CN205982025U - High temperature water vapor oxidation unit that cinder can be collected - Google Patents

High temperature water vapor oxidation unit that cinder can be collected Download PDF

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Publication number
CN205982025U
CN205982025U CN201620600694.7U CN201620600694U CN205982025U CN 205982025 U CN205982025 U CN 205982025U CN 201620600694 U CN201620600694 U CN 201620600694U CN 205982025 U CN205982025 U CN 205982025U
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CN
China
Prior art keywords
oxide skin
vapor oxidation
collecting box
temperature vapor
collectable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201620600694.7U
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Chinese (zh)
Inventor
句光宇
康朝阳
乔梁
王东
王昊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Datang Corp Science and Technology Research Institute Co Ltd Huazhong Branch
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China Datang Corp Science and Technology Research Institute Co Ltd Huazhong Branch
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Priority to CN201620600694.7U priority Critical patent/CN205982025U/en
Application granted granted Critical
Publication of CN205982025U publication Critical patent/CN205982025U/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The utility model relates to a high temperature water vapor oxidation unit that cinder can be collected. A high temperature water vapor oxidation unit that cinder can be collected, includes the high temperature water vapor oxidation furnace, still including the cinder collecting box that is used for holding the sample, the cinder collecting box has the case lid, be equipped with the bearing structure who is used for supporting the cinder collecting box in the furnace of high temperature water vapor oxidation furnace, the cinder collecting box have make its inner chamber with the communicating steam inlet of furnace of high temperature water vapor oxidation furnace and the diapire that is used for accepting the cinder that drops. During the use, pass through the cinder collecting box in bearing structure in the furnace sets up furnace, simultaneously, steam inlet on the cinder collecting box can make vapor get into inside and sample contact, can satisfy test requirement, and the diapire of cinder collecting box can be used for accepting the cinder that comes off, realizes being convenient for study simple structure, convenient to use to the collection of cinder in experimental accomplishing.

Description

A kind of collectable high-temperature vapor oxidation unit of oxide skin
Technical field
This utility model is related to a kind of oxide skin collectable high-temperature vapor oxidation unit.
Background technology
For reducing coal consumption, reducing discharge and improving the thermal efficiency, develop supercritical and the ultra supercritical machine of high efficiency high parameter Group has become the main trend of countries in the world instantly, and develops the key technology of high efficiency supercritical and ultra supercritical coal-fired unit One of be exactly to solve the problems, such as heating surface tubes in boilers, header, steam-water separator and jet chimney heat resisting steel.Boiler blasting, steaming In the design process it is desirable to minimum wall thickness (MINI W.) is more than a certain numerical value, general pipe design wall thickness is much larger than minimum wall thickness (MINI W.) in steam pipe road etc. Value, but pipeline, in running, is constantly subject to steam oxidation or sulfur corrosion etc. to form oxide or sulfide on surface, Oxide and sulfide constantly comes off and causes trommel, produces bulge, and then reveal under stress, therefore, real Test room and study vapor corrosion mechanism and sulfur corrosion mechanism under tube metal high temperature etc., understand fully high temperature corrosion mechanism, can be very big Reduce the formation of corrosion product, thus reducing the corrosion rate of tube wall.
Application No. 201110421972.4, application publication number are that the Chinese patent of CN 102539309 A discloses one kind Metal material high temperature water vapor-phase oxidation experimental provision, is capable of the steam oxidation feelings of simulation study tube metal in laboratory conditions Condition.This device include shell, with in-furnace temperature sensor temperature control equipment, with control valve waterworks, with And it is located at water vapor generation device and the high-temperature vapor oxidation furnace with bell, waterworks and the vapor generation of inside the shell Device has water pipe to connect, and has steam channel to connect, in-furnace temperature passes between water vapor generation device and high-temperature vapor oxidation furnace Sensor has control line to electrically connect with temperature control equipment, and temperature control equipment controls high-temperature vapor by resistance wire control circuit The temperature of the resistive heater in oxidation furnace, bell has steam outlet and in-furnace temperature sensor jack and is provided with sample Hook, water vapor generation device and high-temperature vapor oxidation furnace equal insulation material parcel.During use, sample is passed through heat resisting steel Silk hangs on below sample hook, relies on water vapor generation device to produce vapor and vapor is passed through in steam oxidation stove Thus realizing steam oxidation simulation.
But, existing experimental provision in order to reduce test period, often improves test temperature, then passes through when using Corresponding conversion obtains the test period under tube wall running temperature, and temperature is too high that oxide skin can be led to come off, and this just gives heat-resisting The mensure of the distribution of the mensure of steel oxidation kinetic curve and oxide skin, composition and structure brings error or mistake.Therefore, exist When carrying out the test of higher temperature steam oxidation, laboratory needs a kind of a set of oxide skin collectable high-temperature vapor oxidation dress Put, high-temperature vapor oxidation test can be carried out, the oxide skin coming off can collected in oxidizing process, so that in oxidation examination again Studied after testing end.
Utility model content
The purpose of this utility model is to provide a kind of a kind of oxide skin that can collect oxide skin in oxidizing process can receive The high-temperature vapor oxidation unit of collection.
For achieving the above object, the technical solution adopted in the utility model is:A kind of collectable high-temperature water of oxide skin steams Gas oxidation unit, including high-temperature vapor oxidation furnace, also includes the oxide skin collecting box for holding sample, described oxide skin is received Header has case lid;It is provided with the supporting construction for supporting oxide skin collecting box in the burner hearth of high-temperature vapor oxidation furnace, described Oxide skin collecting box has to be made steam inlet that its inner chamber communicated with the burner hearth of described high-temperature vapor oxidation furnace and is used for accepting The diapire of the oxide skin coming off.
Described steam inlet is the through hole being arranged on described case lid.
Described through hole is evenly arranged on case lid.
Described case lid is pull open-close type case lid.
The side wall of described oxide skin collecting box is provided with the sample peg for hanging sample.
Described sample peg is ceramic bar, and the support that the side wall of described oxide skin collecting box is provided with for ceramic bar insertion is inserted Hole.
A kind of collectable high-temperature vapor oxidation unit of described oxide skin includes waterworks, the going out of described waterworks The mouth of a river is arranged on the burner hearth bottom of described high-temperature vapor oxidation furnace.
Described waterworks are provided with more than two, and the outlet of each waterworks is uniformly arranged in burner hearth bottom.
It is fixed with gripper shoe in described burner hearth, described gripper shoe is evenly equipped with steam passage holes, described supporting construction is arranged on In described gripper shoe and be provided with more than at two, each supporting construction is evenly arranged around the axis of burner hearth.
Described high-temperature vapor oxidation furnace has bell, described bell be provided with stretch into for temperature sensor same in burner hearth When for vapor discharge perforate, described perforate eccentric setting with to the corresponding steam inlet on oxide skin collecting box below Correspond to up and down.
This utility model adopts technique scheme, and oxide skin can be collected high-temperature vapor oxidation unit and be included for holding Oxide skin collecting box is arranged in burner hearth by the supporting construction in burner hearth during use by the oxide skin collecting box of sample, meanwhile, Steam inlet on oxide skin collecting box can make vapor enter internal and sample contacts, disclosure satisfy that test requirements document, and oxygen Change skin collecting box diapire can be used for accept the oxide skin coming off, case lid it can be avoided that oxide skin come off splashing it is ensured that test The accuracy of result, realizes the collection to oxide skin while completing to test, and is convenient for studying, structure is simple, user Just.
Brief description
Fig. 1 is a kind of knot of an embodiment of the collectable high-temperature vapor oxidation unit of oxide skin in this utility model Structure schematic diagram;
Fig. 2 is the structural representation of oxide skin collecting box in Fig. 1.
The each reference of in figure is corresponding entitled:1- storage tank, 2- Water flow adjusting valve, 3- water-supply-pipe, 4- bell, 5- Temperature sensor jack, 6- temperature sensor, 7- attemperating unit, 8- burner hearth, 9- resistance wire, 10- gripper shoe, 11- fixes fence, 12- heat-preservation cotton, 13- metal shell, 14- refractory ceramics case, 15- case lid, 16- steam inlet, 17- supports jack, 18- sample Peg.
Specific embodiment
Below in conjunction with the accompanying drawings embodiment of the present utility model is described further.
A kind of one enforcement such as Fig. 1 ~ Fig. 2 institute of oxide skin of this utility model collectable high-temperature vapor oxidation unit Show, including high-temperature vapor oxidation furnace, for the waterworks to the water supply of high-temperature vapor oxidation furnace with for containing sample Refractory ceramics case 14.
High-temperature vapor oxidation furnace includes metal shell 13, burner hearth 8 and the guarantor being arranged between burner hearth 8 and metal shell 13 Warm cotton 12.Burner hearth 8 is main to be made up of resistance wire 9, the outer silk silicon carbide crucible of well formula and well formula iron sheet inner bag, relies on resistance wire 9 to enter Row heating, resistance wire 9 realizes temperature control by attemperating unit 7.The upper opening of burner hearth 8 goes out to be provided with bell 4, and bell 4 sets Have and stretch in burner hearth 8 for temperature sensor 6 and perforate that unnecessary confession vapor is discharged.
Waterworks are provided with two groups, and each group waterworks all include storage tank 1, Water flow adjusting valve 2 and water-supply-pipe 3, defeated The outlet of water pipe 3 is arranged on the bottom of burner hearth 8, can be supplied water by Water flow adjusting valve 2, enter into high-temperature vapor oxidation furnace And produce required vapor in specimen.Water flow adjusting valve 2 is capable of the adjustment of both sides output, makes vapor equal Even, constant.
Refractory ceramics case 14 as oxide skin collecting box, hang including casing, case lid 15 and for hanging the sample of sample Bar 18.The diapire of refractory ceramics case 14 is used for accepting the oxide skin coming off, it is to be appreciated that diapire herein refers to set on casing The diapire that can accept the oxide skin coming off put, if in being separately provided in casing for accepting the holding of oxide skin coming off Connect wall, then diapire refers to this undertaking wall.The one of which opposing sidewalls of casing are provided with two apertures, constitute for supporting Sample peg 18 supports jack 17.Sample peg 18 adopts refractory ceramics thin bar, punches, be then set to during use on sample In refractory ceramics thin bar, sample can be prevented effectively from and contact with refractory ceramics case 14, improve the accurate of coupon results Property.For the ease of the making of refractory ceramics case 14, operation and maintenance, the case lid 15 of refractory ceramics case 14 is pull open-close type Case lid 15, by the slide assembling on casing.Four steam passage holes are evenly equipped with case lid 15, on the one hand make temperature sensor 6 can extend in refractory ceramics case 14, so that vapor is uniformly distributed in refractory ceramics case 14.Oxide skin Collecting box using the refractory ceramics case 14 with case lid 15 it can be avoided that oxide skin come off splashing it is ensured that result of the test accurate Property.
It is provided with the gripper shoe 10 for supporting refractory ceramics case 14 in the burner hearth 8 of high-temperature vapor oxidation furnace, support It is evenly equipped with plate 10 and fixes fence 11 everywhere, be capable of the positioning to refractory ceramics case 14 and fixation.During use, often locate solid Determine a refractory ceramics case 14 can be placed on fence 11.It is evenly equipped with steam passage holes in gripper shoe 10, burner hearth 8 bottom can be made The vapor producing is evenly distributed in the top of burner hearth 8, and then makes the distribution of the vapor in each refractory ceramics case 14 more Plus uniformly.
Corresponding with the set location of high-temperature vapor oxidation furnace, stove is stretched in the confession temperature sensor 6 that bell 4 is provided with bias Temperature sensor jack 5 in thorax 8.During use, temperature sensor 6 can pass through temperature sensor jack 5 and refractory ceramics Steam passage holes on the case lid 15 of case 14 are inserted the inside of a refractory ceramics case 14, make the temperature data recording more Accurately, and then realize more precise control to temperature.Meanwhile, during use, temperature sensor jack 5 can be for unnecessary vapor Discharge in burner hearth 8, maintain vapor in burner hearth 8 constant.
During work, open bell 4, respectively by four punching samples through sample peg 18 be vacantly placed in four high temperature resistant In ceramic case 14, then four refractory ceramics casees 14 are put in the fixing fence 11 of setting in gripper shoe 10, cover bell 4, Place temperature sensor 6, turn on the power switch and attemperating unit 7, temperature required by attemperating unit 7 setting test, and make Burner hearth 8 is in heated condition, rises to after uniform temperature after temperature, opens Water flow adjusting valve 2, adjusts flow, makes water uniform Flow in burner hearth 8, after temperature reaches design temperature in burner hearth 8, the start recording time, after certain time to be oxidized, close water Flow control valve 2, turn off the power switch and attemperating unit 7, make temperature natural cooling in atmosphere in burner hearth 8, treat burner hearth 8 interior temperature Degree when dropping to indoor temperature, opens bell 4, takes out refractory ceramics case 14, takes out the sample after oxidation and to clear up collection resistance to The oxide skin coming off in high-temperature ceramicss case 14.
In the above-described embodiments, sample is to be suspended in high-temperature ceramicss case by sample peg 18, and for propping up in burner hearth 8 The supporting construction of support oxide skin collecting box is the gripper shoe 10 being provided with steam passage holes.In other embodiment of the present utility model, Oxide skin collecting box can also replace with other forms, be capable of the contact that sample is with vapor and be provided with for accept come off Oxide skin diapire, for example, there is the collecting box of case lid 15 of hinged folding form, columnar collecting box etc..And Sample can also be arranged in collecting box using other forms, is capable of the installation to sample, such as in collecting box Hook of the prior art is arranged on tank wall.Furthermore, the gripper shoe 10 in burner hearth 8 can also replace with other forms, for example, prop up Support net, support screen, support bar etc., are supported to oxide skin collecting box for another example in the form of hanging.
In addition, directly utilizing high-temperature vapor oxidation furnace to produce vapor in above-described embodiment, in other embodiments, Single water vapor generation device can be set, for example with the water being arranged in background technology below high-temperature vapor oxidation furnace Steam generating device.

Claims (10)

1. the collectable high-temperature vapor oxidation unit of a kind of oxide skin, including high-temperature vapor oxidation furnace it is characterised in that:Also Including the oxide skin collecting box for holding sample, described oxide skin collecting box has case lid;The stove of high-temperature vapor oxidation furnace It is provided with the supporting construction for supporting oxide skin collecting box, described oxide skin collecting box has makes its inner chamber and described high temperature in thorax The steam inlet that the burner hearth of steam oxidation stove communicates and the diapire for accepting the oxide skin coming off.
2. a kind of collectable high-temperature vapor oxidation unit of oxide skin according to claim 1 it is characterised in that:Described Steam inlet is the through hole being arranged on described case lid.
3. a kind of collectable high-temperature vapor oxidation unit of oxide skin according to claim 2 it is characterised in that:Described Through hole is evenly arranged on case lid.
4. a kind of oxide skin collectable high-temperature vapor oxidation unit according to claim 1 or 2 or 3, its feature exists In:Described case lid is pull open-close type case lid.
5. a kind of oxide skin collectable high-temperature vapor oxidation unit according to claim 1 or 2 or 3, its feature exists In:The side wall of described oxide skin collecting box is provided with the sample peg for hanging sample.
6. a kind of collectable high-temperature vapor oxidation unit of oxide skin according to claim 5 it is characterised in that:Described Sample peg is ceramic bar, and the side wall of described oxide skin collecting box is provided with the support jack for ceramic bar insertion.
7. a kind of oxide skin collectable high-temperature vapor oxidation unit according to claim 1 or 2 or 3, its feature exists In:A kind of collectable high-temperature vapor oxidation unit of described oxide skin includes waterworks, the outlet of described waterworks It is arranged on the burner hearth bottom of described high-temperature vapor oxidation furnace.
8. a kind of collectable high-temperature vapor oxidation unit of oxide skin according to claim 7 it is characterised in that:Described Waterworks are provided with more than two, and the outlet of each waterworks is uniformly arranged in burner hearth bottom.
9. a kind of oxide skin collectable high-temperature vapor oxidation unit according to claim 1 or 2 or 3, its feature exists In:It is fixed with gripper shoe in described burner hearth, described gripper shoe is evenly equipped with steam passage holes, described supporting construction is arranged on described On fagging and be provided with more than at two, each supporting construction is evenly arranged around the axis of burner hearth.
10. a kind of collectable high-temperature vapor oxidation unit of oxide skin according to claim 9 it is characterised in that:Institute State high-temperature vapor oxidation furnace and there is bell, described bell is provided with while stretching in burner hearth for temperature sensor and supplies vapor The perforate discharged, described perforate eccentric setting is with corresponding up and down to the corresponding steam inlet on oxide skin collecting box below.
CN201620600694.7U 2016-06-20 2016-06-20 High temperature water vapor oxidation unit that cinder can be collected Expired - Fee Related CN205982025U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201620600694.7U CN205982025U (en) 2016-06-20 2016-06-20 High temperature water vapor oxidation unit that cinder can be collected

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201620600694.7U CN205982025U (en) 2016-06-20 2016-06-20 High temperature water vapor oxidation unit that cinder can be collected

Publications (1)

Publication Number Publication Date
CN205982025U true CN205982025U (en) 2017-02-22

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107576611A (en) * 2017-09-20 2018-01-12 西安热工研究院有限公司 A kind of method and apparatus of superheater reheater scale spallation Tachistoscope
CN109903865A (en) * 2019-01-24 2019-06-18 广东核电合营有限公司 The dress sampling device of high-temperature steam oxidation test

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107576611A (en) * 2017-09-20 2018-01-12 西安热工研究院有限公司 A kind of method and apparatus of superheater reheater scale spallation Tachistoscope
CN107576611B (en) * 2017-09-20 2023-12-29 西安热工研究院有限公司 Superheater reheater oxide skin method and device for testing peeling degree
CN109903865A (en) * 2019-01-24 2019-06-18 广东核电合营有限公司 The dress sampling device of high-temperature steam oxidation test

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C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20170222

Termination date: 20190620