical reaction generation hangs Float, subsequently enters(3)Intermediate water tank.Due to(3)Waste water in intermediate water tank is once flowed through(1)Electrochemical reactor can not make Water pollutant is degraded, need to be(1)Electrochemical reactor,(2)Bag filter,(3)Constantly circulate between intermediate water tank, until Water pollutant level reaches setting value, circulation required drive by(5)Centrifugal pump is provided.(3)Many times of water Jing in intermediate water tank Circulation reaches Jing after requirement(5)Centrifugal pump is entered(4)Active carbon filter, Jing(4)Water after active carbon filter is filtered is reachable Mark discharge.

Claims (4)

1. a kind of coal chemical industrial waste water electrochemicial oxidation device, it is characterised in that:Device includes electrochemical reactor, pocket type mistake Filter, active carbon filter, centrifugal pump, intermediate water tank;Electrochemical reactor, bag filter, intermediate water tank, activated carbon are filtered Device is sequentially connected;Electrode assemblie is set in electrochemical reactor, and electrode assemblie is with boron-doped diamond electrode as anode, and rustless steel is electric Extremely negative electrode.
2. a kind of coal chemical industrial waste water electrochemicial oxidation device according to claim 1, it is characterised in that:Electrode assemblie by The electrode plate groups of 12 pieces of parallel distributions are into electrode board size is 250mm × 500mm.
3. a kind of coal chemical industrial waste water electrochemicial oxidation device according to claim 1, it is characterised in that:Bag filter Filtering accuracy be 0.08mm.
4. a kind of coal chemical industrial waste water electrochemicial oxidation device according to claim 1, it is characterised in that:Activated carbon is filtered Filtrate adopts cocoanut active charcoal in device, and granularity is 6-12 mesh.
CN201621169588.4U 2016-10-26 2016-10-26 Coal chemical wastewater electricity chemical oxidation processing apparatus Active CN206127029U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201621169588.4U CN206127029U (en) 2016-10-26 2016-10-26 Coal chemical wastewater electricity chemical oxidation processing apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201621169588.4U CN206127029U (en) 2016-10-26 2016-10-26 Coal chemical wastewater electricity chemical oxidation processing apparatus

Publications (1)

Publication Number Publication Date
CN206127029U true CN206127029U (en) 2017-04-26

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201621169588.4U Active CN206127029U (en) 2016-10-26 2016-10-26 Coal chemical wastewater electricity chemical oxidation processing apparatus

Country Status (1)

Country Link
CN (1) CN206127029U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109205874A (en) * 2018-11-23 2019-01-15 李志强 A kind of bamboo product wastewater treatment equipment based on cocoanut active charcoal filtering

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109205874A (en) * 2018-11-23 2019-01-15 李志强 A kind of bamboo product wastewater treatment equipment based on cocoanut active charcoal filtering
CN109205874B (en) * 2018-11-23 2021-09-24 晋城市福阳化工有限公司 Bamboo product wastewater treatment device based on coconut shell activated carbon filtration

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