CN205687689U - A kind of supertension film device of water treatment facilities - Google Patents

A kind of supertension film device of water treatment facilities Download PDF

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CN205687689U
CN205687689U CN201620535035.XU CN201620535035U CN205687689U CN 205687689 U CN205687689 U CN 205687689U CN 201620535035 U CN201620535035 U CN 201620535035U CN 205687689 U CN205687689 U CN 205687689U
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unit
membrane structure
pressure
reverse osmosis
water
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权秋红
张建飞
元西方
黄瑞
郑新文
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SHANDONG LIAOCHENG BEIJIETE ENVIRONMENTAL PROTECTION ENGINEERING DESIGN Co Ltd
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SHANDONG LIAOCHENG BEIJIETE ENVIRONMENTAL PROTECTION ENGINEERING DESIGN Co Ltd
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Abstract

This utility model relates to the supertension film device of a kind of water treatment facilities, and described reverse osmosis concentrated draining reconcentration device at least includes: dirty water collecting tank, dosing unit, efficient sedimentation tank, sand filtration unit, plastics cartridge filter, DTRO membrane structure unit, two-pass reverse osmosis unit, product water unit;Wherein it is used for the described dirty water collecting tank collecting sewage to be connected with the described efficient sedimentation tank precipitated for completing sewage chemical, described efficient sedimentation tank is connected with the described sand filtration unit being used for filtering sewage by suspended colloid and fine particulates, described sand filtration unit is connected with the plastics cartridge filter being used for realizing secondary filter, described plastics cartridge filter is connected with DTRO membrane structure unit, and described DTRO membrane structure unit is connected with two-pass reverse osmosis unit.

Description

A kind of supertension film device of water treatment facilities
Technical field
This utility model relates to the membrane structure device of a kind of water treatment facilities, particularly relates to the superelevation of a kind of water treatment facilities Film pressing device.
Background technology
High slat-containing wastewater refers to the waste water of total saliferous mass fraction >=1%, typically belongs to used water difficult to degradate.The most industrial dense Saline, its inorganic salinity containing high concentration and substantial amounts of refractory organic or noxious substance, if this type of waste water is not Treated it is directly discharged into natural water body, aqueous bio, Drinking Water and industrial and agricultural production water will necessarily be produced greatly Harm, will cause huge pressure to ecological environment.Processing method be broadly divided into biological treatment and physical chemistry Method.The most relatively common has distillation desalination process, absorption method, embrane method, reverse osmosis, bioanalysis etc..
Biological treatment is that current waste water processes one of most common method, and it has applied range, strong adaptability etc. Feature.But the inorganic salt in high saline sewage has stronger inhibitory action, the Organic substance root of high saline sewage to general microorganism Different according to production process, contained organic kind and chemical property differ greatly, but contained salts substances mostly is Cl-、SO4 2-、 Na+And Ca2+Deng salts substances.Although these ions are all nutrients necessary to growth of microorganism.If but these ions Excessive concentration, can produce suppression and toxic action to microorganism.To this end, the biological treatment of high saline sewage is generally at low salt concn (salinity < is run for 1% time.Day however as water resource is becoming tight, the every regulation of water conservation of country's appearance and receipts The enforcement taken, the enterprise processed to high saline sewage brings burden, when salinity is more than 2g/L in sewage, uses bioanalysis Carry out high-salt sewage intractability bigger.
Physical-chemical process includes distilling desalination process, adsorption technology, film desalination process etc..Distillation desalination process be one the most ancient, The most frequently used desalination process, the way of distillation is allowed to explosive evaporation brackish water heating exactly, then steam is condensed into the process of fresh water. The advantage of the way of distillation is that simple in construction, processing ease, gained fresh water water quality are good etc..The way of distillation has a variety of, applies relatively broad Have: multiple-effect evaporation MED, low temperature multiple-effect distillation LT-MED, multistage flash evaporation MSF etc..Adsorption technology is to utilize adsorbent and pollution Physics chemical action between thing be combined with each other, by pollutant removing from water.According to the difference of adsorption mechanism, physics can be divided into Absorption, chemisorbed and ion-exchange absorption are attached, it is often the case that three kinds of mechanism occur simultaneously.Film desalination process is to utilize permeable pressure head The technology of desalination is realized as motive force.Film desalination process mainly has reverse osmosis (RO), disc tube reverse osmosis (dt-ro) DTRO, Membrane Materials MD, just Infiltration FO, electrodialysis ED etc..It is low that film desalination process has small investment, energy consumption, also is able to reach deep desalting purpose simultaneously, and producing water can As recycle-water.Simple in construction, processing ease, gained fresh water water quality are good, but but there is investment cost height, floor space Greatly, consume energy the shortcomings such as height.
At present, the process technique processing the haline waters such as reverse osmosis concentrated water in the world mainly have employed embrane method and full-boiled process distillation, Wherein " ultrafiltration+reverse osmosis " double membrane process have become the dominant technology of current deep desalting, and some country is to industrial high strong brine Carry out the recycling of fresh water and salt, be truly realized sewage " zero-emission " or " become zero-emission ".Strong brine treatment technology Development trend be to develop concentration new technique, improve pure water productivity and concentration and recovery rate etc..
Summary of the invention
For the deficiency of prior art, this utility model provides the supertension film device of a kind of water treatment facilities, described Reverse osmosis concentrated draining reconcentration device at least includes: dirty water collecting tank, dosing unit, efficient sedimentation tank, sand filtration unit, plastics are protected Peace filter, DTRO membrane structure unit, two-pass reverse osmosis unit, product water unit;Wherein said dirty water collecting tank with described efficiently Sedimentation tank is connected, and described efficient sedimentation tank is connected with described sand filtration unit, and described sand filtration unit is connected with plastics cartridge filter, Described plastics cartridge filter is connected with DTRO membrane structure unit, described DTRO membrane structure unit and two-pass reverse osmosis unit phase Even.
According to one preferred embodiment, described dosing unit includes dosing tank, chemical dissolving box and dosing pump, described Dosing tank dissolves case with described dosing and is connected, and described dosing is dissolved case and is connected with efficient sedimentation tank by dosing pump.
According to one preferred embodiment, described two-pass reverse osmosis unit includes pressing in reverse osmosis GTN3 membrane structure list Unit, reverse osmosis high-pressure GTR4 membrane structure unit, middle pressure booster pump, high-pressure booster, the dense water tank of middle pressure, high-pressure thick water tank;Described DTRO membrane structure unit presses GTN3 membrane structure unit to be connected by middle pressure booster pump in reverse osmosis, presses GTN3 in described reverse osmosis Membrane structure unit water tank dense with middle pressure and product Water circulation unit are respectively connected with;The dense water tank of medium pressure passes through described high-pressure booster It is connected with reverse osmosis high-pressure GTR4 membrane structure unit, described reverse osmosis high-pressure GTR4 membrane structure unit and high-pressure thick water tank and product water Reuse unit is respectively connected with.
According to one preferred embodiment, described DTRO membrane structure unit is also connected with product water unit.
According to one preferred embodiment, described dosing tank is vertical square tube, described square tube length and width a height of 300 × 380 ×550mm。
According to one preferred embodiment, described efficient sedimentation tank is cube shaped frame, its length and width are a height of 5800 × 1200 × 1800mm, wall thickness 10mm.
According to one preferred embodiment, described high-pressure thick water tank and evaporative crystallization unit or degraded exhaust unit phase Even.
According to one preferred embodiment, in described reverse osmosis, pressure GTN3 membrane structure unit employing width of flow path is The middle press mold element of 1.524~1.778mm, described high pressure GTR4 membrane structure unit uses width of flow path to be 1.905~2.159mm High-pressure membrane element.
According to one preferred embodiment, described sand filtration unit is vertical type cylinder shape structure, its a diameter of 380mm, high Degree 380mm, wall thickness 10mm.
According to one preferred embodiment, described dirty water collecting tank is connected with described efficient sedimentation tank, described the most heavy Pond, shallow lake is connected with described sand filtration unit, and described sand filtration unit is connected with plastics cartridge filter, described plastics cartridge filter and DTRO membrane structure unit is connected, and described DTRO membrane structure unit is connected with two-pass reverse osmosis unit;
Described dosing unit includes that case is dissolved in dosing tank, chemical dissolving box and dosing pump, described dosing tank and described dosing Being connected, described dosing is dissolved case and is connected with efficient sedimentation tank by dosing pump;
Described two-pass reverse osmosis unit includes pressing in reverse osmosis GTN3 membrane structure unit, reverse osmosis high-pressure GTR4 membrane structure list Pressure booster pump first, middle, high-pressure booster, the dense water tank of middle pressure, high-pressure thick water tank;
Described DTRO membrane structure unit by middle pressure booster pump and reverse osmosis being pressed GTN3 membrane structure unit be connected, described instead Infiltration is pressed GTN3 membrane structure unit water tank dense with middle pressure and product Water circulation unit are respectively connected with;The dense water tank of medium pressure passes through institute State high-pressure booster to be connected with reverse osmosis high-pressure GTR4 membrane structure unit, described reverse osmosis high-pressure GTR4 membrane structure unit and high pressure Dense water tank and product Water circulation unit are respectively connected with, and described DTRO membrane structure unit is also connected with product water unit.
Accompanying drawing explanation
Fig. 1 is each functional unit connection diagram of this utility model device;
Fig. 2 is that this utility model device BAF is to COD, SS, NH_3-N treating design sketch;
Fig. 3 is this utility model highly dense pond Inlet and outlet water hardness and the change curve of hardness extrusion rate;
Fig. 4 be in this utility model embodiment in be pressed into water, produce water and dense water versus time curve figure;
Fig. 5 is the water inlet of this utility model embodiment mesohigh, produces water and dense water versus time curve figure;
Fig. 6 is supertension water inlet in this utility model embodiment, produces water and dense water versus time curve figure;
Fig. 7 is supertension dense water TDS versus time curve figure in this utility model embodiment;With
Fig. 8 is the reverse osmosis units removal effect figure to COD in this utility model embodiment.
Detailed description of the invention
It is described in detail below in conjunction with the accompanying drawings.
As it is shown in figure 1, dirty water collecting tank is connected with the described efficient sedimentation tank being used for sewage chemical precipitation, described height Effect sedimentation tank is connected with the described sand filtration unit being used for filtering sewage by suspended colloid and fine particulates, described sand filtration unit and use Being connected in the plastics cartridge filter realizing secondary filter, described plastics cartridge filter is connected with DTRO membrane structure unit, institute State DTRO membrane structure unit to be connected with two-pass reverse osmosis unit;Described dosing unit includes dosing tank, chemical dissolving box and dosing Pump, described dosing tank and described dosing are dissolved case and are connected, and described dosing is dissolved case and is connected with efficient sedimentation tank by dosing pump;Institute State two-pass reverse osmosis unit to include reverse osmosis being pressed GTN3 membrane structure unit, reverse osmosis high-pressure GTR4 membrane structure unit, middle pressure increase Press pump, high-pressure booster, the dense water tank of middle pressure, high-pressure thick water tank;Described DTRO membrane structure unit is by middle pressure booster pump and reverse osmosis Middle pressure GTN3 membrane structure unit is connected, and presses GTN3 membrane structure unit and the dense water tank of middle pressure and product Water circulation list in described reverse osmosis Unit is respectively connected with;The dense water tank of medium pressure is connected with reverse osmosis high-pressure GTR4 membrane structure unit by described high-pressure booster, institute State reverse osmosis high-pressure GTR4 membrane structure unit to be respectively connected with high-pressure thick water tank and product Water circulation unit, described DTRO membrane structure list Unit is also connected with product water unit.
Described dosing tank is used for laying in coagulant, and described coagulant includes in aluminum sulfate, ferric chloride and ferrous sulfate One or more.Described sand filtration unit is using quartz sand and manganese sand as sand filtration material, and grit particle diameter is 0.5~1mm.Described high pressure Dense water tank is connected with evaporative crystallization unit or degraded exhaust unit.Described reverse osmosis is pressed GTN3 membrane structure unit use runner width Degree is the middle press mold element of 1.524~1.778mm, described high pressure GTR4 membrane structure unit use width of flow path be 1.905~ 2.159mm high-pressure membrane element.Pressing GTN3 membrane structure unit intake pressure index in described reverse osmosis is 2.0~3.5MPa;Institute Stating high pressure GTR4 membrane structure unit intake pressure index is 3.5~4.5MPa.Described dosing tank is vertical square tube, and described square tube is advised Lattice are 300 × 380 × 550mm.Described efficient sedimentation tank is cube shaped frame, and its specification is 5800 × 1200 × 1800mm, wall Thick 10mm.It is vertical type cylinder shape structure that described sand considers unit, its a diameter of 380mm, highly 380mm, wall thickness 10mm.
Embodiment 1
Water treatment facilities is divided into three unit according to major function: biochemical treatment unit, enter film pretreatment unit, supertension Membrane method unit.
Biochemical treatment unit uses BAF (BAF), is removed SS, COD, BOD, nitrification by biomembrance process, is taken off Nitrogen, dephosphorization, removal AOX etc..Pretreatment section uses high efficiency clarification tank+sand filtration, reduces hardness, COD, glue by physical-chemical reaction Body and turbidity etc., it is ensured that the efficiency of follow-up reverse osmosis advanced processing unit and operation stability.Supertension membrane method unit can be stablized Salinity in removing water, processes high-salt wastewater, does super concentration for zero-emission, reduces evaporation capacity and does technological reserve.
Certain embodiment MTO waste water after anaerobic biochemical treatment, in water containing higher anaerobe, ammonia nitrogen, COD, SS etc..For ensureing reverse-osmosis treated unit influent quality and the stable operation of equipment, use BAF that MTO is given up Water carries out biochemical treatment, its mechanism be by biological contact oxidation process with feedwater rapid filter organically combine, by biodegradation with Two kinds of processing procedures of adsorption filtration are incorporated in same unitary reactor, with the particulate filler of filling in filter tank (such as haydite, Jiao Charcoal, quartz sand, activated carbon etc.) it is carrier, inside filter tank, carry out aeration, make filter material surface grow large number of biological film.Work as sewage When flowing through, utilize the oxygenolysis of the active microorganism of appended biomembrane middle and high concentration on filtrate, give full play to microorganism The physical absorption of biological metabolism, bioflocculation, biomembrane and filler and retain and in reactor along water (flow) direction food chain Classification predation, complete the efficient removal of pollutant.
BAF is using cobblestone and slag haydite as filler.Process though BAF is biomembrane The one of method, but compared with traditional biological filter tank, still has an evident characteristic: the little granular filler of the rough porous that (1) uses As bio-carrier, higher Biomass (up to 10~15g/L) can be kept at filling surface, it is easy to biofilm and stable; (2) biofacies is complicated, and Bacterial community is reasonable, has obvious spatial gradient feature in reactor, be resistant to higher organic and Hydraulic blow load, different pollutant can be removed gradually at same reactor, synchronizes to play biological oxidation, biology Adsorption-flocculation and Physical entrapment effect, effluent quality is good, can meet reuse requirement;(3) it is different from general biofilter and biology Filter tower, need to carry out aeration when removing BOD, ammonia nitrogen, but particulate filler layer has higher oxygen transfer efficiency, and aeration rate is low, fortune Row energy consumption is relatively low, and nitrification and denitrification efficiency is high;(4) filter tank is semiclosed or totally-enclosed structures, and its biochemical reaction is by the external world Temperature impact is less, is suitable for cold district and carries out sewage disposal;(5) microbial biomass of high concentration increase filter tank volume bear Lotus, and then reduce pool volume and floor space, make capital cost be substantially reduced;(6) filter tank running passes through backwash Remove the pollutant retained in filtering layer and the biomembrane come off, it is not necessary to second pond, simplify technological process, use modular construction Design, makes operational management convenient;(7) Sewage Plant abnormal flavour is decreased, without sludge bulking problem, it is not necessary to sludge reflux.
Due to after BAF biochemical treatment, possibly together with the ion of easy fouling in water, part can not be biological The Organic substance of degraded, the dirt easily causing membranous system is blocked up, for ensureing the stable operation of follow-up reverse osmosis units, pretreatment employing carbon Acid sodium and sodium hydroxide softening, PAC coagulation, PAM help solidifying high dense settling pond and sand filtration.Softening process returns at high saline sewage Being widely used in, operating cost is low, can control chemical feeding quantity flexibly according to influent quality;Except removing partial organic substances and micro- Biology, reduces outside float further, and topmost effect is to reduce the basicity in sewage and temporary hardness, it is ensured that follow-up By safety and the economy of water.Coagulation clarification arranges sand filtration filter element after processing, and removes the fine particle in water, suspension further The impurity such as thing, colloid.
High dense settling pond by coagulation, flocculating and precipitating three unit of clarification organically combines and forms.Its technological core is Sludge reflux and tube settling application, provided cohesion core by sludge reflux, added reaction zone concentration of suspension, reinforcement Flocculating effect has reclaimed part medicament simultaneously.
High dense settling pond has removal dirty Organic substance in water, colloid, the effect of float.High dense settling pond entrance is Coagulant dosage unit, is sufficiently stirred for making coagulant and sewage be fully contacted by blender and carries out coagulating, formed a large amount of Flocculation group.Sewage by bottom coagulation section water outlet enter sedimentation tank flocculation unit, flocculation unit by add flocculant with And low rate mixing makes above-mentioned a large amount of flocculations group form big and closely knit alumen ustum.Sewage through flocculation section enters high density clarification The precipitation clarification unit in pond, is provided with enough sloping plate deposition areas in this element, makes the current can be with through sloping plate deposition The flow velocity relaxed flows through sloping plate deposition, and the clear water of top overflow is collected by collecting tank and flowed into next treatment facility, and bottom is precipitated The alumen ustum got off, along swash plate slide downward, is deposited in precipitation clarification unit bottom, and the mud part in bucket is by sludge reflux Front end coagulation section backflow squeezed into by pump, in order to giving full play to the effect of medicament, excess sludge is squeezed into mud pit by sludge lifting pump, enters Enter Treatment of Sludge flow processing.
The feature of high dense settling pond: (1) is provided with outside sludge circulation system and mud is risen to instead from sludge condensation district Answer pond water inlet pipe, mix with former water;(2) cohesion-flocculation is carried out in two reaction zones, first passes through the hybrid reaction of stirring District, subsequently enters pulling flow type reaction zone;(3) synthesis organic flocculant PAM is used;(4) from low speed reaction zone to tube settling district Alumen ustum can keep completely, and the alumen ustum matter produced is equal, density is high;(5) efficient tube settling is used, the settling zone rate of climb Up to 20~40m/h, efficient alumen ustum is well precipitated at this;(6) can effectively complete sludge condensation, effluent quality is steady Fixed, anti impulsion load.
Settling zone water outlet is through the filtering layer of sand filtration, it is possible to effectively removes the impurity such as float, colloid in water, works as filtering layer In the impurity that retains too much time, filtering layer mesopore is blocked, and the resistance of current increases, and the rate of filtration diminishes, and crosses filtering velocity for recovering former Degree, can use sand filtration water outlet and compressed air to carry out regular backwash, the impurity accumulated is rinsed out in filtrate hole, recovers to filter Ability.Conventional filtering layer filler is quartz sand, retains the precision of float more than 5~10 μm, and delivery turbidity is at below 3NTU.
Super concentration high-pressure membrane technology with extraordinary diaphragm and the special membrane structure super reverse osmosis concentration technology as core, GTR series membranes is wider than standard pollution-resistant membrane runner, blocks up more resistant to dirt, and diaphragm is more firm, it is ensured that under high pollution, high concentration ratio Stable operation, reduce cleaning frequency, extend film high-performance;It is divided into middle pressure GTR3 series, high pressure GTR4 series and import DTRO series, can realize the concentration segmentation of TDS, and middle pressure GTR3 film is to more than 15000mg/L, high pressure GTR4 film to 45000mg/ More than L, beneficially balance film efficiency and reduction energy consumption.One of core of this technology is extraordinary diaphragm, can hold compared with conventional film By higher operation pressure, the tolerance float of higher concentration, colloid and COD, substantially improve influent quality index is severe Carve requirement;In membrane structure, have employed broader runner, form accessible turbulent flow, significantly slow down the fouling of film, it is ensured that be long Periodic duty.
Super concentration technique refers to select conventional pretreatment facility (such as softening, filtration etc.), use special antipollution dense Contracting reverse osmosis membrane (middle pressure, high pressure, supertension reverse osmosis membrane), by optimizing the response rate and the operating condition of membranous system, with special Mode realize the concentration minimizing (concentrated solution TDS can generally achieve 5%~10%) of strong brine, playing membranous system While superiority, reduce investment and the operating cost of " zero-emission " integrated artistic.The great advantage of this technology is to utilize special type Membrane structure (wide runner, material are special) makes brackish water realize high power concentration under not undergoing phase transition;Open by using Wide runner design, its support flow guiding disc surface particular design, make divided fluid stream uniform, and form more preferably turbulence effects, maximum journey Reduce film surface scale, pollution and the generation of concentration polarization phenomenon on degree, make that there is stronger antifouling property, place pre-to waste water Reason requires relatively low.This technology has realized breakthrough at aspects such as high slat-containing wastewater process, sewage " zero-emission " at present, Possesses industrialized condition.
The large-scale embodiment system that embodiment testing equipment is made up of 2 40 forty equivalent unit 40s, is respectively at biochemical Reason unit, enters film pretreatment unit and supertension membrane method unit, and device itself can analyze turbidity, electrical conductivity, TDS, pH, SDI Etc. index, embodiment device is the equipment completely system of advanced person, is furnished with complete on-line monitoring instrument and robot control system(RCS), with Time be scheduled that rational sample tap.Each container is allocated as follows: container one is BAF biochemistry unit;Container two For entering film pretreatment+supertension membrane method unit.
Biological aerated filter process (BAF) unit design water inlet scale is 1m3/ h, filler volume is 5m3, total measurement (volume) is 6.23m3, Φ 1416 × 5510mm, filler is cobblestone and slag haydite, and volumetric loading is 0.3kg COD/m3D, if There is 2m3Inlet water tank and each one of water tank, capital equipment and specification or performance parameter such as following table 2-1.
Table 2-1 BAF unit essential equipment (UEE) table
This project enter film pretreatment+supertension membrane method unit, be positioned in container two, pre-processing device design scale is 5m3/ h, it is 2.1m that this embodiment processes the water yield3/h.Supertension embrane method system uses special antipollution to concentrate reverse osmosis membrane, And middle pressure, high pressure, supertension and auxiliary medicine system, by optimizing the response rate and the operating condition of membranous system, with special side Formula realize strong brine concentration minimizing (concentrated solution TDS can generally achieve 5%~8%, play membranous system superiority While, reduce investment and the operating cost of " zero-emission " integrated artistic.Design is pressed aquifer yield 1.8m3/ h, high pressure aquifer yield 0.8m3/ h, supertension aquifer yield 0.1m3/h。
Dirty water collecting tank be used for sewage chemical precipitation described efficient sedimentation tank be connected, described efficient sedimentation tank and Be connected with the described sand filtration unit of fine particulates for filtering sewage by suspended colloid, described sand filtration unit be used for realizing precision The plastics cartridge filter filtered is connected, and described plastics cartridge filter is connected with DTRO membrane structure unit, and described DTRO film is tied Structure unit is connected with two-pass reverse osmosis unit;Described dosing unit includes dosing tank, chemical dissolving box and dosing pump, described dosing Case dissolves case with described dosing and is connected, and described dosing is dissolved case and is connected with efficient sedimentation tank by dosing pump;Described two grades of reverse osmosis Unit includes pressing GTN3 membrane structure unit, reverse osmosis high-pressure GTR4 membrane structure unit, middle pressure booster pump, high pressure to increase in reverse osmosis thoroughly Press pump, the dense water tank of middle pressure, high-pressure thick water tank;Described DTRO membrane structure unit is by pressing GTN3 film in middle pressure booster pump and reverse osmosis Construction unit is connected, and presses GTN3 membrane structure unit water tank dense with middle pressure and product Water circulation unit to be respectively connected with in described reverse osmosis; The dense water tank of medium pressure is connected with reverse osmosis high-pressure GTR4 membrane structure unit by described high-pressure booster, described reverse osmosis high-pressure GTR4 membrane structure unit and high-pressure thick water tank and produce Water circulation unit and be respectively connected with, described DTRO membrane structure unit also with produce water list Unit is connected.
Described dosing tank is used for laying in coagulant, and described coagulant includes in aluminum sulfate, ferric chloride and ferrous sulfate One or more.Described sand filtration unit is using quartz sand and manganese sand as sand filtration material, and grit particle diameter is 0.5~1mm.Described high pressure Dense water tank is connected with evaporative crystallization unit or degraded exhaust unit.Described reverse osmosis is pressed GTN3 membrane structure unit use runner width Degree is the middle press mold element of 1.524~1.778mm, described high pressure GTR4 membrane structure unit use width of flow path be 1.905~ 2.159mm high-pressure membrane element.Pressing GTN3 membrane structure unit intake pressure index in described reverse osmosis is 2.0~3.5MPa;Institute Stating high pressure GTR4 membrane structure unit intake pressure index is 3.5~4.5MPa.
Main Analysis project of the present embodiment is pH, electrical conductivity, CODcr, ammonia nitrogen, SS, total hardness, total alkalinity, The contents such as chloride ion, electrical conductivity, turbidity etc., specific analytical method and detection limit see table 3-1.
Table 3-1 embodiment analyzes method table
BAF is processed as 24 hours running without interruption, supertension membranous system intermittent duty, the micro-life of ozone water outlet Thing limited amount, so embodiment BAF Starting mode uses inocalation method, inocalation method refers in other biological treatment system Mud is added in reactor carry out, as strain, the startup method cultivated.Certain embodiment MTO anaerobic pond mixed liquor 5m3(SV It is 30%, activated sludge concentration: about 4000mg/L), pump in BAF reactor, carry out vexed exposure, hereafter every 24 hours, enter Ozone water outlet about 1m3After, continue vexed exposure, Inlet and outlet water water quality to such as shown in table 3-2 during stable operation.
Table 3-2BAF Inlet and outlet water water quality contrasts
BAF more can be clearly reacted to COD, SS, NH_3-N treating effect by Figure of description 2.
Potassium permanganate composites medicine system is made up of five parts: flocculant PAC dosing part, flocculation aid PAM dosing part, Na2CO3 dosing part, NaOH dosing part, HCl dosing part.The wherein concentration of PAC, PAM, Na2CO3, NaOH, HCl solution It is respectively 5%, 0.2%, 2%, 2%, 35%.First carry out pilot plant test according to water water analysis, determine optimal addition dosage. The dosing of highly dense pond is done lab scale test, and test data is shown in Table 3-3.
Table 3-3 pilot plant test chemical feeding quantity correspondence hardness relation
According to pilot run and the accounting of dosing cost, select PAC, PAM, Na2CO3, NaOH chemical feeding quantity be respectively 30ppm、1.2ppm、20ppm、15ppm.Average hardness extrusion rate is 91.89%, and service data collects as shown in table 3-4:
Table 3-4 highly dense pond Inlet and outlet water hardness data summarization
See Figure of description 3 highly dense pond Inlet and outlet water hardness and the change of hardness extrusion rate.
Supertension membrane method unit normal operation, owing to middle pressure reverse osmosis provides the dense water yield limited, therefore, high pressure and supertension Reverse osmosis operates to periodic running.Carrying out practically data are shown in Table 3-5.
Table 3-5 supertension membrane method unit treating capacity
The middle pressure reverse osmosis response rate is 80%, and film intake pressure is 2.0MPa, upper table data can calculate average salt rejection rate It is 96.3%.The average salt rejection rate of high pressure reverse osmosis is 97.43%, controls at 4.2MPa entering film pressure, and the response rate is 63.63%.The when of supertension reverse osmosis concentrated water pressure 10MPa, the response rate is 50%, and average salt rejection rate is 92.03%.
Pretreatment, middle pressure, high pressure, supertension integrated artistic, former water confluent is 2.4m3/ h, pretreatment efficient sedimentation tank Can run continuously with 24h with middle pressure reverse osmosis, other reverse osmosiss can not run continuously, and high pressure reverse osmosis runs 11h/ days;Superelevation Pressure reverse osmosis runs 7h/ days, and recycled in its entirety rate 95.45%, shown in detailed data table 3-7.
Table 3-7 middle high-pressure and the supertension reverse osmosis response rate and salt rejection rate
Seeing Figure of description 4,5,6,7 four curve chart response situation, middle pressure reverse osmosis runs under stable case, pressure Power controls at 2.0MPa, in order to prevent the dirt of diaphragm from blocking up, at every 2h low-pressure washing about 3min.High pressure reverse osmosis is in stable case Lower operation, pressure is at 4.2MPa, and owing to high pressure feed water by reverse osmosis salinity is high, therefore operating pressure rises very fast, at 50min~ 60min low-pressure washing about 3min, each flushing water is from reverse osmosis produced water.By Figure of description 7 it can be seen that the dense water of supertension TDS meansigma methods is 72100ppm, and dense water can direct follow-up entrance crystallization and evaporation system.
Investigating this technique from COD, former water COD is 105mg/L in meansigma methods, and the middle average COD of pressure reverse osmosis produced water is 6.1mg/L, clearance is 94.2%;The average COD of high pressure reverse osmosis produced water is 16.16mg/L, and clearance is 95.8%;Supertension Reverse osmosis produced water COD meansigma methods is 75mg/L, and clearance is 95.5%.Concrete data are as shown in table 3-8:
In 3-8, pressure produces water, high pressure produces water, supertension produces water COD information slip
Reverse osmosis units sees Figure of description 8 to the removal effect of COD.By this embodiment analysis of experiments table existing Bright:
(1) BAF unit: from the point of view of the data obtained, COD, SS, ammonia nitrogen are put down by BAF All extrusion rates are respectively 62.45%, 55.88%, 64.78%, further increase the biodegradability of waste water, simultaneously for entering height The subsequent treatment of Mi Chi reduces cost.
(2) highly dense pond+sand filtration unit: high efficiency clarification tank device, has effectively played sodium carbonate/sodium hydroxide and has softened, drops The functions such as soft, float colloid and turbidity, determine suitably add dose in the case of (sodium carbonate 20mg/L, hydrogen-oxygen Change sodium 15mg/L, PAC 30mg/L, PAM 1.2mg/L, hydrochloric acid 20mg/L), total hardness clearance 91.89%, it is ensured that follow-up instead The stable operation of penetration equipment.
(3) supertension reverse osmosis units: high dense settling pond, sand filtration, reverse osmosis are properly functioning, middle pressure, high pressure and super The each salt rejection rate of high pressure reverse osmosis is respectively as follows: 96.3%, 97.43% and 92.03%, average salt rejection rate 95.25%, corresponding each instead The permeation unit response rate is respectively as follows: 75%, 63.63% and 50%, flow process recycled in its entirety rate 95.45%.
It can be seen that each unit can be run by complete stability from data above conclusion, it is possible to effectively eliminate in water Most of soluble salt is divided, float, colloid, hardness, basicity, COD, Organic substance and microorganism etc..Original water hardness is low, hard-off By a relatively simple, produce water can directly replenishment cycles sewer or boiler chemical water station processing unit, after the degree of depth softens, benefit Fill boiler feedwater.The crystallizable evaporation of dense water.
It should be noted that above-mentioned specific embodiment is exemplary, those skilled in the art can be open in the present invention Find out various solution under the inspiration of content, and these solutions also belong to disclosure of the invention scope and fall into this Within bright protection domain.It will be understood by those skilled in the art that description of the invention and accompanying drawing thereof be illustrative and not Constitute limitations on claims.Protection scope of the present invention is limited by claim and equivalent thereof.

Claims (10)

1. the supertension film device of a water treatment facilities, it is characterised in that described water treatment facilities at least includes: sewage collecting Case, dosing unit, efficient sedimentation tank, sand filtration unit, plastics cartridge filter, DTRO membrane structure unit, two-pass reverse osmosis unit With product water unit;
Wherein said dirty water collecting tank is connected with described efficient sedimentation tank, and described efficient sedimentation tank is connected with described sand filtration unit, Described sand filtration unit is connected with plastics cartridge filter, and described plastics cartridge filter is connected with DTRO membrane structure unit, described DTRO membrane structure unit is connected with two-pass reverse osmosis unit.
2. the supertension film device of water treatment facilities as claimed in claim 1, it is characterised in that described dosing unit includes adding Medicine-chest, chemical dissolving box and dosing pump, described dosing tank and described dosing are dissolved case and are connected, and described dosing is dissolved case and passed through dosing Pump is connected with efficient sedimentation tank.
3. the supertension film device of water treatment facilities as claimed in claim 1, it is characterised in that described two-pass reverse osmosis unit Including in reverse osmosis press GTN3 membrane structure unit, reverse osmosis high-pressure GTR4 membrane structure unit, middle pressure booster pump, high-pressure booster, The dense water tank of middle pressure, high-pressure thick water tank;
Described DTRO membrane structure unit presses GTN3 membrane structure unit to be connected by middle pressure booster pump in reverse osmosis, described reverse osmosis Middle pressure GTN3 membrane structure unit water tank dense with middle pressure and product Water circulation unit are respectively connected with;The dense water tank of medium pressure passes through described height Pressure booster pump is connected with reverse osmosis high-pressure GTR4 membrane structure unit, described reverse osmosis high-pressure GTR4 membrane structure unit and high-pressure thick water Case and product Water circulation unit are respectively connected with.
4. the supertension film device of water treatment facilities as claimed in claim 1, it is characterised in that described DTRO membrane structure unit Also it is connected with product water unit.
5. the supertension film device of water treatment facilities as claimed in claim 2, it is characterised in that described dosing tank is vertical type square Cylinder, described a height of 300 × 380 × 550mm of square tube length and width.
6. the supertension film device of water treatment facilities as claimed in claim 1, it is characterised in that described efficient sedimentation tank is vertical Square structure, a height of 5800 × 1200 × 1800mm of its length and width, wall thickness 10mm.
7. the supertension film device of water treatment facilities as claimed in claim 3, it is characterised in that described high-pressure thick water tank and steaming Send out crystalline element or degraded exhaust unit is connected.
8. the supertension film device of water treatment facilities as claimed in claim 3, it is characterised in that press GTN3 in described reverse osmosis The middle press mold element that membrane structure unit uses width of flow path to be 1.524~1.778mm, described high pressure GTR4 membrane structure unit uses Width of flow path is the high-pressure membrane element of 1.905~2.159mm.
9. the supertension film device of water treatment facilities as claimed in claim 1, it is characterised in that described sand filtration unit is vertical Cylindrical structural, its a diameter of 380mm, highly 380mm, wall thickness 10mm.
10. the supertension film device of water treatment facilities as claimed in claim 1, it is characterised in that described dosing unit includes Dosing tank, chemical dissolving box and dosing pump, described dosing tank and described dosing are dissolved case and are connected, and described dosing dissolves case by adding Teat pipette is connected with efficient sedimentation tank;
Described two-pass reverse osmosis unit include in reverse osmosis press GTN3 membrane structure unit, reverse osmosis high-pressure GTR4 membrane structure unit, Middle pressure booster pump, high-pressure booster, the dense water tank of middle pressure, high-pressure thick water tank;
Described DTRO membrane structure unit presses GTN3 membrane structure unit to be connected by middle pressure booster pump in reverse osmosis, described reverse osmosis Middle pressure GTN3 membrane structure unit water tank dense with middle pressure and product Water circulation unit are respectively connected with;The dense water tank of medium pressure passes through described height Pressure booster pump is connected with reverse osmosis high-pressure GTR4 membrane structure unit, described reverse osmosis high-pressure GTR4 membrane structure unit and high-pressure thick water Case and product Water circulation unit are respectively connected with, and described DTRO membrane structure unit is also connected with product water unit.
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