CN206054060U - A kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel generates system - Google Patents

A kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel generates system Download PDF

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Publication number
CN206054060U
CN206054060U CN201620299377.6U CN201620299377U CN206054060U CN 206054060 U CN206054060 U CN 206054060U CN 201620299377 U CN201620299377 U CN 201620299377U CN 206054060 U CN206054060 U CN 206054060U
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China
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peculiar
gaseous ammonia
exhaust gas
temperature
vessel
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CN201620299377.6U
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Chinese (zh)
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暴辰生
李剑峰
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Suzhou Shuimukangqiao Environmental Engineering Technology Co Ltd
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Suzhou Shuimukangqiao Environmental Engineering Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/40Engine management systems

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Abstract

This utility model provides a kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel and generates system, the exhaust gas cleaner peculiar to vessel includes particulate matter removal device and catalytic reduction device, the gaseous ammonia generates system includes air-flowing type spraying system and spraying adjusting means, the nozzle of air-flowing type spraying system described in urea liquid Jing is sprayed the high-temperature tail gas sprayed with marine diesel and is sufficiently mixed the gaseous ammonia for producing biuret and using for the catalytic reduction device, and the emitted dose of urea liquid is by spraying adjusting means control.Gaseous ammonia is generated system and will be sufficiently mixed with high-temperature tail gas in urea liquid direct Jing pipelineds to exhaust gas cleaner peculiar to vessel, so as to produce gaseous ammonia and biuret, instead of in selective catalytic reduction by ammonia vaporizer, ammonia surge tank, the gaseous ammonia generating means of the huge equipment composition such as gas flow valve, this is for most of for mobile pollution source diesel engine, the gaseous ammonia generates system and can generate gaseous ammonia in real time by the demand of marine diesel tail gas clean-up, and use urea liquid, good stability, the job security of whole system is higher.

Description

A kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel generates system
Technical field
This utility model is related to environmental technology field, and in particular to tail gas clean-up technical field, more particularly to a kind of ship System is generated with gaseous ammonia used in exhaust gas cleaner.
Background technology
Marine diesel oil contains the oily substance of a large amount of high-flashes, causes which to burn in cylinder of diesel engine and is far from light oil Thoroughly, this contains a large amount of poisonous and harmful substances in resulting in tail gas, comprising sulfur dioxide, nitrogen oxides, trickle carbonized particles Thing, or even also have the material of still unburned microlayer model oils and class Colophonium.These materials are entered in the SCR device of rear class, The blocking of the ceramic catalyst in SCR device can be caused, its service life is substantially reduced, the ceramic catalyst for making price high loses Effect is scrapped.
In prior art, in order to ensure SCR exhaust purifier normal works, in the tail gas catalyzed reduction apparatus of SCR and diesel oil The pretreating device of exhaust purifier is added between machine row's mouth, diesel engine vent gas, can be by the big portion in tail gas after the device Divide trickle carbonized particles thing, still unburned microlayer model oily substance, carbamide resolve into biuret (CONH) particulate matter, gaseous state After ammonia with tail gas in sulfur dioxide occur chemical reaction formed ammonium sulfite and ammonium sulfate granule or drop and class Colophonium Material etc. retained by this pretreating device, so as to by the main gaseous contaminant (NO of diesel emissionX、SO2) and solid-state Grain pollutant, realize that the overwhelming majority is removed.But this technology can increase the volume of exhaust purifier first and improve cost, this With present day devices miniaturization, lightweight, the requirement of low cost, undoubtedly run in the opposite direction.
It is seen that, gaseous ammonia is the required material of catalytic reduction method cleaning of off-gas, then in the diesel oil for working long hours In machine, such as marine diesel is also accomplished by substantial amounts of gaseous ammonia and is reacted, that is, say that the ship of long voyage needs to take With substantial amounts of liquid ammonia, but stablizing for ammonia is poor, once reveal it is light if pollute air, make one poisoning, it is heavy then set off an explosion, Poor stability.
So it is accomplished by a kind of shipborne system that can produce gaseous ammonia in real time to overcome drawbacks described above.
The content of the invention
A purpose of the present utility model is to provide for a kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel and generates system, Which can generate gaseous ammonia in real time by the demand of marine diesel tail gas clean-up, and use urea for vehicle solution, stable Property is good, and the job security of whole system is higher.
Especially, this utility model provides a kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel and generates system, described Exhaust gas cleaner peculiar to vessel includes particulate matter removal device and catalytic reduction device, and the gaseous ammonia generates system includes air-flowing type Spraying system and spraying adjusting means, the nozzle of air-flowing type spraying system described in urea liquid Jing are sprayed and are sprayed with marine diesel The high-temperature tail gas for going out are sufficiently mixed the gaseous ammonia for producing biuret and using for the catalytic reduction device, the urea liquid Emitted dose is by the spraying adjusting means control.
For above-mentioned technical proposal, inventor also has further optimal enforcement scheme.
Preferably, the exhaust gas cleaner peculiar to vessel has air inlet and gas outlet, and the gaseous ammonia generates system to be included First NOXSensor, is arranged at a NO of the air inletXSensor is communicated connection with the spraying adjusting means, institute Spraying adjusting means is stated according to a NOXThe nitrogen oxides of the entrance exhaust gas cleaner peculiar to vessel that sensor is detected Content adjusts the emitted dose of the urea liquid.
Further, the gaseous ammonia generates system includes the second NOX sensor, is arranged at the gas outlet, described the Two NOXSensor communicate connection with the spraying adjusting means, and the adjusting means of spraying is according to the 2nd NOXSensor is examined The amount of nitrogen oxides of the discharge exhaust gas cleaner peculiar to vessel for measuring adjusts the emitted dose of the urea liquid.
Preferably, the gaseous ammonia generates system also includes temperature sensor, and the temperature sensor is arranged on the ship With in exhaust gas cleaner, for detecting the temperature of high-temperature tail gas described in the exhaust gas cleaner peculiar to vessel, the temperature is passed Sensor communicate connection with the spraying adjusting means, and the adjusting means of spraying is opened according to the temperature for detecting the high-temperature tail gas Stop the work of the air-flowing type spraying system.
Further, minimum temperature threshold and maximum temperature threshold value are configured with the spraying adjusting means, by the temperature The temperature of the high-temperature tail gas that degree sensor is detected is compared with the minimum temperature threshold and maximum temperature threshold value, such as The temperature of the high-temperature tail gas is less than the minimum temperature threshold or is higher than the maximum temperature threshold value, then stop the air-flow The work of formula spraying system, otherwise opens the work for keeping the air-flowing type spraying system.
Further, between the minimum temperature threshold is located at 190 DEG C~210 DEG C, the maximum temperature threshold value is located at Between 450 DEG C~470 DEG C.
Preferably, the gaseous ammonia generates system includes at least one temperature sensor, at least one temperature sensing Device is arranged at the air inlet of the exhaust gas cleaner peculiar to vessel.
Further, intake air temperature threshold value is configured with the spraying adjusting means, at the air inlet for detecting The high-temperature tail gas temperature compared with the intake air temperature threshold value, as the temperature of the high-temperature tail gas falls in the air inlet The work of the air-flowing type spraying system in the range of temperature threshold, is then opened, otherwise stops the air-flowing type spraying system Work.
Further, the scope of the intake air temperature threshold value is 220 DEG C~490 DEG C.
Compared with prior art, the utility model has the advantage of:
Gaseous ammonia of the present utility model generates system, and for exhaust gas cleaner peculiar to vessel, the gaseous ammonia generates system will The direct Jing pipelineds of urea liquid are sufficiently mixed with high-temperature tail gas into exhaust gas cleaner peculiar to vessel, so as to produce gaseous state Ammonia and biuret, instead of huge by ammonia vaporizer, ammonia surge tank, gas flow valve etc. in selective catalytic reduction The gaseous ammonia generating means of equipment composition, this is mobile pollution source diesel engine for major part, and especially oceangoing voyage marine diesel comes Speech, the gaseous ammonia generate system and can generate gaseous ammonia in real time by the demand of marine diesel tail gas clean-up, and use It is urea liquid, good stability, the job security of whole system are higher.Gaseous ammonia provided by the utility model generates western ketone Overall structure is simple, small volume, lightweight, more for practicality.
Further, produced biuret after gaseous state urea liquid pyrolytic, can form tiny consolidating with ammonium sulfate State granule, can more easily by the exhaust gas cleaner peculiar to vessel in the particulate matter removal device remove, also it is avoided that In catalytic reduction device, the blockage problem of ceramic catalyst, extends the bulk life time of catalytic reduction device.
Further, during the emitted dose of the urea liquid is the high-temperature tail gas according to the exhaust gas cleaner peculiar to vessel Amount of nitrogen oxides carries out Based Intelligent Control, while ensureing efficiently to take out nitrogen oxides, additionally it is possible to avoid the escaping of ammonia situation Generation, saved cost, and avoided the pollution of environment, improve safety.
According to the detailed description below in conjunction with accompanying drawing to this utility model specific embodiment, those skilled in the art will be more Plus understand of the present utility model above-mentioned and other purposes, advantages and features.
Description of the drawings
Describe some concrete realities of the present utility model hereinafter with reference to the accompanying drawings by way of example, and not by way of limitation in detail Apply example.In accompanying drawing, identical reference denotes same or similar part or part.It should be appreciated by those skilled in the art that What these accompanying drawings were not necessarily drawn to scale.In accompanying drawing:
Fig. 1 is the structured flowchart of the exhaust gas cleaner peculiar to vessel according to this utility model one embodiment.
Specific embodiment
Fig. 1 is the structured flowchart of the exhaust gas cleaner peculiar to vessel according to the present embodiment.As shown in figure 1, the present embodiment is retouched The gaseous ammonia stated generates system, and for exhaust gas cleaner peculiar to vessel, the exhaust gas cleaner peculiar to vessel includes that particulate matter removes dress 4 and catalytic reduction device 3 are put, the gaseous ammonia generates system and may include that air-flowing type spraying system 2 and spraying are adjusted in general manner Device 1, the nozzle ejection of air-flowing type spraying system 2 described in urea liquid Jing are abundant with the high-temperature tail gas that marine diesel sprays Mixing produces biuret and the gaseous ammonia used for the catalytic reduction device 3, and the emitted dose of the urea liquid receives the spray Mist adjusting means 1 is controlled.
Pipeline is provided with the air-flowing type spraying system 2, by the urea liquid Jing pipelineds to nozzle, so as to Into the inside of the exhaust gas cleaner peculiar to vessel, by air-stream spraying by urea liquid be changed into microlayer model state and with high temperature tail Gas is sufficiently mixed, and the carbamide in the presence of high-temperature tail gas in urea liquid is heated to rapidly more than 160 DEG C and then decomposes, and produces Raw gaseous ammonia (NH3) and biuret (CONH), wherein gaseous ammonia (NH3) by the catalytic condition in subsequent catalytic reduction device 3 Nitrogen oxides in lower and tail gas (include NO and NO2) there is following chemical reaction:
4NH3+4NO+O2=4N2+6H2O
8NH3+6NO2=7N2+12H2O
Carbon monoxide and nitrogen oxygen while above-mentioned denitration process, under high temperature and catalytic condition, in tail gas gaseous mixture Compound (includes NO and NO2) there is following chemical reaction:
2CO+2NO+O2=2CO2+N2
4CO+2NO2=4CO2+N2
At the same time, gaseous ammonia (NH3) also there is following chemical reaction with the sulfur dioxide in tail gas, its reaction equation is:
SO2+H2O+xNH3=(HN4)xH2-xSO3
Ammonium sulfite intermediate products are obtained, ammonium sulfite is aoxidized again:
(NH4)XH2-XSO3+1/2O2+(2-x)NH3=(NH4)2SO4
Spray drying method desulfurization is achieved in that, the biuret after the end-product ammonium sulfate and carbamide after desulfurization decomposes can shape It is mixed in diesel engine vent gas into tiny solid granulates.Particulate matter and bavin in subsequent particulate matter removal device 4, by more than In oil machine tail gas, original particulate matter is together removed, and also the ceramic catalyst in the catalytic reduction device 3 would not be caused Blocking.
It is understood that the content into the nitrogen oxides of exhaust gas cleaner peculiar to vessel is the moment in change, because The operation conditions of diesel engine is different, and produced nitrogen oxides are also inevitable different, then purify these major pollutants Be exactly gaseous ammonia needed for nitrogen oxides be also different, then in the present embodiment, then the amount for being also accomplished by carbamide is done Go out to adjust control.
If because when urea liquid emitted dose is fewer, the ammonia for necessarily leading to is not reached and efficiently removes denitrification Requirement (reactant not enough), just necessarily reduce going the efficiency of denitrification.If conversely, urea liquid emitted dose exceedes going The requirement (reactant is superfluous) of denitrification, although the efficiency of denitrification can be improved, but, due to reactant Surplus, the ammonia for having neither part nor lot in reaction are directly discharged in air, cause ammonia (being also poisonous and hazardous gas) to pollute, that is, often The escaping of ammonia phenomenon said.The carbamide of excess injection simultaneously will also result in increase using urea amount causes operating cost to increase.
Therefore, in order to avoid urea liquid emitted dose is not enough or urea liquid overspray, just must be according to motor hand The change of condition (nitrous oxides concentration that the difference of rotating speed and load contains in causing the flow difference of tail gas, its tail gas is different), Immediately change the urea liquid overspray into exhaust gas cleaner, as injection rate of the gaseous ammonia in tail gas depends on completely In the concentration and injection rate of urea liquid, and urea concentration is controlled very well, as long as urea liquid injection accurately can be adjusted Amount.
The exhaust gas cleaner peculiar to vessel has air inlet and gas outlet, and the gaseous ammonia generates system includes a NOX Sensor 5, is arranged at a NO of the air inletXSensor 5 is communicated connection with the spraying adjusting means 1, described Spraying adjusting means 1 is according to a NOXThe nitrogen oxides of the entrance exhaust gas cleaner peculiar to vessel that sensor 5 is detected Content adjusts the emitted dose of the urea liquid.
The gaseous ammonia generates system also includes the 2nd NOXSensor 6, is arranged at the gas outlet, the 2nd NOXPass Sensor 6 communicate connection with the spraying adjusting means 1, and the adjusting means 1 of spraying is according to the 2nd NOXSensor 6 is detected The amount of nitrogen oxides of the discharge exhaust gas cleaner peculiar to vessel for arriving adjusts the emitted dose of the urea liquid.
Mechanical diaphragm type urea pump can be set in exhaust gas cleaner peculiar to vessel, with reference to the spraying adjusting means 1, can It is more accurate that effectively urea liquid emitted dose is controlled.
In addition, in the present embodiment, the high-temperature tail gas into exhaust gas cleaner peculiar to vessel must reach uniform temperature, Tail gas clean-up can be realized.Because if the temperature of high-temperature tail gas enters tail gas clean-up peculiar to vessel less than uniform temperature injection carbamide Carbamide can be caused after device to decompose in ceramic catalyst intercrystalline, block catalytic reduction device 3;And it is higher than uniform temperature urine Plain spirt goes directly be oxidized to NOX, not only do not reduce NOXDischarge, increases NO on the contraryXDischarge.
Therefore, the gaseous ammonia generates system also includes temperature sensor 7, and the temperature sensor 7 is arranged on the ship With in exhaust gas cleaner, for detecting the temperature of high-temperature tail gas described in the exhaust gas cleaner peculiar to vessel, the temperature is passed Sensor 7 communicate connection with the spraying adjusting means 1, and the adjusting means 1 of spraying is according to the temperature for detecting the high-temperature tail gas The work of air-flowing type spraying system 2 described in degree start and stop.
Further, minimum temperature threshold and maximum temperature threshold value are configured with the spraying adjusting means 1, by the temperature The temperature of the high-temperature tail gas that degree sensor 7 is detected is compared with the minimum temperature threshold and maximum temperature threshold value, Temperature such as the high-temperature tail gas be less than as described in minimum temperature threshold or maximum temperature threshold value as described in being higher than, then stop the gas The work of flow type spray system 2, otherwise opens the work for keeping the air-flowing type spraying system 2.
Preferably, between the minimum temperature threshold is located at 190 DEG C~210 DEG C, the maximum temperature threshold value is located at 450 DEG C Between~470 DEG C.
After being monitored to the high-temperature tail gas temperature in exhaust gas cleaner peculiar to vessel, it is 200 such as to arrange minimum temperature threshold DEG C, maximum temperature threshold value be 460 DEG C, then when detect exhaust gas cleaner interior temperature degree peculiar to vessel less than 200 DEG C when then stop to The exhaust gas cleaner peculiar to vessel sprays urea liquid, and same is higher than 400 when exhaust gas cleaner interior temperature degree peculiar to vessel is detected DEG C when also stop spraying urea liquid to the exhaust gas cleaner peculiar to vessel, the normal spraying tune otherwise when diesel engine work Regulating device 1 keeps spraying urea liquid into the exhaust gas cleaner peculiar to vessel.
Certainly, in order to realize monitoring temperature, one can also be arranged in the air inlet of the exhaust gas cleaner peculiar to vessel directly Individual temperature sensor 7, direct detection enter the temperature of the high-temperature tail gas of exhaust gas cleaner peculiar to vessel, also just say in gaseous ammonia Temperature sensor 7 of the generation system with least one air inlet for being arranged at the exhaust gas cleaner peculiar to vessel.
Further, intake air temperature threshold value is configured with the spraying adjusting means 1, at the air inlet for detecting The temperature of the high-temperature tail gas compared with the intake air temperature threshold value, as the temperature of the high-temperature tail gas fall it is described enter temperature In the range of degree threshold value, then the work of the air-flowing type spraying system 2 is opened, otherwise stops the air-flowing type spraying system 2 Work.
Preferably, the scope of the intake air temperature threshold value is 220 DEG C~490 DEG C.
The gaseous ammonia of the present embodiment generates system, and for exhaust gas cleaner peculiar to vessel, the gaseous ammonia generates system and will urinate The direct Jing pipelineds of plain solution are sufficiently mixed with high-temperature tail gas into exhaust gas cleaner peculiar to vessel, so as to produce gaseous ammonia And biuret, set by ammonia vaporizer, ammonia surge tank, gas flow valve etc. are huge in instead of selective catalytic reduction The gaseous ammonia generating means of standby composition, this for it is most of be mobile pollution source diesel engine, especially oceangoing voyage marine diesel saying, The gaseous ammonia generates system and can generate gaseous ammonia in real time by the demand of marine diesel tail gas clean-up, and uses urine Plain solution, good stability, the job security of whole system are higher.Gaseous ammonia provided by the utility model generates the whole of western ketone It is body simple structure, small volume, lightweight, more for practicality.
Further, produced biuret after gaseous state urea liquid pyrolytic, can form tiny consolidating with ammonium sulfate State granule, can more easily by the exhaust gas cleaner peculiar to vessel in the particulate matter removal device remove, also it is avoided that In catalytic reduction device, the blockage problem of ceramic catalyst, extends the bulk life time of catalytic reduction device.
Further, during the emitted dose of the urea liquid is the high-temperature tail gas according to the exhaust gas cleaner peculiar to vessel Amount of nitrogen oxides carries out Based Intelligent Control, while ensureing efficiently to take out nitrogen oxides, additionally it is possible to avoid the escaping of ammonia situation Generation, saved cost, and avoided the pollution of environment, improve safety.
So far, although those skilled in the art will appreciate that herein it is detailed illustrate and describe it is of the present utility model many Individual exemplary embodiment, but, in the case of without departing from this utility model spirit and scope, still can be public according to this utility model The content opened directly determines or derives many other variations or modifications for meeting this utility model principle.Therefore, this practicality is new The scope of type is understood that and regards as covering all these other variations or modifications.

Claims (7)

1. a kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel generates system, and the exhaust gas cleaner peculiar to vessel includes particulate matter Removal device and catalytic reduction device, it is characterised in that the gaseous ammonia generates system includes air-flowing type spraying system and spraying Adjusting means, the nozzle of air-flowing type spraying system described in urea liquid Jing are sprayed the high-temperature tail gas sprayed with marine diesel and are filled Mixing is divided to produce biuret and the gaseous ammonia used for the catalytic reduction device, the emitted dose of the urea liquid receives the spray Mist adjusting means is controlled;The exhaust gas cleaner peculiar to vessel has air inlet and gas outlet, and the gaseous ammonia generates system to be included First NOX sensor, is arranged at a NO of the air inletXSensor is communicated connection with the spraying adjusting means, The spraying adjusting means is according to a NOXThe nitrogen oxidation of the entrance exhaust gas cleaner peculiar to vessel that sensor is detected Thing content adjusts the emitted dose of the urea liquid;
The gaseous ammonia generates system includes the 2nd NOXSensor, is arranged at the gas outlet, second NOX sensor and institute Spraying adjusting means communication connection is stated, the spraying adjusting means is according to the 2nd NOXDescribed in the discharge that sensor is detected The amount of nitrogen oxides of exhaust gas cleaner peculiar to vessel adjusts the emitted dose of the urea liquid.
2. a kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel according to claim 1 generates system, it is characterised in that The gaseous ammonia generates system also includes temperature sensor, and the temperature sensor is arranged on the exhaust gas cleaner peculiar to vessel In, for detecting the temperature of high-temperature tail gas described in the exhaust gas cleaner peculiar to vessel, the temperature sensor and the spraying Adjusting means communication connection, spraying adjusting means air-flowing type spray according to the temperature start and stop for detecting the high-temperature tail gas The work of mist system.
3. a kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel according to claim 2 generates system, it is characterised in that Minimum temperature threshold and maximum temperature threshold value are configured with the spraying adjusting means, the institute that the temperature sensor is detected The temperature and the minimum temperature threshold and maximum temperature threshold value for stating high-temperature tail gas is compared, such as the temperature of the high-temperature tail gas Less than the minimum temperature threshold or higher than the maximum temperature threshold value, then stop the work of the air-flowing type spraying system, The work for keeping the air-flowing type spraying system is opened otherwise.
4. a kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel according to claim 3 generates system, it is characterised in that Between the minimum temperature threshold is located at 190 DEG C~210 DEG C, between the maximum temperature threshold value is located at 450 DEG C~470 DEG C.
5. a kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel according to claim 1 generates system, it is characterised in that The gaseous ammonia generates system includes at least one temperature sensor, and at least one temperature sensor is arranged at described peculiar to vessel The air inlet of exhaust gas cleaner.
6. a kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel according to claim 5 generates system, it is characterised in that Intake air temperature threshold value is configured with the spraying adjusting means, by the temperature of the high-temperature tail gas at the air inlet for detecting Spend compared with the intake air temperature threshold value, as the temperature of the high-temperature tail gas falls in the range of the intake air temperature threshold value, The work of the air-flowing type spraying system is then opened, otherwise stops the work of the air-flowing type spraying system.
7. a kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel according to claim 6 generates system, it is characterised in that The scope of the intake air temperature threshold value is 220 DEG C~490 DEG C.
CN201620299377.6U 2016-04-12 2016-04-12 A kind of gaseous ammonia for exhaust gas cleaner peculiar to vessel generates system Expired - Fee Related CN206054060U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105736094A (en) * 2016-04-12 2016-07-06 苏州水木康桥环境工程技术有限公司 Gaseous ammonia generating system used for marine tail gas purification device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105736094A (en) * 2016-04-12 2016-07-06 苏州水木康桥环境工程技术有限公司 Gaseous ammonia generating system used for marine tail gas purification device

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