CN206126868U - Apparatus for producing of boiling suspension firing borolon powder - Google Patents

Apparatus for producing of boiling suspension firing borolon powder Download PDF

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Publication number
CN206126868U
CN206126868U CN201621164422.3U CN201621164422U CN206126868U CN 206126868 U CN206126868 U CN 206126868U CN 201621164422 U CN201621164422 U CN 201621164422U CN 206126868 U CN206126868 U CN 206126868U
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powder
oxygen
combustion
borolon
spout
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CN201621164422.3U
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洪涛
郭敏
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Suzhou Sanrui Baide New Material Co.,Ltd.
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Urumqi Three Sharp Technology Co Ltd
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Abstract

The utility model belongs to the powder material chemical synthesis field specifically is a boiling suspension firing borolon powder apparatus for producing. Fail device, oxygen conveyor, ignition, hierarchical receipts material cauldron, cooling device, preceding receipts material jar, back receipts material jar, blast pipe, fan including reaction of combustion cauldron, aluminite powder gas, the airtight intercommunication in inner chamber upper portion of reaction of combustion cauldron and hierarchical receipts material cauldron is equipped with cooling device respectively on the inner wall, receive the material jar before the bottom is equipped with respectively and receive the material jar with the back, device, oxygen conveyor and ignition were failed to aluminite powder gas aluminite powder spout, oxygen spout and ignition port set up respectively inside the reaction of combustion cauldron, and oxygen that the oxygen spout upwards sprays makes the boiling of rolling of aluminite powder spout spun aluminite powder, the hierarchical material cauldron lower part of receiving is equipped with the blast pipe that communicates the fan. Use that this device preparation alumina powder process is few, the cycle short, water consumption hardly, can one step of preparation nanometer and the alumina powder of above various particle diameter, the various purity of 2N~6N, with low costs, the formation of the nos three wastes.

Description

A kind of process units of boiling suspension combustion Borolon powder
Technical field
This utility model belongs to powder body material chemosynthesis technical field, specifically a kind of boiling suspension combustion synthesis oxidation The process units of aluminium powder.
Background technology
It is alumina powder jointed at home and abroad develop as a kind of fine chemical product it is extremely rapid, be widely used in aviation boat My god, weapons, electrical apparatus insulation material, ic substrate, high speed cutting tool, high-strength wearproof corrosion-resistant material, high intensity gas Many high-tech tip industries such as body discharging lamp pipe, fluorophor carrier, monocrystal material, catalyst carrier, laser material, are green Color illumination three primary colors fluorescent powder, automobile sensor, tape additive, catalyst support coatings, quasiconductor and liquid crystal display, The important foundation material of transparent high-pressure sodium fluorescent tube, precision instrument and aviation optics etc..
Alumina powder require to accomplish it is ultra-fine, high-purity, have a narrower particle diameter distribution, stable phase is existing without serious reunion As.The preparation method of superfine alumina powder mainly has sol-gal process, Burnt ammonium alum pyrolysismethod, aluminium carbonate ammonium heat at this stage at present Solution, aluminum isopropylate. Hydrolyze method, mercuric chloride activation Hydrolyze method, plasma method, spray pyrolysis, spark-discharge method, hydro-thermal method, Improvement Bayer process, high pure metal aluminium foil choline Hydrolyze method and rafifinal direct hydrolysis method etc..Due to mercuric chloride activation Hydrolyze method, etc. Processes, spray pyrolysis, spark-discharge method, hydro-thermal method, extraction method are due to being affected and side by raw material, preparation method feature The impact of the Maturity of method and be difficult to large-scale industrial production.The production method of prior art has aluminum ammonium salt pyrolysismethod, improvement The modification method of Bayer process, alkoxide hydrolysis and direct hydrolysis method and these methods.
At present, the said method of prior art belongs to aqua-solution method and prepares alumina powder, operation is more, long the production cycle, Water consumption is big, participates in due to be unableing to do without aqueous solution, it is difficult to the shortcoming for overcoming sodium potassium content high, and production process cannot realize into One step is purified;The production procedure wherein having is long, and the production equipment being related to is more, and user of service is more, therefore cost of investment and produces into This high shortcoming;Some production equipments and operation is various causes personnel and equipment Work tool multiple-contact to bring many products Mass defect, it is difficult to prepare high-purity mangesium oxide aluminium powder;Some energy consumptions are high, and resource consumption is high;Low production efficiency;Some three wastes Discharge is more, it is difficult to realize that environment-protecting clean is produced.
And technology-the combustion synthesis method of new generation of alumina powder is prepared, closed by an aluminium powder step of directly burning in oxygen Into alumina powder, drawbacks described above can be effectively overcome.
Therefore, a kind of process units for realizing aluminium powder conbustion synthesis alumina powder in oxygen of exploitation is needed in industry, with Meet the needs of production technology popularization and application of new generation.
Utility model content
The purpose of this utility model there are provided a kind of process units of boiling suspension combustion Borolon powder, to solve The equipment Requirement of production technology certainly of new generation.
This utility model provide technical scheme be:
A kind of process units of boiling suspension combustion Borolon powder, by combustion reaction kettle (1), the defeated device of aluminium powder gas (2), oxygen conveying device (3), igniter (4), classification rewinding kettle (5), chiller (6), front rewinding tank (7), rear rewinding Tank (8), exhaustor (9), blower fan (10);Combustion reaction kettle (1) inner chamber is combustion reaction room, and its underpart bottom is provided with front receipts Batch can (7), periphery are provided with chiller (6);The defeated device of aluminium powder gas (2), oxygen conveying device (3) and igniter (4) Aluminium powder spout, oxygen spout and igniting port are separately positioned in combustion reaction room;Classification rewinding kettle (5) inner chamber is refrigerated separation Room, its underpart bottom are provided with rear rewinding tank (8) and exhaustor (9), and periphery is provided with chiller (6);Exhaustor (9) outlet End is provided with blower fan (10);Combustion reaction room is connected by cavity airtight with the top of refrigerated separation room.
Also included optimization of the present utility model or/and improvement have:
One of preferred version, the horizontal level of the horizontal level of the oxygen spout less than aluminium powder spout, and spout to On.
The two of preferred version, the defeated device (2) of the aluminium powder gas is by material-storage jar (201), carrier gas tank (202) and feed injector (203) constitute, the outlet of material-storage jar (201) and carrier gas tank (202) spout are respectively communicated with feed injector (203) inner chamber.
The three of preferred version, the igniter (4) include high-voltage pulses device, arc ignition device, flame point Fiery device and high-temperature plasma igniter.Flame ignition device can be using oxy arc, oxyhydrogen flame etc..
The four of preferred version, the chiller (6) realize cooling using recirculated water mode.
The five of preferred version, the oxygen conveying device (3) are provided with oxygen storage tank.
Operationally, oxygen conveying device (3) is arranged on the bottom of combustion reaction kettle (1), and spout to this utility model Oxygen is sprayed upwards;The defeated device of aluminium powder gas (2) by aluminium powder raw material with gas mode of movement, i.e., it is aluminium powder is former by the carrier gas of pressure-bearing Material is ejected in combustion reaction kettle (1) in fully decentralized mode, the oxygen flow for being sprayed by oxygen conveying device (3) upward Hold up, certain altitude scope makees upper and lower tumbling motion in the combustion reaction room;After igniter (4) lights aluminium powder, make aluminium powder with Fluidized state is burnt, as aluminium powder is fully contacted with oxygen.Oxidation reaction is rapid and abundant, and production efficiency is high.
Start blower fan (10) and produce outwards pumping, whole process units internal cavity can be made in negative pressure state, the oxidation of production In aluminium powder, the big matter weight granule of size can be collected in the front rewinding tank (7) below combustion reaction kettle (1) by freely falling body, and size is little And the granule of light weight is entered in being pumped to classification rewinding kettle (5) in the rear rewinding tank (8) of lower section, it is achieved thereby that continuous produce During preliminary classification collect.
Igniter (4) can be high-voltage pulses, flame ignition device, arc ignition device, plasma igniting Device etc., flame ignition device can be using common oxy arc, oxyhydrogen flames etc., by uninterruptedly lighting a fire to aluminium powder so that Aluminium powder keeps the stable burning of order, releases substantial amounts of heat and can maintain that what is reacted persistently to carry out.
Chiller (6) can adopt water circulation system.Set on combustion reaction kettle (1) and classification rewinding kettle (5) inwall The chiller (6) put can take away a large amount of heat energy that reaction is produced, and prevent temperature too high, while and can make the height that burning obtains Warm alumina powder is quickly cooled down.
Implement technical solutions of the utility model beneficial effect be:
It is of the present utility model that aluminium powder rolling boiling is made by the oxygen for spraying upwards, tiny aluminum particle is effectively ensured and has existed It is completely dispersed state and oxygen is fully contacted burning, solves and react incomplete caused by aluminium powder is reunited, the problem of burn-out, It is swift in response and complete.Start the preliminary classification of the achievable product of negative pressure collection system that blower fan is realized.
Due to being combustion reaction under the high temperature conditions, some low-melting-point metals in aluminium powder can be vapored away, therefore this practicality It is new in process of production also with the refining effect again to alumina powder product.
Describe the technical solution of the utility model with reference to the accompanying drawings and examples in detail.
Description of the drawings
Fig. 1 is overall structure diagram of the present utility model;
In Fig. 1,1-combustion reaction kettle, the defeated device of 2-aluminium powder gas, 3-oxygen conveying device, 4-igniter, 5-point Level rewinding kettle, 6-chiller, 7-front rewinding tank, 8-rear rewinding tank, 9-exhaustor, 10-blower fan, 201-material-storage jar, 202-carrier gas tank, 203-material ejector.
Specific embodiment
To make those skilled in the art more fully understand the technical solution of the utility model, below in conjunction with the accompanying drawings 1 and implement Example is described in further detail to this utility model.
In embodiment, for the ease of description, the description of each part relative position relation is the cloth according to Figure of description 1 Figure mode being described, such as:The position relationship of upper and lower, left and right etc. is to come true according to the Butut direction of Figure of description 1 Fixed.
Embodiment 1:A kind of process units of boiling suspension combustion Borolon powder, by combustion reaction kettle (1), aluminium powder gas Defeated device (2), oxygen conveying device (3), igniter (4), classification rewinding kettle (5), chiller (6), front rewinding tank (7), Rewinding tank (8), exhaustor (9), blower fan (10) afterwards;Combustion reaction kettle (1) inner chamber is combustion reaction room, and its underpart bottom is arranged There is front rewinding tank (7), periphery is provided with chiller (6);The defeated device of aluminium powder gas (2), oxygen conveying device (3) and igniter (4) aluminium powder spout, oxygen spout and igniting port are separately positioned in combustion reaction room;Classification rewinding kettle (5) inner chamber is cold But separation chamber, its underpart bottom are provided with rear rewinding tank (8) and exhaustor (9), and periphery is provided with chiller (6);Exhaustor (9) outlet side is provided with blower fan (10);Combustion reaction room is connected by cavity airtight with the top of refrigerated separation room.
Using the device of the present embodiment, by oxygen with 3.5m3The flow of/h delivers into combustion reaction kettle (1), by purity More than 99.99%, the aluminium powder of 100 μm of particle diameter passes through flow 1m with the speed of 3Kg/h3The argon of/h delivers into combustion reaction kettle (1);Igniter (4) is with the frequency 15 times/1s arc ignitions;Aluminium powder be ignited after in oxygen with suspension combustion side of seething with excitement Formula continued stable combustion, chiller adopt water-cycling mode, discharge 1000L/h;The alumina powder formed after burning is by argon Air cooling.Obtain the ball-aluminium oxide of D50~1000nm and D50~400nm particle diameters respectively in front collecting tank and rear collecting tank Powder product, purity are more than 99.99%, and wherein sodium content is less than 2ppm.
Embodiment 2:The optimization or/and improvement provided to this utility model with reference to embodiment 1 and accompanying drawing 1 makees further Description:
Horizontal level of the horizontal level of the oxygen spout less than aluminium powder spout, and spout is upwards.
The defeated device (2) of the aluminium powder gas is made up of material-storage jar (201), carrier gas tank (202) and feed injector (203), is store The outlet of batch can (201) and carrier gas tank (202) spout are respectively communicated with feed injector (203) inner chamber.
The igniter (4) is including high-voltage pulses device, arc ignition device, flame ignition device and high temperature etc. Gas ions igniter.Flame ignition device can be using oxy arc, oxyhydrogen flame etc..
The chiller (6) realizes cooling using recirculated water mode.
The oxygen conveying device (3) is provided with oxygen storage tank.
Using the device of the present embodiment, by oxygen with 3m3The flow of/h delivers into combustion reaction kettle (1), by purity More than 99.99%, the aluminium powder of 30 μm of particle diameter passes through flow 0.85m with the speed of 2Kg/h3The argon of/h delivers into combustion reaction Kettle (1);Igniter (4) is with the frequency 10 times/1s arc ignitions;Aluminium powder be ignited after in oxygen with the suspension combustion that seethes with excitement Mode continued stable combustion, chiller adopt water-cycling mode, discharge 600L/h;The alumina powder formed after burning is by argon Air cooling.
After combustion reaction starts, that is, start with negative pressure collection, the alumina powder size granule of quality weight greatly of production Fall directly in the catcher below reaction unit;Size is little and the granule of light weight can be taken out tiny structure and extract product out, realizes Preliminary classification in continuous flow procedure, can obtain two kinds of sized products of nanoscale and submicron order.Respectively in front collecting tank and Obtain the spherical alumina aluminium powder product of two kinds of particle diameters of D50~850nm and D50~450nm afterwards in collecting tank, purity is more than 99.99%, wherein sodium content is less than 2ppm.
It is understood that above example is merely to illustrate that principle of the present utility model and the exemplary reality that adopts Mode is applied, but this utility model is not limited thereto, can be determined with practical situation according to the technical solution of the utility model Specific embodiment.For those skilled in the art, without departing from spirit of the present utility model and essence In the case of, various modifications and improvement can be made, these modifications of increase and improvement are also considered as protection model of the present utility model Enclose.

Claims (7)

1. it is a kind of boiling suspension combustion Borolon powder process units, it is characterised in that including combustion reaction kettle (1), aluminum The defeated device of powder gas (2), oxygen conveying device (3), igniter (4), classification rewinding kettle (5), chiller (6), front rewinding tank (7), rear rewinding tank (8), exhaustor (9), blower fan (10);Combustion reaction kettle (1) inner chamber be combustion reaction room, its underpart bottom Front rewinding tank (7) is provided with, periphery is provided with chiller (6);The defeated device of aluminium powder gas (2), oxygen conveying device (3) and igniting The aluminium powder spout of device (4), oxygen spout and igniting port are separately positioned in combustion reaction room;Classification rewinding kettle (5) inner chamber For refrigerated separation room, its underpart bottom is provided with rear rewinding tank (8) and exhaustor (9), and periphery is provided with chiller (6);Row Trachea (9) outlet side is provided with blower fan (10);Combustion reaction room is connected by cavity airtight with the top of refrigerated separation room.
2. it is according to claim 1 it is a kind of boiling suspension combustion Borolon powder process units, it is characterised in that oxygen Horizontal level of the horizontal level of gas blowout mouth less than aluminium powder spout.
3. it is according to claim 1 it is a kind of boiling suspension combustion Borolon powder process units, it is characterised in that aluminum The defeated device of powder gas (2) is made up of material-storage jar (201), carrier gas tank (202) and feed injector (203), and material-storage jar (201) go out Mouth and carrier gas tank (202) spout are respectively communicated with feed injector (203) inner chamber.
4. it is according to claim 1 it is a kind of boiling suspension combustion Borolon powder process units, it is characterised in that institute State igniter (4) to light a fire including high-voltage pulses device, arc ignition device, flame ignition device and high-temperature plasma Device.
5. it is according to claim 4 it is a kind of boiling suspension combustion Borolon powder process units, it is characterised in that institute The flame for stating flame ignition device includes oxy arc, oxyhydrogen flame.
6. it is according to claim 1 it is a kind of boiling suspension combustion Borolon powder process units, it is characterised in that institute State chiller (6) and cooling is realized using recirculated water mode.
7. it is according to claim 1 it is a kind of boiling suspension combustion Borolon powder process units, it is characterised in that institute State oxygen conveying device (3) and be provided with oxygen storage tank.
CN201621164422.3U 2016-10-25 2016-10-25 Apparatus for producing of boiling suspension firing borolon powder Active CN206126868U (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108436076A (en) * 2018-05-23 2018-08-24 河南省远洋粉体科技股份有限公司 Ball aluminum powder explosion-proof type closed cycle oxygenation after-treatment system

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108436076A (en) * 2018-05-23 2018-08-24 河南省远洋粉体科技股份有限公司 Ball aluminum powder explosion-proof type closed cycle oxygenation after-treatment system

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Effective date of registration: 20180917

Address after: 830022 Xiangyun West Street four, Toutun River District Industrial Park, Urumqi, the Xinjiang Uygur Autonomous Region 508

Patentee after: XINJIANG SANRISEPOWDER NEW MATERIALS CO.,LTD.

Address before: 830011 Xinjiang Uygur Autonomous Region Urumqi Hi-tech Development Zone Industrial Development Zone (New Urban District) Tianjin South Road 682 Pioneer Building 208

Patentee before: URUMQI SANRUI TECHNOLOGY CO.,LTD.

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Address after: Room 1706, Building 30, North Area, Suzhou Nano City, No. 99 Jinji Lake Avenue, Suzhou Industrial Park, Suzhou City, Jiangsu Province 215123

Patentee after: Suzhou Sanrui Baide New Material Co.,Ltd.

Country or region after: China

Address before: No. 418 Quyang Street, High tech Zone, Urumqi City, Xinjiang Uygur Autonomous Region

Patentee before: XINJIANG SANRISEPOWDER NEW MATERIALS CO.,LTD.

Country or region before: China

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