CN206027504U - Electrolyte tubular reactor - Google Patents

Electrolyte tubular reactor Download PDF

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Publication number
CN206027504U
CN206027504U CN201620963318.4U CN201620963318U CN206027504U CN 206027504 U CN206027504 U CN 206027504U CN 201620963318 U CN201620963318 U CN 201620963318U CN 206027504 U CN206027504 U CN 206027504U
Authority
CN
China
Prior art keywords
shaft part
electrolyte
gear
reaction body
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn - After Issue
Application number
CN201620963318.4U
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Chinese (zh)
Inventor
王盛
廖帅玲
温雄
吴良煜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningde Kaixin Battery Material Co Ltd
Original Assignee
Ningde Kaixin Battery Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority to CN201620963318.4U priority Critical patent/CN206027504U/en
Application granted granted Critical
Publication of CN206027504U publication Critical patent/CN206027504U/en
Withdrawn - After Issue legal-status Critical Current
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Abstract

The utility model relates to an electrolyte tubular reactor, including the inside reaction body that is equipped with the reaction cavity, the pipe shaft of reaction body is one end height, the low slope setting of one end, the reaction body is equipped with a plurality of raw material feed port that are used for adding different electrolyte preparation raw materials in high one end, is equipped with the discharge gate of the electrolyte that is used for discharging in low one end, adopt the utility model discloses a continuous production of feeding, stirring, the ejection of compact can be realized to the reactor, and the process time is short, and is few in batches, and the mass range of processing electrolyte is wide, all can produce in same reactor from 200 kilograms of electrolyte to 20 tons of weight to production is remained fewly, greatly promotes product stable quality nature. The utility model discloses reactor's muddy board can the year rotate the shaft part realize the variable speed with or the diversion. Inside material misce bene, EC adds fashionable difficult freezing in addition.

Description

Electrolyte tubular reactor
Technical field
This utility model is related to chemical technology field, and in particular to electrolyte tubular reactor.
Background technology
When needing substantial amounts of production using current reactor production electrolyte, generally requiring many batch multi-reaction kettles is carried out Production, it is impossible to realize charging, stirring, the continuous production of discharging, can only first feed, be stirred for, stirring is discharged after a period of time again. Using specific reactor, a reactor can only produce the electrolyte of concrete mass parts.And had using existing reactor There is more serious residue problem.
The solvent of lithium-ion battery electrolytes in the market have DMC (dimethyl carbonate), DEC (diethyl carbonate), EMC (Ethyl methyl carbonate), EC (ethylene carbonate) etc., EC are the materials that can contain in each formula system, so And the fusing point of EC is 35-38 DEG C, it is in the solid-state that room temperature is crystallization, therefore which will be entered during storage and use is had suffered Row insulation, just can guarantee that it will not crystallize.It is very high that insulation energy consumption is carried out to storage tank, pipeline etc., but the process of electrolyte quota In, the temperature for controlling solvent is needed at 10 DEG C or so, therefore EC is also performed at further cooling after preparation kettle is entered Reason, so not only increases energy consumption, while increasing the process time.
Lithium-ion battery electrolytes containing EC are first separately added into various solvents such as in reactor when preparing at present EC, DMC, DEC etc., various solvents in kettle after be passed through coolant in the chuck of reactor, be reduced to the temperature of solvent 10 DEG C or so, treat temperature be down to it is temperature required after, add additive and lithium salts, stir, blowing.
Using current reactor, not only energy consumption is big, and the time is long, and efficiency is low.
Utility model content
This utility model provides a kind of electrolyte tubular reactor, can be realized feeding, is stirred, discharged using the reactor Continuous production, the process time is short, and the mass range for processing electrolyte is wide, from 200 kilograms to the electrolyte of 20 tons of weight To be produced in same reactor, and produce residual less, greatly improving product quality stability.
This utility model employs the following technical solutions realization:
A kind of electrolyte tubular reactor, it is characterised in that:The reaction body of reaction cavity, reaction tube are provided with including inside In one end, high, one end low dip is arranged the pipe shaft of body, and the reaction body is provided with multiple for adding different electricity in high one end The material inlet of solution liquid preparing raw material, is provided with the discharging opening for discharging electrolyte in low one end;
Multiple rotations rotated around same axial line are sequentially provided with along reaction body axial direction in reaction body cavity Shaft part, the rotating speed of two neighboring rotation shaft part and/or turns to different, is additionally provided with positioned at two neighboring in reaction body cavity Rotate the rotating speed for making two neighboring rotation shaft part between shaft part and/or turn to mutually different actuating device and be used for Install and support each fixed beam for rotating shaft part;Reaction body cavity in be additionally provided with it is multigroup respectively with it is each rotation shaft part coaxially one turn The dynamic mixing plate for making the material mix homogeneously in reaction tube body;
Described reactor also includes the motor for driving each rotation shaft part rotation outside reaction body one end.
Different in order to realize the two neighboring rotating speed for rotating shaft part, the actuating device is for making two neighboring rotary shaft The different gear shift of rotating speed of section, described gear shift include being arranged at one and rotate shaft part tail end and therewith First stud gear and second stud gear and second gear teeth of first stud gear engaged transmission that coaxial synchronous are rotated The 3rd change-speed gearing that wheel coaxial synchronous are rotated and with the 3rd meshed transmission gear and it is arranged at next shaft part front end of rotating 4th change-speed gearing of co-axial synchronous axial system.
Different in order to realize the two neighboring steering for rotating shaft part, the actuating device is for making two neighboring rotary shaft The different gear side steerings of steering of section, described gear side steering include being arranged at one and rotate shaft part tail end and therewith The first change gear and second change gear and the second break-in tooth of the first change gear engaged transmission that coaxial synchronous are rotated Take turns the 3rd change gear of coaxial synchronous rotation, be arranged at the 4th of next rotation shaft part front end and co-axial synchronous axial system The 5th change gear of change gear and engaged transmission between the 3rd change gear and the 4th change gear.
In order that mixed effect is more preferably, it is by two semiellipses that a portion rotates the mixing plate arranged on shaft part The little head end of shape plate is connected with each other the first mixing plate of composition;Wherein another part rotates the mixing plate arranged on shaft part Plate is mixed by an elliptical flat-plate is constituted second;First mixes plate and second mixes plate along reaction body Axial direction is crisscross arranged successively.
In order that EC is not-easy-to-freeze, wherein at least one material inlet is the EC for being connected with EC raw material feed arrangements Charging aperture, remaining material inlet are other feedstocks for being connected with other electrolyte preparing raw material feeding devices Mouthful;After described EC charging apertures are located at other material inlets with the link position for reacting body;And be located at EC charging apertures it Mixing afterwards is equipped with the micropore for penetrating mixing plate on plate.
In order that the effect of stirring and outflow electrolyte is more preferably, described reaction body with the angle of inclination of horizontal plane is 20-30°。
A length of 15 meters -16 meters of described reaction body, a diameter of 0.5-1 rice.
In order to be able to be easy to production, the effusion meter for controlling feed material feed rates in each material inlet, is equipped with.
Drainage screen is provided with described discharging opening.
A kind of electrolyte tubular reaction process, it is characterised in that:Comprise the following steps:
The head tank for storing various electrolyte preparing raw materials is connected with corresponding material inlet, dosage as required Raw material is reacted in body by each material inlet input, Motor drive is then started and is respectively rotated shaft part rotation, positioned at reaction The plate that mixes in body cavity starts to rotate with the rotation for rotating shaft part, makes the raw material in reaction body form rotation Stream, makes various raw materials in addition reaction body be uniformly mixed to discharge outlet and flows, last mix homogeneously Electrolyte is flowed out from discharging opening.
Than prior art, the beneficial effects of the utility model are:
1. the continuous production for feeding, stirring, discharge can be realized using reactor of the present utility model, and the process time is short, Batch is few, and the mass range for processing electrolyte is wide, can be in same reactor to the electrolyte of 20 tons of weight from 200 kilograms In produced, and it is few to produce residual, greatly improving product quality stability.
2. in this utility model reactor mixed plate energy year rotate shaft part realize speed change and, or break-in.
3. materials inside mix homogeneously, and EC is not-easy-to-freeze when adding.
Description of the drawings
Fig. 1 is the structural representation of this utility model embodiment 1.
Fig. 2 is the structural representation of this utility model embodiment 2.
Fig. 3 is the two neighboring rotation shaft part connection diagram of this utility model embodiment 3.
Fig. 4 is the two neighboring rotation shaft part connection diagram of this utility model embodiment 4.
Wherein, description of reference numerals is as follows:1- reacts body, 2- material inlets, 2-1-EC charging apertures, and other are former for 2-2- Material charging aperture, 3- discharging openings, 4- rotate shaft part, and 5- mixes plate, and 5-1- first mixes plate, and 5-2- second is mixed Plate, 6- fixed beams, 7- motors, 8- micropores, 9-1- first stud gears, 9-2- second stud gears, the 3rd change-speed gearings of 9-3-, The 4th change-speed gearings of 9-4-, the first change gears of 10-1-, the second change gears of 10-2-, the 3rd change gears of 10-3-, 10-4- 4th change gear, the 5th change gears of 10-5-, 11- drainage screens.
Specific embodiment
(1) specific embodiment
A kind of electrolyte tubular reactor, it is characterised in that:The reaction body 1 of reaction cavity, reaction are provided with including inside In one end, high, one end low dip is arranged the pipe shaft of body 1, and the reaction body 1 is provided with multiple for adding not in high one end With the material inlet 2 of electrolyte preparing raw material, the discharging opening 3 for discharging electrolyte is provided with low one end;
It is sequentially provided with along reaction 1 axial direction of body in reaction 1 cavity of body multiple around turning that same axial line is rotated Moving axis section 4, it is two neighboring rotate shaft part 4 rotating speed and/or turn to it is different, reaction 1 cavity of body in be additionally provided with positioned at phase Adjacent two rotating speeds for making two neighboring rotation shaft part 4 rotated between shaft part 4 and/or the mutually different transmission dress of steering Put, and for install support it is each rotate shaft part 4 fixed beam 6;Reaction 1 cavity of body in be additionally provided with it is multigroup respectively with each rotary shaft The mixing plate 5 for making the material mix homogeneously in reaction body 1 of 4 coaxial unitary rotations of section;
Described reactor also includes the motor for driving each rotation shaft part 4 rotation outside 1 one end of reaction body 7。
Different in order to realize the two neighboring rotating speed for rotating shaft part 4, the actuating device is for making two neighboring rotation The different gear shift of the rotating speed of shaft part 4, described gear shift include being arranged at rotation 4 tail end of shaft part and The second stud gear 9-2 of the first stud gear 9-1 of co-axial synchronous axial system and first stud gear 9-1 engaged transmissions, And with the 3rd change-speed gearing 9-3 of second stud gear 9-2 coaxial synchronous rotation and set with the 3rd gear 9-2 engaged transmissions It is placed in the 4th change-speed gearing 9-4 of next co-axial synchronous axial system for rotating 4 front end of shaft part.
Different in order to realize the two neighboring steering for rotating shaft part 4, the actuating device is for making two neighboring rotation The different gear side steerings of steering of shaft part 4, described gear side steering include being arranged at one rotate 4 tail end of shaft part and Second change gear of the first change gear 10-1 of co-axial synchronous axial system and the first change gear 10-1 engaged transmissions The 3rd change gear 10-3 that 10-2 and the second change gear 10-2 coaxial synchronous are rotated, it is arranged at 4 front end of next rotation shaft part And the 4th change gear 10-4 of co-axial synchronous axial system and engaged transmission become in the 3rd change gear 10-3 and the 4th To the 5th change gear 10-5 between gear 10-4.
In order that mixed effect is more preferably, it is ellipse by two and half that a portion rotates the mixing plate arranged on shaft part 4 The little head end of circular slab is connected with each other the first mixing plate 5-1 of composition;Wherein another part rotates the mixing arranged on shaft part 4 Agitating plate mixes plate 5-2 by an elliptical flat-plate is constituted second;First mixes plate 5-1 and second mixes Plate 5-2 is crisscross arranged successively along reaction 1 axial direction of body.
In order that EC is not-easy-to-freeze, wherein at least one material inlet 2 is for being connected with EC raw material feed arrangements EC charging aperture 2-1, remaining material inlet 2 are other raw materials for being connected with other electrolyte preparing raw material feeding devices Charging aperture 2-2;After described EC charging apertures 2-1 is located at other material inlets 2-2 with the link position for reacting body 1;And Mixing after EC charging aperture 2-1 is equipped with plate and penetrates the micropore 8 for mixing plate.
In order that the effect of stirring and outflow electrolyte is more preferably, described reaction body 1 with the angle of inclination of horizontal plane is 20-30°。
A length of 15 meters -16 meters of described reaction body 1, a diameter of 0.5-1 rice.
In order to be able to be easy to production, the effusion meter for controlling feed material feed rates in each material inlet 2, is equipped with.
Drainage screen 11 is provided with described discharging opening 3.
A kind of electrolyte tubular reaction process, it is characterised in that:Comprise the following steps:
The head tank for storing various electrolyte preparing raw materials is connected with corresponding material inlet 2, agent as required Raw material is put in reaction body 1 by amount by each material inlet 2, is then started motor 7 and is driven each rotation shaft part 4 to rotate, position The plate that mixes in reaction 1 cavity of body starts to rotate with the rotation for rotating shaft part 4, makes the original in reaction body 1 Material forms eddy flow, is uniformly mixed the inner various raw materials of addition reaction body 1 and flows at discharging opening 3, finally The electrolyte of mix homogeneously is flowed out from discharging opening 3.
This utility model simply preferably adopts arrangement above, this utility model arrange using rotating speed identical;This Utility model can also be arranged using identical is turned to;Mixed plate of the present utility model can also be other shapes of mixed plate;EC enters Material mouth 2-1 can also before other material inlets 2-2 or among;The angle of described reaction body 1 and horizontal plane For 20-30 °;Can also be other angles.
(2) specific embodiment
Embodiment 1
As shown in figure 1, a kind of electrolyte tubular reactor, it is characterised in that:The reaction of reaction cavity is provided with including inside Body 1, reacts pipe shaft high, one end low dip setting in one end of body 1, and the reaction body 1 is provided with multiple in high one end For adding the material inlet 2 of different electrolytes preparing raw material, the discharging opening for discharging electrolyte is provided with low one end 3;
It is sequentially provided with along reaction 1 axial direction of body in reaction 1 cavity of body multiple around turning that same axial line is rotated Moving axis section 4, it is two neighboring rotate shaft part 4 rotating speed and/or turn to it is different, reaction 1 cavity of body in be additionally provided with positioned at phase Adjacent two rotating speeds for making two neighboring rotation shaft part 4 rotated between shaft part 4 and/or the mutually different transmission dress of steering Put, and for install support it is each rotate shaft part 4 fixed beam 6;Reaction 1 cavity of body in be additionally provided with it is multigroup respectively with each rotary shaft The mixing plate 5 for making the material mix homogeneously in reaction body 1 of 4 coaxial unitary rotations of section;
Described reactor also includes the motor for driving each rotation shaft part 4 rotation outside 1 one end of reaction body 7。
A length of 15 meters -16 meters of described reaction body 1, a diameter of 0.5-1 rice.
The effusion meter for controlling feed material feed rates is equipped with described material inlet.
In order that mixed effect is more preferably, it is ellipse by two and half that a portion rotates the mixing plate arranged on shaft part 4 The little head end of circular slab is connected with each other the first mixing plate 5-1 of composition;Wherein another part rotates the mixing arranged on shaft part 4 Agitating plate mixes plate 5-2 by an elliptical flat-plate is constituted second;First mixes plate 5-1 and second mixes Plate 5-2 is crisscross arranged successively along reaction 1 axial direction of body.
Embodiment 2
As shown in Fig. 2 it is unlike the embodiments above, in order that EC is not-easy-to-freeze, wherein at least one feedstock Mouth 2 is the EC charging aperture 2-1 for being connected with EC raw material feed arrangements, and remaining material inlet 2 is for being electrolysed with other Other material inlets 2-2 of liquid preparing raw material feeding device connection;Described EC charging apertures 2-1 and the connection for reacting body 1 Position is after other material inlets 2-2;And be equipped with the mixing plate after EC charging aperture 2-1 penetrate it is mixed Close the micropore 8 of agitating plate.
Drainage screen 11 is provided with described discharging opening 3.
Embodiment 3
As shown in figure 3, unlike the embodiments above, in order that the material mix homogeneously in pipeline, makes the thing of inside Material forms turbulent flow in mixing, arranges the velocity of rotation difference for rotating shaft part:
Different in order to realize the two neighboring rotating speed for rotating shaft part 4, the actuating device is for making two neighboring rotation The different gear shift of the rotating speed of shaft part 4, described gear shift include being arranged at rotation 4 tail end of shaft part and The second stud gear 9-2 of the first stud gear 9-1 of co-axial synchronous axial system and first stud gear 9-1 engaged transmissions, And with the 3rd change-speed gearing 9-3 of second stud gear 9-2 coaxial synchronous rotation and set with the 3rd gear 9-2 engaged transmissions It is placed in the 4th change-speed gearing 9-4 of next co-axial synchronous axial system for rotating 4 front end of shaft part.
Embodiment 4
As shown in figure 4, unlike the embodiments above, in order that the material mix homogeneously in pipeline, makes the thing of inside Material forms turbulent flow in mixing, arranges the two neighboring rotation direction for rotating shaft part different:
Different in order to realize the two neighboring steering for rotating shaft part 4, the actuating device is for making two neighboring rotation The different gear side steerings of steering of shaft part 4, described gear side steering include being arranged at one rotate 4 tail end of shaft part and Second change gear of the first change gear 10-1 of co-axial synchronous axial system and the first change gear 10-1 engaged transmissions The 3rd change gear 10-3 that 10-2 and the second change gear 10-2 coaxial synchronous are rotated, it is arranged at 4 front end of next rotation shaft part And the 4th change gear 9-4 of co-axial synchronous axial system and engaged transmission become in the 3rd change gear 10-3 and the 4th To the 5th change gear 10-5 between gear 10-4.
Above-listed preferred embodiment, is further described to the purpose of this utility model, technical scheme and advantage, It is be should be understood that to the foregoing is only preferred embodiment of the present utility model, it is not to limit this utility model, all Within spirit of the present utility model and principle, any modification, equivalent substitution and improvements made etc. should be included in practical Within new protection domain.

Claims (9)

1. a kind of electrolyte tubular reactor, it is characterised in that:The reaction body (1) of reaction cavity, reaction are provided with including inside In one end, high, one end low dip is arranged the pipe shaft of body (1), and reaction body (1) is provided with multiple for adding in high one end Enter the material inlet (2) of different electrolytes preparing raw material, the discharging opening (3) for discharging electrolyte is provided with low one end;
It is sequentially provided with along reaction body (1) axial direction in reaction body (1) cavity multiple around turning that same axial line is rotated Moving axis section (4), it is two neighboring rotate shaft part (4) rotating speed and/or turn to it is different, reaction body (1) cavity in be additionally provided with It is different positioned at the two neighboring rotating speed for making two neighboring rotation shaft part (4) rotated between shaft part (4) and/or steering Actuating device and for install support it is each rotate shaft part (4) fixed beam (6);It is additionally provided with reaction body (1) cavity multigroup Respectively with it is each rotate shaft part (4) coaxial unitary rotation for the mixing that makes the material in reaction body (1) mix homogeneously Plate (5);
Described reactor also includes each rotating shaft part (4) motor that rotates for driving outside reaction body (1) one end (7)。
2. a kind of electrolyte tubular reactor according to claim 1, it is characterised in that:The actuating device is for making The different gear shift of the two neighboring rotating speed for rotating shaft part (4), described gear shift include being arranged at one Rotate shaft part (4) tail end and the first stud gear (9-1) of co-axial synchronous axial system, engage with first stud gear (9-1) The second stud gear (9-2) of transmission, and second stud gear (9-2) coaxial synchronous rotate the 3rd change-speed gearing (9-3), and With the 3rd gear (9-2) engaged transmission and be arranged at it is next rotate shaft part (4) front end co-axial synchronous axial system the 4th Change-speed gearing (9-4).
3. a kind of electrolyte tubular reactor according to claim 1, it is characterised in that:The actuating device is for making The different gear side steering of the two neighboring steering for rotating shaft part (4), described gear side steering include being arranged at one Rotate shaft part (4) tail end and first change gear (10-1) of co-axial synchronous axial system, and the first change gear (10-1) nibble Close transmission the second change gear (10-2), and the second change gear (10-2) coaxial synchronous rotate the 3rd change gear (10- 3), be arranged at it is next rotation shaft part (4) front end and the 4th change gear (10-4) of co-axial synchronous axial system, and engagement The 5th change gear (10-5) being transmitted between the 3rd change gear (10-3) and the 4th change gear (10-4).
4. a kind of electrolyte tubular reactor according to claim 1, it is characterised in that:A portion rotates shaft part (4) the mixing plate arranged on is connected with each other the first mixing plate (5- for constituting by the little head end of two half elliptic plates 1);Wherein another part rotates the mixing plate arranged on shaft part (4) and is stirred by the second mixing that an elliptical flat-plate is constituted Mix plate (5-2);First mixing plate (5-1) and the second mixing plate (5-2) are handed over successively along reaction body (1) axial direction It is wrong to arrange.
5. a kind of electrolyte tubular reactor according to claim 1, it is characterised in that:
Wherein at least one material inlet (2) is the EC charging apertures (2-1) for being connected with EC raw material feed arrangements, remaining Material inlet (2) is other material inlets (2-2) for being connected with other electrolyte preparing raw material feeding devices;It is described EC charging apertures (2-1) with reaction body (1) link position be located at other material inlets (2-2) after;And enter positioned at EC Mixing after material mouth (2-1) is equipped with plate and penetrates the micropore (8) for mixing plate.
6. a kind of electrolyte tubular reactor according to claim 1, it is characterised in that:Described reaction body (1) with The angle of inclination of horizontal plane is 20-30 °.
7. a kind of electrolyte tubular reactor according to claim 1, it is characterised in that:Described reaction body (1) A length of 15 meters -16 meters, a diameter of 0.5-1 rice.
8. a kind of electrolyte tubular reactor according to claim 1, it is characterised in that:In each material inlet (2) It is provided with the effusion meter for controlling feed material feed rates.
9. a kind of electrolyte tubular reactor according to claim 1, it is characterised in that:Set in described discharging opening (3) There is drainage screen (11).
CN201620963318.4U 2016-08-29 2016-08-29 Electrolyte tubular reactor Withdrawn - After Issue CN206027504U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201620963318.4U CN206027504U (en) 2016-08-29 2016-08-29 Electrolyte tubular reactor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201620963318.4U CN206027504U (en) 2016-08-29 2016-08-29 Electrolyte tubular reactor

Publications (1)

Publication Number Publication Date
CN206027504U true CN206027504U (en) 2017-03-22

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201620963318.4U Withdrawn - After Issue CN206027504U (en) 2016-08-29 2016-08-29 Electrolyte tubular reactor

Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106378073A (en) * 2016-08-29 2017-02-08 宁德市凯欣电池材料有限公司 Electrolyte tubular reactor and reaction method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106378073A (en) * 2016-08-29 2017-02-08 宁德市凯欣电池材料有限公司 Electrolyte tubular reactor and reaction method
CN106378073B (en) * 2016-08-29 2018-04-13 宁德市凯欣电池材料有限公司 Electrolyte tubular reactor and reaction method

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Granted publication date: 20170322

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