CN205797189U - The Muscovitum cladding quick neutralization reactor of operation - Google Patents
The Muscovitum cladding quick neutralization reactor of operation Download PDFInfo
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- CN205797189U CN205797189U CN201620509231.XU CN201620509231U CN205797189U CN 205797189 U CN205797189 U CN 205797189U CN 201620509231 U CN201620509231 U CN 201620509231U CN 205797189 U CN205797189 U CN 205797189U
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- reactor
- muscovitum
- shower tray
- cladding
- quick neutralization
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Abstract
This utility model belongs to Muscovitum processing technique field, relates to a kind of Muscovitum cladding quick neutralization reactor of operation.It includes reactor, described reactor has rabbling mechanism, described reactor top is fixed with a shower tray in hollow, the lower surface of described shower tray is densely covered with spray apertures, shower tray connects can join liquid the liquid addition mechanism in shower tray, and described rabbling mechanism through shower tray and does not contacts with shower tray.During this utility model acid-base neutralization, it is possible to make soda acid quickly mix homogeneously with reactant liquor, thus quickly neutralize, improve the quality of Muscovitum cladding.
Description
Technical field
This utility model belongs to Muscovitum processing technique field, relates to a kind of Muscovitum cladding operation
Quickly neutralization reactor.
Background technology
Mica titanium nacreous material is with splitting as substrate, at smooth mica surface
Superscribe the titanium dioxide of transparent or relatively transparent high index of refraction and the thin of ferrum oxide composition
Layer.When fiber-optic illuminated to time on mica sheet, mica sheet is just as transparent small mirror, part
Light reflects away, and part fiber is transmissive in the way of refraction.Through the light gone
It is refracted on next interface, secondary partially reflective and fractional transmission occurs again, depends on
Secondary continue.Being known by physical optics, the light at two reflective surface can be mutually
Effect, the result of interaction depends on the factors such as phase contrast, angle of incidence, refractive index,
Thus form the pearly-lustre phenomenon interfering feature.
In encapsulation process, it is common that by Muscovitum and TiCl4、FeCl3Solution mixes, and adds
Acid adds alkali regulation pH value, makes TiCl4And FeCl3Change in TiCl2And Fe2O3, parcel
Outside Muscovitum, reach covered effect.During cladding, constant pH can improve
Cladding quality, but prior art is in the adition process of acid or alkali, tends not to realize
The effect of rapid dispersion, neutralizes speed slower.
Chinese patent literature discloses a kind of single coating cobalt titanate green/nacreous mica composite pigment
Preparation method [application number: 201310474467.5], use the sedimentation method, with pretreatment
Muscovitum is substrate, is configured to Muscovitum slurry with deionized water dispersion Muscovitum, adds a small amount of hydrochloric acid
Acidifying, under stirring at 80 DEG C, is slowly added dropwise TiCl4Acid solution and soluble cobalt
Mixed solution, is simultaneously added dropwise sodium hydroxide solution, drips complete regulation pH to 9, ripening,
Filtration washing is dried, and obtains yellow green composite pigment at 1000 DEG C of calcining 2h.Compound face
Material surface is nano grade titanium cobalt green particle, uniform in mica surface cladding densification, cladding
Lightness and the form and aspect of composite pigment are had an impact by rate.When material molar ratio Co/Ti >=2,
The characteristic diffraction peak of composite pigment surface spinel-type cobalt titanate green is notable.The cloud of different-grain diameter
Female covered effect is different, and particle diameter 20-100 μm Muscovitum is that the cobalt titanate green of substrate cladding is combined
The glittering pearl effect of pigment is notable.This is a kind of novel high-performance mica-based yellow green pearl
Photoreactivation pigment, performance is better than common nacreous mica pigment, and preparation technology is simple.
But said method " is adding the acidifying of a small amount of hydrochloric acid, under stirring at 80 DEG C, slowly
Dropping TiCl4Acid solution and the mixed solution of soluble cobalt, be simultaneously added dropwise hydroxide
Sodium solution, drips complete regulation pH to 9 " problem that also do not addresses how quickly to neutralize.
Utility model content
The purpose of this utility model is for the problems referred to above, it is provided that a kind of Muscovitum cladding operation
Quickly neutralization reactor.
For reaching above-mentioned purpose, this utility model have employed following technical proposal: Yi Zhongyun
Main bag covers the quick neutralization reactor of operation, and including reactor, described reactor has and stirs
Mixing mechanism, described reactor top is fixed with a shower tray in hollow, described
The lower surface of shower tray is densely covered with spray apertures, and shower tray connects can join spray liquid
Liquid addition mechanism in dish, described rabbling mechanism through shower tray and not with shower tray
Contact.
In the above-mentioned Muscovitum cladding quick neutralization reactor of operation, described rabbling mechanism
Including driver and the shaft that is connected with driver, if being fixed with on described shaft
Dry stirring paddle, described shower tray center has sealing ring ringwise, this sealing ring
Upper/lower terminal is connected, in sealing ring with upper and lower two face seals of shower tray respectively
Between form resigning hole, described shaft passes resigning hole, and the aperture of resigning hole is more than stirring
Mix the diameter of axle.
In the above-mentioned Muscovitum cladding quick neutralization reactor of operation, described stirring paddle edge
The axially spaced-apart of shaft arranges uniformly.
In the above-mentioned Muscovitum cladding quick neutralization reactor of operation, described liquid addition
Mechanism includes the height wet tank higher than shower tray of in the vertical direction, described liquid
Body storage tank connects shower tray.
In the above-mentioned Muscovitum cladding quick neutralization reactor of operation, described shower tray with
Effusion meter and control valve it is provided with between wet tank.
In the above-mentioned Muscovitum cladding quick neutralization reactor of operation, described Polycondensation Reactor and Esterification Reactor
Portion is plane.
In the above-mentioned Muscovitum cladding quick neutralization reactor of operation, in described reactor
It is fixed with one on wall and can form collision so that the flowing of liquid with the liquid in reactor
The flow-disturbing mechanism that direction changes.
In the above-mentioned Muscovitum cladding quick neutralization reactor of operation, described flow-disturbing mechanism
Including at least one piece of spoiler being fixed on reactor inwall.
In the above-mentioned Muscovitum cladding quick neutralization reactor of operation, described flow-disturbing mechanism
Being fixed on the spoiler on reactor inwall including at least one row, described spoiler is along anti-
Answer the circumferentially-spaced uniform setting of still.
In the above-mentioned Muscovitum cladding quick neutralization reactor of operation, described spoiler is extremely
Rare two rows, and two adjacent row's spoilers are in being crisscross arranged.
Compared with prior art, the utility model has the advantage of: during acid-base neutralization, energy
Enough make soda acid quickly mix homogeneously with reactant liquor, thus quickly neutralize, improve Muscovitum cladding
Quality.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model；
Fig. 2 is the structural representation of shower tray；
Fig. 3 is the structural representation of shower tray lower surface；
Fig. 4 is the partial structurtes schematic diagram of reactor inwall.
In figure: reactor 1, rabbling mechanism 2, shower tray 3, bracing frame 3a, spray apertures
4, liquid addition mechanism 5, driver 6, shaft 7, stirring paddle 8, sealing ring 9,
Resigning hole 10, wet tank 11, effusion meter 12, control valve 13, flow-disturbing mechanism 14,
Spoiler 15.
Detailed description of the invention
This utility model is done further details of with detailed description of the invention below in conjunction with the accompanying drawings
Explanation.
As shown in figures 1 and 3, a kind of Muscovitum cladding quick neutralization reactor of operation, bag
Including reactor 1, described reactor 1 has rabbling mechanism 2, and rabbling mechanism 2 includes driving
Dynamic device 6 and the shaft 7 being connected with driver 6, described shaft 7 is fixed with
Some stirring paddles 8, stirring paddle 8 arranges uniformly along the axially spaced-apart of shaft 7.Institute
Reactor 1 top stated is fixed with a shower tray 3 in hollow, and shower tray 3 is permissible
Being fixed on reactor 1 inwall with bracing frame 3a, the lower surface of described shower tray 3 is close
Being furnished with spray apertures 4, shower tray 3 connects can join the liquid in shower tray 3 liquid
Charging mechanism 5, described rabbling mechanism 2 through shower tray 3 and does not connects with shower tray 3
Touch.
With TiCl4When solution is modified cladding to Muscovitum, need to add HCl solution
Regulate pH value with NaOH solution, make cladding process pH stable, thus realize the equal of cladding
Even property.PH value is being regulated, if N-process is the most fast by HCl solution or NaOH solution
Speed, then under inappropriate acid-base value, Muscovitum can realize being coated with for a long time, and quality can inequality
Even.Shower tray 3 is passed through acid solution or alkali liquor, forms the charging effect of fountain, make acid
Alkali quickly neutralizes, and just can complete to neutralize, reach the temperature of pH value in the short time.
Specifically, shown in Fig. 2, described shower tray 3 center has ringwise
Sealing ring 9, the upper/lower terminal of this sealing ring 9 upper and lower with shower tray 3 respectively
Two face seals connect, sealing ring 9 intermediate formation resigning hole 10, described shaft
7 pass resigning hole 10, and the aperture of resigning hole 10 is more than the diameter of shaft 7.Making
During resigning hole 10, first can dig a hole at shower tray 3 center, then insert in hole
Circular sealing ring seals with shower tray 3, and sealing ring is ring-type, therefore can be formed and allow
Hole 10, position, or with metal tape replacement seal circle, metal tape welds with shower tray 3
Form the structure of resigning hole 10.
For realizing the automaticity of charging, liquid addition mechanism 5 is included in vertical direction
On height higher than the wet tank 11 of shower tray 3, described wet tank 11 connects
Shower tray 3.Effusion meter 12 and control valve it is provided with between shower tray 3 and wet tank 11
13.Effusion meter 12 can be spinner flowmeter.
In plane bottom reactor 1, prevent material from depositing.On reactor 1 inwall admittedly
Surely one is had can to form collision so that the flow direction of liquid with the liquid in reactor 1
The flow-disturbing mechanism 14 changed.
Specifically, flow-disturbing mechanism 14 includes that at least one piece is fixed on reactor 1 inwall
Spoiler 15.When liquid or Muscovitum collide with spoiler 15, flow direction changes
Become, it is achieved turbulent flow or sinuous flow, it is thus possible to improve mixing homogeneously between Muscovitum and reactant liquor
Degree, improves reaction efficiency further and improves the quality of cladding.
Another kind of scheme, as shown in Figure 4, flow-disturbing mechanism 14 includes that at least one row is fixed on
Spoiler 15 on reactor 1 inwall, described spoiler 15 is along the week of reactor 1
To evenly spaced setting.Preferably, spoiler 15 at least two row, and adjacent two
Row's spoiler 15 is in being crisscross arranged.
Operation principle of the present utility model is: Muscovitum, TiCl4 and FeCl3 etc. join
In reactor 1, heated and stirred is reacted, and detects pH value, when pH value sets beyond reaction
During value, add acid or alkali as required, namely open control valve 13, by effusion meter 12
Coutroi velocity controls addition further, thus realizes neutralizing, and acid or alkali are from shower tray 3
Spray apertures 4 in quickly spray, mix with the liquid Rapid contact within reactor 1,
Reach the effect quickly neutralized.It will be appreciated by those skilled in the art that according to actual production
Needing, wet tank 11, effusion meter 12 and control valve 13 are an assembly, Ke Yishe
Put multiple containing wet tank 11, effusion meter 12 and the assembly of control valve 13 thus control
Different acid or the addition of alkali.
Specific embodiment described herein is only for example to this utility model spirit
Explanation.This utility model person of ordinary skill in the field can be to described concrete
Embodiment is made various amendment or supplements or use similar mode to substitute, but not
Spirit of the present utility model can be deviateed or surmount model defined in appended claims
Enclose.
Although the most more employing reactor 1, rabbling mechanism 2, shower tray 3, spray
Drench hole 4, liquid addition mechanism 5, driver 6, shaft 7, stirring paddle 8, seal
Circle 9, resigning hole 10, wet tank 11, effusion meter 12, control valve 13, flow-disturbing machine
The terms such as structure 14, spoiler 15, but it is not precluded from using the probability of other term.
Use these terms to be only used to more easily and describe and explain of the present utility model
Matter；Being construed as any additional restriction is all and this utility model spirit phase
Run counter to.
Claims (10)
1. the Muscovitum cladding quick neutralization reactor of operation, including reactor (1), institute
The reactor (1) stated has rabbling mechanism (2), it is characterised in that described reactor
(1) top is fixed with a shower tray (3) in hollow, described shower tray (3)
Lower surface be densely covered with spray apertures (4), shower tray (3) connects can join spray liquid
Liquid addition mechanism (5) in tray (3), described rabbling mechanism (2) is through spray
Tray (3) and not contacting with shower tray (3).
The Muscovitum the most according to claim 1 cladding quick neutralization reactor of operation, its
Be characterised by, described rabbling mechanism (2) include driver (6) and with driver (6)
The shaft (7) connected, described shaft (7) is fixed with some stirring paddles (8),
Described shower tray (3) center has sealing ring (9) ringwise, this sealing ring (9)
Upper/lower terminal be connected with upper and lower two face seals of shower tray (3) respectively, close
Seal (9) intermediate formation resigning hole (10), described shaft (7) passes resigning hole
(10), the aperture of resigning hole (10) is more than the diameter of shaft (7).
The Muscovitum the most according to claim 2 cladding quick neutralization reactor of operation, its
Being characterised by, described stirring paddle (8) is uniform along the axially spaced-apart of shaft (7)
Arrangement.
The Muscovitum the most according to claim 1 cladding quick neutralization reactor of operation, its
Being characterised by, described liquid addition mechanism (5) includes that the height of in the vertical direction is high
In the wet tank (11) of shower tray (3), described wet tank (11) connects spray
Tray (3).
The Muscovitum the most according to claim 4 cladding quick neutralization reactor of operation, its
It is characterised by, between described shower tray (3) and wet tank (11), is provided with effusion meter
And control valve (13) (12).
The Muscovitum the most according to claim 1 cladding quick neutralization reactor of operation, its
Being characterised by, described reactor (1) bottom is in plane.
The Muscovitum the most according to claim 1 cladding quick neutralization reactor of operation, its
Being characterised by, described reactor (1) inwall is fixed with one can be with reactor (1)
In liquid form collision so that the flow-disturbing mechanism that changes of the flow direction of liquid
(14)。
The Muscovitum the most according to claim 7 cladding quick neutralization reactor of operation, its
Being characterised by, described flow-disturbing mechanism (14) includes that at least is fixed on a reactor (1)
Spoiler (15) on inwall.
The Muscovitum the most according to claim 7 cladding quick neutralization reactor of operation, its
Being characterised by, described flow-disturbing mechanism (14) includes that at least one row is fixed on reactor (1)
Spoiler (15) on inwall, described spoiler (15) is along the week of reactor (1)
To evenly spaced setting.
The Muscovitum the most according to claim 9 cladding quick neutralization reactor of operation,
It is characterized in that, described spoiler (15) at least two row, and two adjacent rows disturb
Stream plate (15) is in being crisscross arranged.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620509231.XU CN205797189U (en) | 2016-05-30 | 2016-05-30 | The Muscovitum cladding quick neutralization reactor of operation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620509231.XU CN205797189U (en) | 2016-05-30 | 2016-05-30 | The Muscovitum cladding quick neutralization reactor of operation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN205797189U true CN205797189U (en) | 2016-12-14 |
Family
ID=57502156
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201620509231.XU Active CN205797189U (en) | 2016-05-30 | 2016-05-30 | The Muscovitum cladding quick neutralization reactor of operation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN205797189U (en) |
-
2016
- 2016-05-30 CN CN201620509231.XU patent/CN205797189U/en active Active
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