CN205606593U - Efflux burner of supercritical water oxidation organic matter - Google Patents
Efflux burner of supercritical water oxidation organic matter Download PDFInfo
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- CN205606593U CN205606593U CN201620448558.0U CN201620448558U CN205606593U CN 205606593 U CN205606593 U CN 205606593U CN 201620448558 U CN201620448558 U CN 201620448558U CN 205606593 U CN205606593 U CN 205606593U
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Abstract
The utility model discloses an efflux burner of supercritical water oxidation organic matter, the inner tube and the urceolus of being in the same place including coaxial suit, top at a reactor section of thick bamboo has one to extend to its inside coaxial jets combustor rather than coaxial arrangement, the coaxial jets combustor be the three -layer with the pipe spreader structure, what lie in inlayer is an auxiliary heat source admission passage, the intermediate level is the oxidant and gets into annular channel, and is outmost for waste liquid entering annular channel, and reactor form the subcritical pool of technology water leg cover district, supercritical water oxidation district, dissoluble inorganic salts.
Description
Technical field
This utility model belongs to environmental conservation and chemical field, relates to the use of supercritical water oxidation and realizes debirs harmless treatment
Reactor, particularly to a kind of supercritical water oxidation organic jet combustion device.
Background technology
Supercritical water oxidation (Supercritical Water Oxidation is called for short SCWO) technology is to enter with supercritical water for medium
The process of row oxidation operation.Water is reaching critical point i.e. temperature 374 DEG C, during more than pressure 22.05MPa, just reaches supercritical
State, being in the water of supercriticality has the physics different from normality water, chemical property.Supercritical water has similar liquids
Density, solvability and good mobility, have again diffusion coefficient and the low-viscosity of similar gas simultaneously.In supercritical water
The boundary of gas-liquid two-phase disappears, and forms homogeneous phase system, and response speed greatly speeds up.The gas such as Organic substance and oxygen faces super
Complete miscibility in boundary's water, at short notice, just can make Organic substance generation oxidation reaction, almost be completely transformed into N2、H2O and
CO2Material Deng environmental sound.The inorganic salt dissolubility in supercritical water being dissolved in water under normal temperature and pressure is minimum, the most miscellaneous former
Son such as phosphorus, sulfur etc. is changed into the inorganic salt postprecipitation such as phosphate and sulfate and separates out.
Although supercritical Water Oxidation Technology has been achieved for the biggest progress, but still suffers from some problems at present, such as debirs
Preheating coking, the corrosion of reactor and blocking, these problems hinder the industrialization of supercritical Water Oxidation Technology to a certain extent
Process.
Before debirs enter overcritical water oxidization reactor, need to be preheating to uniform temperature (300～450 DEG C), to guarantee
Oxidation reaction can be smoothed out.Therefore material is in warm, it may occur that preliminary pyrolysis and oxidation.Some are contained
Viscosity debirs big, easily thermal decomposition, material is through the heating element heater such as heat exchanger or electric heater, and Organic substance is easily sent out
Heat solution, generates coke and tar etc..Material is pyrolyzed coking at warm-up phase, is necessarily substantially reduced heat exchanger and electric heater
Heat exchange efficiency.Additionally, typically can contain inorganic salt in actual waste liquid, inorganic salt also can be in preheating section generation mineralization phenomenon.Cause
In the case of this or caliber relatively low at material flow is less, easily causes the blocking of pipeline, cause system outage.This is asked
Topic is also supercritical Water Oxidation Technology common problem.Accordingly, it would be desirable to seek a kind of novel material preheating method, to solve
The blockage problem that certainly material occurs at preheating section.
Etching problem is the subject matter that SCWO technology fails to solve always at all.In SCWO environment, high concentration is dissolved
The living radical produced in oxygen, high-temperature and high-pressure conditions, reaction and some kinds of inorganic ions etc. all have acceleration to reactor
The effect of corrosion.Especially containing halogen, sulfur or phosphorus in Organic substance, acid can be produced during supercritical water oxidation, it is easier to
Cause the corrosion of reactor.The experiment of corrosion resistant alloy is shown by related research institutes both at home and abroad, rustless steel, nickel-base alloy, titanium etc.
Senior corrosion resistant material is intended to the corrosion suffered in various degree in SCWO system.
The deposition of inorganic salt and the blockage problem brought are another bottlenecks of SCWO technology development.Due under super critical condition
The dissolubility of inorganic matter is the least, and the precipitation producing salt in oxidizing process can cause the blocking of reactor or pipeline, makes heat transference efficiency
Drastically decline, even can have an accident.
Utility model content
This utility model is from optimizing structure of reactor, it is provided that a kind of supercritical water oxidation organic jet combustion mode, if
Pre-heated supercritical water oxidation moisture film reactor in meter is a kind of, transfers to the preheating of debirs in reactor from reactor,
Realize debirs with room temperature injecting reactor, to solve the debirs problem at preheating section, solve conventional supercritical fluid water simultaneously
Reactor existing for oxidation technology problem perishable, susceptible to plugging.
The purpose of this utility model is achieved in the following ways:
A kind of supercritical water oxidation organic jet combustion device, including coaxial package inner core together and urceolus；In reaction
The top of device inner core is coaxial therewith being provided with one and extends to its internal coaxial jet burner, described coaxial jet burner
Being three layers of coaxial sleeve structure, be positioned at innermost layer is that an auxiliary thermal source enters passage, and intermediate layer is that oxidant enters annular leading to
Road, outermost layer is that waste liquid enters circular passage；The circular passage that described reactor inner core and reactor urceolus are formed is along axis
Direction divide into multiple fresh water (FW) chuck district from top to bottom；Formation process water leg district, supercritical water oxygen in described reactor
Change district, the subcritical pool of solubilized inorganic salt.
Further, described multiple fresh water (FW) chuck districts are the circular passages by being formed at reactor inner core and reactor urceolus
Inside arrange what multilamellar shading ring was formed.
Further, described reactor inner tube wall is porous wall structure, and fresh water (FW) forms one by porous wall at reactor wall
The protection moisture film of layer subcritical temperature.
Further, in described inner core, be provided with a supercritical water oxidation product outlet tube, its directly go deep into bottom inner core and
Extend to outside inner core.
Further, the multi-point temperature measurement big envelope of a pressure-bearing it is being provided with near reactor center line position, by many in thermometric big envelope
Root high temperature resisting thermocouple or optical fiber temperature-measurement device connect the data analysis outside multiple temperature sensors, temperature measuring equipment and reactor and control
System processed is connected, and can monitor reactor temperature field distribution, export pipeline and thermometric big envelope and directly be welded on lower flange lid.
Further, respectively set a ring flange at described inner core and the top of urceolus and bottom, pass through between urceolus and ring flange
Connector connects.The sealing of reactor inner core, the sealing of chuck district shading ring rely primarily on fastening force and the packing ring of flange bolt
Sealing.
Further, being auxiliary thermal source in described central passage, intermediate annular passage is oxidant, exports oxygen at auxiliary thermal source
Agent comes into contact with auxiliary thermal source and mixes, and is therefore the mixing chamber of auxiliary thermal source and oxidant below auxiliary thermal source outlet.Outer layer
Circular passage is the organic liquid waste of room temperature, and organic liquid waste outlet is in inside reactor top (i.e. the lower surface of upper flange plate) lower section
At least below 200mm, room temperature organic liquid waste is carried out pre-by central jet back-mixing by the high-temperature product after auxiliary thermal source burning
Heat.
Further, the processing method to organic degree waste liquid of high concentration of the jet combustion device described in utilization:
Auxiliary thermal source uses pure water, and pure water is preheating to the temperature set；Oxidant and the debirs of room temperature respectively enter reaction
Debirs are directly preheated by device, and organic liquid waste and oxidant carry out supercritical water oxidation degradation reaction on reactor top；
Meanwhile, the fresh water (FW) of different temperatures is entered multiple fresh water (FW) chuck districts and is entered the inside of reactor inner core by porous wall,
The inwall of reactor inner core is formed one layer of subcritical protection moisture film；The fresh water (FW) of subcritical state constantly washes away inner tube wall, and one
Aspect has dissolved the inorganic salt generated in course of reaction；Another aspect prevention corrosive substance contacts with wall；
The fresh water (FW) and the product that are dissolved with inorganic salt are discharged from the outlet of reactor bottom.
Further, the processing method to organic degree waste liquid of low concentration of the jet combustion device described in utilization:
Auxiliary thermal source uses Organic substance, and auxiliary fuel is preheating to design temperature, and oxidant and the debirs of room temperature respectively enter
Reactor；Room temperature debirs are preheated by the high-temperature product after auxiliary thermal source and oxidant burning by central jet back-mixing,
Organic liquid waste carries out supercritical water oxidation degradation reaction on reactor top；
Meanwhile, the fresh water (FW) of different temperatures is entered multiple fresh water (FW) chuck districts and is entered the inside of reactor inner core by porous wall,
The inwall of reactor inner core is formed one layer of subcritical protection moisture film；The fresh water (FW) of subcritical state constantly washes away inner tube wall, and one
Aspect has dissolved the inorganic salt generated in course of reaction；Another aspect prevention corrosive substance contacts with wall；
The fresh water (FW) and the product that are dissolved with inorganic salt are discharged from the outlet of reactor bottom.
Further, in said method: use multi-point temperature measurement system to realize the real-time measurement of reactor temperature field.
Further, in said method: the described fresh water (FW) flow in fresh water (FW) chuck subregion and temperature according to reaction need with
And the needs of reactor protection are adjusted.
The beneficial effects of the utility model are as follows:
This utility model have employed a coaxial jet burner to realize the organic jet combustion of supercritical water oxidation.Supercritical
The jet combustion mode of water oxidation of organic compounds is a kind of new combustion system, and auxiliary fuel (methanol, ethanol etc.) is preheating to reaction
The oxidant of temperature and room temperature is respectively from reactor center passage and intermediate annular passage injecting reactor, and it is anti-quickly to carry out oxidation
Answer thus produce katathermal solution flame.Hydrothermal solution flame (700～1200 DEG C) is by the low temperature that injects from outer annular channel (not even
Needing preheating) organic liquid waste is preheating to supercritical water oxidation temperature, and organic liquid waste top in the reactor carries out supercritical water oxidation
Degradation reaction.For usually supercritical water oxidation, hydrothermal solution flame has a higher temperature, faster reaction rate,
And then reaction time and the reactor volume needed can be substantially reduced.Therefore this kind of reactor is rolled up by the jet of auxiliary thermal source
Inhale and realize the preheating of organic liquid waste and catch fire, it is achieved the most preheated direct room temperature of organic liquid waste enters reactor, efficiently solves
Organic liquid waste is in the coking of preheating section, blockage problem.
Organic liquid waste, auxiliary thermal source and oxidant respectively enter reactor with coaxial sleeve structure, and heart line position sets in the reactor
Put sleeve structure and can reduce the open amount of outer cover, reduce structure of reactor design and the difficulty made, improve device
Safety.Additionally, for making, reactant mix homogeneously, reaction are thorough, reactant distribution is uniform, can exist according to practical situation
Center sleeve is additionally arranged at the bottom of spray nozzle device.
Coaxial jet burner outlet is at least below 200mm below inside reactor top (i.e. the lower surface of upper flange plate),
Make hydrothermal solution flame away from upper end cover wall, it is ensured that it is within designing the highest bearing temperature.
It is filled with in fresh water (FW) chuck and quite but is slightly larger than the subcritical state of reactor pressure with reactor inner core internal pressure
The deoxygenation desalination process water of 22.5～25Mpa, 20～350 DEG C.Then, the probability that outer tube wall corrosion occurs is the least, outer tube wall material
As long as the selection of matter meets high pressure and the requirement of middle temperature.The pressure that inner tube wall is born simultaneously is the least, and the protection of water film makes
Inner core wall avoids the generation of corrosion, expands the selection space of material.Barrel palpus with traditional super oxidation reactor near water
Meet high pressure (>=23MPa), high temperature (>=550 DEG C) is compared with the requirement such as corrosion-resistant, the design of above-mentioned reactor and system simultaneously
At utmost reduce the difficulty that inside and outside barrel material selects, select general stainless-steel pipe then can fully meet requirement,
It is easily achieved industrialization to amplify.
Fresh water (FW) chuck district shading ring is divided into multiple district (three floor and more than), is supplied water by district grid, can control respectively
The output of zones of different and water temperature, meet the needs of zones of different reaction and the needs to reactor protection.
Reactor inner tube wall can use porous material, such as: porous ceramics or sintering metal etc..Make through special places such as deoxygenation desalinations
The anaerobic of reason, the fresh water (FW) of non-corrosive subcritical state form one layer of protection moisture film at reactor wall.The technique of subcritical state
Water constantly washes away inner tube wall, has on the one hand dissolved the inorganic salt generated in course of reaction, prevents fouling, on the other hand stops nothing
The corrosive substances such as machine acid contact with wall, prevent the corrosion of reactor.The fresh water (FW) being dissolved with inorganic salt finally flows into reaction
Bottom device inner core thus define subcritical water dissolved salt district.
Accompanying drawing explanation
Fig. 1 is this utility model structure of reactor generalized section.
Fig. 2 is multiple spot temperature measurement on-line big envelope schematic diagram.
Fig. 3 is the enlarged drawing of coaxial burner.
In figure: 1 is auxiliary thermal source inlet tube, 2 is oxygen inlet pipe, and 3 is organic liquid waste inlet tube, and 4 is reactor upper flange
End cap, 5 is reactor urceolus, and 6 is coaxial burner, 6-1 central canal, 6-2 inner tube, 6-3 outer tube, and 7 is upper
Road fresh water (FW) inlet tube, 8 and 11 is shading ring, and 9 is reactor inner core, and 10 is middle branch road fresh water (FW) inlet tube, and 12 is lower
Road fresh water (FW) inlet tube, 13 reactor lower flange end caps, 14 is product outlet tube, and 15 is multi-point temperature measurement big envelope.
Detailed description of the invention
A detailed description of the invention of the present utility model is given below in conjunction with each accompanying drawing.
Supercritical water oxidation organic jet combustion device in Fig. 1, by reactor urceolus 5, reactor inner core 9, upper flange
End cap 4, lower flange end cap 13, coaxial jet burner 6, multi-point temperature measurement big envelope 15 form, reactor urceolus 5 and upper and lower
Flange end cap 4,13 is fastened by bolts, easy accessibility.Coaxial jet burner 6 is welded in upper flange end cap 4 centerline.
This coaxial jet burner 6 is the coaxial sleeve structure of three layers, including central canal 6-1, inner tube 6-2, outer tube 6-3；
Formed central passage by central canal 6-1, be auxiliary thermal source in central passage；Adapter ring is formed by central canal 6-1 and inner tube 6-2
Shape passage, intermediate annular passage is oxygen channel；Outer annular channel, outer layer ring is formed by inner tube 6-2 and outer tube 6-3
Shape passage is the organic liquid waste passage of room temperature.
Auxiliary thermal source inlet tube 1, oxygen inlet pipe 2 and organic liquid waste inlet tube 3 are respectively welded in coaxial burner top.Instead
Answering device urceolus 5 for pressure-bearing wall, reactor inner core 9 is porous wall, and the annular region between inside and outside barrel is fresh water (FW) chuck district,
In fresh water (FW) chuck district, it is provided with multilamellar shading ring 8 and 11 fresh water (FW) chuck is divided into three floor or three floor area above, different
The fresh water (FW) of branch road is respectively by upper branch road fresh water (FW) inlet tube 7, middle branch road fresh water (FW) inlet tube 10, lower branch road fresh water (FW) import
Pipe 12 enters fresh water (FW) chuck district, forms the protection moisture film of one layer of subcritical temperature through porous wall at reactor inner core wall.Instead
The sealing of device inner core, the sealing of chuck district shading ring is answered to rely primarily on the fastening force of flange bolt and the sealing of packing ring.
It is joined directly together bottom product outlet tube 14 and inner core, at the multi-point temperature measurement being provided with a pressure-bearing near reactor center line position
Big envelope 15, export pipeline 14 and thermometric big envelope 15 are directly welded on lower flange lid 13.
Thermometric big envelope 15 in Fig. 2, built with many high temperature resisting thermocouples or optical fiber temperature-measurement device, can monitor hydrothermal solution flame simultaneously
Temperature, the axially different temperature of inner core near wall and reactor inner core difference temperature radially.Number outside temperature measuring equipment and reactor
It is connected with control system according to analyzing, reactor temperature field distribution can be monitored, thus carry out super oxidation moisture film reactor near water
Catching fire and the further investigation of fire-fighting characteristic, moisture film Formation and characteristics etc. of interior-heat liquid extract flame.
The flow velocity of coaxial burner centre auxiliary thermal source is at least the 10 of the waste liquid flow velocity of the oxidant of middle annular space and outer layer annular space
Times.Owing to the jet entrainment effect of auxiliary thermal source, oxidant and waste liquid can be involved in the jet core of auxiliary thermal source.This kind of reactor
Realize the preheating of organic liquid waste by the jet entrainment of auxiliary thermal source and catch fire, whole supercritical water oxidation system being disliked most simultaneously
Bad environment concentrates in reactor inner core, and is protected whole reactor by moisture film, can not only effectively alleviate system
Corrosion and mineralization problem, efficiently solve the material blockage problem at preheating section simultaneously.The structure of this reactor not only meets
The needs of reaction, and ensure that the convenience of installing/dismounting.Just a step reaction can be realized by suspention reactor urceolus flange end cap
Device upper and lower covers and the separation of inner/outer tube, it is simple to detect, keep in repair, change the cleaning of each inner part and each several part.Meanwhile, this reality
It is easily achieved industrialization with the design of the novel structure of reactor related to amplify.
, in reactor inner core, there is hydrothermal solution flame zone (700～1200 DEG C), subcritical moisture film district (＜ in above-mentioned reactor simultaneously
370 DEG C), supercritical water oxidation district (400～650 DEG C) and inorganic salt dissolved salt district (300～370 DEG C).
Above-mentioned reactor, auxiliary thermal source can use various ways, when for processing highly concentrated organic degree waste liquid, auxiliary heat
Source can be pure water, pure water is preheating to sufficiently high temperature (500～600 DEG C), could realize organic liquid waste and reach reaction temperature；
When being used for processing low concentration waste liquid, auxiliary thermal source can use the Organic substance (CH of low-molecular-weight, high heating value4O、C2H6O、
C3H8O etc., this type organic is difficult to be pyrolyzed coking) auxiliary fuel is preheating to 350～450 DEG C, carry out hydrothermal solution flame reaction and release
The heat of amplification quantity, is preheating to the most preheated organic liquid waste reaction temperature and then degrades it.Simultaneously as there is moisture film
Protection and the cooling to hydrothermal solution flame of the room temperature organic liquid waste to reactor, it is to avoid the localized hyperthermia in reactor.
Above-mentioned reactor, has welded multiple spot (at least 6 point) the thermometric envelope of a pressure-bearing at reactor lower flange position of center line
Set, connects multiple temperature sensors by many high temperature resisting thermocouples or optical fiber temperature-measurement device in thermometric big envelope, and temperature measuring equipment is with anti-
The data analysis outside device is answered to be connected with control system, axially different and variations in temperature radially in test reactor, its knot
Structure schematic diagram is as shown in Figure 2.
Reactor inner tube wall can use porous material, such as: porous ceramics or sintering metal etc..Make through special places such as deoxygenation desalinations
The anaerobic of reason, the fresh water (FW) of non-corrosive subcritical state form one layer of protection moisture film at reactor wall.The technique of subcritical state
Water constantly washes away inner tube wall, has on the one hand dissolved the inorganic salt generated in course of reaction, prevents fouling, on the other hand stops nothing
The corrosive substances such as machine acid contact with wall, prevent the corrosion of reactor.The fresh water (FW) being dissolved with inorganic salt finally flows into reaction
Bottom device inner core thus define subcritical water dissolved salt district.
It is filled with in fresh water (FW) chuck and quite but is slightly larger than the subcritical state of reactor pressure with reactor inner core internal pressure
The deoxygenation desalination process water of 22.5～25Mpa, 20～350 DEG C.Then, the probability that outer tube wall corrosion occurs is the least, outer tube wall material
As long as the selection of matter meets high pressure and the requirement of middle temperature.The pressure that inner tube wall is born simultaneously is the least, and the protection of water film makes
Inner core wall avoids the generation of corrosion, expands the selection space of material.Barrel palpus with traditional super oxidation reactor near water
Meet high pressure (>=23MPa), high temperature (>=550 DEG C) is compared with the requirement such as corrosion-resistant, the design of above-mentioned reactor and system simultaneously
At utmost reduce the difficulty that inside and outside barrel material selects, select general stainless-steel pipe then can fully meet requirement,
It is easily achieved industrialization to amplify.
Specific works process of the present utility model is:
Be preheating to the auxiliary thermal source (can be the fuel such as pure water or methanol) of uniform temperature, room temperature oxidant (can be oxidation or
Other oxidants such as person's hydrogen peroxide) and organic liquid waste enter in reactor respectively through inlet tube 1,2 and 3, auxiliary thermal source burns
After high-temperature product by central jet back-mixing, room temperature debirs are preheated, organic liquid waste surpasses on reactor top
Critical oxidative degradation.Meanwhile, the fresh water (FW) of different temperatures flows in fresh water (FW) chuck district through inlet tube 7,10 and 12,
Enter inside reactor by reactor inner core 9, reactor inner core wall is formed one layer of subcritical protection moisture film.Fresh water (FW)
Fresh water (FW) flow and the needs that temperature can need according to reaction and reactor is protected in chuck subregion are adjusted.Upper strata work
Skill coolant-temperature gage can be 300～370 DEG C；Middle level fresh water (FW) temperature can be 200～370 DEG C；Lower floor's fresh water (FW) temperature can be
Less than 200 DEG C even room temperature.It is dissolved with the subcritical temperature fresh water (FW) (＜ 350 DEG C) of inorganic salt and product from bottom
Outlet 14 is discharged.Use multi-point temperature measurement system 15 to measure to realize the real-time of reactor temperature field simultaneously, more convenient,
Accurately, observe and control the carrying out of supercritical water oxidation process in time.
Although detailed description of the invention of the present utility model is described by the above-mentioned accompanying drawing that combines, but not this utility model is protected
The restriction of scope, one of ordinary skill in the art should be understood that on the basis of the technical solution of the utility model, art technology
Personnel need not to pay various amendments or deformation that creative work can make still within protection domain of the present utility model.
Claims (6)
1. a supercritical water oxidation organic jet combustion device, it is characterised in that: include coaxial package inner core together
And urceolus；It is coaxial therewith being provided with one at the top of reactor inner core and extends to its internal coaxial jet burner, described
Coaxial jet burner is three layers of coaxial sleeve structure, and be positioned at innermost layer is that an auxiliary thermal source enters passage, and intermediate layer is oxygen
Agent enters circular passage, and outermost layer is that waste liquid enters circular passage；And described reactor inner core and reactor urceolus are formed
Circular passage divide into multiple fresh water (FW) chuck district from top to bottom along axis direction.
2. supercritical water oxidation organic jet combustion device as claimed in claim 1, it is characterised in that: described is multiple
Fresh water (FW) chuck district is by arranging the formation of multilamellar shading ring in the circular passage that reactor inner core and reactor urceolus are formed.
3. supercritical water oxidation organic jet combustion device as claimed in claim 1, it is characterised in that: described reaction
Device inner tube wall is porous wall structure, and fresh water (FW) forms the protection moisture film of one layer of subcritical temperature by porous wall at reactor wall.
4. supercritical water oxidation organic jet combustion device as claimed in claim 1, it is characterised in that: near described
Inner core position of center line be provided with in the multi-point temperature measurement big envelope of a pressure-bearing, thermometric big envelope by many high temperature resisting thermocouples or optical fiber
Temperature measuring equipment connects multiple temperature sensors, temperature measuring equipment with reactor outside data analysis and control system be connected, monitoring is instead
Answer thermo parameters method in device.
5. supercritical water oxidation organic jet combustion device as claimed in claim 1, it is characterised in that: in described
Being provided with a supercritical water oxidation product outlet tube in Tong, it directly gos deep into bottom inner core and extends to outside inner core.
6. supercritical water oxidation organic jet combustion device as claimed in claim 1, it is characterised in that: described waste liquid
Outlet is positioned at least below 200mm below reactor top.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620448558.0U CN205606593U (en) | 2016-05-17 | 2016-05-17 | Efflux burner of supercritical water oxidation organic matter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620448558.0U CN205606593U (en) | 2016-05-17 | 2016-05-17 | Efflux burner of supercritical water oxidation organic matter |
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| Publication Number | Publication Date |
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| CN205606593U true CN205606593U (en) | 2016-09-28 |
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ID=56967530
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| CN201620448558.0U Expired - Fee Related CN205606593U (en) | 2016-05-17 | 2016-05-17 | Efflux burner of supercritical water oxidation organic matter |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105782995A (en) * | 2016-05-17 | 2016-07-20 | 山东大学 | Jet combustion device and method for super-critical water oxidization of organic matter |
| CN114754358A (en) * | 2022-04-29 | 2022-07-15 | 西安交通大学 | Supercritical hydrothermal combustion treatment device for organic wastes |
-
2016
- 2016-05-17 CN CN201620448558.0U patent/CN205606593U/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105782995A (en) * | 2016-05-17 | 2016-07-20 | 山东大学 | Jet combustion device and method for super-critical water oxidization of organic matter |
| CN114754358A (en) * | 2022-04-29 | 2022-07-15 | 西安交通大学 | Supercritical hydrothermal combustion treatment device for organic wastes |
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Granted publication date: 20160928 Termination date: 20210517 |
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| CF01 | Termination of patent right due to non-payment of annual fee |