CN206008466U - A kind of new gas recovery system for oil - Google Patents

A kind of new gas recovery system for oil Download PDF

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Publication number
CN206008466U
CN206008466U CN201620842382.7U CN201620842382U CN206008466U CN 206008466 U CN206008466 U CN 206008466U CN 201620842382 U CN201620842382 U CN 201620842382U CN 206008466 U CN206008466 U CN 206008466U
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China
Prior art keywords
gas
oil
tank
heat exchanger
drainer
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Expired - Fee Related
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CN201620842382.7U
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Chinese (zh)
Inventor
陈桂华
赵修华
刘岭
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HUNAN CHANGJIANG PETROCHEMICAL ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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HUNAN CHANGJIANG PETROCHEMICAL ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Abstract

This utility model is related to Investigation of Petroleum Vapor Recovery Technology field, more particularly to a kind of new gas recovery system for oil;Including oil-gas transportation device, the oil-gas transportation device is connected with off-gas buffer tank by pipeline, the off-gas buffer tank is connected with preliminary drainer, the preliminary drainer is connected with water tank containing greasy dirt and deep condensation tank, the deep condensation tank is connected with lime set storage tank, nitrogen pot and liquid nitrogen storage tank, the preliminary drainer is connected with plate type heat exchanger, the plate type heat exchanger is connected with electric heater, the electric heater is connected with catalytic reactor, and the catalytic reactor is connected with chimney by a gas heat exchanger;Oil quality that this utility model is condensed out is high, and without impurities left, and it is directly perceived directly to measure yield economic benefit, purifies process safety, efficiently.

Description

A kind of new gas recovery system for oil
Technical field
This utility model is related to Investigation of Petroleum Vapor Recovery Technology field, more particularly to a kind of new gas recovery system for oil.
Background technology
Oil and products thereof is the mixture of multiple Hydrocarbon, and wherein vapour pressure is higher at normal temperatures for light component, pole Volatile, therefore produce to oil depot in the whole storage and transport process of gas station from refinery in oil product, it is widely present oil evaporation damage The problem of consumption.Oil product evaporating loss brings many serious harms to enterprise and society, such as reduces oil quality, environmental pollution, money Source wastes, causes disaster hidden-trouble and harm personal safety etc..Therefore oil vapour is carried out reclaiming imperative, two petroleum vapor recoveries Device is then indispensable conveyance system facility in Petroleum Production, accumulating and transport.
Currently, national departments concerned increasingly payes attention to the improvement to oil vapour pollution and the enforcement of Investigation of Petroleum Vapor Recovery Technology, and will Which combines the important process as recycling economy with clean manufacturing, the utilization of resources, qualified discharge.Strengthen promoting by making laws Dynamics, has just continuously promulgated multiple with the execution standards and norms for forcing effect for only 2007.Such as:《Storage tank farm atmospheric pollution Thing discharge standard》(GB20950-2007)、《Gasoline transports atmosphere pollutants emission standardses》(GB20951-2007)、《Gas station Atmosphere pollutants emission standardses》(GB20952-2007)、《Product oil management of wholesale enterprises technical specification》(SB/T10446- 2007)、《Product oil storage enterprise management technique specification》(SB/T10445-2007)、《Product oil retailer management technique rule Model》(SB/T10390-2007)、《Gas recovery system for oil engineering technology directive/guide》(Q/SH0117-20070、《Environmental impact assessment skill Art directive/guide》(HJ/T2.2-2007)、《Oil depot, gas station's air contaminant treatment project acceptance inspection inspection specifications》(HJ/T431- 2008) etc., especially promulgated by Environmental Protection Department and State Administration for Quality Supervision and Inspection and Quarantine's joint in 2015《Petroleum refining Emission of industrial pollutants standard》(GB31570-2015), VOC emission standard is put forward higher requirement.
The external research work for having started to Investigation of Petroleum Vapor Recovery Technology from the sixties in 20th century, has the oil of multiple maturations at present Gas recovery technology.In the technical field, China falls behind foreign countries more than 20 years, in order to improve the research water of China's Investigation of Petroleum Vapor Recovery Technology Flat, accelerate the localization process of advanced device for recovering oil and gas, need the advanced technology for constantly using for reference and absorbing developed country, improve The research of itself and production capacity.Internal and international at present conventional Investigation of Petroleum Vapor Recovery Technology includes following several classes, has his own strong points Also there is its drawback.
1st, direct combustion gasses recovery technology
Directly combustion method is a kind of method using thermal oxidation technique process evaporation oil gas (organic exhaust gas), its principle be by The gas containing hydrocarbon direct oxidation burning produced in storage and transport process, after the carbon dioxide of generation of burning, water and air are as process Purification gas are directly discharged.The technological process is only used as a kind for the treatment of measures of control exhaust of oil, but can not reclaim oil product, because Without economic benefit.
2nd, condensed oil-gas recovery technology
Method of the condensation method device for recovering oil and gas typically using multistage continuous coo1ing oil gas is made reducing the temperature of Volatile Gas Cohesion reclaimed for liquid, its step is typically realized by pre-cooling, mechanical refrigeration, liquid nitrogen refrigerating etc..Now petroleum vapor recovery Rate is up to 99%.
3rd, adsorb Investigation of Petroleum Vapor Recovery Technology
Adsorption separation technology in every profession and trade is widely used and is developed over nearest twenty or thirty year, becomes a kind of Particularly important gas separation.Absorption method separates and recovers the principle comparative maturity of oil gas, and adsorption separation process is using mixed The strong and weak difference of adhesion between each component and adsorbent in compound, makes hardly possible absorption skill detached with easy absorbed component in mixture Art.
Activated carbon adsorption can make the concentration of oil gas vent be down to very low standard, and assimilation effect is relatively good, but is because The inlet concentration of oil gas is larger, is adsorbed as exothermic reaction, once there is active carbon bed temperature runaway, pipeline is connected with entrucking trestle work again Connect, be likely to result in security incident.Therefore Tokyo, Japan regulations of rules, gas concentration >=1vol%, prohibits the use of combustibility Acticarbon, in Japan prohibits the use of membrane separation process and active carbon adsorption Investigation of Petroleum Vapor Recovery Technology.
4th, thin film selected area update strategy recovery technology
Oil vapour and the membrance separation of air Mixture be according to different gas at various speeds, due to diffusibility with molten Difference between Xie Du, using polymeric membrane to gasoline component in oil gas preferentially through the characteristics of, allow the mixed of gasoline component/air Gas is closed in the case where certain pressure reduction is promoted, technique is relatively easy, but initial investment is costly.
5th, Investigation of Petroleum Vapor Recovery Technology is absorbed
Absorption process is the difference using mixed gas dissolubility in a solvent, realizes that by solution absorption oil gas oil gas is returned The technology of receipts.The general absorbent sprayed using oil gas and from absorption tower top carries out counter current contacting, and absorbent enters to hydrocarbon component Row selective absorbing, unabsorbed gases are discharged through spark arrester.At present, absorption process generally uses 3 kinds of different absorbent, i.e., Light diesel fuel, low temp. gasline and organic solvent.
The above-mentioned five kinds of Investigation of Petroleum Vapor Recovery Technology of Investigation of Petroleum Vapor Recovery Technology (device) Integrated comparative, are more generally adopted at present in the world It is absorption process, absorption method and condensation method, membrane separation process application is fewer, only has application in the minority such as Germany area.Because of oil gas Concentration is big, and possesses larger recovery value, and exhaust emission standard is high, is therefore only difficult to realize row up to standard by above-mentioned single technique Put.
Utility model content
This utility model is directed to drawbacks described above, there is provided a kind of new gas recovery system for oil, which can solve current technology Problem.
For solving above-mentioned purpose, this utility model provides a kind of new gas recovery system for oil, including oil-gas transportation device, The oil-gas transportation device is connected with off-gas buffer tank by pipeline, and the off-gas buffer tank is connected with preliminary drainer, described Preliminary drainer is connected with water tank containing greasy dirt and deep condensation tank, and the deep condensation tank is connected with lime set storage tank, nitrogen pot And liquid nitrogen storage tank, the preliminary drainer is connected with plate type heat exchanger, and the plate type heat exchanger is connected with electric heater, the electricity Heater is connected with catalytic reactor, and the catalytic reactor is connected with chimney by a gas heat exchanger.
Further, spark arrester and gas flowmeter, institute are provided between the oil-gas transportation device and off-gas buffer tank State.
Compared with prior art, this utility model has the benefit that this utility model:
1st, this utility model gas recovery system for oil is best suitable for the property of oil product, and the technique of petroleum refining industry's petroleum refining is just It is to carry out the processes such as " heating distillation ", " vaporization-liquefaction " using the transconversion into heat property of oil under different temperature and pressures, and cold The know-why of solidifying method petroleum vapor recovery is consistent, is best suitable for adopting condensation method for the thermal property and migration characteristic of oil gas Process.
2nd, this utility model gas recovery system for oil feature is simple and clear, direct, be not required to secondary processes.The oil quality being condensed out Height, without impurities left, and it is directly perceived directly to measure yield economic benefit.
3rd, liquid nitrogen refrigerating is compacter relative to traditional mechanical compression refrigeration device, solves explosion-proof asking from source Topic, is not easily blocked, it is easy to safeguard, toggle speed is fast, can tackle frequent starting and stop operation;
4th, the reaction of CO catalytic combustion technologies is thorough, it is ensured that the real-time qualified discharge of tail gas.
5th, be suitable for VOC species up to hundreds of:Such as dichloromethane, monochloro methane, freon, ammonia, vinyl chloride, epoxy third Alkane, oxirane, acetone, methanol, toluene, hexamethylene, ethyl acetate etc.;
6th, process safety, efficiently is purified;
7th, advanced liquid nitrogen heat exchanger, solves ordinary heat exchanger tired by frosting closure;
8th, can be suitable for that a variety of working conditions, particularly load variations are big or the operating mode of intermittent duty;
9th, cooldown rate faster, can be cooled to low temperature in 1 hour;
10th, group technology can meet the various discharge standards of China, such as oil depot standard and atmospheric pollution comprehensive discharge standard;
11st, device is skid-mounted type equipment, and floor space is little, installs simple.
12nd, resource recovery is high, real resource reclaim technology..
Description of the drawings
Fig. 1 is a kind of new gas recovery system for oil structural representation of this utility model.
Specific embodiment
The technical solution of the utility model is described in detail below with reference to accompanying drawing, so that those skilled in the art are more preferable Understand this programme.
Shown in Figure 1, this utility model provides a kind of new gas recovery system for oil, including oil-gas transportation device 1, institute State oil-gas transportation device 1 and off-gas buffer tank 2 is connected with by pipeline, the off-gas buffer tank 2 is connected with preliminary drainer 3, institute State preliminary drainer 3 and be connected with water tank containing greasy dirt 4 and deep condensation tank 5, the deep condensation tank 5 be connected with lime set storage tank 6, Nitrogen pot 7 and liquid nitrogen storage tank 8, the preliminary drainer 3 are connected with plate type heat exchanger 9, and the plate type heat exchanger 9 is connected with electricity and adds Hot device 10, the electric heater 10 are connected with catalytic reactor 11, and the catalytic reactor 11 is connected by a gas heat exchanger 12 It is connected to chimney 13.
Further, spark arrester 14 and gas flowmeter are provided between the oil-gas transportation device and off-gas buffer tank 15, pressure transducer 16 is provided with the off-gas buffer tank 2.
For oil-gas transportation device receives the oil gas from different places, can off-gas buffer tank be first set on pipeline, be entered Spark arrester and gas flowmeter are set before entering surge tank, pressure transducer is set on off-gas buffer tank, monitoring at any time carrys out gas gas Amount and pressure, and starting signal and operating load are provided according to pressure and effusion meter.
The oil gas for gathering enters preliminary drainer through off-gas buffer tank, and the low-temperature receiver in preliminary drainer is liquid nitrogen, right Oil gas is tentatively cooled down first, is cooled to less than 5 DEG C, and the part oil gas for condensing out and moisture enter oil-polluted water tank, can Unified recovery.Oil gas after preliminary drainer is just cold enters deep condensation tank, and deep condensation tank is minimum to be cooled to -100 DEG C, Oil gas under cooling collects entrance lime set storage tank respectively, periodically discharges into into specified storage tank outward, and outer comb line sets effusion meter.
Carry out after heat exchange carrying out import oil gas through the oil gas gas after deep condensation tank deep cooling through plate type heat exchanger pre- Cold, to save the usage amount of liquid nitrogen.Now the oil gas of outer row is low temperature oil gas, and introducing low-pressure steam carries out pre- intensification to oil gas, So that the temperature of outer oil extraction gas is warming up to 50 DEG C or so.
Oil gas after through deep cooling enters catalytic oxidation unit, is preheated to 300 DEG C or so through electric heater, enters catalytic reaction Device, under catalyst action, there is redox reaction and generate carbon dioxide and water in the hydro carbons in waste gas under low temperature state, most Whole discharging directly into atmosphere.
Waste gas after catalytic reaction is preheated to initial oil gas through gas heat exchanger, realizes that internal heat is circulated, reaction After beginning, electric heater need not be then turned on, you can realize thermal cycle.During catalytic reaction bed overtemperature, can by bypass adjust or It is passed through the fresh wind of room temperature to lower the temperature bed, it is ensured that operation safety.
This utility model arrange on-line detector, to enter device for recovering oil and gas, condensation after enter catalytic oxidation unit before, And evacuation port up to standard carries out real-time monitoring, it is ensured that enter catalytic oxidation unit for low concentration oil gas, such as exceeded or condensation is single First EGT exception, then emergency opening exhaust gas bypass, discharging directly into atmosphere.
If this utility model recovery system detects preliminary drainer or deep condensation tank temperature anomaly or condensing unit goes out Mouthful exhaust gas concentration is extremely high, then system automatic switchover import oil gas direct exhaust chimney, and the fresh wind blower fan of CO systems is awaited orders startup, it is ensured that Bed temperature maintains design and asks in interval.The nitrogen produced after liquid nitrogen gasification is set to 0.85Mpa, is directly incorporated into owner's nitrogen Gas pipe network, arranges nitrogen buffer tank before being incorporated to Nitrogen pipe network.

Claims (2)

1. a kind of new gas recovery system for oil, it is characterised in that:Including oil-gas transportation device, the oil-gas transportation device passes through Pipeline is connected with off-gas buffer tank, and the off-gas buffer tank is connected with preliminary drainer, and the preliminary drainer is connected with oil-containing Dirty water tank and deep condensation tank, the deep condensation tank are connected with lime set storage tank, nitrogen pot and liquid nitrogen storage tank, described tentatively cold Solidifying tank is connected with plate type heat exchanger, and the plate type heat exchanger is connected with electric heater, and the electric heater is connected with catalytic reaction Device, the catalytic reactor are connected with chimney by a gas heat exchanger.
2. a kind of new gas recovery system for oil as claimed in claim 1, it is characterised in that:The oil-gas transportation device with useless Spark arrester and gas flowmeter is provided between gas surge tank, is provided with pressure transducer on the off-gas buffer tank.
CN201620842382.7U 2016-08-04 2016-08-04 A kind of new gas recovery system for oil Expired - Fee Related CN206008466U (en)

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Application Number Priority Date Filing Date Title
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107485979A (en) * 2017-08-18 2017-12-19 合肥丰洁生物科技有限公司 A kind of volatile organic matter film separation system
CN108211781A (en) * 2017-12-29 2018-06-29 萍乡市德润科技有限责任公司 A kind of oil gas catalytic decomposition cleaning system and method
CN108905497A (en) * 2018-08-31 2018-11-30 江苏新久扬环保设备科技有限公司 A kind of oil gas purification device and technique
CN108949216A (en) * 2018-09-19 2018-12-07 成都深冷液化设备股份有限公司 A kind of system and method for high efficiente callback oil gas
CN109847398A (en) * 2019-03-21 2019-06-07 成都华气厚普机电设备股份有限公司 A kind of liquid nitrogen spraying device for recovering oil and gas and method
CN110182745A (en) * 2019-06-27 2019-08-30 周志明 A kind of gas recovery system for oil using cool-heat-exchanger
CN110871024A (en) * 2018-09-03 2020-03-10 中国石油化工股份有限公司 Oil gas tank oil gas treatment device and oil gas treatment method based on liquid nitrogen condensation
CN112143867A (en) * 2019-06-28 2020-12-29 南京馥安投资管理有限公司 Oil gas recovery device and method in heat treatment process
CN116549996A (en) * 2023-06-05 2023-08-08 青岛金海晟环保设备有限公司 Energy-saving VOCs oil gas recovery treatment system and recovery method

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107485979A (en) * 2017-08-18 2017-12-19 合肥丰洁生物科技有限公司 A kind of volatile organic matter film separation system
CN108211781A (en) * 2017-12-29 2018-06-29 萍乡市德润科技有限责任公司 A kind of oil gas catalytic decomposition cleaning system and method
CN108905497A (en) * 2018-08-31 2018-11-30 江苏新久扬环保设备科技有限公司 A kind of oil gas purification device and technique
CN110871024A (en) * 2018-09-03 2020-03-10 中国石油化工股份有限公司 Oil gas tank oil gas treatment device and oil gas treatment method based on liquid nitrogen condensation
CN110871026A (en) * 2018-09-03 2020-03-10 中国石油化工股份有限公司 Waste gas treatment device and waste gas treatment method based on liquid nitrogen condensation
CN108949216A (en) * 2018-09-19 2018-12-07 成都深冷液化设备股份有限公司 A kind of system and method for high efficiente callback oil gas
CN109847398A (en) * 2019-03-21 2019-06-07 成都华气厚普机电设备股份有限公司 A kind of liquid nitrogen spraying device for recovering oil and gas and method
CN109847398B (en) * 2019-03-21 2023-08-29 厚普清洁能源(集团)股份有限公司 Liquid nitrogen spraying oil gas recovery device and method
CN110182745A (en) * 2019-06-27 2019-08-30 周志明 A kind of gas recovery system for oil using cool-heat-exchanger
CN112143867A (en) * 2019-06-28 2020-12-29 南京馥安投资管理有限公司 Oil gas recovery device and method in heat treatment process
CN112143867B (en) * 2019-06-28 2022-03-15 南京五域化工科技有限公司 Oil gas recovery device and method in heat treatment process
CN116549996A (en) * 2023-06-05 2023-08-08 青岛金海晟环保设备有限公司 Energy-saving VOCs oil gas recovery treatment system and recovery method

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CF01 Termination of patent right due to non-payment of annual fee
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Granted publication date: 20170315

Termination date: 20170804