CN205900715U - Fill soon, put soon, long -lived lithium ion power batteries - Google Patents

Fill soon, put soon, long -lived lithium ion power batteries Download PDF

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Publication number
CN205900715U
CN205900715U CN201620680565.3U CN201620680565U CN205900715U CN 205900715 U CN205900715 U CN 205900715U CN 201620680565 U CN201620680565 U CN 201620680565U CN 205900715 U CN205900715 U CN 205900715U
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CN
China
Prior art keywords
coating
sides
lithium
ion
power cell
Prior art date
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Expired - Fee Related
Application number
CN201620680565.3U
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Chinese (zh)
Inventor
雷如清
陈善宏
黄志义
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Hefei Zhonghang New Energy Technology Research Institute Co Ltd
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Hefei Zhonghang New Energy Technology Research Institute Co Ltd
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Priority to CN201620680565.3U priority Critical patent/CN205900715U/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The utility model discloses a fill soon, put soon, long -lived lithium ion power batteries, power battery is including positive pole, negative pole, diaphragm paper, electrolyte, soft -packing shell and utmost point ear, the anodal mass flow body is the copper foil for the mass flow body of aluminium foil, negative pole, the two sides of aluminium foil and copper foil all is provided with the coating, anodal both sides are provided with the lithium iron phosphate coating, the both sides of negative pole are provided with compound graphite coating, diaphragm paper is one -course PE material, and diaphragm paper's both sides all are provided with the coating. The utility model provides a battery is under the condition of ensureing the safe handling, and charging current is 4C3A (can be full of in 15 minutes promptly), and discharge current is 6C3A (10 minutes promptly can put completely), discharge current >= 15C3A (sustainable 20 seconds of discharge time ) in the twinkling of an eye, cycle life >= 5000 times (80%DOD).

Description

One kind is filled soon, puts soon, long-lived lithium-ion-power cell
Technical field
The present invention relates to lithium-ion-power cell field and in particular to one kind fill soon, put soon, long-lived lithium-ion-power cell And preparation method thereof.
Background technology
It is known that current human society will be faced with the awkward predicament of sternness on way forward: non-renewable Fossil fuel reserves are limited, and will gradually move towards exhausted, and the storm of energy crisis will grow in intensity;Excessively the opening of fossil fuel Adopt and use in a large number, cause the severe contamination of environment for human survival and the notable destruction of the ecological balance.Therefore, countries in the world Knowledgeable people studies reproducible new energy field, and the Strategic Measure of the searching energy security of every possible means positive, greatly Power develops other clean energy resourcies contained between solar energy, wind energy, biomass energy, water power, nuclear power, Hydrogen Energy and universe, and extremely Pay attention to research and development, apply advanced energy storage and Transmission system.
New-energy automobile is the importance of new forms of energy application, storage and Transmission system.The current new-energy automobile of China is just It is in the new stage developing rapidly;05 month 24 morning in 2014, Party Central Committee leader emphasizes when Shanghai automobile group investigates, and sends out Exhibition new-energy automobile is China from automobile superpower marches toward the only way of automobile power, and R&D intensity to be strengthened conscientiously studies city , with handy policy alive, the product of the exploitation various demands of adaptation, make a staggering growth point.Then State Council and Put into effect the one and another policy supporting China's new-energy automobile development about ministries and commissions are intensive, each place government also launches respectively Supporting policy and measure.Development new-energy automobile has become the main direction of Chinese government's industry development, and so that mention can not Enable the strategic height of " Chinese dream ";Therefore, the general trend of events of Chinese development new-energy automobile has been formed, and this general trend of events is Unshakable.
New-energy automobile has three big core systems: battery, motor and automatically controlled;Wherein, battery is primary core system.Mesh Before, from lithium-ion-power cell pure electronic new-energy automobile be China fundamental state policy.Lithium-ion-power cell has a lot Advantage, such as cell output voltage height (3.2v, 3.7v);There is longer discharge voltage plateau (>=40 minutes or 60%);Not yet There is memory effect, cycle performance is superior;Self-discharge rate low (moon self-discharge rate 3% about);No poisonous and harmful substance, is referred to as Green battery.But, not enough or problem below the lithium-ion-power cell generally existing that current Ge Li electricity factory produces: first It is the cycle life short (≤2000 times) of battery, what particularly battery had in groups afterwards uses less than 3 years with regard to end-of-life;Its Secondary is to allow charge and discharge electric current little (majority is 2c3A fills, 3c3A is put), lead to the charging interval of new-energy automobile oversize, have is slow Fill needs 3.5 hours, that fills soon also wants 30 minutes, and the electric current that particularly sparks does not reach requirement, so that electric automobile is being started It is restricted with when acceleration or climbing;Be again electric automobile fill once electricity course continuation mileage short.
Therefore, how to solve the above problems, improve lithium-ion-power cell gold content further and use advantage, it has also become The technical barrier of those skilled in the art's urgent need to resolve.
Content of the invention
For problems of the prior art, it is an object of the invention to provide one kind fill soon, put soon, long-lived lithium ion Electrokinetic cell, under conditions of guaranteeing safe handling, charging current is 4c to this battery3A (i.e. 15 minutes can be fully charged), electric discharge electricity Flow for 6c3A (can be discharged) for 10 minutes completely, and spark electric current >=15c3A (sustainable 20 seconds of discharge time), circulates the longevity >=5000 times (80%dod) of life.
For achieving the above object, the present invention employs the following technical solutions:
One kind is filled soon, puts soon, long-lived lithium-ion-power cell, and described electrokinetic cell includes positive pole, negative pole, diaphragm paper, electricity Solution liquid, Soft Roll casing and lug, the collector of described positive pole is aluminium foil, the collector of negative pole is Copper Foil;Described aluminium foil and copper The two sides of paper tinsel is provided with coating;The both sides of described positive pole are provided with LiFePO4 coating;The both sides of described negative pole are provided with multiple Close equadag coating;The pe material of described diaphragm paper individual layer, the both sides of diaphragm paper are provided with coating.
Further, the lug of described positive pole is aluminium pole ears;The lug of described negative pole is copper nickel plating lug.
Further, the surface that described diaphragm paper is contacted with positive electrode active materials applies pvdf+paa co-polymer membrane;Live with negative pole Property material surface apply ceramic al2o3Film;Thickness≤3 μm of its one side film.
Further, the coating of the two sides setting of described aluminium foil and Copper Foil is carbon coating.
Further, described Soft Roll casing is aluminum-plastic composite membrane shell.
Further, in described LiFePO4 coating, the particle diameter of LiFePO4 raw material is: d10≤ 0.70 μm, d50≤ 2.30 μm, d90≤5.00μm;Specific surface area s >=13.00m2/g;Specific capacity c >=160mah/g.
Further, the one side thickness of the coating of two sides setting of described aluminium foil and Copper Foil is 1-3 μm.
The present invention has following Advantageous Effects:
Under conditions of guaranteeing safe handling, charging current is 4c to the battery of the application3A (i.e. 15 minutes can be fully charged), Discharge current is 6c3A (can be discharged) for 10 minutes completely, and spark electric current >=15c3A (sustainable 20 seconds of discharge time), Cycle life >=5000 time (80%dod).
Brief description
Fig. 1 is the internal structure schematic diagram of electrokinetic cell of the present invention.
Specific embodiment
Below, refer to the attached drawing, is more fully illustrated to the present invention, shown in the drawings of the exemplary enforcement of the present invention Example.However, the present invention can be presented as multiple multi-forms, it is not construed as the exemplary enforcement being confined to describe here Example.And it is to provide these embodiments, so that the present invention is fully and completely, and will fully convey the scope of the invention to this The those of ordinary skill in field.
For ease of explanation, here can using " on ", the space relative terms such as D score " left " " right ", for saying Shown in bright in figure a element or feature are with respect to the relation of another element or feature.It should be understood that except in figure Outside the orientation illustrating, spatial terminology is intended to the different azimuth in use or operation including device.For example, if in figure Device is squeezed, be stated as positioned at the element of other elements or feature D score will be located into other elements or feature " on ".Cause This, exemplary term D score can comprise both upper and lower orientation.Device can otherwise position and (ratate 90 degrees or be located at Other orientation), can correspondingly explain used herein of space explanation relatively.
As shown in figure 1, this application provides one kind fill soon, put soon, long-lived lithium-ion-power cell, described electrokinetic cell bag Include positive pole 1, negative pole 2, diaphragm paper 14, electrolyte, Soft Roll casing 13 and lug, the collector 3 of described positive pole 1 is aluminium foil, bears The collector 4 of pole 2 is Copper Foil;The two sides of described aluminium foil and Copper Foil is provided with coating 5;The both sides of described positive pole 1 are provided with phosphorus Sour iron lithium coating 11;The both sides of described negative pole 2 are provided with composite graphite coating 12;Described diaphragm paper 14 is the pe material of individual layer, The both sides of diaphragm paper are provided with coating.
The lug 9 of positive pole 1 is aluminium pole ears;The lug 10 of negative pole 2 is copper nickel plating lug.The two sides setting of aluminium foil and Copper Foil Coating is carbon coating.Collector outsourcing comes can not be directly using it is necessary to process through applying carbon.One side applies carbon thickness and controls in 1- 3 μm, to prevent electrolyte to the corrosion, oxidation of collector so as to the adhesive force of both positive and negative polarity active material is significantly improved, fall Low contact resistance, reduces polarization, strengthens electric conductivity, extends its service life.
The surface that diaphragm paper 14 is contacted with positive electrode active materials applies pvdf+paa co-polymer membrane 16;Connect with negative active core-shell material Tactile surface applies ceramic al2o3Film 15;Thickness≤3 μm of its one side film.The diaphragm paper of outsourcing can not be directly using it is necessary to divide Do not apply different films on the two sides of diaphragm paper.The purpose of film is to ensure that the high temperature stability performance of electrokinetic cell is good and prevent interior Portion's short circuit and high-temperature oxydation, to improve security performance and the cycle life of electrokinetic cell.
Soft Roll casing 13 is aluminum-plastic composite membrane shell.
In LiFePO4 coating 11, the particle diameter of LiFePO4 raw material is: d10≤ 0.70 μm, d50≤ 2.30 μm, d90≤5.00μ m;Specific surface area s >=13.00m2/g;Specific capacity c >=160mah/g.
Composite graphite coating 12 by the high native graphite of specific capacity (c >=360mhh/g) and non-laminar structure, exist a lot The cave the difficult graphited soft carbon that differ in size and form, its component ratio is native graphite 80%+ soft carbon 20%.
Diaphragm paper 14 is by pvdf+paa co-polymer membrane 16 and ceramic al2o3Film 15 together constitutes coating barrier film 8;Collector 3 Together constitute carbon-coated aluminum foils 6 with the coating 5 of its both sides;The coating 5 of collector 4 and its both sides together constitutes painting carbon Copper Foil 7.
Described above simply to illustrate that the present invention, it is understood that the invention is not limited in above example, meets The various variants of inventive concept are all within protection scope of the present invention.

Claims (7)

1. one kind fill soon, put soon, long-lived lithium-ion-power cell, described electrokinetic cell includes positive pole, negative pole, diaphragm paper, electrolysis Liquid, Soft Roll casing and lug it is characterised in that described positive pole collector be aluminium foil, negative pole collector be Copper Foil;Described The two sides of aluminium foil and Copper Foil is provided with coating;The both sides of described positive pole are provided with LiFePO4 coating;The both sides of described negative pole It is provided with composite graphite coating;Described diaphragm paper is the pe material of individual layer, and the both sides of diaphragm paper are provided with coating.
2. lithium-ion-power cell according to claim 1 is it is characterised in that the lug of described positive pole is aluminium pole ears;Institute The lug stating negative pole is copper nickel plating lug.
3. lithium-ion-power cell according to claim 1 is it is characterised in that described diaphragm paper and positive electrode active materials connect Tactile surface applies pvdf+paa co-polymer membrane;The surface contacting with negative active core-shell material applies ceramic al2o3Film;Its one side film Thickness≤3 μm.
4. lithium-ion-power cell according to claim 1 it is characterised in that described aluminium foil and Copper Foil two sides setting Coating is carbon coating.
5. lithium-ion-power cell according to claim 1 is it is characterised in that described Soft Roll casing is aluminum-plastic composite membrane Shell.
6. lithium-ion-power cell according to claim 1 is it is characterised in that LiFePO4 in described LiFePO4 coating The particle diameter of raw material is: d10≤ 0.70 μm, d50≤ 2.30 μm, d90≤5.00μm;Specific surface area s >=13.00m2/g;Specific capacity c >= 160mah/g.
7. lithium-ion-power cell according to claim 1 it is characterised in that described aluminium foil and Copper Foil two sides setting The one side thickness of coating is 1-3 μm.
CN201620680565.3U 2016-06-30 2016-06-30 Fill soon, put soon, long -lived lithium ion power batteries Expired - Fee Related CN205900715U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201620680565.3U CN205900715U (en) 2016-06-30 2016-06-30 Fill soon, put soon, long -lived lithium ion power batteries

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106848384A (en) * 2017-03-10 2017-06-13 合肥中航新能源技术研究院有限责任公司 A kind of long-life lithium sulphur electrokinetic cell of high-energy-density
CN108091847A (en) * 2017-12-11 2018-05-29 北京国能电池科技有限公司 Anode material for lithium-ion batteries and preparation method thereof and lithium ion battery

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106848384A (en) * 2017-03-10 2017-06-13 合肥中航新能源技术研究院有限责任公司 A kind of long-life lithium sulphur electrokinetic cell of high-energy-density
CN108091847A (en) * 2017-12-11 2018-05-29 北京国能电池科技有限公司 Anode material for lithium-ion batteries and preparation method thereof and lithium ion battery

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20170118

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CF01 Termination of patent right due to non-payment of annual fee