CN205700084U - A kind of supporting tail gas absorbing system of aliphatic - Google Patents

A kind of supporting tail gas absorbing system of aliphatic Download PDF

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Publication number
CN205700084U
CN205700084U CN201620667954.2U CN201620667954U CN205700084U CN 205700084 U CN205700084 U CN 205700084U CN 201620667954 U CN201620667954 U CN 201620667954U CN 205700084 U CN205700084 U CN 205700084U
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absorption tower
alkali cleaning
tail gas
pipe
stair oxidation
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CN201620667954.2U
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金瑞浩
童卫明
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Zhejiang Jisheng Construction Chemical Co Ltd
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Zhejiang Jisheng Construction Chemical Co Ltd
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Abstract

nullThe utility model discloses a kind of supporting tail gas absorbing system of aliphatic,Including synthesis emptying end gas pipe、Running water pipe、Acetone storage tank emptying offgas duct、Liquid caustic soda storage tank pipe and alkali cleaning absorption tower,Described synthesis emptying end gas pipe is connected with condenser,Described condenser is connected with naphthalene recovery tower,Described naphthalene recovery tower is connected with stair oxidation absorption tower,Also include membrane pump,Described membrane pump is connected with FRP hydrogen peroxide measuring tank,Described FRP hydrogen peroxide measuring tank connects stair oxidation absorption tower,Described running water pipe and acetone storage tank emptying offgas duct lead to stair oxidation absorption tower,Described stair oxidation absorption tower is connected with alkali cleaning absorption tower,Described liquid caustic soda storage tank pipe is connected with carbon steel liquid caustic soda measuring tank,Described carbon steel liquid caustic soda measuring tank connects alkali cleaning absorption tower,Described alkali cleaning absorption tower is provided with blow-down pipe,The utility model can reclaim the naphthalene in tail gas,And utilize alkaline hydrogen peroxide solution to absorb the formaldehyde in tail gas.

Description

A kind of supporting tail gas absorbing system of aliphatic
Technical field
The utility model relates to water reducer production technical field, more specifically, particularly to a kind of supporting tail of aliphatic Gas absorption system.
Background technology
Water reducer is a kind of under conditions of maintaining concrete slump constant, can reduce outside the concrete of mixing water amount Add agent.Mostly belong to anion surfactant, have lignosulfonates, naphthalene sulphonate formaldehyde polymer etc..It is mixed in addition After solidifying soil mixture, peptizaiton is had to cement granules, its workability can be improved, reduce unit consumption of water, improve concrete mixing The mobility of thing;Or minimizing unit cement consumption, save cement.Sulfur dioxide and three oxidations can be produced during preparing water reducer Sulphur gas, the tail gas that preparation completes contains naphthalene and formaldehyde.
As it is shown in figure 1, existing tail gas absorbing system includes that synthesis emptying end gas pipe the 1st, running water pipe the 2nd, acetone storage tank is put Empty offgas duct the 3rd, liquid caustic soda storage tank pipe 4 and alkali cleaning absorption tower 5, alkali cleaning absorption tower 5 absorbs the sour gas in tail gas, but in tail gas Formaldehyde water assimilation effect bad, efficiency is very low, discharges not up to standard, and existing tail gas absorption flow process can not reclaim naphthalene, Cause the wasting of resources.
Utility model content
For the deficiencies in the prior art, the utility model provides one and can reclaim naphthalene and utilize alkaline hydrogen peroxide molten Liquid absorbs the supporting tail gas absorbing system of aliphatic of formaldehyde.
For achieving the above object, the utility model provides following technical scheme: a kind of aliphatic supporting tail gas absorption system System, including synthesis emptying end gas pipe, running water pipe, acetone storage tank emptying offgas duct, liquid caustic soda storage tank pipe and alkali cleaning absorption tower, described Synthesis emptying end gas pipe is connected with condenser, and described condenser is connected with naphthalene recovery tower, and described naphthalene recovery tower is connected with one-level oxygen Changing absorption tower, also including membrane pump, described membrane pump is connected with FRP hydrogen peroxide measuring tank, and described FRP hydrogen peroxide measuring tank connects Stair oxidation absorption tower, described running water pipe and acetone storage tank emptying offgas duct lead to stair oxidation absorption tower, described one-level oxygen Changing absorption tower and being connected with alkali cleaning absorption tower, described liquid caustic soda storage tank pipe is connected with carbon steel liquid caustic soda measuring tank, and described carbon steel liquid caustic soda measures Groove connects alkali cleaning absorption tower, and described alkali cleaning absorption tower is provided with blow-down pipe.
By using technique scheme, containing sulfur dioxide, sulfur trioxide, naphthalene and formaldehyde in synthesis emptying end gas, After being passed through condenser, sulfur dioxide and formaldehyde are still gas, and major part sulfur trioxide becomes liquid, can be collected separately, and one Part naphthalene crystal separates out, and can collect recovery;The remaining tail gas containing sulfur dioxide, formaldehyde and part naphthalene is passed through naphthalene and reclaims Tower, naphthalene recovery tower can more thoroughly separate naphthalene and other gases, thus reclaim naphthalene recycling;Now remaining containing titanium dioxide The tail gas of sulphur and formaldehyde is passed through stair oxidation absorption tower, and alkaline hydrogen peroxide solution is pumped into FRP hydrogen peroxide measuring tank by membrane pump Measuring, then passing to stair oxidation absorption tower, the alkaline hydrogen peroxide solution in stair oxidation absorption tower can be by formaldehyde Thoroughly absorb, and a part of sulfur dioxide can only be absorbed;Running water pipe and acetone storage tank emptying offgas duct also lead to stair oxidation Absorption tower, it is therefore an objective to the solution in dilution stair oxidation absorption tower and cooling, prevents thermal discharge excessive, and acetone gas also may be used To be absorbed in stair oxidation absorption tower;The now remaining tail gas containing sulfur dioxide is passed through alkali cleaning absorption tower, and liquid caustic soda is store Barrel is connected with carbon steel liquid caustic soda measuring tank, is used for measuring liquid caustic soda amount, and carbon steel liquid caustic soda measuring tank connects alkali cleaning absorption tower, notes liquid caustic soda Entering alkali cleaning absorption tower, such sulfur dioxide is just completely absorbed in alkali cleaning absorption tower, such that it is able to harmless is nontoxic Gas is entered in air by blow-down pipe;Whole system absorbs the respond well and thorough of toxic and harmful, and reclaims Naphthalene recycles.
Further, described naphthalene recovery tower is provided with floss hole.
By using technique scheme, the liquid discharge in naphthalene recovery tower can be collected by floss hole, reduces to environment Directly discharge, and this liquid does not contains naphthalene, can be with separate collection naphthalene and other materials.
Further, being provided with air compensation device between described naphthalene recovery tower and stair oxidation absorption tower, described acetone storage tank is put Empty offgas duct leads to air compensation device.
By using technique scheme, air compensation device may advantageously facilitate the gas flowing in stair oxidation absorption tower, from And increase the time of contact of tail gas and alkaline hydrogen peroxide solution, it is ensured that assimilation effect.
Further, described stair oxidation absorption tower is provided with the first explosion-proof circulating pump.
By using technique scheme, the first explosion-proof circulating pump can circulate the liquid in stair oxidation absorption tower, reach To the purpose of recycling, economize on resources.
Further, it is provided with explosion proof and corrosion protection blower fan between described stair oxidation absorption tower and alkali cleaning absorption tower.
By using technique scheme, the gas that stair oxidation absorption tower is discharged can quickly be drawn by explosion proof and corrosion protection blower fan Enter alkali cleaning absorption tower, prevent gas from the way revealing or with air contact and contaminated air, and efficiency can be improved.
Further, described alkali cleaning absorption tower is provided with PH meter.
By using technique scheme, PH meter can measure the pH value of solution in alkali cleaning absorption tower, thus staff The amount that liquid caustic soda enters can be adjusted accordingly.
Further, described alkali cleaning absorption tower is provided with the second explosion-proof circulating pump.
By using technique scheme, the second explosion-proof circulating pump can circulate the liquid in alkali cleaning absorption tower, reaches weight The multiple purpose utilizing, economizes on resources.
In sum, synthesize containing sulfur dioxide, sulfur trioxide, naphthalene and formaldehyde in emptying end gas, after being passed through condenser, Sulfur dioxide and formaldehyde are still gas, and major part sulfur trioxide becomes liquid, can be collected separately, and the analysis of a part of naphthalene crystal Go out, recovery can be collected;The remaining tail gas containing sulfur dioxide, formaldehyde and part naphthalene is passed through naphthalene recovery tower, and naphthalene recovery tower can More thoroughly separating naphthalene and other gases, thus reclaim naphthalene recycling;The now remaining tail containing sulfur dioxide and formaldehyde Gas is passed through stair oxidation absorption tower, and alkaline hydrogen peroxide solution is pumped into FRP hydrogen peroxide measuring tank and measures, then by membrane pump Being passed through stair oxidation absorption tower, formaldehyde can thoroughly be absorbed by the alkaline hydrogen peroxide solution in stair oxidation absorption tower, and only A part of sulfur dioxide can be absorbed;Running water pipe and acetone storage tank emptying offgas duct also lead to stair oxidation absorption tower, it is therefore an objective to Solution in dilution stair oxidation absorption tower and cooling, prevent thermal discharge excessive, and acetone gas also can be at stair oxidation Absorbed in absorption tower;The now remaining tail gas containing sulfur dioxide is passed through alkali cleaning absorption tower, and liquid caustic soda storage tank pipe is connected with carbon Molten steel alkali measuring tank, is used for measuring liquid caustic soda amount, and carbon steel liquid caustic soda measuring tank connects alkali cleaning absorption tower, liquid caustic soda is injected alkali cleaning and absorbs Tower, such sulfur dioxide is just completely absorbed in alkali cleaning absorption tower, such that it is able to by gas nontoxic for harmless by putting Blank pipe enters in air;Whole system absorb toxic and harmful respond well and thorough, and reclaimed naphthalene carry out again profit With.
Brief description
Fig. 1 is the flow chart of prior art;
Fig. 2 is the flow chart of the supporting tail gas absorbing system of the utility model aliphatic;
Fig. 3 is the enlarged drawing of part A in Fig. 2.
Brief description: the 1st, synthesize emptying end gas pipe;2nd, running water pipe;3rd, acetone storage tank emptying offgas duct;4th, liquid caustic soda storage tank Pipe;5th, alkali cleaning absorption tower;6th, condenser;7th, naphthalene recovery tower;8th, stair oxidation absorption tower;9th, membrane pump;10th, FRP hydrogen peroxide meter Measuring tank;11st, carbon steel liquid caustic soda measuring tank;12nd, blow-down pipe;13rd, floss hole;14th, air compensation device;15th, the first explosion-proof circulating pump;16、 Explosion proof and corrosion protection blower fan;17th, PH meter;18th, the second explosion-proof circulating pump.
Detailed description of the invention
With reference to Fig. 2 and Fig. 3, to the utility model aliphatic, the embodiment of supporting tail gas absorbing system is described further.
A kind of supporting tail gas absorbing system of aliphatic, including synthesis emptying end gas pipe the 1st, running water pipe the 2nd, acetone storage tank emptying Offgas duct the 3rd, liquid caustic soda storage tank pipe 4 and alkali cleaning absorption tower 5, described synthesis emptying end gas pipe 1 is connected with condenser 6, and the present embodiment is excellent Choosing, condenser 6 is spiral sheet condenser 6, and the temperature of condenser 6 inner cooling water is 5 DEG C, connects below described condenser 6 Being connected to naphthalene recovery tower 7, described naphthalene recovery tower 7 is connected with stair oxidation absorption tower 8, also includes membrane pump 9, and described membrane pump 9 is even Being connected to FRP hydrogen peroxide measuring tank 10, described FRP hydrogen peroxide measuring tank 10 connects stair oxidation absorption tower 8, described running water pipe 2 Leading to stair oxidation absorption tower 8 with acetone storage tank emptying offgas duct 3, described stair oxidation absorption tower 8 is connected with alkali cleaning absorption tower 5, described liquid caustic soda storage tank pipe 4 is connected with carbon steel liquid caustic soda measuring tank 11, and described carbon steel liquid caustic soda measuring tank 11 connects alkali cleaning absorption tower 5, The top on described alkali cleaning absorption tower 5 is provided with blow-down pipe 12.
The present embodiment is preferred, and the bottom of described naphthalene recovery tower 7 is provided with floss hole 13 and the first accumulator tank.
The present embodiment is preferred, is provided with air compensation device 14 between described naphthalene recovery tower 7 and stair oxidation absorption tower 8, described Acetone storage tank emptying offgas duct 3 leads to air compensation device 14.
The present embodiment is preferred, and described stair oxidation absorption tower 8 is provided with the first explosion-proof circulating pump 15, and described first explosion-proof follows Ring pump 15 is connected with the second accumulator tank.
The present embodiment is preferred, is provided with explosion proof and corrosion protection blower fan between described stair oxidation absorption tower 8 and alkali cleaning absorption tower 5 16。
The present embodiment is preferred, and described alkali cleaning absorption tower 5 is provided with PH meter 17.
The present embodiment is preferred, and described alkali cleaning absorption tower 5 is provided with the second explosion-proof circulating pump 18, described second explosion-proof circulating pump 18 are connected with the 3rd accumulator tank.
During aliphatic produces water reducer, synthesis emptying end gas and acetone can be produced, synthesis emptying end gas contains two Sulfur oxide, sulfur trioxide, naphthalene and formaldehyde, after being passed through condenser 6, sulfur dioxide and formaldehyde are still gas, major part three oxidation Sulphur becomes liquid, can be collected separately, and a part of naphthalene crystal separates out, and can collect recovery;Remaining containing sulfur dioxide, first The tail gas of aldehyde and part naphthalene is passed through naphthalene recovery tower 7, and naphthalene recovery tower 7 can more thoroughly separate naphthalene and other gases, thus reclaims Naphthalene recycles;The now remaining tail gas containing sulfur dioxide and formaldehyde is passed through stair oxidation absorption tower 8, and membrane pump 9 is by alkalescence Hydrogenperoxide steam generator pumps into FRP hydrogen peroxide measuring tank 10 and measures, and then passes to stair oxidation absorption tower 8, and stair oxidation is inhaled Formaldehyde can thoroughly be absorbed by the alkaline hydrogen peroxide solution received in tower 8, and can only absorb a part of sulfur dioxide;Running water pipe 2 and acetone storage tank emptying offgas duct 3 also lead to stair oxidation absorption tower 8, it is therefore an objective to dilution stair oxidation absorption tower 8 in solution And cooling, prevent thermal discharge excessive, and acetone gas also can be absorbed in stair oxidation absorption tower 8;Now remaining Tail gas containing sulfur dioxide is passed through alkali cleaning absorption tower 5, and liquid caustic soda storage tank pipe 4 is connected with carbon steel liquid caustic soda measuring tank 11, is used for measuring Liquid caustic soda amount, carbon steel liquid caustic soda measuring tank 11 connects alkali cleaning absorption tower 5, and liquid caustic soda is injected alkali cleaning absorption tower 5, and such sulfur dioxide just exists It is completely absorbed in alkali cleaning absorption tower 5, such that it is able to entered in air gas nontoxic for harmless by blow-down pipe 12;Whole Individual Systemic absorption toxic and harmful respond well and thorough, and reclaimed naphthalene and recycle.
The above is only preferred embodiment of the present utility model, and protection domain of the present utility model is not limited merely to Above-described embodiment, all technical schemes belonging under the utility model thinking belong to protection domain of the present utility model.Should refer to Go out, for those skilled in the art, under the premise of without departing from the utility model principle some improvement and Retouching, these improvements and modifications also should be regarded as protection domain of the present utility model.

Claims (7)

1. the supporting tail gas absorbing system of aliphatic, including synthesis emptying end gas pipe, running water pipe, acetone storage tank emptying tail gas Pipe, liquid caustic soda storage tank pipe and alkali cleaning absorption tower, it is characterised in that described synthesis emptying end gas pipe is connected with condenser, described condensation Device is connected with naphthalene recovery tower, and described naphthalene recovery tower is connected with stair oxidation absorption tower, also includes membrane pump, and described membrane pump connects Having FRP hydrogen peroxide measuring tank, described FRP hydrogen peroxide measuring tank connects stair oxidation absorption tower, described running water pipe and acetone storage Groove emptying end gas pipe leads to stair oxidation absorption tower, and described stair oxidation absorption tower is connected with alkali cleaning absorption tower, and described liquid caustic soda is store Barrel is connected with carbon steel liquid caustic soda measuring tank, and described carbon steel liquid caustic soda measuring tank connects alkali cleaning absorption tower, and described alkali cleaning absorption tower is provided with Blow-down pipe.
2. the supporting tail gas absorbing system of aliphatic according to claim 1, it is characterised in that described naphthalene recovery tower is provided with row Put mouth.
3. the supporting tail gas absorbing system of aliphatic according to claim 2, it is characterised in that described naphthalene recovery tower and one-level Being provided with air compensation device between oxidative absorption tower, described acetone storage tank emptying offgas duct leads to air compensation device.
4. the supporting tail gas absorbing system of aliphatic according to claim 3, it is characterised in that described stair oxidation absorption tower It is provided with the first explosion-proof circulating pump.
5. the supporting tail gas absorbing system of aliphatic according to claim 4, it is characterised in that described stair oxidation absorption tower And it between alkali cleaning absorption tower, is provided with explosion proof and corrosion protection blower fan.
6. the supporting tail gas absorbing system of aliphatic according to claim 5, it is characterised in that described alkali cleaning absorption tower is provided with PH counts.
7. the supporting tail gas absorbing system of aliphatic according to claim 6, it is characterised in that described alkali cleaning absorption tower is provided with Second explosion-proof circulating pump.
CN201620667954.2U 2016-06-27 2016-06-27 A kind of supporting tail gas absorbing system of aliphatic Active CN205700084U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110354646A (en) * 2019-07-01 2019-10-22 珠海醋酸纤维有限公司 Water absorbs acetone recovery system and its sterilizing methods

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110354646A (en) * 2019-07-01 2019-10-22 珠海醋酸纤维有限公司 Water absorbs acetone recovery system and its sterilizing methods

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