SUMMERY OF THE UTILITY MODEL
An object of the utility model is to provide a boats and ships waste gas deNOx systems can make boats and ships waste gas temperature satisfy the required temperature of SCR reaction and reduce the atmosphere pollution.
The utility model discloses a boats and ships waste gas deNOx systems, include
The exhaust gas denitration pipeline is connected with the exhaust end of the diesel engine through a first valve;
the exhaust gas bypass pipeline is connected with the exhaust end of the diesel engine through a second valve;
the denitration reactor is connected in the waste gas denitration pipeline;
one end of the heating pipeline is connected with the air outlet of the incinerator through a third valve, and the other end of the heating pipeline is communicated with the waste gas denitration pipeline;
the heating bypass pipeline is connected with the air outlet of the incinerator through a fourth valve; wherein,
the first valve and the third valve are opened, the second valve and the fourth valve are closed, and the waste gas of the incinerator and the waste gas of the diesel engine are mixed and subjected to temperature regulation in the waste gas denitration pipeline through the heating pipeline, enter the denitration reactor, are subjected to denitration and are discharged; the first valve and the third valve are closed, the second valve and the fourth valve are opened, and the waste gas of the incinerator and the waste gas of the diesel engine are directly discharged through the heating bypass pipeline and the waste gas bypass pipeline respectively.
Furthermore, the exit end of this denitration reactor is equipped with the exhaust pipe, and this exhaust pipe passes through the exhaust valve and is connected with this waste gas denitration pipeline, and this waste gas denitration pipeline is equipped with the fifth valve after the position of being connected with this exhaust pipe, and this first valve, this fourth valve and this fifth valve are closed, and this third valve and this exhaust valve open, burn burning furnace waste gas and get into this denitration reactor through this heating pipeline, this waste gas denitration pipeline and then discharge by this exhaust pipe.
Further, the length of the pipeline between the air outlet of the incinerator and the inlet of the denitration reactor is less than 2.5 meters.
Further, the exhaust end of the heating bypass line is connected with the exhaust bypass line at a position after the second valve.
Further, the exhaust end of the exhaust gas denitration pipeline is connected with a waste heat boiler, and the exhaust end of the exhaust gas bypass pipeline is connected with the waste heat boiler through a sixth valve.
Furthermore, each valve is an automatic control valve.
Further, be equipped with turbo charger between this diesel engine and this boats and ships exhaust gas denitration system, this turbo charger includes exhaust inlet end, exhaust outlet end, air inlet end and air outlet end, and this exhaust inlet end is connected with the exhaust end of this diesel engine, and this exhaust outlet end is connected with this exhaust gas denitration pipeline, this exhaust gas bypass pipeline.
Further, a mixer is further arranged in the waste gas denitration pipeline, and a urea solution spray gun is arranged in the mixer before the mixer is positioned in the denitration reactor.
Further, a soot blower is arranged in the denitration reactor.
Furthermore, a first induced draft fan is arranged behind the third valve of the heating pipeline, and a second induced draft fan is arranged behind the fourth valve of the heating bypass pipeline.
The embodiment of the utility model provides an in, through heating pipe connection burning furnace and waste gas denitration pipeline, the high temperature waste gas that will burn burning furnace mixes with the waste gas of diesel engine, utilizes the difference in temperature between them, improves the temperature of diesel engine waste gas, reduces the temperature that burns burning furnace waste gas, has improved energy utilization efficiency to the temperature that makes boats and ships waste gas satisfies the required temperature of denitration reaction. Meanwhile, the temperature of the mixed waste gas of the incinerator and the waste gas of the diesel engine is reduced, the generation of dioxin in the waste gas of the incinerator is avoided, the mixed waste gas of the incinerator and the waste gas of the diesel engine are discharged after denitration reaction treatment, and the air pollution can be effectively reduced.
Detailed Description
To further illustrate the technical means and effects of the present invention adopted to achieve the intended purpose of the present invention, the following detailed description of the embodiments, structures, features and effects of the present invention will be made with reference to the accompanying drawings and preferred embodiments.
It should be noted that, in the present specification, "before" and "after" refer to the flow direction of the exhaust gas in the pipe as a reference direction, and "after" refers to the position downstream in the flow direction of the exhaust gas.
Referring to fig. 1, a ship exhaust gas denitration system according to an embodiment of the present invention includes a turbocharger 11 connected to a diesel engine 10, an exhaust gas denitration pipeline 12 and an exhaust gas bypass pipeline 13 connected between the turbocharger 11 and a waste heat boiler 18, a heating pipeline 16 connected between an incinerator 15 and the exhaust gas denitration pipeline 12, and a heating bypass pipeline 17 connected between the incinerator 15 and the exhaust gas bypass pipeline 13. The utility model discloses boats and ships waste gas denitration system still is including the first valve 121, blender 122, denitration reactor 14 and the fifth valve 124 that are arranged in waste gas denitration pipeline 12, is arranged in second valve 131 and the sixth valve 132 of waste gas bypass pipeline 13, is arranged in third valve 161 and the first draught fan 162 of heating pipeline 16 to and be arranged in fourth valve 171 and the second draught fan 172 of heating bypass pipeline 17. Wherein, each valve in the embodiment of the utility model provides an is automatic control valve.
The turbocharger 11 is located between the diesel engine 10 and the exhaust gas denitration system. The turbocharger 11 includes an air inlet end 111, an air outlet end 112, an exhaust gas inlet end 113 and an exhaust gas outlet end 114, wherein the air inlet end 111 is communicated with the atmosphere and is a scavenging inlet of the diesel engine 10, the air outlet end 112 is connected with the air inlet end 101 of the diesel engine 10, the exhaust gas inlet end 113 is connected with the exhaust end 102 of the diesel engine 10, and the exhaust gas outlet end 114 is connected with the exhaust gas denitration pipeline 12 and the exhaust gas bypass pipeline 13, that is, the exhaust gas denitration pipeline 12 and the exhaust gas bypass pipeline 13 are connected with the exhaust end 102 of the diesel engine 10.
Exhaust gas denitration pipeline 12 is connected with exhaust end 102 of diesel engine 10 through first valve 121, mixer 122, denitration reactor 14 is connected in exhaust gas denitration pipeline 12 with fifth valve 124, fifth valve 124 is located between denitration reactor 14 and waste heat boiler 18, mixer 122 sets up before denitration reactor 14, be equipped with urea solution spray gun 123 in mixer 122, urea solution spray gun 123 is used for atomizing urea solution, mixer 122's effect is the ammonia and the abundant mixing of waste gas that hydrolyze the formation with urea solution, insufficient mixing can lead to waste gas reaction insufficient in denitration reactor 14, not only can lead to exhaust gas escape to handle not up to standard, ammonia also can increase simultaneously.
The heating line 16 connects the incinerator 15 and the exhaust gas denitration line 12. Specifically, one end of the heating pipeline 16 is connected to the air outlet of the incinerator 15 through the third valve 161, one end (exhaust end) of the heating pipeline 16 is connected to the exhaust gas denitration pipeline 12, and the connecting position of the heating pipeline 16 and the exhaust gas denitration pipeline 12 is located behind the first valve 121. Further, in order to ensure the amount of the incinerator flue gas entering the flue gas denitration line 12 and prevent the backflow of the incinerator flue gas, the heating line 16 is further provided with a first induced draft fan 162 after the third valve 161.
When the first valve 121, the third valve 161 and the fifth valve 124 are opened, the exhaust gas generated by the diesel engine 10 enters the exhaust gas denitration pipeline 12 through the turbocharger 11, the temperature of the exhaust gas of the diesel engine passing through the turbocharger 11 is reduced, at this time, the exhaust gas generated by the incinerator 15 enters the exhaust gas denitration pipeline 12 through the heating pipeline 16 and is merged with the exhaust gas of the diesel engine, and the temperature of the exhaust gas formed by mixing the exhaust gas of the diesel engine and the exhaust gas of the incinerator is higher than that of the exhaust gas of the diesel engine, so that the temperature of the exhaust gas is increased to the temperature meeting the denitration reaction. The mixed exhaust gas first enters the mixer 122, is fully mixed with the ammonia gas generated by the decomposition of the urea solution in the mixer 122, and then enters the denitration reactor 14 for denitration, so that NO and NO in the exhaust gas are denitrated 2Is reduced to N2And H2And O, finally, the denitrated waste gas enters the waste heat boiler 18 through a fifth valve 124 for waste heat recovery and then is discharged. Further, in order to prevent dust, particulate matters, and the like in the exhaust gas from blocking the catalyst pore channels of the denitration reactor 14, a soot blower (not shown) may be disposed in the denitration reactor 14 to perform timed purging on the surface layer of the catalyst, and the working medium of the soot blower is high-pressure compressed air.
In this embodiment, the lowest outlet flue gas temperature of the incinerator 15 is 850 ℃, and in order to avoid the generation of dioxin, the exhaust gas of the incinerator 15 should be cooled to 350 ℃ within a range of 2.5m from the outlet of the incinerator 15, and therefore, the distance between the air outlet of the incinerator 15 and the exhaust gas denitration line 12 should be shortened as much as possible, and the line length between the air outlet of the incinerator 15 and the inlet of the denitration reactor 14 should be less than 2.5m, so that the temperature of the incinerator exhaust gas is lowered to 350 ℃ within a distance as short as possible. In this embodiment, the mixing temperature of the two kinds of exhaust gas is 310 ℃ to 350 ℃. It will be appreciated that controlling the temperature of the exhaust gas mixture and the rate of temperature reduction of the incinerator exhaust gas can also be achieved by controlling the amount of exhaust from the incinerator 15.
The embodiment of the utility model provides a high temperature waste gas that will burn burning furnace 15 mixes with the waste gas of diesel engine 10, utilizes the difference in temperature between them, improves the temperature of diesel engine waste gas, reduces the temperature of burning furnace waste gas, has improved energy utilization efficiency to the required temperature of denitration reaction is satisfied to the temperature that makes boats and ships waste gas. Meanwhile, the temperature of the mixed waste gas of the incinerator and the waste gas of the diesel engine is reduced, the generation of dioxin in the waste gas of the incinerator is avoided, the mixed waste gas of the incinerator and the waste gas of the diesel engine are discharged after denitration reaction treatment, and the air pollution can be effectively reduced.
In this embodiment, the main working medium of the incinerator 15 is ship oil, sludge, waste such as plastic, cardboard, can, food waste, etc., and when the amount of the waste is small, the amount of high-temperature exhaust gas generated cannot satisfy the purpose of raising the exhaust gas temperature of the diesel engine, the ship fuel can be used as the medium for operation. It can be understood that the working medium of the incinerator 15 is mainly used for incinerating garbage and is supplemented by fuel oil, and even if a small amount of fuel oil is used, the working medium can save most of fuel oil consumption compared with the method that a fuel oil burner is directly used for heating waste gas.
Referring to fig. 1, in the present embodiment, an outlet end of the denitration reactor 14 is provided with an exhaust pipeline 19, and the exhaust pipeline 19 is connected to the exhaust denitration pipeline 12 through an exhaust valve 191. When the first valve 121, the fourth valve 171 and the fifth valve 124 are closed and the third valve 161 and the exhaust valve 191 are opened, the incinerator flue gas enters the denitration reactor 14 through the heating pipeline 16 and the flue gas denitration pipeline 12 and is discharged through the exhaust pipeline 19.
Due to SO in diesel exhaust gases3Will react with NH3The reaction produces ammonium bisulfate, which can condense on the surface of the catalyst to block the catalyst when the temperature is reduced, and can cause the condensation of the ammonium bisulfate for a long time The catalyst may become clogged or even deactivated. Therefore, when the denitration reactor 14 is stopped, a small amount of fuel oil is burned (garbage is not burned) by the incinerator 15, and the incinerator exhaust gas is directly introduced into the denitration reactor 14, the temperature of the denitration reactor 14 is raised to 350 ℃, at which time ammonium bisulfate is decomposed and discharged from the exhaust valve 191 of the exhaust line 19 along with the exhaust gas, so that the content of gaseous ammonium bisulfate in the denitration reactor 14 is gradually reduced. After the incinerator 15 was operated for two hours, it was considered that the ammonium bisulfate in the denitration reactor 14 had been completely discharged, at which time the incinerator 15 was closed and the exhaust valve 191 was closed. The embodiment of the utility model provides an utilize and burn burning furnace waste gas's high temperature to make the ammonium bisulfate on catalyst surface volatilize, reach the purpose that makes catalyst regeneration in the denitration reactor 14.
With continued reference to fig. 1, the exhaust gas bypass line 13 is connected to the exhaust end 102 of the diesel engine 10 through a second valve 131, and the heating bypass line 17 is connected to the air outlet of the incinerator 15 through a fourth valve 171.
Further, the exhaust end of the heating bypass line 17 is connected to the waste gas bypass line 13 at a position after the second valve 131, so that the incinerator waste gas can enter the waste gas bypass line 13 through the heating bypass line 17, and the exhaust end of the waste gas bypass line 13 is connected to the waste heat boiler 18 through the sixth valve 132. In addition, in order to ensure the amount of the incinerator flue gas entering the flue gas bypass line 13 and to prevent the backflow of the incinerator flue gas, the heating bypass line 17 is further provided with a second induced draft fan 172 after the fourth valve 171.
When the second valve 131, the fourth valve 171 and the sixth valve 132 are opened, the exhaust gas generated by the diesel engine 10 enters the exhaust gas bypass pipeline 13 through the turbocharger 11, the exhaust gas generated by the incinerator 15 enters the exhaust gas bypass pipeline 13 through the heating bypass pipeline 17, and the exhaust gas are mixed and then enter the waste heat boiler 18 through the sixth valve 132 for waste heat recovery and then are discharged. In the present embodiment, in order to avoid the generation of dioxin, the length of the heating bypass line 17 should also be shortened as much as possible.
Next, the detailed description of the operation process of the ship exhaust gas denitration system of the present invention is as follows.
When the ship runs in the ECA area, the first valve 121, the third valve 161, and the fifth valve 124 are opened, and the second valve 131, the fourth valve 171, the sixth valve 132, and the exhaust valve 191 are closed at the same time, the exhaust gas generated by the diesel engine 10 enters the exhaust gas denitration pipeline 12 through the turbocharger 11, the exhaust gas generated by the incinerator 15 enters the exhaust gas denitration pipeline 12 through the heating pipeline 16 and joins with the diesel engine exhaust gas, so that the temperature of the exhaust gas formed by mixing the diesel engine exhaust gas and the incinerator exhaust gas is higher than the temperature of the diesel engine exhaust gas, and the temperature of the exhaust gas is increased to the temperature satisfying the denitration reaction. The mixed exhaust gas first enters the mixer 122, and the gas fully mixed with the ammonia gas generated by the decomposition of the urea solution in the mixer 122 enters the denitration reactor 14 for denitration, so that NO and NO in the exhaust gas are denitrated 2Is reduced to N2And H2And O, finally, the denitrated waste gas enters the waste heat boiler 18 for waste heat recovery and then is discharged so as to meet the requirement of the current regional waste gas emission.
When the ship runs in a non-ECA area, the denitration reactor 14 is closed, the urea solution is closed, the working medium of the incinerator 15 is changed into fuel oil, at the moment, the first valve 121, the fourth valve 171 and the fifth valve 124 are closed, the second valve 131, the third valve 161, the sixth valve 132 and the exhaust valve 191 are opened, the exhaust gas of the diesel engine 10 is discharged through the turbocharger 11 and then directly enters the waste heat boiler 18 from the exhaust gas bypass pipeline 13 for waste heat recovery without entering the denitration reactor 14, the exhaust gas generated by burning the fuel oil in the incinerator 15 enters the denitration reactor 14 through the heating pipeline 16 and the exhaust gas denitration pipeline 12, the temperature of the denitration reactor 14 is increased to 350 ℃, at the moment, the ammonium bisulfate is decomposed and is discharged from the exhaust valve 191 of the exhaust pipeline 19 along with the exhaust gas, and the catalyst in the denitration reactor 14 is regenerated.
After the incinerator 15 is operated for two hours, it is considered that the ammonium bisulfate in the denitration reactor 14 is completely discharged, and at this time, the incinerator 15 is closed, and the third valve 161 and the exhaust valve 191 are closed. If the incinerator 15 needs to burn garbage, the fourth valve 171 is opened to make the exhaust gas generated by the incinerator 15 enter the exhaust gas bypass line 13 through the heating bypass line 17, the incinerator exhaust gas is merged with the diesel engine exhaust gas, the temperature is reduced, and the merged exhaust gas enters the waste heat boiler 18 through the sixth valve 132 to be discharged after waste heat recovery.
To sum up, the utility model discloses a boats and ships waste gas deNOx systems includes following advantage at least:
the utility model discloses a heating pipe connects and burns burning furnace and waste gas denitration pipeline, utilizes the diesel engine and burns the waste gas difference in temperature of burning furnace to the control burns the distance and the discharge of air of burning furnace and diesel engine exhaust gas piping, when making the exhaust gas temperature reach the required temperature of denitration reaction, has realized cooling, has avoided burning the purpose that generates the dioxin in the burning furnace waste gas to the waste gas of burning the burning furnace, and has carried out denitration treatment to burning the burning furnace flue gas, has reduced the atmosphere pollution. Meanwhile, when the denitration reactor is not operated, a small amount of waste gas of the incinerator is independently and directly introduced into the denitration reactor, and the ammonium bisulfate on the surface of the catalyst of the denitration reactor is volatilized by utilizing the high temperature of the waste gas, so that the purpose of catalyst regeneration is achieved, and the service life of the catalyst is prolonged.
Finally, the present invention uses specific embodiments to illustrate the effects achieved: