CN206069976U - A kind of association type silicomangan production system - Google Patents

A kind of association type silicomangan production system Download PDF

Info

Publication number
CN206069976U
CN206069976U CN201621062599.2U CN201621062599U CN206069976U CN 206069976 U CN206069976 U CN 206069976U CN 201621062599 U CN201621062599 U CN 201621062599U CN 206069976 U CN206069976 U CN 206069976U
Authority
CN
China
Prior art keywords
electric furnace
slag
silicomanganese
ladle
furnace
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201621062599.2U
Other languages
Chinese (zh)
Inventor
张伟
张忠
梅海军
王泽斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhong Yuan Zhiyuan Co Ltd
Original Assignee
Zhong Yuan Zhiyuan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhong Yuan Zhiyuan Co Ltd filed Critical Zhong Yuan Zhiyuan Co Ltd
Priority to CN201621062599.2U priority Critical patent/CN206069976U/en
Application granted granted Critical
Publication of CN206069976U publication Critical patent/CN206069976U/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Manufacture And Refinement Of Metals (AREA)

Abstract

The utility model discloses a kind of association type silicomangan production system.It includes the first silicomanganese electric furnace, the second silicomanganese electric furnace, the first furnace top bin, the second furnace top bin, the first ladle, the second ladle, slag ladle, the first ingot mould, the second ingot mould and water quenching pool, first silicomanganese electric furnace, the second silicomanganese electric furnace are connected with the first furnace top bin, the second furnace top bin respectively, first silicomanganese electric furnace is connected with the second silicomanganese electric furnace by slag ladle, first silicomanganese electric furnace is also connected with the first ladle, and the first ladle is connected with the first ingot mould;Second silicomanganese electric furnace is connected with the second ladle, water quenching pool respectively, and the second ladle is connected with the second ingot mould.This utility model passes through technique adjustment and lower slag ratio and controls, and a silicomanganese electric-furnace slag MnO content is reached between 20% 28%.Slag Jing cast, it is broken after carry out high silicon manganese-silicon alloy production and application as another silicomanganese electric furnace raw material, reduce the total quantity of slag of two silicomanganese electric furnaces, improve the target of comprehensive recovery, two electric furnace comprehensive recoveries can improve at least 2%.

Description

A kind of association type silicomangan production system
Technical field
The utility model relates to silicomangan process units technical field, and in particular to a kind of association type silicomangan Production system.
Background technology
The production of manganese-silicon, whether as commodity silicomanganese or the semi-finished product as other products, is a silicon all the time Manganese electric furnace single-body type is produced, that is, go out one stove slag of a stove alloy strip.Silicomanganese electroslag is typically processed by the way of water quenching, water quenching Afterwards as low price raw material or Solid state fermentation, pollute environment and comprehensive utilization value is relatively low, due to current mid-carbon fe-mn slag and Other carbon manganese slags are more ripe as the method for manganese-silicon raw materials for production, but silicomanganese electroslag comprehensive utilization technique compared with It is few, it is most of to coordinate other modes to utilize for silicomanganese electroslag(Such as electrolytic manganese etc.), apparently DeGrain at present.
Traditional silicomanganese preparation method is:1st, the adjuvant such as manganese ore and coke, Silicon stone is upper to furnace roof material Jing after broken, dispensing Storehouse, into electric furnace smelting.In ore-smelting electric furnace, the high oxide decomposes of manganese, manganese oxide, silicon oxide and phosphorus pentoxide Reduced by carbon.Its reaction is as follows:
2MnO2=Mn2O3+1/2O2↑ 570℃
3Mn2O3=2Mn3O4+1/2 O2↑ 900℃
Mn3O4+C=3MnO+CO↑
SiO2+2C=Si+2CO↑
MnSi14 1475℃
MnSi17 1490℃
P2O5+5C=2P+5CO↑
Furnace reduction overall reaction and the row's carbon reaction of high silicon are as follows:
MnSiO3+3C=MnSi+3CO↑
3MnSiO3+4C=Mn3C+3SiO2+3CO↑
SiO2+2C=Si+2CO↑
Mn3C+3Si=3MnSi+C
2nd, after reaching certain smelting cycle, Jing tapping holes come out of the stove molten iron into ladle wait next step operation, and slag is entered Jorum, coming out of the stove to finish is not repeated to utilize after rear slag directly carries out water quenching.
3rd, after molten iron drossing, heat converts production medium-low carbon ferromanganese commodity, or the batching after casting, finishing, sample analysis, into Sold for commodity silicomanganese.Its flow chart is as shown in Figure 1.
The shortcoming of above-mentioned prior art is:Former process slag is not used, and the response rate of manganese is produced only 85% or so It is relatively costly;Slag treatment needs also exist for certain expense.
In sum, this utility model devises a kind of association type silicomangan production system.
Utility model content
For deficiency present on prior art, it is to provide a kind of association type silicomangan life that this utility model purpose is Product system, is controlled by technique adjustment and lower slag ratio, a silicomanganese electric-furnace slag MnO content is reached between 20%-28%.Slag High silicon manganese-silicon alloy production and application is carried out as another silicomanganese electric furnace raw material Jing cast, after crushing, reduce two silicomanganese The total quantity of slag of electric furnace, improves the target of comprehensive recovery, and two electric furnace comprehensive recoveries can improve at least 2%.
To achieve these goals, this utility model is by the following technical solutions realizing:A kind of association type silicomanganese Alloy production system, including the first silicomanganese electric furnace, the second silicomanganese electric furnace, the first furnace top bin, the second furnace top bin, the first molten iron Bag, the second ladle, slag ladle, the first ingot mould, the second ingot mould and water quenching pool, the first silicomanganese electric furnace, the second silicomanganese electric furnace respectively with First furnace top bin, the second furnace top bin are connected, and the first silicomanganese electric furnace is connected with the second silicomanganese electric furnace by slag ladle, the first silicomanganese Electric furnace is also connected with the first ladle, and the first ladle is connected with the first ingot mould;Second silicomanganese electric furnace respectively with the second ladle, Water quenching pool is connected, and the second ladle is connected with the second ingot mould.
This utility model the first silicomanganese electric furnace controls basicity of slag in 0.1-0.4, and coke amount of allocating is subtracted by normal rates Few 5% -10%, in the case where ensureing that the working of a furnace is stable, in making slag, MnO contents are maintained between 20%-28%.Furnace rear silicomanganese is gone out Electroslag is poured into a mould, and is buckled in iron bucket by smelting personnel after cast(The vehicle frequency is arranged according to the quantity of slag)It is transported to appointed place Storage is to be broken.As the second silicomanganese electric furnace smelting high silicon manganese-silicon alloy raw material after slag is broken, through burdening calculation, Burden Example is stepped up with 5% as gradient from the beginning of 10%(It is up to 30%), while MnO contents are controlled below 10% in slag, carry out Normal Water Quenching.
The beneficial effects of the utility model:The slag that the low-silicon ferro-silicon-manganesc of carbon containing 1%-2% is produced is crushed, is matched somebody with somebody in proportion Enter to another production silicon-manganese alloy electric furnace in, using silicon-manganese alloy production temperature it is higher the characteristics of, be passed through oxidation Reduction reaction, makes full use of the MnO in slag, reaches raising comprehensive recovery, reduces the purpose that electric furnace produces the quantity of slag.Production technology Control is simple, low cost of manufacture, and product recovery rate is high, and production process slag yields poorly, and preferably resolves waste residue yield excessive Problem, be typical new cleanproduction process, meet national industry demand for development, economic benefit and social benefit are notable.
Description of the drawings
With reference to the accompanying drawings and detailed description describing this utility model in detail;
Flow charts of the Fig. 1 for this utility model background technology;
Fig. 2 is system diagram of the present utility model;
Fig. 3 is flow chart of the present utility model.
Specific embodiment
Technological means, creation characteristic, reached purpose and effect to realize this utility model is easy to understand, below With reference to specific embodiment, this utility model is expanded on further.
Reference picture 2-3, this specific embodiment are employed the following technical solutions:A kind of association type silicomangan production system, Including the first silicomanganese electric furnace 1, the second silicomanganese electric furnace 2, the first furnace top bin 3, the second furnace top bin 4, the first ladle 5, second Ladle 6, slag ladle 7, the first ingot mould 8, the second ingot mould 9 and water quenching pool 10, the first silicomanganese electric furnace 1, the second silicomanganese electric furnace 2 respectively with First furnace top bin 3, the second furnace top bin 4 are connected, and the first silicomanganese electric furnace 1 is connected with the second silicomanganese electric furnace 2 by slag ladle 7, the One silicomanganese electric furnace 1 is also connected with the first ladle 5, and the first ladle 5 is connected with the first ingot mould 8;Second silicomanganese electric furnace 2 respectively with Second ladle 6, water quenching pool 10 are connected, and the second ladle 6 is connected with the second ingot mould 9.
The core technology of this specific embodiment reduces coke 5-10% coke amount of allocating by technique adjustment, makes silicomanganese electricity In stove slag, MnO contents are reached between 25%-28%;Adopt low basicity operation simultaneously, coordination electrode position makes the working of a furnace stably transport OK.
Its concrete technology is as follows:The determination of 1 coke amount of allocating:Reaction in furnace is controlled by losing charcoal mode, slag MnO is made Content reaches more than 20%.Coke allocate into it is too low occur that electric furnace is underload, the phenomenon such as stove varus slag, the working of a furnace are difficult to stable fortune OK.Excessively then make reaction in furnace relatively abundant conversely, coke is allocated into, MnO contents are reduced in slag, it is difficult to which reaching next stove that steps into will Ask.By constantly adjustment coke allocation ratio, grope optimal operating parameter.Empirical tests, reduce 5-10% in the normal amount of allocating of coke When, while MnO contents in slag can be made to reach more than 20%, it is ensured that the stable operation of the working of a furnace.
The determination of 2 basicity of slags:In silicomanganese electric furnace production process, basicity of slag is normally controlled between 0.6-0.8, with Ensure slag fluidity, make to come out of the stove smooth.MnO is generated after the high oxide decomposes of manganese, because in silicomanganese smelting furnace material SiO2 contents are higher, are combined into manganous silicate with MnO.CaO in slag can improve the reducing condition of manganous silicate, by MnO from silicon Cement out in sour manganese, improve the reaction density of free MnO, be conducive to the reduction of MnO.Suppression is needed in silicon manganese slag production process The reduction of MnO processed, to realize the raising of MnO contents in slag, meet the high silicon silicomanganese smelting of next step enters stove requirement.Therefore, Need using low basicity operation between 0.1-0.4 when smelting.But slag reduces causing slag fluidity to reduce, and comes out of the stove not Freely, affect the stable operation of the working of a furnace.To overcome basicity to reduce the problem of the slag fluidity brought difference, adjusted by furnace charge, made Electrode is further inserted deeply, is improved in-furnace temperature, is made slag possess higher temperature, so as to improve mobility.
The determination of silicon manganese slag amount of allocating when 3 silicon silicomanganese are smelted:What silicon manganese slag was smelted as high silicon silicomanganese in cooling, after crushing Raw material, can meet into stove requirement in terms of grade and granularity.But compare:For other manganese ores, grade is relatively low.The higher meeting of amount of allocating Causing entirety to enter stove manganese grade reduces, and affects smelting index.The relatively low then reduces cost amount of amount of allocating is less than normal, it is impossible to embody resource The meaning of comprehensive utilization.By being stepped up silicon manganese slag allocation ratio, silicon manganese slag allocation ratio is found out in 15-25%, electric furnace Global index is the most economical.
The controlling of production process of this specific embodiment is simple, low cost of manufacture, and product recovery rate is high, production process slag Yield poorly, preferably resolve the excessive problem of waste residue yield, be typical new cleanproduction process, meet national industry development Require, economic benefit and social benefit are notable.Controlled by technique adjustment and lower slag ratio, contain a silicomanganese electric-furnace slag MnO Amount is reached between 20%-28%.Slag carries out high silicon manganese-silicon alloy production as another silicomanganese electric furnace raw material Jing cast, after crushing Use.The total quantity of slag of two silicomanganese electric furnaces is reduced, the target of comprehensive recovery is improved.Jing tests two 16500KVA silicomanganese electricity Stove comprehensive yield improves 2%, and half a year can nearly million yuan of reduces cost.4100 tons of outer waste discharge slag is reduced simultaneously, realizes the synthesis of resource Utilize, with good economic and social benefit.
Embodiment 1:In April, -2013 in November, 2012 carries out production experiment, using a 16500KVA silicomanganese electric furnace Common manganese-silicon is produced while carrying out silicon manganese slag production of the MnO contents between 25%-28%.As another after silicon manganese slag is broken Platform 16500KVA silicomanganese electric furnace raw materials carry out high silicon manganese-silicon alloy production and application(It also is used as common designations production).Reduce The total quantity of slag of two silicomanganese electric furnaces, improves comprehensive recovery 2%, and application effect is preferable.
Ultimate principle of the present utility model and principal character and advantage of the present utility model has been shown and described above.One's own profession The technical staff of industry it should be appreciated that this utility model is not restricted to the described embodiments, described in above-described embodiment and description Simply illustrate principle of the present utility model, on the premise of without departing from this utility model spirit and scope, this utility model is also Various changes and modifications are had, these changes and improvements are both fallen within the range of claimed this utility model.This utility model Claimed scope is by appending claims and its equivalent thereof.

Claims (1)

1. a kind of association type silicomangan production system, it is characterised in that including the first silicomanganese electric furnace (1), the second silicomanganese electric furnace (2), the first furnace top bin (3), the second furnace top bin (4), the first ladle (5), the second ladle (6), slag ladle (7), first Ingot mould (8), the second ingot mould (9) and water quenching pool (10), the first silicomanganese electric furnace (1), the second silicomanganese electric furnace (2) respectively with the first furnace roof Feed bin (3), the second furnace top bin (4) are connected, and the first silicomanganese electric furnace (1) is connected with the second silicomanganese electric furnace (2) by slag ladle (7), First silicomanganese electric furnace (1) is also connected with the first ladle (5), and the first ladle (5) is connected with the first ingot mould (8);Second silicomanganese Electric furnace (2) is connected with the second ladle (6), water quenching pool (10) respectively, and the second ladle (6) is connected with the second ingot mould (9).
CN201621062599.2U 2016-09-20 2016-09-20 A kind of association type silicomangan production system Expired - Fee Related CN206069976U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201621062599.2U CN206069976U (en) 2016-09-20 2016-09-20 A kind of association type silicomangan production system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201621062599.2U CN206069976U (en) 2016-09-20 2016-09-20 A kind of association type silicomangan production system

Publications (1)

Publication Number Publication Date
CN206069976U true CN206069976U (en) 2017-04-05

Family

ID=58438332

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201621062599.2U Expired - Fee Related CN206069976U (en) 2016-09-20 2016-09-20 A kind of association type silicomangan production system

Country Status (1)

Country Link
CN (1) CN206069976U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113969351A (en) * 2021-11-22 2022-01-25 东北大学 Method for preparing silicon-manganese alloy by using cooperation of reduction and electrolysis through multi-loop direct current electrode arc heating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113969351A (en) * 2021-11-22 2022-01-25 东北大学 Method for preparing silicon-manganese alloy by using cooperation of reduction and electrolysis through multi-loop direct current electrode arc heating
CN113969351B (en) * 2021-11-22 2022-09-06 东北大学 Method for preparing silicon-manganese alloy by using cooperation of reduction and electrolysis through multi-loop direct current electrode arc heating

Similar Documents

Publication Publication Date Title
CN105624438B (en) A kind of method using poor manganese slag refining ferromanganese alloy
WO2019071794A1 (en) Method for recovering valuable components from mixed slag containing copper and iron
CN102352423A (en) Method for selecting and smelting titanium from vanadium titanomagnetite at low temperature
CN109943685A (en) A kind of external refining production method of hypoxemia low titanium high-carbon-chromium bearing steel
CN103526066B (en) Continuous process for producing manganese-silicon alloy and slag rich in silicomanganese and producing micro-and low-carbon manganese-silicon alloy by utilization of slag rich in silicomanganese
CN109777918A (en) A kind of external refining production method refining high-carbon-chromium bearing steel inclusion particle
CN104141024A (en) Method for producing high-purity pure iron
CN101220413A (en) Technique for smelting ferroferrite with sponge iron
CN102181639B (en) One-step method for producing low-carbon/micro-carbon manganese-silicon alloy by using submerged arc furnace
CN106435310B (en) A kind of technique with grate ferrosilicon process refining manganese silico-aluminum
CN102912131A (en) Preparation method of vanadium-aluminum alloy
CN109402327A (en) A kind of external refining production method of super clean high-carbon-chromium bearing steel
CN113088791A (en) Method for preparing rare earth steel by reducing rare earth oxide step by step in refining process
CN105349875A (en) Novel low-cost ferrosilicon with calcium treatment effect and preparation method thereof
CN105970073B (en) A kind of preparation method of steel-making additive for smelting molybdenum-containinstainless steel
CN103866133B (en) The device for refining and its application method of silicomangan tailings
CN110438352A (en) A kind of method of rare earth yield in raising rare earth ferrosilicon alloy
CN1312307C (en) Mangan-alloy production
CN105886765A (en) Method for producing ferrosilicon
CN206069976U (en) A kind of association type silicomangan production system
CN101671762A (en) Production method for medium and low alloy special steel
CN111041240B (en) Method for preparing ferrotitanium alloy by using perovskite concentrate as raw material
CN107586915A (en) The alloyage process of manganese element in a kind of middle potassium steel
CN101736122B (en) Method for improving recovery rate of smelt nonmagnetic steel aluminum
CN1020116C (en) Electric furnace steelmaking method capable of reducing manganese from mangamese-containing ore

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20170405

Termination date: 20180920