A kind of Prebaked Anode In Aluminium Cell group structure
Technical field
This utility model relates to a kind of aluminium electrolysis anode, particularly a kind of Prebaked Anode In Aluminium Cell group structure.
Background technology
Modern Aluminium Industry, all uses prebaked anode to produce electrolytic aluminium.Prebaked anode is generally cuboid, has stable geometry, with stone tar, pitch coke as aggregate, with coal tar pitch as binding agent, has different sizes according to the size of electrolytic cell currents and the difference of technique, and its electric current density is typically at 0.68-0.9A/cm2In the range of, each carbon block uses the cycle typically at 23-30 days.
In existing prebaked anode Aluminum Electrolysis Production, anode steel claw all uses phosphorus pig iron casting formula to be connected with anode carbon block, upper surface at pre-baked anode carbon blocks conducting direction is provided with 2-4 a diameter of 160-180mm, it is the circular groove of 80-110mm deeply, it is commonly called as charcoal bowl, when anode assembling, charcoal bowl is used for laying anode joint, with the phosphorus pig iron, anode joint is cast in charcoal bowl, steel pawl head and aluminum conducting rod are connected by aluminum steel blast weldering, so conductive anode rod and anode carbon block is connected as a single entity, composition anode carbon block group, casting type pre-baked anode carbon blocks group is unique anode material that modern prebaked cell is currently used.
During Aluminum Electrolysis Production, the oxygen that carbon anode and alumina eltrolysis decompose out the most constantly reacts, carbon dioxide gas and constantly consume, need timing to change, referred to as anode anode scrap in the carbon block industry changed.Prd-baked Al electrolysis produces and must produce a large amount of anode anode scrap, and it is last century 60~the seventies that non-residual electrode produces, and prd-baked Al electrolysis technical maturity carrys out the industry dream never realized.
Now the current processing mode to traditional anode anode scrap is in anode assembling workshop, the anode scrap that conducting rod connects is smashed after coming off, the anode steel bowl poured by the phosphorus pig iron again is smashed the aluminum conducting rod after coming off and is used for new carbon block, so recycling, the Renewal process having thereby resulted in carbon block is wasted time and energy.
And the 10-15% that generation amount is aluminium ingot yield of generally anode anode scrap, thereby produce waste greatly, produce ten thousand tons of electrolytic aluminiums of 2600-2700 per year by present China to calculate, anode anode scrap is up to 260-390 ten thousand tons/year, the anode carbon block wasted every year according to 2700 yuan/ton of value calculation of anode carbon block is worth and reaches 10,000,000,000 yuan, global waste is more, anode anode scrap soaks for a long time in the fused electrolyte of electrolysis bath, and anode carbon element itself has the porosity of 25-27%, substantial amounts of electrolyte has been adsorbed in anode scrap body, the main component of electrolyte is fluoride salt, anode anode scrap containing a large amount of fluoride salts is extremely serious to the pollution of environment.
Casting type steel pawl carbon block connected mode, joint face contact drop is bigger, the phosphorus pig iron molten iron temperature poured into about 1600 DEG C, after cooling, gap must occur, thus, when steel pawl carbon block anode unit works in electrolysis bath between phosphorus pig iron bowl and charcoal bowl, produce the voltage drop of about 150mv between steel pawl and carbon block contact surface, cause electricity to damage about at 400~500 KWhs/ton of aluminum.
When using existing casting type anode carbon block group, in order to reduce as far as possible anode scrap waste must try one's best anode scrap is burnt thin, at anode carbon block end of lifetime, the end face of anode carbon block is sufficiently close to electrolyte level face, by magnetic field and airflow influence, bath surface constantly has strong wave to produce, or because producing control deviation, in actual production process, anode steel claw is often by electrolyte etch, the ferrum of steel pawl dissolves in electrolyte, enter aluminum water immediately and affect aluminium ingot quality, in actual production, the steel pawl average life that potroom uses only has about 3 years, this also makes production cost have certain increase.And at anode carbon block end of lifetime, the thinnest anode scrap thickness, necessarily bring charcoal pole conduction inequality, cause electrolysis bath fluctuation of operating conditions, electricity damages to be increased.
Summary of the invention
The purpose of this utility model is, it is provided that a kind of Prebaked Anode In Aluminium Cell group structure.This utility model has non-residual electrode and produces, make the utilization rate of anode carbon block by traditional 70~80%, bring up to 100%, it is possible to decrease the production cost of electrolytic aluminium, the steel pawl life-span is long, electrolysis bath stable conditions, electricity damages relatively low feature, in addition, it is easy to connect that this utility model also has anode carbon block new, old, saving heat energy, is connected firmly, the feature that conductive effect is good.
The technical solution of the utility model: a kind of Prebaked Anode In Aluminium Cell group structure, include mechanical type steel pawl base plate, the lower section of mechanical type steel pawl base plate is provided with the connecting portion of mechanical type steel pawl and carbon block, mechanical type steel pawl is connected with the lower section of the connecting portion of carbon block new anode carbon block, new anode carbon block be provided with connecting portion with mechanical type steel pawl and carbon block with the use of carbon block upper T shape be connected plush copper, carbon block upper T shape connects the both sides of plush copper and is provided with T-shaped connection plush copper load shoulder, bottom be provided be connected with carbon block upper T shape plush copper with the use of carbon block bottom T-shaped connecting groove, the bottom of carbon block bottom T-shaped connecting groove is provided with T-shaped connecting groove hook load shoulder;The lower section of described new anode carbon block connects anode carbon block of haveing been friends in the past.
Aforesaid Prebaked Anode In Aluminium Cell group structure, described mechanical type steel pawl base plate be connected above mechanical type steel pawl bridge foot, mechanical type steel pawl bridge foot be connected above anode aluminium guide-bar, anode aluminium guide-bar is provided with anode aluminium guide-bar pin hole.
Aforesaid Prebaked Anode In Aluminium Cell group structure, described mechanical type steel pawl bridge foot is connected through aluminum steel blast weldering composite plate with anode aluminium guide-bar.
Aforesaid Prebaked Anode In Aluminium Cell group structure, described mechanical type steel pawl includes, with the connecting portion of carbon block, the loose slot being located at mechanical type steel pawl base plate both sides, loose slot is provided with mechanical type steel pawl t shape fastening bolt, the bottom of mechanical type steel pawl t shape fastening bolt is provided with t shape stud base's crossbeam, t shape stud base's crossbeam is positioned at the lower section of loose slot, after the two ends of mechanical type steel pawl t shape fastening bolt pass loose slot, the section of passing held thereon is provided with mechanical type steel pawl t shape fastening bolt nut.
Aforesaid Prebaked Anode In Aluminium Cell group structure, the both sides of described mechanical type steel pawl base plate are additionally provided with the t horizontal clamping screw of shape bolt of horizontal direction, and one end of the horizontal clamping screw of t shape bolt withstands on the side of described mechanical type steel pawl t shape fastening bolt after putting in loose slot.
Aforesaid Prebaked Anode In Aluminium Cell group structure, described t shape stud base is provided with t shape stud base's crossbeam crossbeam.
Aforesaid Prebaked Anode In Aluminium Cell group structure, is provided with thermal distortion compensation pad between described mechanical type steel pawl t shape clamp nut and mechanical type steel pawl base plate.
Aforesaid Prebaked Anode In Aluminium Cell group structure, described thermal distortion compensation pad is the steel pad of arch.
Aforesaid Prebaked Anode In Aluminium Cell group structure, described T-shaped connects the thickness degree of depth less than carbon block bottom T-shaped connecting groove of plush copper load shoulder, described carbon block upper T shape connect plush copper and carbon block bottom T-shaped connecting groove with the use of time, the upper surface of T-shaped connecting groove hook load shoulder and T-shaped connect formation gap between the lower surface that plush copper load is takeed on, and are provided with fastening bolt in gap.
Aforesaid Prebaked Anode In Aluminium Cell group structure, is provided with the bonding conduction bed of material between described new anode carbon block and old anode carbon block.
The beneficial effects of the utility model: this utility model uses mechanical type anode steel claw and novel anode carbon block, mechanical type is used to be connected between mechanical type anode steel claw with new anode carbon block, new anode carbon block connects use with the old pole of band, new pole, non-residual electrode produces, the utilization rate making anode carbon block is promoted to 100% by original 70~80%, reduce the cost of electrolysis production, because not doing the best, anode is burnt thin, need only control to suitable carbon block thickness, therefore, there is not the steel pawl possibility by electrolyte etch, make the mechanical type steel pawl life-span greatly enhance casting type steel pawl.Because there is not thin anode carbon block, just without the situation that conduction is uneven, therefore, operating mode is the most stable, and electricity damages and is relatively low.Casting type steel pawl carbon block connected mode, joint face contact drop is bigger, the phosphorus pig iron molten iron temperature poured into about 1600 DEG C, after cooling, between phosphorus pig iron bowl and charcoal bowl, gap must occur, when thus steel pawl carbon block anode unit works in electrolysis bath, between steel pawl and carbon block contact surface, produce the voltage drop of about 150mv, electricity is caused to damage about at 400~500 KWhs/ton of aluminum, use the mechanical type steel pawl of the present invention, invar pawl is bigger than casting type steel pawl with the contact surface of carbon block, contact fastening, ungauged regions gap exists, contact resistance between steel pawl and carbon block is little, the electricity that can reduce the steel pawl junction with carbon block damages about half.Meanwhile, between old anode carbon block upper T shape connection plush copper load shoulder and new anode carbon block bottom T-shaped connecting groove hook load shoulder after grafting, having large hole gap, pore-size preferably 10 × 11mm(is high × wide).This utility model is by inserting pureed fastening material (stemming used in steel and iron industry) in hole, pureed fastening material quick solidification under the high temperature of old anode itself, form fastening bolt, make the connection of new anode carbon block and old anode carbon block closely, decrease the resistance of new anode carbon block group, reduce the electricity damage of carbon block group itself.In addition, this utility model is by arranging mechanical type carbon block connecting portion on the steel plate of anode steel claw, it is connected with using mechanical type between anode carbon block, thus replaces the connected mode of traditional phosphorus pig iron casting, make old anode carbon block remove and the connection procedure of new anode carbon block is more quick and convenient;Simultaneously, this utility model need not take old anode carbon block and steel pawl to composing room and is replaced when jointed anode carbon block, after can realizing connecting by potroom Inner electrolysis groove, turn back to electrolysis bath use, the heat of minimizing anode carbon block group scatters and disappears and (facts have proved, the heat of anode carbon block Renewal process Anodic carbon block group scatters and disappears and is about 20%), save heat energy.Additionally, by the t horizontal clamping screw of shape bolt arranging horizontal direction on the steel plate of mechanical type steel pawl t shape fastening bolt side, mechanical type steel pawl t shape fastening bolt is locked in loose slot, makes this utility model the most more firmness;By arranging mechanical type steel pawl t shape fastening bolt nut in the upper end of mechanical type steel pawl t shape fastening bolt, when anode carbon block connects with steel ZHUANLIAN, regulation mechanical type steel pawl t shape fastening bolt nut enables anode carbon block and mechanical type steel pawl base plate to keep being in close contact, and improves conductive effect;By arranging thermal distortion compensation pad in the lower section of mechanical type steel pawl t shape clamp nut, it is to avoid steel pawl expands after being heated and makes to form gap between new anode carbon block and mechanical type steel pawl base plate and increase resistance, further ensures conductive effect of the present utility model;By arranging mechanical type steel pawl bridge foot between steel plate and aluminum conducting rod, isolate aluminum guide, it is to avoid the anode aluminium guide-bar of low melting point directly causes work safety accident with mechanical type steel pawl contacts baseplate after-tack or thawing, improve the safety of this utility model use.In sum, this utility model has non-residual electrode and produces, and makes the utilization rate of anode carbon block by traditional 70~80%, bring up to 100%, can reduce the production cost of electrolytic aluminium, the steel pawl life-span is long, electrolysis bath stable conditions, electricity damages relatively low beneficial effect, change conveniently additionally, this utility model also has anode carbon block, saving heat energy, it is connected firmly, the beneficial effect that conductive effect is good.
Accompanying drawing explanation
Accompanying drawing 1 is structural representation of the present utility model;
Accompanying drawing 2 is the side view of accompanying drawing 1.
Description of reference numerals: 1-anode aluminium guide-bar pin hole, 2-anode aluminium guide-bar, 3-aluminum steel blast weldering composite plate, 4-mechanical type steel pawl bridge foot, 5-mechanical type steel pawl t shape fastening bolt, 6-mechanical type steel pawl t shape fastening bolt nut, 7-thermal distortion compensation pad, the horizontal clamping screw of 8-t shape bolt, 9-mechanical type steel pawl base plate, 10-carbon block and steel ZHUANLIAN junction, 11-carbon block bottom T-shaped connecting groove, 12-t shape stud base's crossbeam, 13-anode both shoulders upper surface, 14-fastening bolt, the new anode carbon block of 15-, the old anode carbon block of 16-, 17-T shape connects plush copper load shoulder, 18-T shape connecting groove hook load is takeed on, 19-carbon block upper T shape connects plush copper.
Detailed description of the invention
With embodiment, this utility model is further described below in conjunction with the accompanying drawings, but is not intended as the foundation that this utility model is limited.
Embodiment of the present utility model:
Embodiment: a kind of Prebaked Anode In Aluminium Cell group structure, as shown in accompanying drawing 1-2, include mechanical type steel pawl base plate 9, the lower section of mechanical type steel pawl base plate 9 is provided with mechanical type carbon block connecting portion, the lower section of mechanical type carbon block connecting portion connects new anode carbon block 15, new anode carbon block 15 be provided with mechanical type carbon block connecting portion with the use of carbon block upper T shape be connected plush copper 19, carbon block upper T shape connects the both sides of plush copper 19 and is provided with T-shaped connection plush copper load shoulder 17, bottom be provided be connected with carbon block upper T shape plush copper 19 with the use of carbon block bottom T-shaped connecting groove 11, the bottom of carbon block bottom T-shaped connecting groove 11 is provided with T-shaped connecting groove hook load shoulder 18;The lower section of described new anode carbon block 15 connects anode carbon block 16 of haveing been friends in the past.
Described mechanical type steel pawl base plate 9 be connected above mechanical type steel pawl bridge foot 4, mechanical type steel pawl bridge foot 4 be connected above anode aluminium guide-bar 2, anode aluminium guide-bar 2 is provided with anode aluminium guide-bar pin hole 1.
Described mechanical type steel pawl bridge foot 4 is connected through aluminum steel blast weldering composite plate 3 with anode aluminium guide-bar 2.
Described mechanical type carbon block connecting portion includes the loose slot being located at mechanical type steel pawl base plate 9 both sides, loose slot is provided with mechanical type steel pawl t shape fastening bolt 5, the bottom of mechanical type steel pawl t shape fastening bolt 5 is provided with t shape stud base's crossbeam 12, t shape stud base's crossbeam 12 is positioned at the lower section of loose slot, after the two ends of mechanical type steel pawl t shape fastening bolt 5 pass loose slot, the section of passing held thereon is provided with mechanical type steel pawl t shape fastening bolt nut 6.
The both sides of described mechanical type steel pawl base plate 9 are additionally provided with the t horizontal clamping screw of shape bolt 8 of horizontal direction, and one end of the horizontal clamping screw of t shape bolt 8 withstands on the side of described mechanical type steel pawl t shape fastening bolt 5 after putting in loose slot.
Described t shape stud base is provided with t shape stud base's crossbeam crossbeam 12.
It is provided with thermal distortion compensation pad 7 between described mechanical type steel pawl t shape fastening bolt nut 6 and mechanical type steel pawl base plate 9.
Described thermal distortion compensation pad 7 is the steel pad of arch.
Described T-shaped connects the thickness degree of depth less than carbon block bottom T-shaped connecting groove 11 of plush copper load shoulder 17, described carbon block upper T shape connect plush copper 19 and carbon block bottom T-shaped connecting groove 11 with the use of time, form gap between upper surface and the lower surface of T-shaped connection plush copper load shoulder 17 of T-shaped connecting groove hook load shoulder 18, in gap, be provided with fastening bolt 14.
The bonding conduction bed of material (the bonding conduction bed of material is made up of) it is provided with Colophonium 5-30%, graphite 70-95% between described new anode carbon block 15 and old anode carbon block 16.
Operation principle of the present utility model: first the old anode carbon block of high temperature state is mentioned from electrolysis bath;Then the old anode carbon block 16 of high temperature state is taken off from mechanical type anode steel claw and (first unscrew the t horizontal clamping screw of shape bolt 8, then mechanical type steel pawl t shape fastening bolt nut 6 is unscrewed, mechanical type steel pawl t shape fastening bolt 5 is removed to both sides, old anode can be taken off);nullThen the new anode carbon block 15 of normal-temperature is installed to mechanical type anode steel claw (first by mechanical type steel pawl t shape fastening bolt 5 to two side shiftings,Increase the spacing between both sides mechanical type steel pawl t shape fastening bolt 5,Then the carbon block upper T shape of anode carbon block 15 is connected plush copper 19 to be placed between mechanical type steel pawl t shape fastening bolt 5,Mechanical type steel pawl t shape fastening bolt 5 is promoted to make it draw close to centre,The carbon block upper T shape making t shape stud base's crossbeam 12 snap in new anode carbon block 15 connects the T-shaped connection plush copper load of plush copper 19 both sides and takes on 17 bottoms,Then mechanical type steel pawl t shape fastening bolt nut 6 is tightened,The carbon block upper T shape of new anode carbon block 15 is connected between the bottom surface that plush copper is firmly fixed to t shape stud base's crossbeam 12 and mechanical type steel pawl base plate 9,Then the t horizontal clamping screw of shape bolt 8 is tightened,Mechanical type steel pawl t shape fastening bolt 5 is fixed,New anode carbon block 15 and the connection of anode steel claw can be completed),Then the anode both shoulders upper surface 13 of the old anode carbon block 16 of the high temperature state taken off and the upper surface (i.e. carbon block and steel ZHUANLIAN junction 10) of carbon block upper T shape connection plush copper 19 are carried out polishing and remove alumina mulch and fluoride salt foreign material,Then anode both shoulders upper surface 13 and the upper surface of carbon block upper T shape connection plush copper 19 of old anode carbon block 16 it are water-cooled,It is made to be cooled to 50 DEG C-150 DEG C,Then first old anode carbon block 16 both shoulders upper surface 13 after cooling and upper T shape connect and are coated with last layer coal tar on the upper surface of plush copper 19,Cover one layer of bonding conductive material of carbon block again,Then old anode carbon block 16 upper T shape is connected plush copper 19 and new anode carbon block 15 bottom T-shaped connecting groove 11 grafting being installed on anode steel claw,After grafting,The T-shaped connecting groove hook load of new anode carbon block 15 take on 18 is connected between plush copper load shoulder 17 gap formed with the T-shaped of old anode carbon block 16 in insert pureed fastening material (stemming used by steel and iron industry),The high temperature utilizing old anode carbon block 16 self forms fastening bolt 14 after making pureed fastening material quick solidification,Both new anode carbon block group;Work in finally the new anode carbon block group obtained being turned back to electrolysis bath, i.e. realize the prd-baked Al electrolysis without anode anode scrap produces and produce.