CN206109003U - Waste cupric liquor's electrolysis electrodialysis recovery unit - Google Patents
Waste cupric liquor's electrolysis electrodialysis recovery unit Download PDFInfo
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- CN206109003U CN206109003U CN201621088660.0U CN201621088660U CN206109003U CN 206109003 U CN206109003 U CN 206109003U CN 201621088660 U CN201621088660 U CN 201621088660U CN 206109003 U CN206109003 U CN 206109003U
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- anode
- electrolytic
- electrolysis bath
- pole
- waste liquid
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- Electrolytic Production Of Metals (AREA)
Abstract
The utility model relates to an acid waste cupric liquor's recovery unit relates to a waste cupric liquor's electrolysis electrodialysis recovery unit, including seething the formula electrolysis trough from top to bottom, seethe the formula electrolysis trough from top to bottom and have delivery port, water inlet and staggered arrangement's electrolytic plate positive pole and electrolytic plate negative pole from top to bottom, monopole membrane electrodialysis device, monopole membrane electrodialysis device has anode chamber, cathode chamber and the setting anode film between anode chamber and cathode chamber, and the storage tank, the water inlet that seethes the formula electrolysis trough from top to bottom is used for inputing waste cupric liquor, the delivery port that seethes the formula electrolysis trough from top to bottom is through circulation peristaltic pump and monopole membrane electrodialysis device anode chamber intercommunication, monopole membrane electrodialysis device cathode chamber is through circulation peristaltic pump and storage tank intercommunication. The acid waste cupric liquor electrolysis electrodialysis device of this scheme of adoption, electrolysis dwell time is long, and the electrolytic efficiency is high, and copper recovery is rateed highly, the circulated use of spent acid, application range is wide.
Description
Technical field
This utility model is related to the retracting device of acid contained waste liquid, is related to a kind of acid contained waste liquid electrolytic electro-dialysis and returns
Receive copper and spent acid equipment.
Background technology
Acid contained waste liquid is widely present in multiple industries such as plating, printed substrate, and yield is big, environmental pollution
Seriously, mainly there are chemical precipitation method, electrolysis, ion exchange and membrane processing method etc. to electroplating wastewater processing.Wherein electrolysis
Find broad application because copper ion therein can be reclaimed, but traditional electrolyte method has electrolysis effect when waste water is processed
Rate is low, copper ion and waste acidity recovery not exclusively, the deficiency such as complex management.
Utility model content
The technical problems to be solved in the utility model is：Electrolysis is there is when waste water is processed in order to solve traditional electrolyte method
Efficiency is low, copper ion and waste acidity recovery not exclusively, the not enough problem such as complex management, this utility model provides a kind of cupric and gives up
The electrolytic electro-dialysis retracting device of liquid, the electrolysis bath of tumble type up and down that cathode-anode plate is crisscross arranged are obtained in that more electrolysis stop
The time is stayed, electrolysis effectiveness is good, efficiency high, be electrolysed and electrodialysis plant synergism, so that copper organic efficiency is further improved,
And can reclaim and obtain high purity acid solution.
This utility model solves the technical scheme adopted by its technical problem：
A kind of electrolytic electro-dialysis retracting device of contained waste liquid, including：
Upper and lower tumble type electrolysis bath, the upper and lower tumble type electrolysis bath have outlet, water inlet and are staggered up and down
Electrolytic zinc-coated steel sheet anode and electrolytic zinc-coated steel sheet negative electrode,
One pole EDBM device, the one pole EDBM device have anode chamber, cathode chamber and are arranged on anode chamber
Anode film and cathode chamber between, and
Storage tank,
The water inlet of the upper and lower tumble type electrolysis bath is used to be input into contained waste liquid, and the upper and lower tumble type electrolysis bath goes out
The mouth of a river is connected with one pole EDBM device anode chamber by circulating peristaltic pump, and the one pole EDBM device cathode chamber passes through
Circulation peristaltic pump is connected with storage tank.
Specifically, the one pole EDBM device cathode chamber is connected with the water inlet of upper and lower tumble type electrolysis bath, described
There is between the water inlet of one pole EDBM device cathode chamber and upper and lower tumble type electrolysis bath a valve.
Preferably, the electrolytic zinc-coated steel sheet anode of the upper and lower tumble type electrolysis bath is corrosion resistant plate and electrolytic zinc-coated steel sheet negative electrode is copper
Plate.
Preferably, the spacing of the electrolytic zinc-coated steel sheet anode and electrolytic zinc-coated steel sheet negative electrode is 1cm.
Preferably, the electrolytic zinc-coated steel sheet anode apart from upper and lower tumble type electrolysis bath upper plate distance be 1cm, the electrolysis
The distance of the upper and lower tumble type electrolysis bath lower shoe of plate cathode distance is 0.5cm,.
Preferably, the anode film of the one pole EDBM device is one pole anode film.
Preferably, the anode chamber of the one pole EDBM device adopts stainless steel polar plate, cathode chamber to adopt copper polar plate.
The beneficial effects of the utility model are：
This utility model provides a kind of electrolytic electro-dialysis retracting device of contained waste liquid, and it is upper that cathode-anode plate is crisscross arranged
Lower tumble type electrolysis bath is obtained in that more electrolysis time of staying, and electrolysis effectiveness is good, efficiency high.Electrolysis is assisted with electrodialysis plant
Same-action, so that copper organic efficiency is further improved, and can reclaim and obtain high purity acid solution.
This utility model provides a kind of electrolytic electro-dialysis retracting device of contained waste liquid, it is possible to use peristaltic pump will be electrolysed
Liquid is electrolysed in electrolysis bath interior circulation, with the electrolysis negative effect for overcoming concentration difference to bring, obtains higher electrolytic efficiency.
Description of the drawings
With reference to the accompanying drawings and examples this utility model is further illustrated.
Fig. 1 is a kind of schematic diagram of the electrolytic electro-dialysis retracting device of contained waste liquid of the present utility model；
In figure：1. upper and lower tumble type electrolysis bath, 2. electrolytic zinc-coated steel sheet anode, 3. electrolytic zinc-coated steel sheet negative electrode, 4. anode chamber, 6. cathode chamber,
5. anode film, 7. storage tank, 8. valve, 9. circulates peristaltic pump, 11. outlets, 12. water inlets.
Specific embodiment
This utility model is described in further detail presently in connection with accompanying drawing.These accompanying drawings are simplified schematic diagram,
Basic structure of the present utility model is only illustrated in a schematic way, therefore which only shows the composition relevant with this utility model.
As shown in figure 1, a kind of electrolytic electro-dialysis retracting device of contained waste liquid, including：
Upper and lower tumble type electrolysis bath 1, upper and lower tumble type electrolysis bath 1 have outlet 11, water inlet 12 and upper and lower staggered row
Electrolytic zinc-coated steel sheet anode 2 and the electrolytic zinc-coated steel sheet negative electrode 3 of row,
One pole EDBM device, one pole EDBM device have anode chamber 4, cathode chamber 6 and are arranged on 4 and of anode chamber
Anode film 5 between cathode chamber 6, and
Storage tank 7,
The water inlet 12 of tumble type electrolysis bath 1 is used to be input into contained waste liquid, the outlet of upper and lower tumble type electrolysis bath 1 up and down
11 are connected with one pole EDBM device anode chamber 4 by circulating peristaltic pump 9, and one pole EDBM device cathode chamber 6 is by following
Ring peristaltic pump 9 is connected with storage tank 7.
After electrolysis, waste liquid enters the anode chamber 4 of one pole EDBM device, after 5 electrodialysis process of anode film, anode
If 4 waste liquid copper ion concentration of room reaches requirement, solution enters storage tank 7.
In a kind of specific embodiment, one pole EDBM device cathode chamber 6 enters water with upper and lower tumble type electrolysis bath 1
Mouth 12 is connected, and has a valve 8 between the water inlet 12 of one pole EDBM device cathode chamber 6 and upper and lower tumble type electrolysis bath 1.
Re-electrolysiss can be carried out into upper and lower tumble type electrolysis bath 1 under the control of valve 8 according to actual needs.
Preferably, the electrolytic zinc-coated steel sheet anode 2 of tumble type electrolysis bath 1 is corrosion resistant plate and electrolytic zinc-coated steel sheet negative electrode 3 is copper coin up and down.
In a kind of specific embodiment, the spacing of electrolytic zinc-coated steel sheet anode 2 and electrolytic zinc-coated steel sheet negative electrode 3 is 1cm.This is apart from electric power
Line intensive, the such distance cathode copper efficiency highest under the conditions of copper ion concentration identical of substep.
In a kind of specific embodiment, electrolytic zinc-coated steel sheet anode 2 apart from the distance of upper and lower 1 upper plate of tumble type electrolysis bath is
1cm, electrolytic zinc-coated steel sheet negative electrode 3 are 0.5cm apart from the distance of upper and lower 1 lower shoe of tumble type electrolysis bath,.
Preferably, the anode film 5 of one pole EDBM device is one pole anode film 5.
In a kind of specific embodiment, the anode chamber 4 of one pole EDBM device adopts stainless steel polar plate, cathode chamber 6
Using copper polar plate.
With it is above-mentioned according to desirable embodiment of the present utility model as enlightenment, by above-mentioned description, related work people
Member can carry out various change and modification completely in the range of without departing from this utility model technological thought.This reality
The content being not limited to new technical scope in description, it is necessary to its technology is determined according to right
Property scope.
Claims (7)
1. the electrolytic electro-dialysis retracting device of a kind of contained waste liquid, it is characterised in that include：
Upper and lower tumble type electrolysis bath, the upper and lower tumble type electrolysis bath have outlet, water inlet and upper and lower staggered electricity
Solution plate anode and electrolytic zinc-coated steel sheet negative electrode,
One pole EDBM device, the one pole EDBM device have anode chamber, cathode chamber and are arranged on anode chamber and the moon
Anode film between pole room, and
Storage tank,
The water inlet of the upper and lower tumble type electrolysis bath is used to be input into contained waste liquid, the outlet of the upper and lower tumble type electrolysis bath
Connected with one pole EDBM device anode chamber by circulating peristaltic pump, the one pole EDBM device cathode chamber is by circulation
Peristaltic pump is connected with storage tank.
2. the electrolytic electro-dialysis retracting device of a kind of contained waste liquid according to claim 1, it is characterised in that：The one pole
EDBM device cathode chamber is connected with the water inlet of upper and lower tumble type electrolysis bath, the one pole EDBM device cathode chamber with
There is between the water inlet of tumble type electrolysis bath a valve up and down.
3. the electrolytic electro-dialysis retracting device of a kind of contained waste liquid according to claim 1 and 2, it is characterised in that：It is described
The electrolytic zinc-coated steel sheet anode of tumble type electrolysis bath is corrosion resistant plate and electrolytic zinc-coated steel sheet negative electrode is copper coin up and down.
4. the electrolytic electro-dialysis retracting device of a kind of contained waste liquid according to claim 1 and 2, it is characterised in that：It is described
The spacing of electrolytic zinc-coated steel sheet anode and electrolytic zinc-coated steel sheet negative electrode is 1cm.
5. the electrolytic electro-dialysis retracting device of a kind of contained waste liquid according to claim 1 and 2, it is characterised in that：It is described
Electrolytic zinc-coated steel sheet anode is 1cm apart from the distance of upper and lower tumble type electrolysis bath upper plate, the upper and lower tumble type of the electrolytic zinc-coated steel sheet cathode distance
The distance of electrolysis bath lower shoe is 0.5cm.
6. the electrolytic electro-dialysis retracting device of a kind of contained waste liquid according to claim 1 and 2, it is characterised in that：It is described
The anode film of one pole EDBM device is one pole anode film.
7. the electrolytic electro-dialysis retracting device of a kind of contained waste liquid according to claim 1 and 2, it is characterised in that：It is described
The anode chamber of one pole EDBM device adopts stainless steel polar plate, cathode chamber to adopt copper polar plate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621088660.0U CN206109003U (en) | 2016-09-28 | 2016-09-28 | Waste cupric liquor's electrolysis electrodialysis recovery unit |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621088660.0U CN206109003U (en) | 2016-09-28 | 2016-09-28 | Waste cupric liquor's electrolysis electrodialysis recovery unit |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN206109003U true CN206109003U (en) | 2017-04-19 |
Family
ID=58522039
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201621088660.0U Expired - Fee Related CN206109003U (en) | 2016-09-28 | 2016-09-28 | Waste cupric liquor's electrolysis electrodialysis recovery unit |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN206109003U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115159634A (en) * | 2022-07-26 | 2022-10-11 | 太原理工大学 | Method for removing chloride ions in high-chlorine wastewater through electric flocculation and electric flocculation device |
-
2016
- 2016-09-28 CN CN201621088660.0U patent/CN206109003U/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115159634A (en) * | 2022-07-26 | 2022-10-11 | 太原理工大学 | Method for removing chloride ions in high-chlorine wastewater through electric flocculation and electric flocculation device |
| CN115159634B (en) * | 2022-07-26 | 2024-01-16 | 太原理工大学 | Method for removing chloride ions in high-chlorine wastewater by electric flocculation and electric flocculation device |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170419 Termination date: 20170928 |